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Narayana IIT Academy

18-10-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2011_P2)_RPTA-9_Key &Sols

NARAYANA IIT ACADEMY


INDIA
Sec: Sr.IIT-IZ-CO-SPARK
Time: 3 Hours

JEEADVANCE
2011-P2-Model

Date: 18-10-15
Max Marks: 240

KEY & SOLUTIONS


CHEMISTRY
1
D
C
7
2
13
19 A-PT,
B-PS,
C-PQ,
D-PR

PHYSICS
21
D
27
C
33
1
39 A-S;
B-QT;
C-R;
D-PT

2
8

A
B

3
14
15
20 A-PQST,

D
A

4
10

16

B
BCD

5
11

17

CD

6
12

18

B-PQR,
C-PS,
D-PS

22
C
23
28
C
29
34
9
35
40 A-PRT;

A
AD
7

24
30
36

C
AD
5

25
31
37

B
AC
9

26
32
38

B
BC
5

A
BC
1

44
B
45
50 ABCD 51
56
4
57

C
BD
1

46
52
58

B
AD
3

B-QS;
C-Q;
D-S;

MATHEMATICS
41
B
42
C
47
C
48
D
53
2
54
2
59 A-R,
60 A-R,
B-P,
C-PQR,
D-S

3
9

43
49
55

B-RS,
C-RS,
D-PR

Sr.IIT-IZ-CO-SPARK_P2_Solutions

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18-10-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2011_P2)_RPTA-9_Key &Sols

Narayana IIT Academy

CHEMISTRY
1.

Due to hydrogen bond it cant liberate H 2


O

O S S2
2.

O
..
O:

:O
..
N
..

..
O:

:O
. .:

3.

..
N
. . O
..
. . N

Asymm. form
Lone pair is eight

..
O:

Symm.form

O S S S S O

5.

X is S4O62 :

6.

SiF4 cant under go complete hydrolysis :


SiF4 H 2O Si OH 4 HF

SiF4 2HF H 2SiF6

7.

X is C3O2 : O C C C O .

12.

No carbon is sp 2
O3 can act as bleaching in dry state .Moist SO 2 and Cl2 moist acts as bleaching agent
O

NaO P O P O P ONa
ONa

ONa

ONa

14.

X Na 5 P3O10

16.

Cu ,S , C , KBr , KI are oxidized by conc .H 2SO 4

17.

PH3 forms phosphonium salt only with strong anhydrous acid.

Sr.IIT-IZ-CO-SPARK_P2_Solutions

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18-10-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2011_P2)_RPTA-9_Key &Sols

Narayana IIT Academy

PHYSICS
21.
22.
23.
24.
25.
26.
27.
28.
29.

conceptual
conceptual
conceptual
conceptual
conceptual
conceptual
conceptual
conceptual
Corresponding displacement
wave
D

B
C

Aliter:
x
wt
v
x
s - s 0 sin w t
v

ds
x
v
S0 W cos w t
dt
v
V mirrors p
At A & C max imum slope
max speed

p = p0 cos

A Slope Ve
V Ve

C Slope +Ve
Vis Ve

B,D slope zero


V=0
30.
31.
32.

conceptual
conceptual
conceptual

33.

p02
Independent of wavelength.
P
2 v

34.

1
2

x=9

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I A

35.

18-10-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2011_P2)_RPTA-9_Key &Sols

I 1 A12

25
I 5 A52
A1
5
2
7.5 3.5
A sin
60 cm
A5

36.

A 3.5 2 4.95 5

37.

Let the Time when the race car emitted a pulse corresponding to 1.5 kHz be t,
Then the time it reaches the observer is equal to
1000
t

1
10 t 2

1000
2

10
vs
vs

5t 2
10
vs
vs
1.5
v s 10t
t

Solving for velocity of sound we get vs=360 m/s


38.
39.
40.

B,C,D,E,F are all either at rest of moving down.


Conceptual
displacement wave at
t = t3
P
C

corresponding
displacement
wave

A
displacement is
towards
right (+ve)

displacement is towards
left (-ve)

At t = t1 particle is at extreme hence speed is zero


At t = t2 particle is at mean position hence speed is maximum
A is moving towards Ve (left)
C is moving towards +Ve (right)
t = t3 displacement of C is +Ve & it is increasing V is +Ve towards right.
Displacement of A is ve

Sr.IIT-IZ-CO-SPARK_P2_Solutions

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18-10-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2011_P2)_RPTA-9_Key &Sols

Narayana IIT Academy

MATHEMATICS
41.


a c . bd

22
2y 2 4y 9
3
4x 2 16x 25
3

2y2 4y 9 4x 2 16x 25 63 . This is possible only when y 1, x 2

42.

Let the new plane is (3x 8y 15z 91) (5x 17y 29z 2) 0 . It should be same as
x y z k . Hence

3 5 8 17 15 29 91 2
1

; k 184 .
1
1
1
k
2

43.

cos

44.

3 1
NP AB AF
4
2

45.

Direction ratios are proportional to 2, 7, 5

49.

We have f ' g; g ' h; h ' f hence a f i g j h k; b g i h j f k; c h i f j g k

Consider A f 3 g3 h 3 3fgh we can see that

50.

dA
0 . We can see that A=1.
dx

a 4 1 x 0
0 2 3 y 1


3 0 b z 2
a 4
0 2

3 4b 20 2 6a ab 3, 3 4a 12
2 0 6

3 30 2ab, 1 1

3 0 b

If ab 15 system has unique solution


If ab = 15, 1

60
20, 2 6a 18, 3 4a 12
a

For a = 3, 1 2 3 0
For a 3 or b 5, at least one of 1 , 2 , 3 is non zero
51.

Take i, j as sides of right triangle.

52.


AB AC AD a . AB AC b; AB AD c
1 1


AB.a 3 AC.a AD.a 3 ; AB AC a b ; AB AD a c
3
3

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53.

We have

18-10-15_Sr.IIT-IZ-CO-SPARK_JEE-ADV_(2011_P2)_RPTA-9_Key &Sols
1


AD.BC AD BC 4d.(c b) d c b d b as the triangle ABC
4

is

equilateral.

This gives 4 3 b 6 b cos 6 b cos

1
4

32
9 5 . (2mi j k).(i 2mj 3k) | 4m 3 | 2
m
32
4 4
9

)
Take r x y z(
3

54.

56.
57.

Direction ratios of the line of intersection of 2x y z 0 and x y 2z 0 are 1, 3,1

58.

P(3, 5, 2)

59.

We have ab bc ca 1;(a b) 2 (b c) 2 (c a) 2 1 .
(a b c) 2

OP

60.

A)

OQ

This gives

3
.
2

Hence

3
7
3
2
2 . We know, if x y z 0; x 2 y 2 z 2 1 then 9xyz
2
2
2

OR

a a ab 12
2

7
2

x y x y a b 32 x y a b and


xya

then

1 1
x a (a b)
2
3

then

1
4p 5
q

B) 2a 3b r 4c 3b 2c r 4a 2c 4a r 3b 48[a b c] r

16( 2)
[a b c] r
5

implies 5, 3


c.c 36


b b
C) Given a c, b c c p(a b) . We have (a b) (b c)
p
p

Hence m

6
14p

We have c p(a b) 36 p 2 9.25.

224
3
p
this gives m 4
9.25
2 14

D) pq=6, p+q=r+1=5 then the value of 3p 2q is 0 or 5

Sr.IIT-IZ-CO-SPARK_P2_Solutions

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