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Product type
: Solid.
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Fertilizer. Manufacture of chemical products. Manufacture of specialty fertilizers.
Uses advised against
Reason
Not approved
Supplier's details
: Agrium Wholesale
13131 Lake Fraser Drive, S.E.
Calgary, Alberta, Canada, T2J 7E8
Agrium U.S. Inc.
Suite 1700, 4582 South Ulster St.
Denver, Colorado, U.S.A., 80237
Emergency telephone
number (with hours of
operation)
Classification of the
substance or mixture
: While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe
handling and proper use of the product. This SDS should be retained and available for
employees and other users of this product.
: Not classified.
Signal word
: No signal word.
: No known significant effects or critical hazards.
Hazard statements
NotApplicable.
NoAplicable.
Nonapplicable.
Precautionary statements
General
Prevention
Response
Storage
Disposal
Hazards not otherwise
classified
Date of issue/Date of revision
: Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
: Not applicable.
: Not applicable.
: Not applicable.
: Not applicable.
: None known.
: 4/21/2015.
: 4/20/2015.
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: Substance
Ingredient name
CAS number
Potassium chloride
Sodium chloride
>95
>3
7447-40-7
7647-14-5
: Wash out mouth with water. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Never give anything by mouth to an
unconscious person. Stop if the exposed person feels sick as vomiting may be
dangerous. Do not induce vomiting unless directed to do so by medical personnel. If
vomiting occurs, the head should be kept low so that vomit does not enter the lungs.
Get medical attention if symptoms occur.
Skin contact
Ingestion
: No action shall be taken involving any personal risk or without suitable training.
: 4/21/2015.
: 4/20/2015.
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: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Environmental precautions
: If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
: Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.
Advice on general
occupational hygiene
: Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. See also
Section 8 for additional information on hygiene measures.
: 4/21/2015.
: 4/20/2015.
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Exposure limits
Potash
Appropriate engineering
controls
Environmental exposure
controls
: Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation.
Eye/face protection
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Wash
contaminated clothing before reusing.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: sealed eyewear or safety glasses
with side-shields.
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
: The personal protective equipment required varies, depending upon your risk
assessment. Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical products if a risk
assessment indicates this is necessary.
: No special protective clothing is required.
: Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
: Use a properly fitted, particulate filter respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product and the safe working
limits of the selected respirator.
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: 4/20/2015.
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: Not applicable.
: Not applicable.
Viscosity
: Not applicable.
Auto-ignition temperature
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: No specific data.
Incompatible materials
: No specific data.
Hazardous decomposition
products
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Result
Species
Potassium chloride
Sodium chloride
LD50 Oral
LD50 Oral
Rat
Rat
Conclusion/Summary
Dose
2600 mg/kg
3000 mg/kg
Exposure
-
Irritation/Corrosion
Conclusion/Summary
Skin
Eyes
Respiratory
Sensitization
Conclusion/Summary
Skin
Respiratory
Mutagenicity
Product/ingredient name
Test
Experiment
Result
Potassium chloride
Potassium chloride
Subject: Bacteria
Experiment: In vivo
Subject: Mammalian-Animal
Cell: Somatic
Negative
Negative
Conclusion/Summary
Carcinogenicity
Product/ingredient name
Result
Species
Dose
Exposure
Potassium chloride
Sodium chloride
Rat - Male
Rat - Male
1820 mg/kg
-
Conclusion/Summary
Reproductive toxicity
Conclusion/Summary
Teratogenicity
Product/ingredient name
Result
Species
Dose
Exposure
Potassium chloride
Negative - Oral
Rat - Female
310 mg/m
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: 4/20/2015.
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: Inorganic salt. Prolonged or repeated exposure may dry the skin, causing irritation.
: May cause irritation of the digestive tract with accompanying nausea, vomiting and
diarrhea.
Ingestion
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
: Not available.
effects
Potential delayed effects
: Not available.
Long term exposure
Potential immediate
effects
Potential delayed effects
: Not available.
: Not available.
Result
Species
Dose
Exposure
Potassium chloride
Sodium chloride
Rat - Male
Rat - Male
1820 mg/kg
2533 mg/kg
2 years
Conclusion/Summary
General
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
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: 4/20/2015.
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Result
Species
Exposure
Potassium chloride
96 hours
72 hours
Conclusion/Summary
48 hours
48 hours
96 hours
96 hours
72 hours
48 hours
96 hours
48 hours
96 hours
3 weeks
96 hours
21 days
8 weeks
Aquatic half-life
Photolysis
Biodegradability
Potassium chloride
Readily
Bioaccumulative potential
Product/ingredient name
LogPow
BCF
Potential
Potassium chloride
<1
low
Mobility in soil
Soil/water partition
coefficient (KOC)
Other adverse effects
: Not available.
: 4/21/2015.
: 4/20/2015.
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TDG
Classification
Mexico
Classification
ADR/RID
IMDG
IATA
UN number
Not regulated.
Not regulated.
Not regulated.
Not regulated.
Not regulated.
Not regulated.
UN proper
shipping name
Transport
hazard class(es)
Packing group
Environmental
hazards
No.
No.
No.
No.
No.
No.
Additional
information
: Transport within users premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
: Not a pollutant.
: Not listed
: Not listed
: Not listed
: Not listed
SARA 304 RQ
: Not listed
: Not applicable.
SARA 311/312
Classification
Composition/information on ingredients
Name
Fire
Sudden
hazard release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Potassium chloride
100
No.
No.
No.
No.
No.
State regulations
Massachusetts
New York
Date of issue/Date of revision
: 4/20/2015.
Version
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New Jersey
Pennsylvania
California Prop. 65
Not listed.
International regulations
International lists
National inventory
Australia
Canada
China
Europe
Japan
Malaysia
Republic of Korea
Taiwan
: Not determined.
New Zealand
Philippines
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA).
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Flammability
0
Health
Instability/Reactivity
Special
Copyright National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify
chemicals does so at their own risk.
History
Date of issue/Date of
revision
: 4/21/2015.
: 4/20/2015.
Version
: 1
Key to abbreviations
: 4/21/2015.
: 4/20/2015.
Version
:1
9/10
: 4/21/2015.
: 4/20/2015.
Version
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