Académique Documents
Professionnel Documents
Culture Documents
Prepared By
Michael D. Feist
Final Report
Prepared For
Southern California Gas Company
555 West Fifth Street
Los Angeles, CA 90013
August 2006
Final Report
Prepared for
Southern California Gas Company
555 West Fifth Street
Los Angeles, CA 90013
August 2006
Prepared by:
Reviewed by:
______________________________
Michael D. Feist,
Research Engineer
Department of Engine and Emissions
Research
_________________________________
Terry L. Ullman,
Assistant Director of Research
Department of Engine and Emissions
Research
Approved by:
______________________________
Daniel W. Stewart,
Director of Research
Department of Engine and Emissions Research
FOREWORD
The work covered by this final report was performed for Southern California Gas
Company (So Cal Gas) in response to SwRI Proposal 03-43390A, dated July 5, 2005. The
purpose of this project was to evaluate engine performance and emission levels of Detroit Diesel
Corporation (DDC) Series 50G MK and Series 50G TK engines when operated on natural gas
blends of varying methane number (MN).
The testing process for this project included determining the presence of engine knock, as
well as characterizing emission levels using transient emission measurement procedures
developed by the EPA for heavy-duty highway engines. The methane number of the natural gas
blends ranged from MN 65 to MN 89. When possible, both high and low Wobbe Index blends
were tested at each methane number.
This project was performed by the Department of Engine and Emissions Research in the
Engine, Vehicle, and Emissions Research Division of SwRI, under the supervision of Mr.
Christopher A. Sharp, Manager of the Diesel Technology Section. The SwRI project leader, Mr.
Michael D. Feist, Research Engineer, was supported by Mr. Kevin Hohn, Engine Operator, and
Mr. Keith Echtle, Laboratory Supervisor. The So Cal Gas point of contact for this work was Mr.
Mike Landau.
Report 11657
ii
TABLE OF CONTENTS
Page
FOREWORD ................................................................................................................................. ii
LIST OF FIGURES ...................................................................................................................... iv
LIST OF TABLES ..........................................................................................................................v
1.0 INTRODUCTION ....................................................................................................................1
2.0 TECHNICAL APPROACH ....................................................................................................2
2.1 Test Engines ...................................................................................................................... 2
2.2 Fuel ................................................................................................................................... 3
2.3 Test Procedure .................................................................................................................. 5
3.0 RESULTS .................................................................................................................................8
3.1 Knock Testing ................................................................................................................... 8
3.2 Emission and Performance Results ................................................................................... 8
4.0 SUMMARY............................................................................................................................22
No. of Pages
Appendix
A
Torque and Power Maps for DDC Series 50G TK and MK Engines........................... 2
Detailed Emission Results for a DDC Series 50G TK Engine ................................. 120
Report 11657
iii
LIST OF FIGURES
Figure
Page
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Report 11657
iv
LIST OF TABLES
Table
Page
Natural Gas Fuel Blends Tested Using a DDC Series 50G TK Engine ...........................4
2
3
Natural Gas Fuel Blends Tested Using a DDC Series 50G MK Engine ..........................5
Scope of Testing to Evaluate Low Methane Number Natural Gas Using DDC
Series 50G Engines ..........................................................................................................6
FTP Transient Composite Emission Results for a DDC Series 50G TK Engine
Using Various Natural Gas Fuel Blends ........................................................................14
FTP Transient Composite Emission Results for a DDC Series 50G MK Engine
Using Various Natural Gas Fuel Blends ........................................................................14
4
5
Report 11657
1.0
INTRODUCTION
This report summarizes engine performance and emission levels of Detroit Diesel
Corporation (DDC) Series 50G MK and TK engines run on various low methane number (MN)
natural gas blends. Engine knock was evaluated with each blend prior to performing transient
emission tests. This evaluation was performed by operating the engine at various high load
points and monitoring the electronic knock detection system of the engine as well as the torque
feedback signal from the dynamometer system.
Emissions testing adhered to the Code of Federal Regulations (CFR), Title 40, Part 89.
For each blend, one cold-start and three hot-start heavy-duty transient FTP cycles were run.
Measurements for each transient cycle included oxides of nitrogen (NOx), carbon monoxide
(CO), carbon dioxide (CO2), total hydrocarbon (HC), exhaust particulate matter (PM), methane
(CH4), and non-methane hydrocarbon (NMHC).
Fifteen natural gas blends were tested with the DDC Series 50G TK engine, while eight
fuel blends were tested with the Series 50G MK engine. Blends for both engines ranged from
MN 65 to MN 89, both high and low Wobbe Index.
REPORT 11657
1 of 22
2.0
TECHNICAL APPROACH
This section of the report contains a description of the test articles, fuel blends, and
measurement procedures used in this program to characterize performance and emission levels of
the engines.
2.1
Test Engines
The Detroit Diesel Corporation Series 50G TK engine shown in Figure 1, which was
tested during this program, was supplied by So Cal Gas. This engine required several parts and
repairs before it was operational. These included an exhaust oxygen sensor, a knock sensor, an
ignition module, an exhaust manifold, and a fuel temperature sensor. Also, the TK engine
control module (ECM) was not retaining the air fuel ratio (AFR) learn table when the engine was
shut down. This caused the incorrect AFR table to be used when the engine was restarted. SwRI
supplied an ECM that was reprogrammed with the correct program and calibration files.
A Series 50G MK engine, shown in Figures 2 through Figure 4, was loaned to SwRI for
use during this project by Detroit Diesel Corporation. This engine is designed to operate with an
oxidation catalyst, which was supplied by So Cal Gas. The unused catalyst was de-greened by
operating the MK engine at maximum power for 10 hours. At the completion of the de-greening
process, it was evident the engine was using oil. Stewart and Stevenson was contracted to
rebuild the MK engine, replacing the worn cylinder liners and pistons.
After being rebuilt, the MK engine was installed at SwRI in a durability test cell for a
125-hour break-in procedure. The engine was run through a series of steady-state points
recommended by DDC for the first two hours of operation. The oil was then changed and the
remaining 123 hours of operation was performed at maximum power. At the completion of the
break-in procedure, the MK engine was installed in a transient capable test cell for knock and
emission testing.
Typically used in bus applications, both of these inline 4-cylinder natural gas engines had
a rated maximum power output of 275 hp, and a peak torque of 890 lb-ft. Both spark ignited
engines had a displacement of 8.5 L and were turbocharged, intercooled, and electronically
controlled.
REPORT 11657
2 of 22
2.2
Fuel
The fuel for initial engine run-in and diagnostic efforts was natural gas from a
commercial pipeline. The pipeline gas was approximately 95 percent methane by volume, with
the balance being ethane, propane, nitrogen, and carbon dioxide. SwRI transported this gas to
the dynamometer test cell in a pressure vessel containing approximately 13,000 scf of gas at
3,000 psig. During the 125-hour break-in procedure for the Series 50G MK engine, pipeline
natural gas was available at the durability test cell and supplied directly to the engine.
REPORT 11657
3 of 22
Natural gas blends of varying methane number and Wobbe Index where produced by
SwRI, as specified by Southern California Gas Company. Each custom fuel was blended in a
pressure vessel containing approximately 7,000 scf of gas at 3,000 psig. The composition of the
blends were analyzed using a Hewlett Packard Micro-GC as per ASTM D1945. The fifteen
natural gas blends tested with the DDC Series 50G TK engine are listed in Table 1, while the
eight blends tested with the MK engine are listed in Table 2.
Fuel #
Methane
(%)
Ethane
(%)
Propane
(%)
Nitrogen
(%)
1177 / 1067
12-TK
74.0
16.0
5.6
4.3
1388
1155 / 1046
13-TK
76.2
14.6
4.8
4.3
66.9
1396
1160 / 1050
14-TK
76.7
14.6
4.8
3.8
68.3
1384
1145 / 1037
8-TK
78.0
13.0
4.8
4.1
68.5
1393
1151 / 1042
9-TK
78.5
13.1
4.8
3.5
70.6
1371
1126 / 1019
10-TK
79.6
11.7
4.3
4.3
70.4
1398
1145 / 1036
11-TK
80.7
11.9
4.5
2.8
72.1
1368
1117 / 1011
1-TK
81.0
10.5
4.3
4.1
72.0
1400
1139 / 1031
2-TK
82.3
10.9
4.3
2.3
74.2
1391
1125 / 1018
15-TK
83.3
10.9
3.4
2.4
75.7
1357
1096 / 991
3-TK
83.2
9.1
3.6
4.0
75.2
1400
1126 / 1018
4-TK
84.7
9.9
3.5
1.7
79.1
1347
1078 / 974
5-TK
84.6
8.8
2.5
4.0
79.9
1397
1107 / 1000
6-TK
87.6
8.8
2.4
1.1
87.6
1325
1039 / 938
7-TK
89.5
4.3
2.2
4.0
Methane
Number
Wobbe
Index
HHV/LHV
(BTU/scf)
64.3
1400
66.8
Notes:
Fuel number 7-TK is CARB specification emission test fuel.
All blends are volume based.
REPORT 11657
4 of 22
Fuel #
Methane
(%)
Ethane
(%)
Propane
(%)
Nitrogen
(%)
1173 / 1063
1-MK
74.4
16.1
5.2
4.2
1385
1143 / 1035
2-MK
78.5
13.0
4.6
3.9
69.8
1390
1143 / 1035
3-MK
79.4
13.1
4.1
3.4
72.4
1367
1116 / 1010
4-MK
81.3
10.3
4.3
4.1
73.4
1395
1131 / 1023
5-MK
83.1
10.7
3.8
2.3
79.2
1349
1079 / 975
6-MK
84.7
8.8
2.4
3.9
78.4
1403
1116 / 1008
7-MK
86.7
9.7
2.5
1.0
88.1
1332
1042 / 940
8-MK
90.0
4.3
2.1
3.6
Methane
Number
Wobbe
Index
HHV/LHV
(BTU/scf)
64.8
1399
68.9
Notes:
Fuel number 8-MK is CARB specification emission test fuel.
All blends are volume based.
The knock resistance of the fuel blends was expressed by the MN of the natural gas. The
methane number of the fuel blends was calculated using the California Air Resources Board
(ARB) mathematical method. The Wobbe Index is a measure of the interchangeability of the
fuel and was calculated by dividing the higher heating value by the relative density of the fuel.
2.3
Test Procedure
Table 3 outlines the test procedure followed for each fuel blend. Prior to testing a new
blend, the AFR table was cleared and repopulated by operating the engine over a matrix of
steady-state speed and load points. The next step was to operate the engine at wide open throttle
(WOT) over a series of steady-state speeds to look for the occurrence of engine knock, or auto
ignition. During this operation, several knock detection signals from the engine control unit
(ECU) were monitored to determine the presence of knock. In addition, the feedback torque
signal from the dynamometer torque meter was monitored for noticeable perturbations from the
mean torque value. This process was repeated while varying the engine inlet air temperature
from 65 to 90F and maintaining the inlet air dew point at approximately 58F.
REPORT 11657
5 of 22
3
4
5
Notes:
If the engine produces noticeable knock during any step, discontinue testing and move
on to the next fuel blend.
Provided the engine produced no noticeable sign of knock, transient emission tests were
performed. Emissions testing included one cold-start and three hot-start heavy-duty transient
FTP cycles for each fuel blend. Using dilute measurement techniques, the emission of total
hydrocarbons (HC), carbon monoxide (CO), oxides of nitrogen (NOx), and particulate matter
(PM) were measured for each test. The experimental setup shown schematically in Figure 5 was
used to measure full-flow dilute exhaust emissions over the transient tests. Methane (CH4) levels
were measured by analyzing proportional bag samples of the CVS-diluted exhaust using a Gas
Chromatograph (GC) FID analyzer. Non-methane hydrocarbon (NMHC) was expressed as the
difference between measured HC and CH4 levels. NMHC levels were adjusted for FID response
as appropriate.
The total hydrocarbons were measured using continuous sampling techniques with a
heated flame ionization detector (HFID). The NOx levels were measured continuously using a
chemiluminescent analyzer. The PM level for each test was determined using dilute sampling
techniques that collected particulate matter on T60A20 Pallflex filter media. Each filter was
weighed before and after sampling to establish the mass accumulated for the given emissions
test.
REPORT 11657
6 of 22
NOx
Analyzer
HC
Analyzer
Mixing
Orifice
Positive Displacement
Pump (PDP)
10 Diameters
Filter
Pack
Dilution
Air
Sample
Zone
Heat Exchanger
Exhaust
Pipe
CO, CO2
Sample Bag
Sample PM
Exhaust Aftertreatment
Gas Meter
Pump
Bag Sample
Gas Analyzer
Engine
Sample Line
Heated Line
90mm PM Filters
REPORT 11657
7 of 22
3.0 RESULTS
This section of the report summarizes knock and emission results for the project.
Summary tables of the emission results for each blend can be found in Appendix B for the TK
engine and Appendix C for the MK engine. Detailed emission results for each test can be found
in Appendix D for the TK engine and Appendix E for the MK engine.
3.1
Knock Testing
The MK engine showed no sign of knock when tested with the fuels listed in Table 2.
The TK engine showed no sign of knock with any fuel blend listed in Table 1 except for Blend
2-TK (methane number 73, high Wobbe). The knock signals from the engine showed slight
activity when the TK engine was run at maximum power with Blend 2-TK; however, the knock
signal was intermittent, and it did not cause the performance of the engine to deteriorate.
After testing Blends 1-TK through 14-TK, So Cal Gas elected to re-blend and retest MN
73, high Wobbe fuel (Blend 15-TK). The second blend of MN 73, high Wobbe fuel showed no
sign of knock.
The absence of knock behavior during this screening indicates that it is likely that these
fuels might be used without resulting in damage to the engine. However, actual test stand
durability tests or in use testing would need to be performed to verify the durability of the engine
when operated on the various fuel blends. For example, due to the laboratory water-to-air
intercooler system, varying the inlet temperature of the intake air had little affect on the intake
manifold air temperature. The intake manifold temperature remained close to the 112F set point
regardless of the set point of the intake air temperature. Also, the absolute intake air humidity
level was held constant throughout the test process. Therefore, the knock evaluation was
performed under a narrow range of engine operating conditions.
3.2
The DDC Series 50G engines are designed and calibrated to run lean. Running an air-tofuel ratio (AFR) significantly leaner than stoichiometric reduces peak combustion temperatures,
and therefore, reduces the emission of nitrogen oxides (NOx). Another method used to lower
combustion temperature is delayed or retarded ignition timing. A drawback to running lean and
with delayed ignition timing is that the power output of the engine can be compromised.
The DDC TK engine has an active AFR learning process based on feedback from a wideranging oxygen sensor. The purpose of this learning process is to compensate for varying gas
compositions and different engine operating conditions, and to continually correct the AFR of
the engine to maintain the desired lambda. Lambda is the ratio of the measured AFR over the
stoichiometric AFR. Values less than one indicate the engine is running rich, while values
greater than one indicate the engine is running lean. However, the AFR learning process is
limited, and only able to correct lambda in a lean direction by a limited amount. This is done to
prevent lean misfire which would result in poor engine operation.
REPORT 11657
8 of 22
The AFR learn table for the TK engine was generally saturated at the maximum lean
offset for each fuel blend, indicating the TK engine was not able to correct the AFR to the
desired value. Therefore, the AFR of the TK engine was driven by the composition of the
different gas blends. The MK engine AFR learn table had a mix of both positive and negative
values, none of which were at the maximum lean or rich offset values. This indicated the MK
engine was able to maintain the desired AFR for each fuel blend, based on feedback from the
oxygen sensor.
When run on low methane number and high Wobbe gas blends, the AFR of the DDC
Series 50G TK engine decreased and the engine operated with a slightly richer combustion
mixture than intended. Shown in Figure 6 is the average lambda value for the second hot-start
transient test for each fuel blend tested with the TK engine. With low Wobbe gas blends, lambda
decreased as the methane number decreased, indicating the TK engine ran richer with lower
methane number fuels. All high Wobbe gas blends showed a substantial decrease in lambda
regardless of methane number with the TK engine.
High Wobbe
1400 Wobbe
1368 Wobbe
1398 Wobbe
1371 Wobbe
1393 Wobbe
1.3
1384 Wobbe
Lambda
1.32
1396 Wobbe
1400 Wobbe
1.34
1388 Wobbe
1.36
1400 Wobbe
1357 Wobbe
1.38
1.28
1397 Wobbe
1347 Wobbe
Low Wobbe
1325 Wobbe
1.4
1.26
1.24
1.22
1.2
65
67
69
71
73
76
80
Methane Number
REPORT 11657
9 of 22
89
As shown in Figure 7, the MK engine did not show an obvious trend when lambda was
compared to the methane number or Wobbe Index of the fuel. This is another indication the MK
engine was able to maintain the desired AFR with each fuel blend. The calculated average
lambda value for the MK engine was greater then the average value for the TK engine during the
transient test. The MK engine closes the gas valve and stops fuel delivery to the engine during a
motoring event, causing the AFR of the MK combustion mixture to increase dramatically. As
seen in Figure 8, the lambda value for the TK engine remained relatively constant during positive
torque operation, as well as for negative torque operation (motoring). The MK engine, on the
other hand, saturated the lambda sensor to a value of 5.6 during motoring events, indicating the
combustion mixture was mostly air.
Shown in Figure 9 is the average lambda values for the MK engine when recalculated
using only values less then 1.8. Lambda was recalculated to insure an AFR trend was not being
overlooked using the complete lambda data set. The average MK engine lambda of 1.28
indicates the MK engine may have been operating slightly richer then the TK engine during nonmotoring events throughout the project.
As lambda decreases and the AFR of the engine is closer to stoichiometric, the power
output of the engine increases. This is due to the oxidation of more fuel, higher combustion
temperatures, and increased cylinder pressures. Figure 10 shows the actual work performed by
the TK engine during the second hot-start transient test for each gas blend as well as the
reference work for the cycle. It is evident in Figure 6 and Figure 10, that the AFR of the engine
directly affects engine performance. As lambda decreases, the power output of the engine
increases. As shown in Figure 11, the MK engine did not show a trend when cycle work or
reference work was compared with MN or Wobbe Index. The MK engine produced slightly
more power than the TK engine on all gas blends. Torque and power maps for each blend can be
found in Appendix A, while the actual and reference work for each test can be found in
Appendix B and C.
REPORT 11657
10 of 22
1.95
Low Wobbe
High Wobbe
1332 Wobbe
1403 Wobbe
1349 Wobbe
1395 Wobbe
1367 Wobbe
1385 Wobbe
1399 Wobbe
1.85
1390 Wobbe
1.9
Lambda
1.8
1.75
1.7
1.65
1.6
65
69
73
80
89
Methane Number
MK Lambda
6
800
600
400
200
Torque (lb-ft)
1000
-200
Lambda
Torque (feedback)
0
60
62
64
66
68
70
72
74
76
78
80
Time (s)
11 of 22
1.6
Low Wobbe
High Wobbe
1332 Wobbe
1403 Wobbe
1349 Wobbe
1367 Wobbe
1395 Wobbe
1.3
Lambda
1385 Wobbe
1399 Wobbe
1.4
1390 Wobbe
1.5
1.2
1.1
0.9
0.8
65
69
73
80
89
Methane Number
21.5
21.0
20.5
20.0
19.5
19.0
18.5
18.0
MN 65
MN 67
MN 69
MN 71
MN 73
MN 76
MN 80
MN 89
Methane Number
12 of 22
24.5
24.0
23.5
23.0
22.5
22.0
21.5
21.0
20.5
MN 65
MN 69
MN 73
MN 80
MN 89
Methane Number
REPORT 11657
13 of 22
Wobbe
Blend
Number
65
67
67
69
69
71
71
73
73
76
76
80
80
89
Index
High
Low
High
Low
High
Low
High
Low
High
Low
High
Low
High
Low
ID
12-TK
13-TK
14-TK
8-TK
9-TK
10-TK
11-TK
1-TK
2-TK
3-TK
4-TK
5-TK
6-TK
7-TK
BSCH4
1.04
1.16
1.16
1.27
1.18
1.39
1.26
1.59
1.19
1.88
1.41
2.08
1.50
2.70
BSNMHC
0.54
0.49
0.54
0.50
0.48
0.47
0.38
0.57
0.49
0.49
0.40
0.48
0.27
0.22
BSCO
2.09
2.02
2.09
2.00
2.11
1.99
2.09
2.05
2.28
2.00
2.10
1.96
2.09
1.86
BSNOx
4.48
3.90
4.01
3.23
3.89
2.77
4.08
2.27
4.91
1.93
3.81
1.55
3.33
1.11
BSPM
0.001
0.000
0.004
0.001
0.001
0.001
0.001
0.001
0.002
0.002
0.001
0.003
0.001
0.001
BSCO2
510
513
513
505
515
519
514
532
516
536
523
552
508
528
Wobbe
Blend
Number
65
69
69
73
73
80
80
89
Index
High
Low
High
Low
High
Low
High
Low
ID
1-MK
2-MK
3-MK
4-MK
5-MK
6-MK
7-MK
8-MK
BSCH4
1.00
1.11
1.11
1.32
1.24
1.66
1.38
2.05
BSNMHC
0.02
0.01
0.07
0.02
0.00
0.01
0.00
0.00
BSCO
0.00
0.00
0.03
0.00
0.01
0.01
0.01
0.01
BSNOx
5.15
4.39
4.25
3.83
4.31
3.31
4.57
2.73
BSPM
0.002
0.002
0.003
0.004
0.005
0.004
0.002
0.002
BSCO2
536
528
497
512
523
524
515
520
Particulate and carbon monoxide (CO) emissions with the TK and MK natural gas
engines were low, as expected. Due to the use of an oxidation catalyst with the MK engine, the
emission of CO was near zero with all fuel blends. Emission of CO and PM showed little
variation with the different gas blends for both the TK and MK engines.
With the TK engine, the emission of CO2 decreased with high Wobbe and low MN gas
blends. The MK engine, however, showed little change in CO2 with regard to Wobbe Index and
slightly increased with lower MN gas blends.
NOx emission levels for both engines were similarly affected by the compositions of the
different gas blends. Figure 12 shows the MK engine average hot-start brake-specific NOx
emission results for the various gas blends. With low Wobbe gas blends, NOx levels increased as
methane number decreased. The high Wobbe gas blends had high NOx emission regardless of
the methane number of the fuel. NOx levels are highly dependant on combustion temperature,
which is driven by the AFR and flame speed of the mixture. In comparing Figure 6, the average
REPORT 11657
14 of 22
TK engine lambda value during a hot-start test, with Figure 12, it is evident that the AFR of the
engine notably affected NOx emission from the TK engine. All high Wobbe TK gas blends
caused lambda to decrease and NOx levels to increase. Low Wobbe TK gas blends showed a
trend of decreasing lambda with decreasing methane number. A similar trend was observed with
the TK engine as NOx levels showed an increasing trend with decreasing methane number. As
shown in Figure 13, NOx levels decreased as lambda increased.
6
Low Wobbe
High Wobbe
NOx (g/hp-hr)
0
MN 65
MN 67
MN 69
MN 71
MN 73
MN 76
MN 80
MN 89
Methane Number
REPORT 11657
15 of 22
4.50
4.00
3.50
NOx (g/hp-hr)
3.00
2.50
2.00
1.50
1.00
0.50
0.00
1.29
1.3
1.31
1.32
1.33
1.34
1.35
1.36
1.37
Lambda
REPORT 11657
16 of 22
6
Low Wobbe
High Wobbe
NOx (g/hp-hr)
0
MN 65
MN 69
MN 73
MN 80
MN 89
Methane Number
REPORT 11657
17 of 22
3.0
Low Wobbe
High Wobbe
2.5
THC (g/hp-hr)
2.0
1.5
1.0
0.5
0.0
MN 65
MN 67
MN 69
MN 71
MN 73
MN 76
MN 80
MN 89
Methane Number
2.5
Low Wobbe
High Wobbe
THC (g/hp-hr)
2.0
1.5
1.0
0.5
0.0
MN 65
MN 69
MN 73
MN 80
MN 89
Methane Number
REPORT 11657
18 of 22
Another factor that may have increased combustion temperatures and aided in more
complete oxidation of the fuel was the gas composition. Low Wobbe Index fuels have increased
diluents, causing slower, cooler combustion. Low methane number fuels have increased
concentrations of ethane and propane, causing increased flame speed and subsequent combustion
temperature increases.
Shown in Figures 17 and 18 are the average hot-start non-methane hydrocarbon (NMHC)
results for the TK and MK engines. Although THC emission levels decreased as methane
number decreased, NMHC increased as methane number decreased with the TK engine.
Typically, the NMHC percentage of THC is similar to the percentage of non-methane material in
the gas blend. As the methane number of the fuel is decreased, the methane concentration is
decreased. Therefore, low methane concentration blends are expected to produce higher NMHC
emission levels.
With oxidation catalyst, the MK engine produced near zero NMHC emission. This
indicates that nearly all of the hydrocarbon emission was methane, which is a non-regulated
emission. Penetration of methane through the oxidation catalyst is expected as methane is not
easily catalytically oxidized, but the catalyst was effective at eliminating non-methane
hydrocarbon as seen in Figure 18.
0.6
Low Wobbe
High Wobbe
0.5
NMHC (g/hp-hr)
0.4
0.3
0.2
0.1
0.0
MN 65
MN 67
MN 69
MN 71
MN 73
MN 76
MN 80
MN 89
Methane Number
REPORT 11657
19 of 22
0.10
Low Wobbe
High Wobbe
NMHC (g/hp-hr)
0.08
0.06
0.04
0.02
0.00
MN 65
MN 69
MN 73
MN 80
MN 89
Methane Number
Figures 19 and 20 show the composite brake-specific emission results for each fuel blend.
The composite results were largely driven by NOx emission for both engines. All high Wobbe
gas blends produced higher NOx emission for both the TK and MK engines. With low Wobbe
blends, NOx increased as methane number decreased.
REPORT 11657
20 of 22
6
5.5
Low Wobbe
High Wobbe
NOx+NMCH (g/hp-hr)
4.5
4
3.5
3
2.5
2
1.5
1
0.5
0
MN 65
MN 67
MN 69
MN 71
MN 73
MN 76
MN 80
MN 89
Methane Number
High Wobbe
4.5
NOx+NMCH (g/hp-hr)
4
3.5
3
2.5
2
1.5
1
0.5
0
MN 65
MN 69
MN 73
MN 80
MN 89
Methane Number
21 of 22
4.0
SUMMARY
DDC Series 50G TK and Series 50G MK engine were tested for engines performance and
emission levels using natural gas blends of various methane number (MN) and Wobbe Index.
The engines showed no sign of knock with any fuel except fuel Blend 2-TK (MN 73, high
Wobbe) with the TK engine. This gas composition was re-blended as fuel Blend 15-TK and
retested with the TK engine. Blend 15-TK showed no sign of knock.
The TK and MK engines showed emission differences when run on the various gas
blends. High Wobbe gas blends produced increased NOx emission with both engines. Low
Wobbe blends showed increased NOx emission as the methane number of the fuel blend
decreased. A possible explanation for these trends include the richening of the combustion
mixture, as the TK engine was not able to maintain the desired AFR with high Wobbe and lower
MN gas blends. Other possible explanations for the increased NOx emission include effectively
advanced ignition timing from higher concentrations of ethane and propane and lower
concentrations of diluents. Each of these factors likely caused increased combustion
temperatures and NOx emission.
With the TK engine, non-methane hydrocarbon emission increased as the MN of the fuel
decreased. The emission of CO showed little variation with the different gas blends. Carbon
dioxide emission decreased with high Wobbe Index and low MN blends with the TK engine.
The MK engine showed near zero emission of NMHC and CO for all fuel blends, while
carbon dioxide emission increased slightly with low MN fuels.
SwRI appreciates the opportunity to perform this testing, and looks forward to meeting
your future emission research needs.
REPORT 11657
22 of 22
APPENDIX A
Torque and Power Maps for
DDC Series 50G TK and MK Engines
1000
12-TK
13-TK
14-TK
8-TK
9-TK
10-TK
11-TK
2-TK
15-TK
3-TK
4-TK
5-TK
6-TK
7-TK
1-TK
900
800
700
Torque (lb-ft)
600
500
400
300
200
100
0
500
700
900
1100
1300
1500
1700
1900
2100
2300
2500
Speed (rpm)
13-TK
14-TK
8-TK
9-TK
10-TK
11-TK
2-TK
15-TK
3-TK
4-TK
5-TK
6-TK
7-TK
1-TK
300
Power (hp)
250
200
150
100
50
0
500
700
900
1100
1300
1500
1700
1900
2100
2300
Speed (rpm)
2500
1200
1-MK
2-MK
3-MK
4-MK
5-MK
6-MK
7-MK
8-MK
1000
Torque (lb-ft)
800
600
400
200
0
500
700
900
1100
1300
1500
1700
1900
2100
2300
2500
Speed (rpm)
2-MK
3-MK
4-MK
5-MK
6-MK
7-MK
8-MK
300
Power (hp)
250
200
150
100
50
0
500
700
900
1100
1300
1500
1700
1900
2100
2300
Speed (rpm)
2500
APPENDIX B
Summarized Emission Results for
A DDC Series 50G TK Engine
Actual,
Ref,
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
1.98
1.52
1.59
1.51
1.48
BSCH4
1.28
1.01
1.04
1.01
0.96
BSNMHC
0.70
0.52
0.54
0.51
0.53
BSCO
2.11
2.09
2.09
2.07
2.09
BSNOx
3.43
4.65
4.48
4.86
4.89
BSPM
0.001
0.001
0.001
0.0005
0.001
BSCO2
553
503
510
508
507
hphr
20.69
21.72
21.57
21.51
21.81
hphr
21.22
21.22
21.22
21.22
21.22
1.51
0.99
0.52
2.08
4.80
0.001
506
21.68
21.22
1%
3%
2%
0.3%
3%
15%
1%
N/A
N/A
Actual,
Ref,
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
1.98
1.60
1.65
1.61
1.58
BSCH4
1.41
1.12
1.16
1.14
1.12
BSNMHC
0.58
0.48
0.49
0.47
0.46
BSCO
2.08
2.01
2.02
2.04
2.06
BSNOx
2.98
4.05
3.90
4.24
4.26
BSPM
0.001
0.0002
0.000
0.001
0.0003
BSCO2
542
509
513
506
506
hphr
20.54
21.25
21.15
21.11
21.20
hphr
21.01
21.01
21.01
21.01
21.01
1.60
1.13
0.47
2.04
4.18
0.001
507
21.19
21.01
1%
2.08
1.64
1.70
1.59
1.54
1%
1.44
1.12
1.16
1.09
1.05
2%
0.64
0.52
0.54
0.50
0.49
1%
2.11
2.09
2.09
2.08
2.00
3%
2.88
4.19
4.01
4.38
4.60
84%
0.004
0.004
0.004
0.005
0.004
0.3%
566
504
513
508
498
N/A
20.62
21.24
21.15
21.17
21.48
N/A
20.95
20.95
20.95
20.95
20.95
1.59
1.09
0.50
2.06
4.39
0.004
503
21.30
20.95
3%
3%
4%
2.4%
5%
19%
1%
N/A
N/A
Actual,
Ref,
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
2.20
1.69
1.76
1.62
1.52
BSCH4
1.52
1.23
1.27
1.15
1.16
BSNMHC
0.67
0.47
0.50
0.46
0.35
BSCO
2.06
1.98
2.00
2.01
2.02
BSNOx
2.31
3.37
3.23
3.58
3.51
BSPM
0.001
0.001
0.001
0.001
0.0004
BSCO2
544
498
505
499
496
hphr
20.47
21.18
21.08
21.42
21.18
hphr
21.05
21.05
21.05
21.05
21.05
1.61
1.18
0.43
2.00
3.49
0.001
498
21.26
21.05
5%
2.05
1.60
1.66
1.55
1.53
3%
1.46
1.13
1.18
1.13
1.13
15%
0.59
0.47
0.48
0.42
0.40
1%
2.11
2.11
2.11
2.06
2.04
3%
2.83
4.06
3.89
4.19
4.25
46%
0.001
0.001
0.001
0.0001
0.0001
0.2%
542
511
515
505
501
N/A
20.62
21.25
21.16
21.56
21.53
N/A
21.04
21.04
21.04
21.04
21.04
1.56
1.13
0.43
2.07
4.17
0.0004
506
21.45
21.04
2%
0.1%
8%
2%
2%
148%
1%
N/A
N/A
Fuel 14-TK
MN 67
High Wobbe
3-Oct
Fuel 9-TK
MN 69
High Wobbe
26-Sep
B-1
Fuel 11-TK
MN 71
High Wobbe
28-Sep
Actual,
Ref,
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
2.39
1.78
1.86
1.75
1.72
BSCH4
1.78
1.33
1.39
1.31
1.30
BSNMHC
0.61
0.45
0.47
0.44
0.42
BSCO
2.05
1.98
1.99
1.97
1.99
BSNOx
1.96
2.90
2.77
3.23
3.14
BSPM
0.001
0.001
0.001
0.002
0.002
BSCO2
558
513
519
504
504
hphr
20.05
20.94
20.81
20.85
20.81
hphr
20.59
20.59
20.59
20.59
20.59
1.75
1.31
0.44
1.98
3.09
0.001
507
20.87
20.59
2%
2.18
1.56
1.64
1.58
1.56
1%
1.64
1.20
1.26
1.22
1.21
3%
0.54
0.36
0.38
0.36
0.35
0.5%
2.24
2.07
2.09
2.11
2.11
5%
2.87
4.27
4.08
4.41
4.56
41%
0.002
0.001
0.001
0.001
0.002
1%
560
506
514
507
507
N/A
20.35
21.48
21.32
21.23
21.07
N/A
20.98
20.98
20.98
20.98
20.98
1.57
1.21
0.36
2.10
4.42
0.001
507
21.26
20.98
1%
1%
1%
1%
3%
22%
0.1%
N/A
N/A
Actual,
Ref,
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
2.75
2.06
2.15
2.02
2.01
BSCH4
2.01
1.52
1.59
1.48
1.49
BSNMHC
0.75
0.54
0.57
0.53
0.52
BSCO
2.14
2.04
2.05
2.05
2.04
BSNOx
1.64
2.37
2.27
2.48
2.48
BSPM
0.002
0.0003
0.001
0.001
0.001
BSCO2
579
525
532
525
525
hphr
19.34
20.48
20.32
20.41
20.40
hphr
20.30
20.30
20.30
20.30
20.30
2.03
1.50
0.53
2.04
2.44
0.001
525
20.43
20.30
1%
2.04
1.63
1.68
1.52
1.51
1%
1.60
1.13
1.19
1.23
1.17
2%
0.44
0.50
0.49
0.29
0.34
0.3%
2.38
2.26
2.28
2.21
2.19
2%
3.80
5.09
4.91
5.52
5.45
52%
0.001
0.002
0.002
0.001
0.002
0.04%
559
510
516
509
504
N/A
20.50
21.38
21.25
21.62
21.59
N/A
21.40
21.40
21.40
21.40
21.40
1.55
1.18
0.38
2.22
5.35
0.002
507
21.53
21.40
4%
2.18
1.77
1.83
1.71
1.72
4%
1.64
1.34
1.38
1.32
1.32
29%
0.54
0.43
0.45
0.39
0.40
2%
2.20
2.21
2.21
2.15
2.09
4%
2.78
3.72
3.59
3.84
3.75
30%
0.009
0.007
0.008
0.005
0.003
1%
554
508
514
504
503
N/A
21.11
22.03
21.90
22.15
22.11
N/A
21.32
21.32
21.32
21.32
21.32
1.73
1.33
0.41
2.15
3.77
0.005
505
22.10
21.32
2%
1%
6%
3%
2%
45%
0.5%
N/A
N/A
Actual,
Ref,
BSCO2
585
529
536
526
525
hphr
19.25
20.06
19.94
20.15
20.14
hphr
20.10
20.10
20.10
20.10
20.10
Fuel 2-TK
MN 73
High Wobbe
8-Sep
Fuel 15-TK
MN 73
High Wobbe
31-Oct
Fuel 4-TK
MN 76
High Wobbe
19-Sep
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
2.99
2.27
2.37
2.13
2.11
BSCH4
2.36
1.80
1.88
1.72
1.70
BSNMHC
0.63
0.46
0.49
0.41
0.42
BSCO
2.07
1.99
2.00
1.97
1.93
BSNOx
1.48
2.01
1.93
2.20
2.25
BSPM
0.001
0.002
0.002
0.001
0.0001
2.17
1.74
0.43
1.96
2.15
0.001
526
20.12
20.10
4%
2.27
1.74
1.81
1.64
1.66
3%
1.71
1.36
1.41
1.32
1.32
7%
0.56
0.38
0.40
0.32
0.34
2%
2.11
2.10
2.10
2.08
2.02
6%
2.74
3.98
3.81
3.95
3.86
105%
0.001
0.001
0.001
0.001
0.001
0.4%
553
518
523
513
511
N/A
20.07
21.00
20.87
21.35
21.11
N/A
20.72
20.72
20.72
20.72
20.72
1.68
1.33
0.35
2.07
3.93
0.001
514
21.15
20.72
3%
2%
8%
2%
2%
29%
1%
N/A
N/A
B-2
Actual,
Ref,
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
3.37
2.43
2.56
2.29
2.20
BSCH4
2.71
1.98
2.08
1.87
1.82
BSNMHC
0.66
0.45
0.48
0.42
0.38
BSCO
2.06
1.95
1.96
1.93
1.91
BSNOx
1.10
1.63
1.55
1.70
1.71
BSPM
0.004
0.002
0.003
0.002
0.003
BSCO2
597
545
552
534
526
hphr
18.87
19.22
19.17
19.77
20.00
hphr
19.71
19.71
19.71
19.71
19.71
2.31
1.89
0.42
1.93
1.68
0.002
535
19.66
19.71
5%
2.29
1.68
1.77
1.56
1.55
4%
1.92
1.43
1.50
1.34
1.34
9%
0.37
0.25
0.27
0.22
0.21
1%
2.09
2.08
2.09
2.00
2.03
3%
2.39
3.48
3.33
3.88
4.11
10%
0.001
0.001
0.001
0.001
0.001
2%
546
502
508
492
494
N/A
20.45
21.27
21.15
21.58
21.56
N/A
20.97
20.97
20.97
20.97
20.97
1.60
1.37
0.23
2.04
3.82
0.001
496
21.47
20.97
5%
4%
10%
2%
8%
16%
1%
N/A
N/A
Actual,
Ref,
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
4.54
2.67
2.92
2.62
2.54
BSCH4
4.49
2.42
2.70
2.42
2.32
BSNMHC
0.05
0.25
0.22
0.20
0.22
BSCO
2.18
1.81
1.86
1.79
1.77
BSNOx
0.83
1.16
1.11
1.24
1.26
BSPM
0.001
0.001
0.001
0.001
0.0004
BSCO2
599
517
528
522
519
hphr
18.20
19.45
19.27
19.34
19.56
hphr
19.56
19.56
19.56
19.56
19.56
2.61
2.39
0.22
1.79
1.22
0.001
519
19.45
19.56
3%
3%
11%
1%
4%
55%
1%
N/A
N/A
Fuel 6-TK
MN 80
High Wobbe
21-Sep
B-3
APPENDIX C
Summarized Emission Results for
A DDC Series 50G MK Engine
Actual,
Ref,
BSCO
0.03
0.00
0.00
0.00
0.00
BSNOx
5.16
5.15
5.15
5.04
4.96
BSPM
0.006
0.002
0.002
0.003
0.001
BSCO2
558
533
536
538
530
hphr
22.39
22.60
22.57
22.58
22.66
hphr
22.27
22.27
22.27
22.27
22.27
0.01
0.00
5.05
0.002
534
22.61
22.27
56%
173%
2%
63%
1%
N/A
N/A
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
1.25
0.99
1.03
0.97
1.01
BSCH4
1.13
0.98
1.00
0.96
0.99
BSNMHC
0.12
0.01
0.02
0.01
0.02
0.99
0.98
2%
2%
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
1.28
1.09
1.12
1.08
1.13
BSCH4
1.23
1.09
1.11
1.08
0.99
1.10
2%
1.29
1.16
1.18
1.21
1.16
1.18
2%
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
1.62
1.30
1.35
1.32
1.34
BSCH4
1.54
1.29
1.32
1.32
1.34
1.32
2%
1.42
1.22
1.25
1.21
1.20
Actual,
Ref,
BSNMHC
0.05
0.00
0.01
0.00
0.13
BSCO
0.03
0.00
0.00
0.04
0.04
BSNOx
4.84
4.31
4.39
4.62
4.48
BSPM
0.005
0.002
0.002
0.002
0.001
BSCO2
544
525
528
521
538
hphr
22.95
22.96
22.96
23.07
23.02
hphr
22.08
22.08
22.08
22.08
22.08
1.05
0.04
0.02
4.47
0.002
528
23.02
22.08
5%
1.23
1.09
1.11
0.83
1.16
173%
0.06
0.07
0.07
0.38
0.00
81%
0.06
0.02
0.03
0.06
0.05
3%
4.56
4.20
4.25
4.36
4.43
19%
0.004
0.002
0.003
0.003
0.002
2%
536
490
497
N/A
514
N/A
23.54
23.73
23.70
23.82
23.79
N/A
22.93
22.93
22.93
22.93
22.93
1.03
0.15
0.04
4.33
0.002
502
23.78
22.93
17%
134%
41%
3%
11%
3%
N/A
N/A
Fuel 3-MK
MN 69
High Wobbe
15-Mar
Actual,
Ref,
BSNMHC
0.07
0.02
0.02
0.00
0.00
BSCO
0.00
0.00
0.00
0.01
0.01
BSNOx
3.51
3.88
3.83
3.85
3.91
BSPM
0.009
0.003
0.004
0.003
0.004
BSCO2
546
507
512
514
515
hphr
23.02
23.44
23.38
23.38
23.54
hphr
22.81
22.81
22.81
22.81
22.81
1.32
0.01
0.01
3.88
0.003
512
23.45
22.81
2%
1.40
1.22
1.24
1.21
1.20
173%
0.02
0.00
0.00
0.00
0.00
66%
0.04
0.01
0.01
0.00
0.00
1%
4.39
4.29
4.31
4.26
4.54
8%
0.008
0.004
0.005
0.001
0.003
1%
538
520
523
523
531
N/A
22.49
22.61
22.59
22.59
22.72
N/A
22.13
22.13
22.13
22.13
22.13
1.21
1.21
0.00
0.00
4.36
0.003
525
22.64
22.13
1%
1%
N/A
140%
4%
57%
1%
N/A
N/A
Fuel 5-MK
MN 73
High Wobbe
9-Mar
C-1
Actual,
Ref,
BSNMHC
0.05
0.00
0.01
0.00
0.04
BSCO
0.01
0.01
0.01
0.01
0.00
BSNOx
3.39
3.29
3.31
3.33
3.44
BSPM
0.005
0.004
0.004
0.002
0.001
BSCO2
549
520
524
518
506
hphr
22.57
22.72
22.70
22.78
22.82
hphr
22.27
22.27
22.27
22.27
22.27
1.62
0.01
0.01
3.36
0.002
514
22.77
22.27
2%
1.44
1.37
1.38
1.35
1.41
173%
0.02
0.00
0.00
0.00
0.00
73%
0.01
0.01
0.01
0.01
0.01
2%
4.80
4.53
4.57
4.66
4.44
70%
0.005
0.002
0.002
0.003
0.006
1%
533
512
515
514
513
N/A
23.37
23.70
23.65
23.66
23.59
N/A
22.95
22.95
22.95
22.95
22.95
1.38
1.38
0.00
0.01
4.54
0.004
513
23.65
22.95
2%
2%
N/A
28%
2%
54%
0.2%
N/A
N/A
Actual,
Ref,
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
2.16
2.04
2.05
2.12
2.06
BSCH4
2.16
2.04
2.05
2.12
2.06
BSNMHC
0.00
0.00
0.00
0.00
0.00
BSCO
0.01
0.01
0.01
0.03
0.01
BSNOx
2.90
2.70
2.73
2.79
2.96
BSPM
0.000
0.003
0.002
0.003
0.003
BSCO2
547
516
520
512
517
hphr
22.18
22.47
22.43
22.42
22.57
hphr
22.14
22.14
22.14
22.14
22.14
2.07
2.07
0.00
0.02
2.82
0.003
515
22.49
22.14
2%
2%
N/A
90%
5%
5%
0.5%
N/A
N/A
Fuel 7-MK
MN 80
High Wobbe
24-Mar
Test Name
Cold Start 1
Hot Start 1
Composite
Hot Start 2
Hot Start 3
BSHC
1.79
1.64
1.66
1.62
1.63
BSCH4
1.73
1.64
1.66
1.62
1.59
1.63
1%
1.46
1.37
1.39
1.35
1.41
C-2