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INVESTIGATORY
PROJECT
TOPIC: Variance in conductivity of solution
PROJECT BY: Chinmay Shah
CLASS: XII-B
GUIDED BY: Mrs Priyanka Sinha
BOARD ROLL NO:
Chinmay Shah
CERTIFICATE
This is to certify that Chinmay Shah ,
student of class XII-B has successfully
completed the Chemistry Project under
the guidance of Mrs Priyanka Sinha.
This project is genuine and is not
plagiarism of any kind. The references
used in making this project file are
declared at the end of the file.
Externals Sign:
Internals
Sign
______________
_____________
Principals signature
School stamp
Chinmay Shah
ACKNOWLEDGEMENT
I wish to express my deep gratitude and sincere thanks
to the Principal, Mrs Murial Fernandez, Ryan
International School, Sanpada for her encouragement
and for all the facilities she has provided for this project
work.
I extend my hearty thanks to my subject teacher Mrs
Priyanka Sinha and Lab Assistant Devesh Sir who
guided me to the successful completion of this project.
I take this opportunity to express my deep sense of
gratitude for their invaluable guidance, constant
encouragement and immense motivation which has
sustained my efforts at all stages of this project work. I
cant forget to offer my sincere thanks to my
classmates who helped me to carry out this project
work successfully and for their valuable advice and
support which I received for them time to time.
Chinmay Shah
INDEX
Sr No.
Contents
Page No.
Introduction
Apparatus Required
Theory
Procedure
10
Physical Constants
13
14
Result
20
Conclusion
21
10
Precautions
22
11
Bibliography
23
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AIM
Chinmay Shah
INTRODUCTION
Conductivity is the ability of a solution to pass an
electric current.
This depends on a number of factors including
concentration, mobility of the ions, valence of the
ions and temperature. As the temperature of a
solution increases, the mobility of the ions in the
solution also increases and consequently this will
lead to an increase in its conductivity.
Pure water does not conduct electricity, but any
solvated ionic species would contribute to conduction
of electricity. An ionically conducting solution is
called an electrolyte solution and the compound,
which produces the ions as it dissolves, is called an
electrolyte.
The conductivity of an electrolyte solution depends
on concentration of the ionic species and behaves
differently for strong and weak electrolytes. The
conductivity also changes with change in
temperature due to difference in viscosity of liquid.
In this work the electric conductivity of water
containing various electrolytes will be studied with
varying temperature and concentration.
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Chinmay Shah
APPARATUS REQUIRED
1) Glass beakers;
2) CuSO4 solution;
3) ZnSO4 solution;
4) Rheostat;
5) Bunsen Burner;
6) Ammeter;
7) Voltmeter;
8) Thermometer;
9) Measuring Flask;
10) Electrodes;
11) Tripod Stand;
12) Wire Gauze;
13) Weighing Scale;
14) Spatulas and Stirrers;
Chinmay Shah
THEORY
Movement of ions in water can be studied by
installing a pair of electrodes into the liquid and by
introducing a potential difference between the
electrodes. Like metallic conducting materials,
electrolyte solutions follow Ohms law:
R = V/I
where R is the resistance (,ohms), V is the
potential
difference (V,Volts) ,and I is the current
(A,Amperes).
1
Conductance G (S, Siemens or ) is then defined
as reciprocal of the resistance:
G = 1/R
Conductance of a given liquid sample decreases
when the distance between the electrodes increases
and increases when the effective area of the
electrodes increases. This is shown in the following
relation:
G=
where is the conductivity (S m1 ), A is the crosssectional area of the electrodes (m2 ; i.e., the effective
area available for conducting electrons through the
liquid), and l is the distance between the electrodes
(m).
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2
1
Molar conductivity m (S m mol ) is defined as:
m = / c
where c is the molar concentration of the added
electrolyte.
The factors which affect the electrical conductivity of
the solutions are:
1. The nature of the electrolyte added;
2. Size of the ions produced and dissolution;
3. The nature of the solvent and its viscosity;
4. Concentration of the electrolyte;
5. Temperature (it increases with the increase of
temperature);
The variation is different for strong and weak
electrolytes.
For Strong Electrolytes, It is given according to the
equation:
Chinmay Shah
PROCEDURE
The electrolyte chosen is CuSO4
1.5g of CuSO4 is measured and put in a solution
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Chinmay Shah
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PHYSICAL CONSTANTS
For the purpose of accuracy and convenience, some
important aspects of the electrolyte process are kept
constant in the experiment as their variation might
affect the conductivity of the electrolyte. They are:
VOLTAGE;
NATURE OF ELECTRODES;
SIZE OF ELECTRODES;
SEPARATION BETWEEN ELECTRODES;
VOLUME OF THE ELECTROLYTES [150 mL];
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Chinmay Shah
OBSERVATION
For CuSO4 electrolyte:
Concentration Temperature
Ammeter
reading[I]
Voltmeter
reading [V]
Resistance
R=V / I
Conductance
G=1 / R
(M)
(mA)
(V)
()
(S)
(C)
0.0626
0.125
0.292
33
17.56
2.35
134.603
0.0074
35
17.62
2.35
133.333
0.0075
50
17.74
2.15
121.168
0.0083
33
33.032
2.1
69.369
0.0144
35
33.250
2.005
66.6665
0.0150
43
38.353
1.565
57.530
0.0173
50
23.748
2.13
50.584
0.0197
35
17.465
2.023
35.333
0.0283
40
7.9193
1.406
17.754
0.0458
50
9.2486
1.523
16.467
0.0607
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0.07
0.06
0.05
Conductance
0.0626 M
0.04
0.125 M
0.03
0.292 M
0.02
0.01
35.0 36.0 37.0 38.0 39.0 40.0 41.0 42.0 43.0 44.0 45.0 46.0 47.0 48.0 49.0 50.0
Temperature
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Chinmay Shah
0.03
T= 35C
Conductance (S)
0.0225
0.015
0.0075
0
0.0626
0.125
Concenteration (M)
16
0.292
Chinmay Shah
Temperature
Ammeter
reading[I]
Voltmeter
reading [V]
Resistance
R=V / I
Conductance
G=1 / R
(M)
(C)
(mA)
(V)
()
(S)
0.206
0.289
0.366
35
50.9925
3.21
6.295
0.1588
40
50.629
3.16
6.241
0.1602
50
46.098
2.85
6.182
0.1617
35
44.194
2.72
6.154
0.1624
40
42.711
2.6
6.146
0.1626
50
42.657
2.6
6.118
0.1634
35
43.366
2.66
6.133
0.1630
40
41.958
2.57
6.125
0.1632
50
42.865
2.62
6.112
0.1636
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0.164
0.163
0.162
Conductance
0.161
0.206 M
0.289 M
0.16
0.366 M
0.159
0.158
0.157
0.156
35.0 36.0 37.0 38.0 39.0 40.0 41.0 42.0 43.0 44.0 45.0 46.0 47.0 48.0 49.0 50.0
Temperature
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0.1635
T= 35C
Conductance (S)
0.162
0.1605
0.159
0.1575
0.156
0.206
Concenteration (M)
19
0.289
0.366
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RESULT
20
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CONCLUSION
On heating a solution, it is known that viscosity
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PRECAUTIONS
Chinmay Shah
BIBLIOGRAPHY
BOOKS:
Chemistry (Part I) Textbook for Class XII; National
Council of Educational Research and Training
Concepts of Physics 2 by H C Verma; Bharti
Bhawan(Publishers & Distributors)
WEB LINKS:
www.icbse.com
http://www.jenway.com/adminimages/A02_001A_Effect_of
_temperature_on_conductivity.pdf
http://www.researchgate.net/
http://www.emedicalprep.com/studymaterial/chemistry/electro-chemistry/electrolyticconductance-factors.html
en.wikipedia.org
http://chem-guide.blogspot.in/2010/04/variation-ofconductivity-with.html
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