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this plug of material is cut off the end of the final slab and recycled to the primary steel
production unit.
Typical Compositions of Steel for Line Pipe
Alloying elements are added to pipeline steels to alter the mechanical properties of the steel
but also have an impact on the corrosion behaviour. Table 5 lists the typical alloying
elements and their effect on steels. The API Specification 5L allows for a wide range of
compositions, specifying only the maximum levels of a limited number of alloying elements.
This tolerance allows the steel producer to achieve the specified strength, toughness and
weldability by a range of fabrication routes.
slabs cut in two then one side of the longitudinal weld of the pipe will be made from steel
from the centre of the slab where the highest levels of inclusions and tramp compounds are
present. When formed into pipe the inclusions would be adjacent to the longitudinal weld;
this type of pipe may be unsuitable for sour service. With all pipe made from strip it is usual
to reject pipe made from 'jointers", these jointers are the welds that connect the individual
strips together to make the long coils.
Thermo-Mechanical Controlled Processes for Plate Production
Hot rolling can roll the slab to the correct dimensions and the slab then subsequently heat
treated
to obtain the final mechanical properties. In the traditional hat rolling process the
steel slabs are heated well into the austenite region, 1200 - 1250 OC, and held at this
temperature (soaked) where re-crystallisation produces coarse austenitic grains. The plate
is hot rolled starting at this temperature and the rolling is continued as the plate cools to
about 1000 C.The rolling results in the formation of large elongated grains. After rolling
the steel is allowed to cool in air. Recrystallisation of the austenite grains occurs and some
grain refining.
To refine the grains further the steel is normalised by re-heating into the austenitic region to
re-crystallised grains and then cooling at a controlled rate to obtain a fine ferrite grain
size. An alternative is to quench and temper the hot rolled steel plate. In this process the
steel is heated into the austenite region to re-crystallise the grains and then cooled rapidly to
freeze the grains. By cooling rapidly the non-equilibrium structure, martensite, is formed.
The steel is fine grained, very strong but brittle and requires tempering which reduces the
strength and improves the toughness. The Q&T procedure gives more control of the final
properties than normalising. The final strength of the plate material produced by hot rolling
and heat treatment is achieved by a relatively high alloying content, micro-alloying and
limited grain refining. In consequence the upper limit of strength is around X60 though
higher grades can be achieved with careful control of the heat treatment. The carbon
equivalent of these steels is high however, which has an impact on the weldability. Typically
these steels have CE's in the range 0.35 - 0.43. The blend of strength and toughness that
can be produced by hot rolling is limited. The higher grade, higher quality plates for pipeline
fabrication is increasingly being produced by the controlled rolling processes.
There are several variants of the controlled rolling process, often termed thermo-mechanical
control process (TMCP) that involve rolling the plate in several stages at carefully controlled
temperatures. Schematics of the conventional hot rolling production procedures and the
various TMCP procedures are given in the Figures.
Option 1 is the simplest TMCP and is the original controlled rolling process developed to
produce large sheets of high strength steel for construction of ships and super tankers. The
slab is heated to 1200 - 1250 OC and the steel is rolled to the roughing stage. The plate is
allowed to cool to a temperature where it remains austenitic but reworking the grains will not
re-crystallise as a result of the work input during the second phase of rolling. The steel is
cooled further until it is on the borderline of the transition zone of austenite to ferrite and is
finished by re-rolling at this temperature to form elongated austenite grains. On further
cooling the steel re-crystallizes into fine ferrite and pearlite grains. The energy input in
working of the austenite (y) grains at the transition temperature results in a relatively fine
ferrite grain structure though the steel retains a marked banded appearance, rather alike
grain in wood. All the working of the plate occurs in the austenite region and this option is
termed TM(y).
Option 2 is to roll the plate for the third time whilst it is in the austenite + ferrite zone before
complete conversion to ferrite has occurred; this results in a very fine ferrite grain structure
though with residual structural banding. Some dislocation strengthening also occurs, as
there can be no relaxation of the imposed stress by re-crystallisation. Since the working of
the steel occurs in both the austenite region and the ferrite region this option is termed
TM(y + a).
Option 3 is to roll the plate as in Option 2 and to cool the steel using water-cooling
immediately the third rolling is completed. This allows the conversion to ferrite grains but
freezes the growth of these grains that would occur if the plate were allowed to cool slowly
in the air. This option involves working the plate in the austenitic and ferritic regions and
accelerated cooling and is termed TM(y + a) + ACC. The rate of cooling is restricted to
avoid quenching the structure, which would result in the formation of bainite and martensite,
and these would require subsequent tempering.
Option 4 is to roll the plate at the high temperature and then allow some cooling and rerolling
of the steel in the temperature region where re-crystallisation of the worked austenite
grains will not take place. The steel is then water cooled until the temperature is in the
ferrite region; the steel is essentially quenched. This produces a very strong material with a
fine but disordered grain structure and requires to be tempered. Because the working
occurs in the austenitic region but grain growth is restricted it is termed TM(a) + Q&T.
Option 5 is Option 4 with the steel quenched to a sufficiently high temperature such that it
has sufficient residual heat to self temper. This avoids the need to reheat but can only be
applied to relatively thick material. This option is termed TM(a) + QST.
Option 6 is to hot roll the steel as with all previous options, allow the steel to cool to the zone
where re-crystallisation does not occur and to re-roll and then cool the material into the
ferrite zone. Ferrite formation starts to occur and the material is re-heated slightly to raise it
into the austenite zone where it is re-worked as it cools through the austenite-ferrite
transformation temperature. The material is then acceleration cooled. This option is termed
TM(7)IC + (a)ACC.
The initial slab heating stage for hot rolling is important as it controls the micro-alloying
process and the starting size of the grains. Each of the micro-alloying elements requires a
different temperature for solubilisation and precipitation. During the rolling process the
grains are deformed and, if this is at the re-heating temperature between the recrystallisation
temperature and the transition temperature, or in the dual phase austenite ferrite
temperature band, then the grain size is refined by re-crystallisation between the
rolling passes when the imposed strain is above the critical deformation level. Because
grain growth is restricted by the precipitation strengthening precipitates formed at the grain
boundaries the grains cannot grow thermally and are increasingly refined by each
recrystallisation step.
Accelerated cooling is increasingly being used because the rate of cooling from the dual
phase (y + a) temperature band has a marked effect on steel strength. The more rapid is
the cooling, the greater is the increase in the strength of the steel even with a low alloying
content. Because a low alloying content reduces the carbon equivalent, and hence the
weldability, these steels provide very high strength and toughness with excellent weldability.
The rate of cooling is restricted to avoid quenching the structure as this would result in the
formation of bainite and martensite and these would require subsequent tempering.
After forming the plate will contain residual hydrogen that takes time to diffuse out. Most
steel manufacturers stack plate to maintain the temperature high for longer, which
encourages hydrogen degassing. In the pipe fabrication specification provided by the pipe
producer it may be necessary to check that stacking is allowed especially for plate of 20 mm
thickness or above and for plate which will be used for fabrication of pipe for sour service.
Shape Control
In the 1960's there was an increase in production of oil and gas and a concomitant demand
for large diameter pipe that meant that very wide steel sheets of strong, tough steel were
needed from which to form the pipe. For example to produce a 48-inch diameter pipe by the
U-0-E process requires a sheet of steel -4 m by 12.5 m. Much of the new production was
also sour. It was known that pipelines able to tolerate sour product had to be constructed in
a manner that avoided hard spots at welds in the material to avoid risk of sulphide stress
cracking (SCC) as defined in NACE MR-0176. This requirement is best met by the use of
steel with a low alloying content, but as discussed above, to obtain high strength steels with
low alloy contents required steel with a fine grain size to provide both strength and
toughness. The plate for these large diameter pipes was obtained by use of the controlled
rolling process, at that time restricted to Option 1.
Pipe fabricated from controlled rolled steel was used for transmission of sour crude oil and
the pipe failed by internal cracking, as a result of the formation of hydrogen gas within the
steel. Some of the atomic hydrogen evolved during internal corrosion migrates into the steel
and is reformed as hydrogen gas at manganese sulphide inclusion platelets in the steel. The
builcl up of hydrogen gas develops large pressures that raise sufficient internal stress to
cause the internal cracking of the steel, a similar process to the blistering of tank steel at
laminations. The working of the steel had resulted in a marked banding of the steel
microstructure as the grains were elongated in the rolling direction. Such steel has marked
anisotropic properties between the longitudinal and transverse directions, for example
significant differences in tensile strengths and a factor of 2 - 3 in absorbed impact energy.
More importantly for sour service inclusions of manganese sulphide are also flattened and
elongated and thus presented a large surface area for absorption of the atomic hydrogen
migrating through the steel. Here comment is restricted to the methods used to alter
inclusion morphology to reduce steel susceptibility to HIC and also reduce the anisotropy.
The first attempt to produce steels resistant to HIC was by incorporation of copper into the
steel. Subsequent to some corrosion the copper forms an enriched copper sulphide layer
on the inner surface and, by catalysing the combination of hydrogen atom to molecular
hydrogen, the quantity of atomic hydrogen entering the steel is reduced. However cracking
still occurred when copper-containing pipe formed from controlled rolled steel was used for
producer it may be necessary to check that stacking is allowed especially for plate of 20 mm
thickness or above and for plate which will be used for fabrication of pipe for sour service.
Inclusion Shape Control
In the 1960's there was an increase in production of oil and gas and a concomitant demand
for large diameter pipe that meant that very wide steel sheets of strong, tough steel were
needed from which to form the pipe. For example to produce a 48-inch diameter pipe by the
U-0-E process requires a sheet of steel -4 m by 12.5 m. Much of the new production was
also sour. It was known that pipelines able to tolerate sour product had to be constructed in
a manner that avoided hard spots at welds in the material to avoid risk of sulphide stress
cracking (SCC) as defined in NACE MR-0176. This requirement is best met by the use of
steel with a low alloying content, but as discussed above, to obtain high strength steels with
low alloy contents required steel with a fine grain size to provide both strength and
toughness. The plate for these large diameter pipes was obtained by use of the controlled
rolling process, at that time restricted to Option 1.
Pipe fabricated from controlled rolled steel was used for transmission of sour crude oil and
the pipe failed by internal cracking, as a result of the formation of hydrogen gas within the
steel. Some of the atomic hydrogen evolved during internal corrosion migrates into the steel
and is reformed as hydrogen gas at manganese sulphide inclusion platelets in the steel. The
build up of hydrogen gas develops large pressures that raise sufficient internal stress to
cause the internal cracking of the steel, a similar process to the blistering of tank steel at
laminations. The working of the steel had resulted in a marked banding of the steel
microstructure as the grains were elongated in the rolling direction. Such steel has marked
anisotropic properties between the longitudinal and transverse directions, for example
significant differences in tensile strengths and a factor of 2 - 3 in absorbed impact energy.
More importantly for sour service inclusions of manganese sulphide are also flattened and
elongated and thus presented a large surface area for absorption of the atomic hydrogen
migrating through the steel. Here comment is restricted to the methods used to alter
inclusion morphology to reduce steel susceptibility to HIC and also reduce the anisotropy.
The first attempt to produce steels resistant to HIC was by incorporation of copper into the
steel. Subsequent to some corrosion the copper forms an enriched copper sulphide layer
on the inner surface and, by catalysing the combination of hydrogen atom to molecular
hydrogen, the quantity of atomic hydrogen entering the steel is reduced. However cracking
still occurred when copper-containing pipe formed from controlled rolled steel was used for
transmission of wet sour gas. Steel composition had to be reformulated again to reduce the
sulphide inclusions and to alter their shape.
The primary method of improving resistance to HICwas reduction of residual sulphur in
the
steel. The small quantity of sulphide remaining, as manganese sulphide, could be further
modified by shape inclusion. Primary calcium treatment of steel is used after the aluminium
additions to reduce the concentration of sulphur. The calcium is added after the aluminium
addition as calcium silicide or carbide into the molten steel. As a vapour it combines with
sulphur and oxygen in the steel and the reaction products are removed in the floating slag.
Very low levels of sulphur are achievable typically in the range 0.001 - 0.003%.
Magnesium has the same effect but is more expensive than calcium, though magnesium is
still used to form ductile iron pipe from cast iron. A secondary addition of calcium was
introduced at the ladle stage to shape the residual sulphides as spheroids. With calcium
treatment the residual sulphide is associated with the calcium principally as calcium sulphide
rather than as manganese sulphide. These particles tend to be fine and globular and,
because they are hard, retain their shape through the hot rolling process. The area
presented to the atomic hydrogen is markedly reduced resulting in less internal hydrogen
accumulation and a marked improvement in resistance to HIC. The ratio of Ca to S should
be restricted with a minimum of 1.5:1 to 2:lat the ladle analysis. A lower calcium ratio
provides inadequate calcium to form the spheroids whilst excess calcium forms
unfavourable compounds that affect the mechanical properties in the HAZ. A typical
composition for internal crack resistant steel is given in Table 2.
PIPE FABRICATION
Pipe for the oil and gas industry is largely restricted to four fabrication routes: seamless,
longitudinally welded by electrical resistance welding, helical or spiral welded and
longitudinally welded using submerged arc welding. Production of pipe by furnace
buttwelding
of hot plate, though permitted, cannot produce the large diameters required.
Nowadays many pipe fabricators are independent and not part of an integrated steel
company. Fabricators also tend to specialise in certain pipe fabrication techniques and few
produce pipe material over the full range of diameters and wall thicknesses. The Oil and
Gas Journal make a regular survey of pipe fabricators but this listing may not be
comprehensive as some East European and Far Eastern fabricators are omitted.
Independent pipe mills form pipe from plate or coiled plate that is bought from whatever
source can provide suitable material, at an acceptable price. For the production of a large
quantity of pipe the plate may be sourced from several steel suppliers. The mechanical
properties of the pipe will be consistent with specification but caution is necessary regarding
the weld procedures as small variations in composition can affect the quality of the weld
achieved.
Seamless Pipe
Seamless pipe is formed by hot working steel to form a pipe without a welded seam. The
process is shown schematically in the Figures. The initially formed pipe may be
subsequently cold worked to obtain the required diameter and wall thickness and heat
treated to modify the mechanical properties. A solid bar of steel, termed a billet, is cut from
a slab and is heated and formed by rollers around a piercer to produce a length of pipe.
The Mannesmann mill is perhaps the best known type of piercing mill. In this mill the steel
billet is driven between rotating, barrel-shaped rolls set at a slight angle to each other. The
rolls rotate at about 100 - 150 rpm and the billet also rotates. The piercer is placed just
beyond the point where the billet is squeezed by the rolls so that as the formed billet passes
through the "pinch" zone between the two rollers the reducing stress tend to open the metal
over the piercer.
The piercing mill produces the primary tube that requires finishing to form the pipe. The wall
thickness is further reduced and the pipe finished in plug rolling mills that drive the pipe over
long mandrels fitted with plugs of the correct internal diameter between rollers that extrude
the tube to the required external diameter. An older process is the Pilger process. This
process uses eccentric rolls to form the pipe in discrete stages. A mandrel is inserted into
the partly formed pipe from the piercing mill. The assembly is driven into the open rolls and,
as the rolls rotate back and forth, sequential sections of the pipe are drawn into the
eccentric rolls and the outer diameter formed to the required dimension set by the roller
eccentricity. Other methods use multiple conical or conventional horizontal rolls or offset
rollers. Pipe is finished in a reeling process in which it is driven between slightly conical
rollers followed by passage through a sizing mill that ensures circularity.
After forming, the pipe may be delivered as produced or, more usual for the oil industry, as
either normalised or quenched and tempered. These heat treatments homogenise the
mechanical properties and further improve strength and toughness. After forming is
completed the pipe is inspected for internal laminations and pressure tested hydraulically.
The hydraulic test is at high pressure and for up to 20 seconds.
This type of pipe is generally available in diameters up to 16-inch but can be obtained in
sizes up to a maximum of 28-inch from a restricted number of suppliers. The larger
diameter pipe is made by expansion of smaller diameter pipe. Seamless pipe is the
preferred material of several operators for small to modest diameter pipelines. Its principal
advantages are its good track record in service and that there are no welds in the pipe
sections.
The larger diameter seamless pipe may be more expensive than pipe fabricated by the
alternative processes. Disadvantages of seamless pipe are a fairly wide variation of wall
thickness, typically +5I1 -12.5% and out-of-roundness and straightness. The premier pipe
fabrication mills can produce seamless pipe to closer tolerances. The outer surface of the
pipe may also be highly distorted such that when it is grit-blasted, prior to coating, tiny
slivers of steel rise up. This can be a serious drawback when the pipe is to be coated with a
thin anti-corrosion coating such as fusion bonded epoxy (FBE) and it is prudent for the
pipeline engineer to check for such effects when pre-qualifying pipe suppliers.
the tube into an exact circular pipe. Typically the cold expansion is limited to below 1 2%
and the expander is shaped to avoid damage to the weld. The pipe is hydrostatically tested
and then re-inspected using automatic ultrasonic testing and radiography. The weld may
also be MPI tested. Finally the end faces of the pipe are end faced or bevelled, fitted with
end protectors and the pipe moved to the storage racks.
U-0-E pipe is used for the larger diameter pipelines. It is competitive with seamless pipe for
the intermediate diameters (14-inch to 28-inch). For the smaller diameter pipes the pipe
fabricator may use cut down plate because producing narrow plate is less economical.
Because inclusions and segregation tend to concentrate at the centre of the plate a pipe
formed from a split plate may have inclusions and segregation adjacent to the weld. Such
pipe may be unsuitable for sour service. If split plates are to be used then an odd number
should be cut to avoid the centre line of the original plate abutting the longitudinal weld.
U-0-E pipe is the premier pipe material for large diameter high-pressure pipelines. it has
smaller variations in wall thickness and out of roundness than seamless pipe; a typical wall
thickness tolerance is +12%, -10% and ovality klolMoany. p ipe fabricators can produce
pipe to tighter tolerances, typically k5% and ovality k%Oh. Specifications may be based
on
percentages or dimension as mm. When specifying, the percentage route is better for the
larger diameters and the dimension better for small diameter pipe. Press bent pipe is used
for very heavy wall pipe and is formed similarly to U-0-E by forming a cylinder from plate
and welding longitudinally. The bending uses three rollers, one offset and moved to form
the required diameter.
Helical (Spiral) Welded Pipe
A coil of hot-coiled plate is uncoiled, straightened and flattened and the edges dressed. The
plate is then helical wound to form a pipe. The width of the strip and the angle of coiling
determine the pipe diameter. As the pipe is formed the helical seam is welded using inert
gas welding or submerged arc welding (SAW) first internally and as the seam rotates to the
top position the external weld is made. A continuous length of pipe is produced. After
forming the pipe is passed through a sequence of rollers to ensure circularity.
The pipe weld is tested using radiography or ultrasonic testing and the pipe is then cut to the
required lengths. The pipe joints are hydrostatically tested before being re-inspected. If the
pipe passes inspection then it is end-faced or bevelled, the end protector caps are fitted and
the pipe transported to the pipe racks. A schematic of the process is given in the Figures.
The end of the coiled plate is welded to the start of the next plate coil and this results in a
weld perpendicular to the helical weld forming the pipe. This weld joint should not be less
than 300 mm from the end of the pipe. This weld may not receive the same degree of
scrutiny as the helical welds and the pipe specification may need to call for an additional
inspection of these welds after the hydrotesting stage.
Helical welded pipe can be made in a wider range of diameters and wall thickness than
nominal API Specification 5L sizes. It can also be produced in long lengths above the
normal double random length of 12 m. Because the pipe is formed from plate the wall
thickness tolerances are good being similar to U-0-E pipe though there may higher out-of
roundness.
It has been used for large diameter pipelines, both crude oil and gas, but is
generally considered a less reliable material than U-0-E formed pipe. It is cheaper than U
0-E and is widely used for caissons, sleeves, low-pressure hydrocarbon service, dried gas
service and for water transportation where the service is moderate. The large length of
weldment and the need for some of this weld to be at the bottom of the pipe, where the
worst case corrosion occurs, is seen as a potential weakness which tends to preclude this
type of pipe from general high pressure service. The helical welding may reduce the data
gained in intelligence pig surveys because the sensors skip at the welds resulting in blind
spots just downstream of the welds.
Selection of Pipe Wall Thickness
The diameter of a pipeline is selected based on hydraulic studies. The wall thickness is
determined by service pressure including hydraulic heads, the design factor, the corrosion
allowance and the fabrication tolerance (wall thickness variation). It is then common
practice to select the nearest higher API Specification 5Lstandard thickness pipe. The
larger negative tolerance in wall thickness for seamless pipe as compared to SAW pipe
means that for a given diameter a seamless pipe will need to be thicker on average than an
ERW or SAW pipe. As wall thickness increases the complexity of welding may increase.
However many modern pipe fabricators can produce pipe to closer tolerances and this may
need to be reviewed using a cost benefit analysis. Many companies insist on smaller
tolerances than API Specification 5Ltolerances and also specify exactly the wall thickness
they require. However for small batches of pipe this may not be economical, as standard
API sizes tend to be cheaper than non-standard.
The corrosion allowance is determined by calculation and a method is given in the Section
on Internal Corrosion. For a non-corrosive service (e.g. a refined product pipeline) there is
no need for a corrosion allowance. In a mildly corrosive environment a corrosion allowance
alone may be adequate, though it is usual to use a corrosion inhibitor to suppress pitting
corrosion. More aggressive environments may demand a corrosion allowance and
continuous corrosion inhibition. For very corrosive environments carbon steel may not be a
suitable material and an alternative corrosion resistant material may have to be used.
There are no easily applicable criteria for these changeovers. The design life expectancy of
the pipeline, the pressure and flow profiles over the design life and the expectations of
changes in production fluid composition all need to be taken into account. Other factors
relevant include the criticality of the line, the ease of inspection, the availability of inhibitor,
the level of skill of operatives and, increasingly, the environmental aspects. These are
discussed elsewhere.
Pipeline Joint Lengths
When fabricating land pipelines the welders move along the pipeline, welding the pipe joints
to the end of the growing pipeline. This allows considerable flexibility in the lengths of
individual joints. Manual welding remains the most flexible welding procedure. If semi
automatic welding techniques are used, as the complexity of the welding procedures
increases, so the need to reduce the tolerance on pipe length generally increases to
accommodate the machine limitations.
Bends
It is important to check that the material can be hot formed and retain its strength. The hot
bend fabrication process may excessively reduce the strength of very low carbon steels. If
this is the case then special steel joints may be required from which the bends can be
fabricated.
If a pipeline is to be constructed to allow inspection by magnetic flux leakage pigging tools
then there are restrictions on the acuteness of the bends. The bend size decreases with
increasing pipeline diameter. For 6 and 8-inch pipes the pigs may require 5-D bends
minimum whilst for 24-inch pipes the more advanced pigs are designed for 1 %-D or 2-0
bends.
Straightness
Usually the out of straightness of the pipe follows a log-normal distribution with diameter
and, as would be expected, the larger the diameter of the pipe the straighter is the pipe.
API Specification 5L allows 24 mm in a 12 m joint. Usually it is possible to obtain pipe to 12
mm in a joint length of 12 m. To reduce total cost over specification of straightness should be
avoided.
Residual Magnetism
The final step in pipe fabrication is to bevel the ends of the pipe to ensure that they are
square to the longitudinal axis of the pipe and are ready for welding. The bevels may be
inspected for laminations using magnetic particle inspection. Pipe should be de-magnetised
as residual magnetism can cause problems during welding, as control of the plasma arc is
lost. The plasma is an electrical current that is distorted by the magnetism. Note that
problems with magnetisms may also arise when attempting to repair a pipeline that has
been inspected using a magnetic flux inspection pig.
inhibition.
In conjunction with the technical reason for selection of the CRA there will need to be a
justification of the particular CRA selected on strictly economic grounds. In all cases the
design life is of critical importance. If the cost benefit analysis is between a CRA and
carbon steel it is important to include hidden costs of operating a carbon steel pipeline, e.g.
the regular monitoring and inspection, transport and application of inhibitor, and the higher
risk of failure of the pipeline. If the analysis is to distinguish between different CRAs then
the costs associated with installation and potential failure risk tend to dominate. Several
studies are reported which indicate that the more expensive material option can be the
cheapest overall for modest diameter (to 10-inch), short length (to 15 km) pipelines with
design lives of fifteen or more years. Outside this diameter-length domain the overall
operation of the Field may need to be re-evaluated taking account of the processing costs to
alter the corrosiveness of the produced fluids.
Alloying Elements
The corrosion resistance of carbon steel is markedly improved by the addition of nickel
andlor chromium. The separate effects of nickel and chromium are shown in the Figures.
Other elements, for example molybdenum, are also be added to improve resistance to
specific types of corrosion attack. Relatively small additions of chromium result in marked
reduction of corrosion in sweet systems (fluids containing carbon dioxide). The bulk of
corrosion in sweet systems is suppressed and reaches a minimum when the nickel content
is 9% or greater or the chromium content equals or exceeds 12%. Unfortunately, though
general corrosion is reduced, other corrosion mechanisms become dominant, for example
chloride stress corrosion cracking, crevice corrosion and pitting. The external corrosion
issues must also be addressed. The selection of the CRA is largely determined by the need
to avoid these potential internal and external failure mechanisms.
Use of a single alloying element would minimise material cost. Chromium alone would be
the preferred alloying element because it is cheaper than nickel but the simple chromium
alloys have poor weldability, showing delayed cracking and a marked reduction in the
mechanical properties of the heat affected zone (HAZ). To overcome these limitations,
blends of chromium, nickel and iron are used.
In addition to nickel and chromium other alloying elements may be used to improve the
material resistance to pitting and crevice attack. Molybdenum and nitrogen are two
elements that have the most significant effect.
The chromium and nickel steels are corrosion resistant because, subsequent to a small
amount of corrosion, the alloys form a continuous and tenacious surface film enriched in the
corrosion resistant element. This is particularly the case with chromium where the
chromium forms a chromium oxide film. This film is normally invisible but it can be grown by
anodising andlor oxidising and then become sufficiently thick to appear tinted by light
diffraction. The film has a high electrochemical potential compared to the base material and
is less likely to corrode.
The corrosion resistance resulting from the presence of the surface film is termed passivity
and the film is termed the passive film. The passive film is not a static entity but is
constantly being reformed but at such a low rate that the material appears to be uncorroded.
If conditions are such that the surface film is preserved and can reform correctly then the
material will give long service. High levels of chloride and the other halides can prevent
local reformation of the film and corrosion occurs at these defective areas. Because the
normal chromium oxide film is cathodic to the anodic (corroding) areas a galvanic couple is
established.
The rate of corrosion at the anode will depend on the ratio of the cathodic and anodic areas.
If this area ratio is large then the continued corrosion may appear as pitting attack. The
effective area ratio of cathode to anode depends on the local conductivity of the water.
The pitting resistance number is a convenient method of comparing the corrosion resistance
of the CRAs. The number has no fully developed theoretical basis but is empirically proven.
The PREN is sometimes also called the pitting index and is calculated from:
where the symbols represent the weight percentages (%) of chromium, molybdenum, tungsten and
nitrogen.
CHECKLIST
Type of pipe
Steel making route
Identification of pipeline service conditions
Limitations on pipe steel chemistry
Limitations on longitudinal weld chemistry
Minimum yield strength (SMYS)
Upper strength limitation
Non-ductile transition temperature (NDTT)
Minimum acceptable average and minimum toughness
Toughness test temperature
Non-destructive testing, acceptance criteria, procedures for out-of-specification product
Hydrostatic testing, acceptance criteria, procedures for out-of-specification product
Wall thickness tolerance
Length tolerance
Ovality
Straightness
End finish: square, standard or special bevels
Internal cleanliness of the pipe
Provision of caps at pipe ends
Avoidance of jointers, split skelps, residual magnetism
inspection requirements, frequencies, reporting procedures
Performance tests required, special tests, acceptance criteria
Track record of fabricator
Warranties
Pre-qualification requirements, mill visits, complaints procedures
TABLES