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HEAT
HISTORY
18th Century
In the 18th century it was assumed that there was an invisible substance called caloric.
When objects got hot it was assumed that they gained caloric, therefore hot objects should
be heavier than cold objects, but there was no evidence to prove this, hence this theory was
untrue.
1842 J. P. Joules
He conducted a series of experiments that heat was not a material substance. He also
converted different types of energy into heat energy. He then measured the amount of
energy created and produce, and found that they where in a constant ratio he was the first to
conclude that heat was a form of energy.
Today
Today we believe that when an object gains heat, its molecules gain kinetic energy, and
move and vibrate faster. We also believe that heat cannot be created or destroyed, but
changed from one form to another.
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Heat can be transferred by three methods:
(i)
Conduction
(ii)
Convection
(iii) Radiation
Conduction
This is the flow of heat through a material, without the movement or flow of the material
itself. The experiment below demonstrates that there are materials which are good
conductors of heat (poor conductors are called insulators). We also realize all metals are
good conductors compared to others.
Convection
These are the flow of a liquid or gas caused by the change in density, in which the whole
medium moves and carries heat energy with it. If we observe the experiment on page
(diagram of convection) , we will observe purple streaks rising in the water above the
crystals, and being carried to the far side of the beaker. This flow of water is called
convection current.
What Causes Convection Currents?
The water at the bottom of the tank, close to heat source expands. As is expands it becomes
less dense than the cooler surrounding water, so it rises. It moves away from the heat
source and loses some of its heat energy to the surrounding and begins to cool. As it
becomes denser, it sinks back to the bottom of the tank.
Radiation
This is the transfer of heat energy by means of electromagnetic waves. Radiation can take
place without a material medium.
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Objects increase in size or expand, when they are heated, and contract when they are
cooled. They are three types of expansion and they are:
1.) Linear Expansion: objects increase in length when heated.
2.) Superficial Expansion: objects increase in area when heated.
3.) Cubical Expansion: objects increase in volume.
Bimetallic Strip
a.)
b.)
A bimetallic strip is made of two different metals, e.g. brass and iron, welded or riveted
together. When cold the double strip is straight, fig. (a).
As it is heated the brass expands more than the iron and so the brass forms the outside of a
curve, and the iron on the inside, fig. (b).
Bimetallic strips are used in thermo stats and many other mechanical switching circuits.
Expansion of Liquids
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When we first heat the round bottom flask, the liquid level drops, because glass is a poor
conductor by heat, so the glass flask expands and increase the inside volume. The liquid
which has not started to expand as yet drops to yet to fill the extra volume in the flask.
Once the liquid become heated it expands rapidly and spills over the top. This demonstrates
that cubical (volume) expansion of liquid is very large. The expansion of liquids which we
see is called apparent expansion; the real expansion is greater than what we observed,
because of expansion of liquids container which takes up some of the liquids expansion.
Expansion of Water
Most liquids contract as they cool and further contact when they reach their freezing point.
Water, however, contracts as it cools from 100C - 4C, and expands between 4C - 0C.
When a pond freezes over; the denser water (4C) remains at the bottom of the pond. The
less dense water 3C - 0C floats in layers above the denser water. The water on the surface
is frozen, but floats because it is less dense than water below it (this is because it increases
in volume). The density layers stop convection currents from spreading the heat. Since ice
is a poor conductor of heat, the top layer of ice on the pond acts as an insulator blanket and
reduces further heat loss. Aquatic animals and plants use this phenomenon to live in ponds
during the winter.
Heat flows from a body of high temperature to one of lower temperature. The thermometer
is used to measure temperature.
There are two scales:
(i)
Celsius Scale (C)
(ii)
Absolute/Kelvin Scale (K)
Celsius Scale
On this scale there is a lower fixed point which is called the ice point (temperature of
melting pure ice, 0C) and upper fixed point, called the steam point (temperature of steam
just above boiling water, 100C)
Kelvin Scale
This scale is used for temperatures which are colder than the freezing point of ice and
higher than the boiling point of water. The lowest possible temperature is called absolute 0
which also known as 0K which is -273C.
Examples:
C
- 273
273
50
323
100
373
Temperature Change
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Examples:
(a) Initial temperature:
Final temperature:
Temperature change (T):
50 C
110 C
60 C
323 K
383 K
60 K
80 C
10 C
-70 C
353 K
283 K
-70 K
[the negative sign (-) means that the object is lossing heat energy or is cooling]
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Heat Capacity =
C =
Units: J/C or
Heat Energy
Temperature Rise
E
T
J/K
c =
Units:
Heat Energy
Temperature rise Mass
E
M T
J/(kgC) or J/(kgK)
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E = mcT
[This formula is used to calculate the heat energy required to heat up a substance]
Substance
Water
4200
Aluminum (alloy)
880
Copper
380
Ice
2100
Nylon
1700
Glass
670
Lead
126
Marble
880
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Examples:
(i)
How many joules of heat are required to raise the temperature of 550 g of water
from 12oC to 18oC? (remember the specific heat of water is 4200 J/kg oC)
(ii)
(iii)
A 250 g sample of water with an initial temperature of 98.8 oC loses 7500 joules
of heat. What is the final temperature of the water?
(Remember, final temp = initial temp - change in temp and that specific heat
capacity of water 4200 J/kg oC)
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State Of Matter
GAS
Change of State
LIQUID
Change of State
SOLID
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Units: Joules (J)
Specific Latent Heat of Fusion ( )
The specific latent heat of fusion of a solid is the heat required to change 1kg of it, from a
solid to a liquid without any temperature change.
Units: J/kg
Heat Formulas
We now have two formulas to use to determine the heat energy:
(i)
E = mcT
(ii)
E = m
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Examples:
(i)
An ice lolly has a mass of 100g, if the specific latent heat of fusion of ice is
340 000J / kg; calculate the amount of heat needed to melt the lolly.
(ii)
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Electrical Method
We set up the experiment as shown in the diagram above. We then determine the mass of
the material. We use a thermometer and measure the initial temperature of the material.
Next we supply a known amount of energy to the material and we measure the temperature
rise in the material.
We use a heater of known power supply and use the heater for approximately five (5)
minutes. We can use the formula below to determine how much energy was sent to the
material.
heat energy supplied = power of heater time
E = Pt
We the find the temperature change of the material by using
temperature change (T) = initial temperature final temperature
T = T final T initial
Final we use the formula below to calculate the specific heat capacity of the material
specific heat capacity =
c =
Pt
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m T
Method of Mixtures
This is the most common practical used to find the specific heat capacities of solids and
liquids. We usually add a hot solid (or a hot liquid) of known temperature to a cold liquid
and determine the final temperature.
We assume that all the heat from the hot substance goes to the cooler one if we can reduce
heat loss by using insulation.
We then use the formula below to determine the specific heat capacity of the substance
heat loss by solid = heat gained by liquid
solid
liquid
liquid
(T final T liquid )
Where:
m solid = mass of the solid
c solid = specific heat capacity of solid
m liquid = mass of liquid
c liquid = specific heat capacity of liquid
T solid = initial temperature of solid
T liquid = initial temperature of liquid
T final = final temperature of mixture
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Example:
Find the specific heat capacity (c) of aluminum by the following procedure below:
(i)
(ii)
(iii)
(iv)
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