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WATER
K.GOPALAKRISHNA
ENVIRONMENTAL ENGINEERING DIVISION
DEPARTMENT OF CIVIL ENGINEERING
IIT. MADRAS
FEBRUARY 2009
K.GOPALAKRISHNA
T.S.S.
Colloidal
D.S.
(60%)
(30%)
(8%)
Floating (E.S.S.)
(2%)
Inorganic solids with a diameter less than 0.002 mm and Sp Gr more than 1.
Filter through What man filter 10
Dry filter paper
Difference in weight
Fixed Solids
Balance Solids
represents Minerals like Ca++, Mg++, Fe++
Quantification
Domestic q specific waste water production in lpcd.
This is about 60% to 90% of water supplied
QD = N.q x 10-3 m3 /d.
Industrial wastes Depends upon Industry and number of working hours.
It may be noted that only permitted industries which form the infrastructure of the
municipal sector are allowed to form the municipal waste waters.
These include
laundries, motor garages, small scale sector units etc. They are expected to pretreat the
waste water to the required norms before being let off to the municipal sewers.
Storm Flow
mm rain
Intensity in l/s/ha
Intensity l/s/ha
Runoff Coefficient
A Cumulative area to be drained in hectares
e Return Storm water (te - 15 mins)
QSW = (A . .e x 10-3) m3 / day
Peak Flow
Maximum daily flow 1.8 to 2 average daily flow
Maximum hourly flow (average daily flow in m3/ day / Y) m3/ hr
Y 10 to 18
Design Flow
Design Flow (in m3/ hr): Daily flow (m3/ day) + Daily flow (m3/ day) + Infiltration
(m3/day)
Y = 10 to 18
working hours
24
Characteristics of Sewage
Waste water contains more than 99 percent water coming as return water and less
than 1 percent solids which are added in the form of either organic or inorganic solids.
99.8% Water
0.2 % Solids (both organic and inorganic)
Material
Diameter (mm)
Coarse Gravel
>2
Fine Gravel
21
Coarse Sand
1 0.5
Medium Sand
0.5 0.25
Fine Sand
0.25 0.1
0.1 0.05
Silt
0.05 0.01
Fine Silt
0.01 0.005
Clay
0.01 0.001
Fine Clay
0.001 0.0001
Colloidal Clay
< 0.0001
PHYSICAL CHARECTERISTICS
The significant physical characteristics of waste water is its total solid content
which is composed of floating, settleable, colloidal and dissolved contents. Other
parameters include particle size distribution, turbidity, color, temperature, conductivity,
density, specific gravity and specific weight.
Solids : Waste water contains a variety of solid materials varying from coarse to
colloidal. Coarse materials are usually removed before the sample is analyzed for
solids. The various solid classification is identified in the following table.
TEST
DESCRIPTION
Total Volatile Dissolved Solids (TVDS) Solids Volatized when TDS is ignited at
500 C
Fixed Dissolved Solids (FDS)
The standard test for settleable solids consist of placing a waste water
sample on a one liter Imhoff Cone and noting volume of settled solids after one
hour. Typically about 60% of suspended solids in a municipal waste water is
settleable.
in Vapor state, they are much more mobile and therefore more likely to be
released to the atmosphere
(2) the presence of some of these compounds in the atmosphere may pose a
significant health risk (3) they contribute to the general increase in the
reactive hydrocarbons in the atmosphere, which can lead to the formation of
photochemical oxidants. The release of these compounds in sewers and
treatment plants especially at head works is of concern with respect of health
of personnel involved.
DISINFECTION BYPRODUCTS : It has been found that when chlorine is
added to waste water, variety of organic compounds containing chlorine are
formed. Collectively these compounds are known as disinfection byproducts
(DBP). Although present in low concentrations, they are of concern because of
suspected carcinogenicity. Typical classes of these compounds include
trihalomethane (THM), halo acetic acid (HAA), trichlorophenol and aldehydes.
Because of the concerns, considerable attention has been focused over the past
few years on the use of ultra violet (UV) disinfection as a replacement to
chlorination. In addition considerable attention has been focused on the
modifications to the conventional treatment processes to improve the treatment of
these compounds and to advanced processes for the removal of these.
PESTICIDES AND AGRICULTURAL CHEMICALS : Pesticides,
herbicides and other agricultural chemicals are toxic to many organisms and
therefore can be significant contaminants to surface of waters. These chemicals
are not common constituents of domestic waste water, but result primarily from
surface run off from agricultural, vacant and park lands. Concentration of these
may retard the treatment process, result in fish kills or may result in toxic food
chain to humans.
BIOLOGICAL CHARECTERISTICS : The biological characteristics of
waste water are of fundamental importance in the control of diseases caused by
pathogenic organisms of human origin, and because of their fundamental role
played in the stabilization and decomposition of organic matter. The se include
bacteria, fungi, algae, protozoa and viruses.
Bacteria are single celled prokaryotic organisms. The interior of the cell
contains a colloidal suspension of proteins, carbohydrates etc called cytoplasm.
This contains ribonucleic acid (RNA) which plays a major role in synthesis of
proteins. It also contains deoxyribonucleic acid (DNA) which contains all the
necessary information for reproduction.
Protozoa are motile microscopic eukaryotes that are usually single celled.
The majority of protozoa are aerobic heterotrophes and often consume bacteria as
an energy source.
10
11
Living Organisms
Macro Worms
Micro Bacteria, Virus, Protozoa, Algae and Fungus
Dissolved Oxygen
Fresh Water will have DO depending upon water temperature and ambient
pressure
At 10 C and 1 atm 11.3 mg/l
At 30 C and 1 atm 7.8 mg/l
(atm atmosphere)
DO is determined by Winklers modification method or probes.
Winklers Azide modification Method ( D.O)
Mn
+ 2OH + O
12
200 x300
203 ml
300 4
Kinetics of BOD
(Biochemical Oxygen Demand)
It is assumed that for major portion it occupies a first order curve
The rate of Biochemical oxidation of organic matter is directly proportional to
remaining concentration of unoxidized matter.
dL / dt = -KL
Or dL / L = -Kdt
Integrating:
Log e Lt = -Kt + C
at t = 0, Lt =L and C = Log eL
Log e Lt - Log eL = - Kt
Log e Lt / L = -Kt
Log10 Lt / L = - 0.434 Kt = -K1t
Lt / L = 10-K1
Xt = L (1- Lt /L)
t
= L (1- 10-K1 )
t
L = Xt / (1- 10-K1 )
K1 (T) = K1 20 (1.047) T-20
t could be 3 or 5 days; referred as BOD327 or BOD520
13
C. O. D
(Chemical Oxygen Demand)
Organic matter + Cr2 O72- + H+
2 Cr 3+ + CO2 + H2O
BOD / COD
BOD / COD
54 gm / cap / day
Nitrogen
The nitrogen in waste water could be present as organic nitrogen, nitrite or nitrate
nitrogen.
Total organic Nitrogen 20% of BOD ( For Indian municipal waste waters)
Chlorides
Measured using Sox let apparatus indicates grease, oils & fats
Normal Sewage 100 to 150 mg / l
Excess leads to incrustation of pipes
Should be reduced to 10 mg / l before B.T
14
pH value
I. Primary Treatment
a)
Screens
Coarse screens
Fine screens
b)
Grit chamber
c)
Skimming tank
d)
Biological Treatment
b)
15
Nitrogen removal
Ammonia stripping
Denitrification
b)
Phosphate removal
c)
Chlorides removal by RO
d)
e)
Sand filters
f)
Disinfection
a)
Sludge thickness
b)
Sludge Digesters
c)
d)
Bag filters
e)
Vacuum filters
f)
Incineration
Biological Treatments
Aerobic
a)
b)
c)
Aerated Lagoons
d)
e)
f)
Stabilization ponds
g)
Anaerobic
a)
b)
16
c)
Anaerobic Lagoons
d)
Septic tanks
e)
Imhoff tanks
In the aerobic system the organic matter is bio oxidized in the presence of dissolved
oxygen. In the anaerobic system the organic matter is bio reduced in the absence of
dissolved oxygen. The amount energy evolved in an aerobic oxidation for microbial
sustain is 16 to 20 times the amount of energy evolved in an anaerobic reduction. Hence
aerobic degradation is 16 to 20 times faster than an anaerobic degradation making aerobic
treatment more compact.
Grease
Bye pass
Pumps
Screens
pass
Grit cum
Grease
Chamber
PST
Balancing tank
Screenings
BT
FST
Grit
Tertiary
Sludge
Thickness
Land
Disposal
Sludge
Drying beds
Gas
Incineration
Sludge
Digester
17
Theory of Settling
A particle in a still fluid of lesser density will move to settle. It will accelerate
initially until the frictional resistance of the fluid equals the impelling force and
there on it reaches a constant settling velocity (HSV).
Discrete Settling
No change in shape or size of particle and HSV remains constant. Depth is no
criteria for efficiency. It is applicable for plain sedimentation.
Hindered Settling
Shape and size increases with settling. There is acceleration with depth. It is
applicable for flocculent settling.
Frictional Resistance or Drag
FD = CD*A**(2/2). (Kg.m/Sec2)
Where,
CD = Coefficient of drag. (Relative to viscosity)
A = Projected surface area (d2/4)
= HSV m/sec
= Mass density of fluid
Impelling Force,
Fi = (1-)*g*V
Where,
1 = Mass density of particle
= Mass density of fluid
V = Volume of particle = (*d3/6)
At steady state condition,
Fi = Fd
4 * g * (1 ) * d
..eqn1
3 * CD *
Re =
*d
CD =
24*
*d
24
Re
Substituting in equation 1
=
1 g 1
d 2
18
As per Stokes law this is valid for Laminar (Re = 1) or nearly laminar flow.
Free Board
L
Outlet
Inlet
V1
Sludge Zone
Let L and B be the effective length and breadth and H be HMD of tank.
Design Flow (Q) = BHV1
Where, V1 = Average flow through velocity
V1/ = L/H
or
V1= L*/H
19
Re = (V1*R / )
Stability Conditions
Fr = V12/ (g*R) > 10-5
g = 9.81 m/sec2
2)
L < 2H
45
30
15
10
Cum% with
with velocity<= (p)
100
55
25
10
20
10
0
80
40
20
1-r
Ci Ce
Ci
Re for Laminar
Transient
Grit Chamber
Aerated Grit Chamber
PST
SST
DT
3 to 5 minutes
6 minutes
2.5 hrs
3.5hrs
36m/h
25m/h
1.5m/h
0.6m/h
Re<= 1
Re= 1-2000
1
2650
2650
1650
1350
21
PST
S2*
QD
FST
Se
QD
QR
Activities
1. Agitation leads to better contact between M.O. and colloidal BOD
2. Agitation sets M.O. in virulent action
3. Agitation leads to adsorption forming bioflocs
4. Agitation of DO in MLSS
Design features
1. Sludge loading or F/M ratio
2. Volume of reactor
3. Excess sludge produced
4. Recirculation
5. Aeration required
6. Design of aerators
22
(Cells)
3. Nitrification
NH3 + O2
NO2- (Nitrosomonas)
NO2- + O2
NO3- (Nirtobacter)
I.
volume in m3
MLSS in kg / m3
LS = L / MV
3
0.5
0.3
0.05
High rate
(Partial treatment)
Conventional
Extended
aeration
23
Methods of aeration
Completely Mixed Flow (using mechanical aeration)
Plug Flow (using compressed air aeration)
CMF
1. Mechanical aeration by rotors
2. Instant dispersion, Less concentration of reactants, longer aeration period
required
3. Larger Tank volume
4. Less efficiency (actual DT 0.7 Theoretical DT)
5. Better agitation, hence suited for industrial wastes.
PF
1. Compressed air aeration
2. Flow is laminar, better efficiency, hence lesser tank volume (actual DT =
Theoretical DT)
3. No mixing, hence suited for uniform (municipal wastes)
24
OC ( Oxygenation Capacity)
OR ( Oxygenation Rate )
Oxygenation rate of a given system is defined as the rate of increase of oxygen
concentration under design Temp and pressure in kg / hour
OC = K2 Cs*
OR = KT (CST CL)
K2
KT
CL
Design details:
Data: QD , QH , Min working temperature (Design)Si , Se ,M, Ls and SVI
L = Si* QD X 10-3 (Kgs/day)
Se = 20mg/l
E=
Si * Se
X 100
Si *
25
L
(kgs)
Ls
VAT -
Ws
L
(m3) or
(m3)
Ls M
M
V AT
QD
Recirculation:
QD
AT
Se
FST
QR
Ps
1000 Pv (ml / l )
(mg / l )
Xa
SVI =
Xa
1000
= MR (gm/l) =
Pv
SVI
M MLSS concentration in AT in gms/l or Kg.m3Ps
MR - MLSS concentration in return sludge
MR =
1000
SVI
R%=
QR
X 100
QD
QR (MR-M) = QM
QR
M
=
Q
MR M
R% = 100 X
M
100.M .SVI 10 3
100M
=
=
1000
MR M
1 M .SVI 10 3
M
SVI
Aeration Requirements:
Krs O2 uptake rate for substrate respiration. (Kg O2 / Kg BOD)
Kre O2 uptake for endogenous respiration. ( Kg O2/Kg MLSS day)
Krn - O2 uptake for Nitrification. ( Kg O2/Kg day) ( All are temp. dependent)
O2 consumption / day Rod
Rod = Krs
E
L + Kre Ws + Krn L NOx
100
Roh =
1
1
1
(---,,---) +
(--- ,, ---) + (---,,---)
24
24
15
OC = K2 Cs*
OR = KT ( CST CL )
K 2CS *
OC
= K (C C )
T
ST
L
OR
K2
=
KT
D10
DT
CS *
D10
OC = OR
DT (C ST C L )
OR =
Roh
27
OC (Kgs/hr) =
HP =
Roh
CS *
D10
DT (C ST C L )
Roh
(hp) empirical
1 .2
E
Ps (Excess sludge) Kg MLSS/day = [1.2 Ls0.23 100 L] Kgs/ day
[1.2 takes care of the unit per day]
Ws
Sludge age or Mean cell residence time = P
s
days
PST
FST
28
Operational problems:
(iii) Foaming:
Foams occur in the aeration tank due to excess grease (>10 mg/l). The foam may
create in aerosols and carried for long distances with pathogens. On short term this could
be controlled by spraying defoamers ( like Alkyl benzynesulphonate) and by proper
grease removal.
Monitoring of ASP:
1. BOD
2. MLSS
3. SVI
29
Advantages:
Maintenance is easier and cheaper. But first cost is very high and requires more
land space. There may also be problems of psychoda flies in a conventional TF. A
conventional TF with no recirculation works on a low F/M ratio.
PST
TF
FST
Designs:
30
Vitrified clay rings of 10 cms have also been used. Hydraulic head need for
distribution is 0.6 m above TF surface. These may have occasional psychoda flushing.
Ponding is due to clogging of the filters. Ponding leads to anaerobic conditions in the
filters, odour problems and reduction in efficiencies. If the influent BOD (pre settled)
exceeds 400 mg/l, it may lead to clogging needing dilution by recirculation.
QP
Q+ Qr = Qp
Si*
Si
Ps
( SL
QP
0.7m / h)
ATF
L
VTF
KgBOD
m3d
c. Recirculation ratio
R% =
QR
100
Q
31
I Design of HRTF
S i * S e
100
Si *
E reqd =
E=
100
1 a Ly
(100 E 1)
or LV =
Si (mg/L)
- check
4 KgBOD
m 2 day
Operation problems:
i. Bulking spray chlorine in return flow, control shock loads.
ii. Psychoda flies check recirculation and anaerobic condition due
to clogging.
iii. Maintenance of arms and nozzles.
iv. Cleaning media once in six months and replacement of media once
in five years.
The TF works similar to extended aeration system with sludge age as 30 to 45 days.
32
Types of ponds:
i. Fully aerobic (shallow ponds) meant for algal cultivation 30 cm.
ii. Facultative depth 1.2 m to 1.5 m with 30 cm to 40 cm anaerobic.
waste stabilization.
iii. Maturation ponds depth 1m used as polishing pond.
lato
Influent
Waste water
min
50
26
07
40
66
24
30
126
70
20
182
120
10
225
162
Inorganic
+ organic
Bacteria
Aerobic
Algae
Anaerobic
33
Algae C106H180O45N16P1
(Euglema, spirogyra and blue green algae)
By dry weight 52.5% C, 9.2% N, 1.3% P.
So the waste should have this minimum CNP.
106 CO2 + 90 H2O + 16 NO3 + PO4
C106H180O45N16P +154O2
Designs:
Si INF BOD gm/m3
Se - eff BOD gm/m3 [60 mg/L]
BOD (ult) removed (Si Se) gm/m3
(Si Se) QD gm/day.
O2 required
34
( E )cals / day
Area of pond required =
hectares.
8
0.06 [x] 10
1.75 m3
Volume of pond =
0.06 [x]
DT (Days) =
Volume of pond
QD
1m
F.B - 0.25 m
1.75 m
Slope
Grass
Turfin
g
1 : 2.5
1 : 1.5
Puddle Clay Bed (70 cm)
Sand Cushion (30 cm)
35
1m
0.25 m
1.75 m
Grass
Turfing
36
Algal harvest:
1. Rice husk filters.
2. Coagulation
3. Centrifugation
4. Coagulation using natural coagulants likes nirmali, red sorella seeds.
Maturation ponds
Polishing ponds with one meter depth where water hyacinth (eichornea crassipes)
is cultivated. This is a water weed with 95% water by volume. Hence it may lead to loss
of water. Under favourable conditions, each hectare of hyacinth can remove 30 to 40 Kgs
of nitrogen and potassium, 10 to15 Kgs of phosphorous, and 3 to 4 Kgs of magnesium
from effluents. In Indian conditions 250 to 400 tons (dry weight) per hectare of hyacinth
could be cultivated. Hyacinth could be harvested (mechanically or labor intensive
means), comminuted (chopped or crushed) and bio digested with nitrogen supplement for
60 to 80% CH4 which has a calorific value of 5300 Kcals/m3 and this could be upgraded
to 7900 Kcals/m3 by lime scrubbing.
One hectare under ideal conditions can yield 900 1800 Kg/day which can be a calorific
equivalent to 400 to 500 liters of petrol. The sludge is a good fertilizer.
37
1. Irrigational use
2. Infiltration to ground water
3. Storing in basins for long term evaporation
38
Disadvantages:
1. Health hazard both direct (farmers) and indirect (food chain).
2. If waste water does not match with soil condition, may result in
damage to soil ( N2 robbing due to excess carbon, soil build up).
3. Heavy metal etc are phyto- toxic.
4. Excessive land requirements.
5. Odour and fly problem.
6. The water demand may be seasonal.
L leachate
39
Cs = 5Ci
Ec permissible
mhos / cm
1800
1200
800
400
Sodium content:
This affects soil by cation exchange (with Ca++ and Mg++) resulting in
break down of soil. The water become less porous and will have less
water holding capacity (field capacity) and aeration (soil sickness).
Hence lime is added when excess of Na+ (salt) content.
% Na+ = 100 (Na+ ) / Na+ + Ca++ + Mg++ + K+
40
Very good
Good
Medium
unsuitable
RSC
Condition
< 1.25
1.25-2.5
> 2.5
Safe
Marginal
unsuitable
SAR (meq./l)
0-10
10-18
18-26
> 26
(all in meq.)
Hazard to soil
Low
Medium
High
Very high
41
Anaerobic Lagoons
Anaerobic lagoons generally provided prior to aerobic unit in case
of high BOD loadings. They help reducing BOD by 40 60%. Anaerobic
activity also helps in nurturing the nature of solids by liquid fraction.
Disadvantages:
Odour, high start-up period, highly sensitive to inhibitors like
heavy metals. A buffer zone of 1000 m is recommended for habitation.
Stages:
1. liquefaction and acid formation by acedogens.
Acetic, butyric, propionic and volaric acids.
2. Methane formation by methanogens.
These are obligate anaerobes. Any trace of pH is inhibitive. Highly
sensitive for temp. they are thermophillic bacteria and no methane takes
place below 150 C.
Ks at T 0C = 0.002 (1.035) T-20
Ks - system rate coefficient
Methanogens are highly sensitive to pH.
Below pH 7.5 no methane formation occurs.
(Ks (per day) at 30 0C = 0.145 / day)
DT =(loge (Si /Se)) / Ks
Ex.
Si 1000 mg / l, Se 500 mg / l,
(50% removal)
42
Pond temp 0C
DT (days)
( BOD)
15 - 20 0C
5 days
30%
20 25 0C
3 4 days
40 50%
25 35 0C
3 days
50 60%
Example:
Data:
Population = 5000
Q = 120 lpcd
Design temp. = 25 0C
BODinf = 1200 mg / l
Facultative pond loading 150 kg / hec / day
Ks = 0.145
Estimate land saving by having an anaerobic lagoon prior to facultative
pond. The anaerobic lagoon is designed for 50% - 40%
43
Case 1:
BODinf = 1200 mg / l
BODeff = 600 mg / l
DT = (loge (1200/500)) / 0.145
=5 days
Volume of lagoon = 5000 x 120 x 10-3 x 5
= 3000 m2
Depth = 3m
Area = 1000 m2 = 0.1 hectares
Area of stabilization pond alone = ( 5000 x 120 x 10-3 x 1200 x 10-3) /
150
= 4.8 hectares
Stab. pond + anae. lagoon = ( 5000 x 120 x 10-3 x 1200 x 10-3 x 0.5) / 150
= 2.4 hectares
Total = 2.4 + 0.1 + 2.5 hectares
Land savings = 48%
Xxx
44
Aerated Lagoons
Mechanically aerated lagoons are earthen basins 2.5 to 3 m deep, provided with
surface aerators installed on floats (Poly urathene foam). Raw sewage is fed
directly after screening. The D.T. could be 1 to 10 days, and hence smaller tanks
are needed.
There are essentially three types.
1.
2.
3.
Facultative type
Aerobic flow through type
Extended aeration type
1.Facultative type
These are akin to the algal ponds except that oxygen is now derived from
mechanical aeration instead of algal photosynthesis.
FB
Baffle
Inf
Eff
Aerobic
Anaerobic
The power input would be sufficient for diffusing enough oxygen into the liquid,
but not sufficient for maintaining solids in suspension. These settle in the pond
and undergo anaerobic digestion.
Inf
Baffle
Eff
Aerobic
45
Here the power input is high enough to keep all the solids in suspension as in an
activated sludge process, but no attempts are made to hold back the solids and
they flow through the effluent. Efficiency is not very high unless attempts are
made to hold back solids in SST.
Similar to above but solids are retained and a part of solids in recirculated.
Solids build up
Power
Sludge
DT
Depth
Nitrification
Misc
Fac
30-150 mg/l
Low
Accumulates
in
pond
4-10 days
3-5 m
75-85%
-NoSimple to operate
More land
Eff / good quality
Suitable for Sewage
farming
Flow through
30 to 300
More
Solids in effluent
Ext aeration
4000 5000
More
Stabilized
sludge
with drawn
2-6 days
1-2 days
3-5 m
3-5 m
70-80%
95-98%
-NoGood
Simple to operate More
trained
More power bills
personnel
needed
Eff / suitable for More power bill
specific
purpose Least land suitable
only
for Ind & municipal
waste
46
=
=
>
=
70,000
300 mg/l
70 mg/l
12,400 m3/d
10oC
106 / 100 ml
0.6 per. day
DT
Lagoon volume
8 days
12,400 x 8
99,200 m3
62
400
Depth 4m
Dispersion No
D
30.8 W
_D_
UL
_Dt_
L2
0.3
KLt
From Chart
0.6 (1.035)10-20 =
0.42 / day
0.42 / day x 8 =
0.23
3.36
47
BOD
So
=
77%
=
=
0.23 x 300
69 mg/l
Power required
4010 Kg / day
334 Kg / hr
_______334________
0.75 (2 Kg O2/KWH)
220 KW
=
165 HP
In summer power required will be more due to more BOD removal. This has to
be calculated winter criteria is important for Lagoon size. Summer criteria is
important for power calculations.
Sludge accumulation:
Cleaning Period
Sludge Vol
5 years
0.05 m3 / cap / yr x 5 x 70,000
17,500 m3
400 x 62
Land required
Net area
24,800 m2
31,000 =
70,000
2
2
(Stab. pond 3.7 m / cap. (ASP 0.2 m / cap)
0.478 m2/cap
Coliform removal
Kb
=
1.2 at 20oC
or
0.21 at 10oC
Kbt
=
0.21 x 8
=
1.68
from chart
Removal =
70%
Hence for MPN (103) chlorination is required.
48
Q, So
Solids X mg/l
Vol - V
c = t = V
Q, S, X
Q
At steady state:
Y (So-S) Q - Kd (XV)
Net solids produced
Y
Kd
Yield coefficient
BOD degradation rate (Per day)
X=
Y (So-S)
1 + Kdt
S=
1 + Kdt
YKt
= XQ (Kg/hr)
Solids leaving
Data
Population
Si
Se
>
70,000
300 mg/l
70 mg/l
QD
12,400 m3/d
49
15oC
0.015 per day at 20oC
0.5
0.07 per day
Assume DT
Lagoon Size
Depth
3 days
12, 400 x 3 = 37,200 m3
4m
Lagoon area
=
=
37,200
4
100m x 93m
K20oC (1.035)T-20
0.015 (1.035)15-20
1 + Kdt
YK1t
1 + (0.07) (3)
0.5 (0.0126)3
64 mg/l (Soluble)
K15oC
BODeff in winter
9300 m2
0.0126/day
Solids in lagoon
X
Y(So-S)
1+Kdt
64 + 97
300 64
97 mg/l
161 mg/l.
79%
300
Efficiency without FST
300 142
300
52%
Power required
3000 kg / day =
___130 Kg/hr__ =
0.75(2 Kg O2/kwh)
130 Kg/hr
87 KW
120 HP
50
These are attached growth system where in pretreated wastewater for grit and
grease removal is treated in a facultative tank with 3 to 4 hours hydraulic retention
period. Large size discs made of inert material rotate at a slow speed of 3 to 4 rpm
wherein adsorption of the colloidal matter taken place forming zoogleal media. The
adsorbed media slough off as bioflocs which are sedimented either in the same tank or in
a final sedimentation. The discs are kept 2/3 submerged so that air is drawn is to keep the
system aerobic
There are over 2000 installations in Europe. Could be plain surfaced, corrugated
or slotted. Relatively low power and land requirement. But has more mechanical parts
and so operation and maintenance is difficult. More suited as a package unit for
recirculation with tube settlers.
51
Zoogleal film layer develops on the disc and sloughens as sludge. The speed
could be 3 to 6 r.p.m. Diameter of the discs 3 to 4 m. Plastic, asbestos, PVC or
polystyrene discs are used. Shaft diameter 6 yo 8 cm. Spacing 2 to 5 cm (clear)
Loading g BOD/m2 d
BOD removal ()
6 to 10
90 %
20 to 25
80 %
52
BOD
removal
rate (ra)
(gms BOD/
m2 day)
100
50
10
100
1000
1500
Ka
g
m day
gms
m3
If we know value of Ka
2
KaA
mg gms KaA
S
or 3
S
o
2Q
L
m
2Q
53
Design a bio disc for 1000 persons to remove 80% BOD using 3m dia. discs
(plain surfaced) spaced 5 cm c/c.
Temperature expected 20OC
Organic loading 20 gms/m3 day
BOD5 54 gms/cap/day
Flow 200 lpcd
QD = 200 m3 / day
So
54 x1000
270mg / L
200
3. No. of discs =
d2
4
54 x1000
2700m2
20
x 2sides 14m2
2700
195
14
V
62.4
7.5hours
Q 200m3 / d
200m3 / dx103
6. Hydraulic loading on disc =
74l / m2 day
2
2700m
54
KaA
mg KaA
S
o
L 2Q
2
Q
2
(2.3)2700
2.3x 2700
49mg / L
270
2 x200
2 x 200
270 49
81% Hence OK.
270
9. Excess sludge (
55
Sludge Analysis:
1.
2.
3.
4.
Characterization of sludge:
1. pH should be about 7 or slightly alkaline.
2. volatile acids calorimetric tests
3. Alkyl benzene sulphonate test: to measure detergents. More than 1.5 % ABS will
impair digester performance.
4. Heavy metals such as Cd, Ni, Cr, Cu, Zn, Hg, Pb can interface with performance.
5. NPK and Ca values for fertilizer value
6. pathogen including worms
7. calorific value important if to be incinerated
8. centrifugability for dewatering
56
Disposal of sludge:
1. Agricultural use: by spraying digested wet sludge or flesh activated sludge.
Alternatively sludge is dried and mixed with soil as cakes. Domestic sludge may
be more suitable. Industrial sludge should be checked for toxicity in particular
heavy metals.
2. Land Filling: sludge should be fairly dry or mixed with refuse. Care should be
taken about leaching and general ground water pollution. It can also be mixed
with fly ash from thermal power station.
3. sludge can be incinerated, but air pollution should be controlled.
4. Marine discharge; widely practiced in many countries including UK. But if toxic
chemicals like Hg are discharged, it may accumulate in fish etc and end up in
food chain. Further, the reduction in DO level in water due to discharge should be
watched.
Overall reaction
4C3H7O2NS + 6H2O
57
Digesters are designed for Kg VSS/ m3 of tank. (in the mesophilic range 2.5 Kg
VSS/m3 ). If the total contribution of sludge is 80 gm/cap/day with 65% VSS and 95%
m/c (5% DS), we will have 1.5 l/cap/day and a detention time of 30 days.
Stirrer with heating coils: efficient, but we have to depend upon many mechanical
parts.
Characteristics
Fluid limit for pumping
Plastic
Rigid
Stable lumps
Appears dry
Dry cakes
Sludge conditioning:
Chemicals like lime, ferrous, Sulphates or polyelectrolyte could be used for conditioning
for mechanical dewatering. The presence of ammonium bicarbonate in sludge increases
the demand for these chemicals. This is reduced by elutriation which is washing the
sludge with water twice the volume of sludge. This reduces the chemical demand by 70%
58
and increases specific resistance. This is done after thickening and before mechanical
dewatering.
Mechanical dewatering:
Has no effect on pathogens. Done either by vacuum filtration or pressure application.
(a) Vacuum filtration
Works at 0.8 to 0.9 atmospheres. The vacuum is applied inside, which sucks the liquid
leaving the solids on the strainer made of polyethylene or polythene. The solids are
scrapped.
(b) Rotary concentrators:
Consists of long cylinders with strainer sludge is introduced at one end and as the unit is
rotated the water is lost through the strainer.
(c) Pressure application in bag filters:
Preconditioning of sludge is essential. Sludge is pumped through strainer bags and these
are pressed to squeeze the water out. The pressure applied is 60 to 100 psi (4 to 6
kg/cm2). It is a batch process and it gives a solid of 455 DS.
(d) Centrifuge:
Sludge conditioning by polyelectrolyte is essential. Centrifuge speed should be optimum
to avoid shearing.
G
5.5 N2 d
107
G = gravitational force
N= rpm
D= av in mm
G should be less than 10,000 to avoid shearing.
Sludge digesters:
The organic solids are liquefied and gasified by acid formers and methane formers. The
digested sludge with about 40% m/c is further dried.
The optimum temperature for digestion (mesophilic) is 30OC to 35OC and it takes 30 to
50 days for digestion. In thermophilic range it takes less than 10 days.
Mixing is done thoroughly in digesters to distribute the incoming sludge, to reduce scum,
to maintain uniform temperature. Power drivers mechanical mixing devices are used.
59
General circular tanks of 6 to 12 m depth with hopper bottom are designed. In India, the
average sludge production is taken as 35 to 60 l/c. it could be fixed or floating dome type.
Loading Factors:
Based on
1. kg volatile solids added per day per m3 digester capacity or
2. kg volatile solids added per day per kg volatile solids in the digester.
For conventional digesters 0.5 to 1.6 kg/m3 d of volatile solids could be used.
For high rate digesters it could be 1.6 to 6.4 kg/m3 d.
Population basis:
Type of plant
Dry
(gm/cap/d)
primary
Primary + TF
Primary + ASP
72
108
114
solids Volume
(m3/1000cap/d)
1.44
2.70
3.8
Volume required
35-45d (m3/d)
50-65
95-122
133
60
INTRODUCTION
Studies of waste treatment facilities have shown that any inadequacy in the
design, staff organization, or operation and maintenance (O and M) has invariably led to
a waste of capital, man-power and energy. Wise use of personnel according to well
organized O and M program can conserve treatment efficiency at a minimum total cost.
(1) The basic requirements of successful operation and maintenance of wastewater
treatment plants are:
(i)
(ii)
(iii)
(iv)
(v)
(vi)
(2) The importance of plant operation comes into focus when we realize that it is the
culmination of all preceding efforts aimed at for control of water pollution. A
plant which may be over loaded or has other short comings can produce its best
results if competent and careful operating techniques are applied. The word
Operator is applied to anyone charged with the responsibility of the operation
of the treat5ment plant. Operation of wastewater treatment plants is greatly
affected by the motivation and training of the individual operator.
This training must include basic knowledge of unit processes, the plant
equipments, how to recognize potential trouble, now to diagnose, and to make
temporary repairs, and finally to know as to where to obtain additional assistance.
Voluntary Certification and Mandatory Certification is required for rating the
61
operators ability in operation of plants and at the same time classifying plants as
to the grade of operator ability required.
(3) The certificate is indicative of the knowledge, experience, and competency of the
operator. Certification programs give the operator improved status, greater
flexibility in changing jobs, and opportunity for higher wages. Certification
usually provides benefits to the municipal or industrial employer by increased
efficiency in plant operators and maintenance, more reliable reports and record,
and more confidence in the operators recommendations for repairs and
improvements.
To prevent our wastewater treatment system from being perpetuated as
Monuments to inefficiency the key of operation and maintenance gap must be
closed.
(4) Availability of operation and maintenance manuals for each facility enables the
plant operators to check for specific problems and apply corrective measures.
In this article the problems associated with the operation and maintenance of
different wastewater treatment units are described.
62
ASP include, rate of water flow, air supply, MLSS, aeration period, DO in aeration tank
and clarifiers, rate of sludge return and condition of sludge.
The most important control parameters in activated sludge system are the DO in
the aeration tank and the MLSS. It is desirable to maintain a minimum aeration tank DO
of about 1 to 2 mg/L. If the DO levels are not controlled, localized regions may become
saturated with oxygen or super saturated with nitrogen or carbon dioxide. These
conditions lead to adsorption of fine bubbles on the flock, causing poor setting and
possible flotation. Activated sludge can have poor settling characteristics because of (1)
poor bio-flocculation, (2) excessive bound water, (3) small gas bubble entrainments in the
floc, (4) growth of type of bacteria or fungi (filamentous organisms) that have a large
surface area compared to their mass, (5) excessive amounts of hexane soluble oils and
grease. To maintain the required MLSS in the aeration tank the sludge settled in the
clarifier is returned to the aeration tank through sludge return pumps. The return flow is
to be adjusted such that it is approximately equal to the percentage ratio of the volume
occupied by the settleable solids from the aeration tanks effluent to the volume of the
clarified liquid (supernatant) after settling for 30 min. in a 1000 ml graduated cylinder.
This ratio should not be less than 15 percent at any time. For example, if after 30 min of
settling, the settleable solids occupied a volume of 150 ml, the percentage would be equal
to 17.7 percent [(150ml/850 ml) x 100]. Another method often used to control the rate of
return sludge pumping as well as plant operation I based on an empirical measurement
known as the sludge volume index (SVI). This index is defined as the volume in
milliliters occupied by one gram of activated sludge (MLSS), dry weight, after settling
for 30 min in a 1000 ml graduated cylinder.
SVI
Sludge under 100 SVI will settle well. Sludge which does not settle well or settles and
compacts poorly, leaving a small amount of clear supernatant is called bulking sludge. (6)
Bulking sludge is an operational problem that occurs in higher loaded plants with
insufficient aeration, presence of toxic substances in the influent, frequent organic shock
loads containing exceptionally high amount of carbohydrates. Bulking results from
increased growth of filamentous bacteria and with resultant poor settling of the MLSS in
63
the final clarifier. To correct this condition rapidly, the filamentous organisms, because of
their large surface area to volume ratio, can be selectively destroyed by large doses of
chlorine or hydrogen peroxide. The latter is more effective because it has less deleterious
effect on the desirable organisms. Sludge bulking can be controlled by cutting off
aeration tank in-flow and re-aeration the sludge for at least 6 to 8 hours before recommencing the plant flow.
64
dumping of fine materials in one place at the time of placing filter media. In many cases,
forking or raking the media to a depth of 20 to 30 cm will effectively remove ponding.
Washing the filter media with a jet of water or giving rest to the filter for 2 or 3 days may
also be effective. Pre-chlorination of the waste or application of caustic soda up 10 mg/L
has also been tried with success to eliminate clogging and ponding problems. When using
chemicals treatment may be given for 8 hours period on alternate days.
Filters under drains should be inspected frequently for clogging. If clogging
evidenced by reduced flow from any drain, this should be flushed and cleaned with sewer
rods.
Psychoda filter flies sometimes infest the filter and cause not only nuisance to the
workers but also clog the beds.* Application of chlorine at a rate of 3 to 5 mg/L or
gammexane at a rate of 180 gm/ha or DDT at a rate of 3 to 10 kg/ha of wall surface once
in a week are the methods available for the flushing of the larvae. Adult flies are
controlled by pyrethrum spray.
65
pumping exists, they should be used for mixing digester contents breaking down scum,
mixing lime with sludge for pH adjustment etc., where there is no mixing and recirculation facility, the operator has to rely upon natural mixing of raw and digested
sludge in the digestion tank.
Digestion is generally carried out in the mesophilic range and the temperature of
the sludge generally varies from 25OC to 35OC. Thermometers, to record temperature,
should be dept in order and reading noted twice or thrice a day.
Sludge should be withdrawn from the digesters only when it is fully digested,
judged by the dark grayish brown color without visible raw sewage sludge solids. Sludge
should be sampled and tested to find out the condition before withdrawing. Generally not
more than 10 percent of the capacity of digester should be drawn at a time, sludge
withdrawn being limited by the capacity of the sludge drying beds.
Frequent pH test of the sludge should be made and this should be correlated with
the alkalinity of the supernatant of the sludge which may range from 1500 to 3000 kg/L.
This affords an excellent check on operation. Digestion proceeds most favorably at pH
values of 7.0, it is usually desirable to raise the pH be adding lime to the sludge as it is
enters the digester. The alkalinity of the supernatant is a useful guide to control the
dosage. A start may be made using 20 to 40 kg of lime per m3 of sludge, with more added
if the pH value or alkalinity does not rise appreciable in a few days.
Difficulties in the digestion tanks such as foaming due to overloading or
accumulation of acid sludge or excessive formation of H2S have to be corrected by
neutralization an adjustment of pH. H2S in moist gas leads to corrosion of meters piping
and flame trap through which the digester gas is drawn. This can be overcome by the
removal of the H2S by passing the gas through iron oxide or other scrubbers or by heating
the gas to a high temperature to eliminate moisture in it
Gas pipes should be kept free from sediments, gas meters being periodically
lubricated and fusible plugs in the flame traps frequently checked.
66
proponic acid and (b) fermentation of these organic acids into methane and other gases.
The former process is accomplished in the digester by facultative anaerobic bacteria
which are abundant in nature. The second phase, methane formation is brought about by
methane bacteria, which are strict anaerobes. Anaerobic lagooning, as applied in the
treatment of wastewater represents the controlling application of a process which occurs
under natural conditions when organic matter decays in the presence of water but absence
of air. If the object is to operate the lagoons at the maximum efficiency, it is necessary to
keep the environment ideal for the bacteria to grow and oxidize the organic matter.
Operation and Maintenance Anaerobic lagoons
1. The anaerobic lagoons should be filled with fresh water and fresh cow dung
should be added and allowed to digest for a period of 30 days. The quantity of
cow dung (4 percent suspension) required is about 10 percent by volume of the
lagoon. Slowly waste may be fed and pH maintained between 6.8 and 7.8. In
about a months time lagoon will be ready for regular operation. This
commissioning of the anaerobic lagoon should be started one month before
starting of the prior units.
2. During the operation of the lagoon, if there is any failure, digested cow dung
suspension should be added. If the lagoon is not functioning satisfactorily, new
wastewater should be by-passed till the lagoon starts functioning normally.
3. At the time of commissioning the anaerobic lagoon consultants should be called
to the factory to assist. It may be necessary to apply lime to maintain the pH in the
lagoon 6.8 to 7.0. This should be done under the guidance of the consultant.
4. The optimum temperature for majority of bacteria known as mesophilic bacteria
is about 33OC to 37OC. The optimum pH for most of the bacteria is between 6.5
and 8.0 with expectation. Methane bacteria are very sensitive to acidic pH and in
general do not thrive under 6.5. This has been one of the reasons why many
lagoons have become ineffective as methane bacteria are slow multipliers.
Methane bacteria are not present in wastewater or in normal solid. They have to
be added through seed or digesting cow dung.
67
5. Bacteria work under constant and steady feed conditions. To extract maximum
work out them, it is advantageous to feed them with wastewater continuously
rather than on a feast and fast basis.
6. Various laboratory tests have been used to determine the condition, progress and
efficiency of digestion. (1) pH, (2) Alkalinity. (3) Volatile acids and (4) BOD.
7. The pH value is generally relied upon in judging the general performance of the
anaerobic lagoon, a neutral condition, as indicated by an average value of 6.8 to
7.2, is considered normal. Alkalinity as CaCO3 of 2000 mg/L is considered good.
The concentration of volatile acids will foretell the approach of digestion
difficulties in advance of pH and alkalinity. Volatile acids concentration should be
steady and below 3000 mg/L. BOD reduction of 70 to 80 percent is normal.
Lower removal indicates poor performance.
8. It is always necessary to maintain proper records. This would help to evaluate the
performance of the lagoon and help to furnish useful data when further expansion
of the plant is contemplated.
9. A well maintained lagoon with properly cleaned surroundings and sides will
avoid mosquito breeding. This will improve site conditions.
68
attained to a level of about 4000 mg/L. This process of building up the solids in
the tank will take 2 to 4 weeks.
3. Once the solids level is reached to about 4000 mg/L, the tank is then ready for
continuous inflow of wastewater enters, there will be overflow from the tank
entering into the settling tank. Depending upon the design of the settling tank, it
may take abut 2 to 3 hours to fill the tank. The sludge in the settling tank will be
taken to the return sludge pump through a valve. Opening of the valve should be
controlled to effect an average flow of the incoming of wastewater. The return
sludge is pumped continuously and put back into the tank. While this process is
on, the liquid level in the settling tank will rise up slowly as the wastewater
continuously flows into the aeration tank. The overflow from the settling tank will
constitute the treated effluent. As stated earlier aerators and the return sludge
pumps in the treatment plant should be operated continuously even when there is
an intermittent flow of wastewater into the aeration tank.
4. With continued operation of the aeration tank and the return sludge, the MLSS
concentration will increased until the capacity of the system to settle and retain
the solids is exceeded. For this reason, it is necessary to withdraw a small fraction
of the solids in the mixed liquor and dispose of it separately. This excess sludge is
withdrawn from the settled sludge which is normally returned to the aeration tank.
The volume of the excess sludge to be wasted per day is usually between 0.26 and
0.43 percent of the wastewater inflow. Instead of wasting sludge everyday. It may
be accumulated for 3 to 4 days and then wasted in one lot.
5. The excess sludge should be spread to a depth of 8 to 12 inches and allowed to
day for sufficient time. Generally about 10 days drying period is required before it
can be spaded out. If experience indicates more time for drying, then additional
drying beds will have to be provided. The sludge, after it is dried sufficiently, will
be collected and used as manure. Just prior to rainy season, some extra sludge
may be wasted from the system so as to provide a buffer capacity for storage of
excess sludge during monsoon season when the sludge on the drying beds may
not loose moisture readily.
69
6. The day to day operational requirements may range from regular lubrication of
bearings and greasing of reduction gear units of aerators. Also the recording of
such parameters as flow measurements, suspended solids and other characteristic
may be carried out regularly.
7. Occasional samples may be withdrawn and got analyzed at a convenient
laboratory to help to maintain records of performance of the installation.
Representative samples should be taken, preserved properly during transport and
tested.
8. Tests for BOD on the influent and effluent, and for suspended solids on the
influent and effluent, mixed liquor suspended solids and return sludge should be
carried out regularly once in a week. Frequency of sampling can be increased if
desired. Occasional samples may be collected and analyzed for the nutrients
(Phosphates, ammonia, nitrates, nitrite etc.) in the influent and effluent.
9. It is always necessary to maintain proper records. This would help to evaluate
performance of the aeration tank and help to furnish useful date when further
expansion of the plant is contemplated.
10. W well maintained plant with properly cleared surroundings and a small patch of
garden with appropriate landscaping can convert a waste disposal plant into a
pleasant spot, which would be a credit to the authorities. Plants like coconut, palm
and eucalyptus may also be planted so that it can be natural screen or filter for any
unpleasant odors.
70
application of these ponds, particularly in the tropics where sunshine is plentiful and
money is scarce, for the treatment of industrial waste also. The term Waste Stabilization
Ponds has been more widely adopted as it is more descriptive of the real function, and
includes aerobic as well as anaerobic modes of stabilization. The word waste includes
both sewage as well as industrial wastes. Neither the term Oxidation Pond nor the term
sewage lagoons include all these aspects.
This process involves two steps in the decomposition of the organic matter
present in the wastewater. The carbonaceous matter in the effluents is first broken down
by the aerobic organisms with the formation of carbon dioxide. The carbon dioxide so
formed is utilized by algae during photosynthesis which liberate oxygen. This oxygen
dissolved in water is used by the aerobic bacteria for further oxidation of organic matter.
71
Overloading of Ponds
Stabilization ponds can withstand to a certain extent fluctuations on the waste
load. But as far as possible sudden or extreme variation in the characteristics of the waste
entering the pond should be avoided. In case where anaerobic conditions are found to be
developing due to overloading, measures like pond surface agitation (by pump
recirculation or motor boat operation) and addition of chemicals like sodium nitrate may
be adopted. However overloading should be avoided by studying the causes for the same
or by expanding the size of the pond to take care of the increased load.
Observation
1.
2.
3.
4.
5.
Pond condition
Very good
Good
Tending to be
over loaded
Tending to be
anaerobic
Overloaded and
anaerobic
Preventive steps
Only remove marginal and
floating scum accumulation
Algamats
and
scum
accumulation to be removed
If overloading is temporary, by
pass the flow to reduce load on
pond remove floating matter
May be due to the presence of
sulfur bacteria. By pass part of
the influent until normalcy is
established.
If temporary by pass part of the
influent permanent, remedies
such as cleaning and re
commissioning the pond are to
be taken.
72
73
Sedimentation tanks
The primary sedimentation tanks handle raw waste which is allowed to settle at
the bottom. The settling tanks are generally provided with mechanical scrapers to divert
the sludge to a zone to facilitate continuously or periodical withdrawal of sludge. The
scraper arms are constantly immersed in wastewater and are subjected to corrosion.
Since, sewage and most of the industrial wastes have much lower resistivity that water,
the parts are likely to corrode much faster than in the case of water. The specifications for
the steel used for the under-water mechanisms should be carefully drawn to ensure
maximum protection from corrosion. It is normally specified that all the steel below the
liquid level shall be at least 1/4 thick. It is a good practice to keep all chains, bearings or
brackets above the liquid surface. All castings in the driving mechanism should be high
grade cast iron.
It is possible to give cathodic protection to the scraper mechanism of the clarifier
either by sacrificial anode or by impressed current. The choice of either of the method or
cathodic protection will depend upon the comparative costs. In any case, the cost of such
protective measures will not be higher than the cost of good quality acid resistant paint.
74
Trickling filters
In trickling filters the mechanical components include the header, the distribution
arm and distribution nozzles, the header and distribution arms are normally of mild steel
and should be protected from corrosion by proper painting etc. The corrosion and
resulting blockage of distribution nozzles are of common occurrences. This can be voided
by selection of proper corrosion resistant material such as brass or PVC for nozzles.
75
Preventive maintenance
It will be seen from the above discussion that anticorrosive paints, coatings
linings have to be used in various equipments to prevent corrosion. The paints, coatings
and linings require periodical renewal. Proper maintenance demands that a scheduling be
drawn up in each paint so that the operator may abide by it and undertake repainting or
cleaning at appropriate intervals without waiting for corrosion to become obvious. The
accent should be on preventive maintenance rather than just maintenance in the form of
repairs, and replacements of broken down parts.
No doubt, proper design and specifications at the tendering stage would go a long
way in ensuring long life. However, once the plant is built it is entirely in the hands of the
operator or the supervisor to ensure proper preventive maintenance and carry out
judicious replacement of spare parts piping etc. bearing in mind the requirements
described above.
76