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LMN

: MATHEMATICS, PHYSICS & CHEMISTRY


1 : , U

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PART A MATHEMATICS
1.

A complex number z is said to be

1.

unimodular if ?z?51. Suppose z1 and z2


z1 2 2 z2
are complex numbers such that
2 2 z1 z2

z1 2 2 z2
2 2 z1 z2

z2

, z1 S

is unimodular and z2 is not unimodular.


Then the point z1 lies on a :

2.

z
?z?51 z1 z2

(1)

circle of radius

(2)

straight line parallel to x-axis.

(2)

U
x- U U U

(3)

straight line parallel to y-axis.

(3)

y-

(4)

circle of radius 2.

(4)

2.

(1)

U U U
U

at (1, 1) :

x 2 12xy23y 250

(1)

(1)

U Z

The normal to the curve, x212xy23y250,

2.

meets the curve again in the fourth

(1, 1)

quadrant.
(2)

does not meet the curve again.

(2)

(3)

meets the curve again in the second

(3)

U m Z

(4)

U Z

quadrant.
(4)

meets the curve again in the third


quadrant.

3.

The sum of first 9 terms of the series

3.

13 1 2 3
13 1 2 3 1 3 3
13
1
1
1 .... is :
1
113
11 31 5

13 1 2 3
13 1 2 3 1 3 3
13
1
1
1 ....
1
113
11 31 5

9
(1)

192

(1)

192

(2)

71

(2)

71

(3)

96

(3)

96

(4)

142

(4)

142

C/Page 2

SPACE FOR ROUGH WORK /

4.

Let f (x) be a polynomial of degree four

4.

f (x)


U U

having extreme values at x51 and x52.

x51

f ( x )

If lim 1 1
5 3 , then f (2) is equal
x 0
x2

f ( x )

lim 1 1
53
x 0
x2

x52

, f (2) UU

to :

5.

(1)

(1)

(2)

28

(2)

28

(3)

24

(3)

24

(4)

(4)

The negation of ~ s (~ r s ) is equivalent

5.

~ s (~ r s )

to :

6.

(1)

sr

(1)

sr

(2)

s~r

(2)

s~r

(3)

s (r ~ s)

(3)

s (r ~ s)

(4)

s (r ~ s)

(4)

s (r ~ s)

1 2 2

If A 5 2 1 22 is a matrix satisfying
a 2 b

6.

1 2 2
A 5 2 1 22
a 2 b

(a, b) is equal to :

U AAT59I, cU U ,
I, 333 ,
(a, b)

(1)

(22, 21)

(1)

(22, 21)

(2)

(2, 21)

(2)

(2, 21)

(3)

(22, 1)

(3)

(22, 1)

(4)

(2, 1)

(4)

(2, 1)

the equation AA T 59I, where I is 333


identity matrix, then the ordered pair

C/Page 3

SPACE FOR ROUGH WORK /

7.

The integral

dx

x 2 ( x 4 1 1)3 4

equals :

7.

(1)

x 41 1 4
2
1c
x4

(2)

x4 1 1 4

1c
x4

(3)

( x 411) 4 1 c

(4)

2( x 4 1 1) 4 1 c

9.

x ( x 1 1)

UU

(1)

x 41 1 4
2
1c
x4

(2)

x4 1 1 4

1c
x4

(3)

( x 411) 4 1 c

(4)

2( x 4 1 1) 4 1 c

8.

dx
2

numbers l and n (l, n > 1) and G1, G2 and


G3 are three geometric means between l

S l n
(l, n > 1) U (A.M.) m U l
n U (G.M.) G1, G2

and n, then G14 1 2G24 1 G 34 equals.

G3 ,

If m is the A.M. of two distinct real

8.

(1)

4 l2m2n2

(1)

4 l2m2n2

(2)

4 l2mn

(2)

4 l2mn

(3)

4 lm2n

(3)

4 lm2n

(4)

4 lmn2

(4)

4 lmn2

Let y(x) be the solution of the differential

9.

G1 1 2G2 1 G3

UU

equation

dy
1 y 5 2 x log x , ( x / 1).
dx
Then y(e) is equal to :

(1)

2e

(1)

2e

(2)

(2)

(3)

(3)

(4)

(4)

( x log x )

C/Page 4

SPACE FOR ROUGH WORK /

dy
1 y 5 2 x log x , ( x / 1)
dx
y(x) , y(e) UU

( x log x )

10.

The number of integers greater than 6,000

10.

that can be formed, using the digits 3, 5, 6,

3, 5, 6, 7 8 , U,
6,000 Z

7 and 8, without repetition, is :

11.

(1)

72

(1)

72

(2)

216

(2)

216

(3)

192

(3)

192

(4)

120

(4)

120

The number of points, having both

11.

co-ordinates as integers, that lie in the


interior of the triangle with vertices (0, 0),

, (0, 0), (0, 41) (41, 0) ,


U S
Z ,

(0, 41) and (41, 0), is :

12.

(1)

780

(1)

780

(2)

901

(2)

901

(3)

861

(3)

861

(4)

820

(4)

820

Let a and b be the roots of equation

12.

x 2 26x2250. If a n 5a n 2b n , for n/1,


a 2 2a8
then the value of 10
is equal to :
2a9

a b m U x226x2250
n/1 , an5an2bn ,
a10 2 2a8
2a9

(1)

23

(1)

23

(2)

(2)

(3)

26

(3)

26

(4)

(4)

C/Page 5

SPACE FOR ROUGH WORK /

13.

Let

13.

2x
tan21 y 5 tan21 x 1 tan21
1 2 x2

where ? x ? <

2x
tan21 y 5 tan21 x 1 tan21
1 2 x2

1
. Then a value of y is :
3

3 x 1 x3

(1)

(1)

1 1 3 x2

3 x 2 x3

(2)

(2)

1 2 3 x2

3 x 1 x3

(3)

(3)

1 2 3 x2

3 x 2 x3

(4)

14.

(4)

1 1 3 x2

The distance of the point (1, 0, 2) from the


point

of

intersection

of

the

14.

line

?x? <

1 1 3 x2

3 x 2 x3
1 2 3 x2

3 x 1 x3
1 2 3 x2

3 x 2 x3
1 1 3 x2

y 11
x 22
z 22
5
5
3
4
12
x2y1z516 U ,

(1)

13

(1)

13

(2)

2 14

(2)

2 14

(3)

(3)

(4)

3 21

(4)

3 21

SPACE FOR ROUGH WORK /

, y

3 x 1 x3

y 11
x 22
z 22
5
5
and the plane
3
4
12
x2y1z516, is :

C/Page 6

1
3


(1, 0, 2)

15.

The area (in sq. units) of the region

15.

described by

{(x, y) : y2[ 2x y / 4x 2 1} mU

( )

{(x, y) : y2 [ 2x and y / 4x 2 1} is :

16.

(1)

9
32

(1)

9
32

(2)

7
32

(2)

7
32

(3)

5
64

(3)

5
64

(4)

15
64

(4)

15
64

Let O be the vertex and Q be any point on

16.

the parabola, x258y. If the point P divides


the line segment OQ internally in the ratio
1 : 3, then the locus of P is :

17.

U x258y O U
Q P, U U OQ
1 : 3 U U , P

(1)

x 2 52y

(1)

x 2 52y

(2)

x 2 5y

(2)

x 2 5y

(3)

y 2 5x

(3)

y 2 5x

(4)

y 2 52x

(4)

y 2 52x

The mean of the data set comprising of 16

17.

observations is 16. If one of the observation


valued 16 is deleted and three new
observations valued 3, 4 and 5 are added

16
16 , U U, 3
3, 4 5 ,
,
16

to the data, then the mean of the resultant


data, is :
(1)

14.0

(1)

14.0

(2)

16.8

(2)

16.8

(3)

16.0

(3)

16.0

(4)

15.8

(4)

15.8

C/Page 7

SPACE FOR ROUGH WORK /

18.

The area (in sq. units) of the quadrilateral

18.

y2
x2
1
51
9
5

U U

S U mU
( )

formed by the tangents at the end points


of the latera recta to the ellipse

y2
x2
1
5 1 , is :
9
5

19.

(1)

27

(1)

27

(2)

27
4

(2)

27
4

(3)

18

(3)

18

(4)

27
2

(4)

27
2

parallel to the plane, x13y16z51, is :

U 2x25y1z53, x1y14z55 cU
U , x13y16z51
U , U

(1)

2x16y112z5213

(1)

2x16y112z5213

(2)

2x16y112z513

(2)

2x16y112z513

(3)

x13y16z527

(3)

x13y16z527

(4)

x13y16z57

(4)

x13y16z57

The equation of the plane containing the

19.

line 2x25y1z53; x1y14z55, and

20.

The number of common tangents to the


circles

x 2 1y 2 24x26y21250

x21y216x118y12650,

20.

and

is :

x21y216x118y12650

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

C/Page 8

SPACE FOR ROUGH WORK /

cU S

x21y224x26y21250

21.

system of linear equations :

, U
U

2x 122x21x 35lx 1

2x 122x21x 35lx 1

2x112x2

2x112x2

The set of all values of l for which the

21.

2x 123x 212x 35lx 2

2x 123x 212x 35lx 2

5lx3

22.

contains more than two elements.

(2)

is an empty set.

(3)

is a singleton.

(4)

contains two elements.

If 12 identical balls are to be placed in 3

5lx3

U ,
(1)
(2) U
(3)
(4)

has a non-trivial solution,


(1)

22.

identical boxes, then the probability that


one of the boxes contains exactly 3 balls

12 , 3 U
, U 3

is :

23.

11

(1)

1
22
3

(2)

55 2 11

3 3

(3)

2
55
3

(4)

1
220
3

50

(3)

2
55
3

(4)

1
220
3

23.

(1 2 2 x )

10

50

12

m U

is :

(1)

1 50
2 11
2

(2)

1 50
3 11
2

(3)

1 50
3
2

(4)

1 50
3 21
2

(1)

1 50
2 11
2

(2)

1 50
3 11
2

(3)

1 50
3
2

(4)

1 50
3 21
2

C/Page 9

(2)

55 2 11

3 3

12

of x in the binomial expansion of

(1 2 2 x )

(1)

10

The sum of coefficients of integral powers

11

1
22
3

( )
(

)
SPACE FOR ROUGH WORK /

( )
(

24.

24.

The integral
4

log x 2

log x 2 1 log (36 2 12 x 1 x 2 )

26.

is equal to :

UU

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

If the function.

25.

k x 1 1 , 0 [ x [ 3
g( x ) 5
m x 1 2 , 3 < x [ 5

k x 1 1 , 0 [ x [ 3
g( x ) 5
m x 1 2 , 3 < x [ 5

is differentiable, then the value of k1m is :

, k1m

(1)

(1)

(2)

(2)

(3)

16
5

(3)

16
5

(4)

10
3

(4)

10
3

(2, 3)

Locus of the image of the point (2, 3) in

26.

(2x23y14)1k (x22y13)50, k e R

the line (2x23y14)1k (x22y13)50,


k e R, is a :

(1)

(1)
(2)

circle of radius

(3)

3.
straight line parallel to x-axis.
straight line parallel to y-axis.

(4)

circle of radius

(2)

27.

log x 2

log x 2 1 log (36 2 12 x 1 x 2 ) d x

dx

25.

lim

x0

is equal to :

27.

lim

x0

( 1 2 cos 2 x )( 3 1 cos x ) UU
x tan 4 x

(2)

(3)

(4)

(2)
(3)
(4)
C/Page 10

(4)

1
2
4

1
2
4

(1)

2.

( 1 2 cos 2 x )( 3 1 cos x )
x tan 4 x

(3)


x- U U
y- U U
2
3

(1)

SPACE FOR ROUGH WORK /

28.

If the angles of elevation of the top of a

28.

tower from three collinear points A, B and


C, on a line leading to the foot of the
tower, are 308, 458 and 608 respectively,

U A, B C, U U
S U ,
U U
308, 458 608 , AB : BC

then the ratio, AB : BC, is :


(1)

2:3

3:1

(2)

3:1

(3)

3: 2

(3)

3: 2

(4)

1: 3

1: 3

having at least three elements is :

A B U
, A3B
,
,

(1)

510

(1)

510

(2)

219

(2)

219

(3)

256

(3)

256

(4)

275

(4)

275

Let A and B be two sets containing four

29.

and two elements respectively. Then the


number of subsets of the set A3B, each

30.

2:3

(2)

(4)
29.

(1)

Let a , b and c be three non-zero vectors

30.

such that no two of them are collinear and

( a 3 b )3 c 5

1
b c a . If u is the
3

angle between vectors b and c , then a


value of sin u is :

a , b c U

U

( a 3 b )3 c 5

22 3
3

(1)

22 3
3

(2)

2 2
3

(2)

2 2
3

(3)

2 2
3

(3)

2 2
3

(4)

2
3

(4)

2
3

SPACE FOR ROUGH WORK /

u , sin u

(1)

C/Page 11

1
b c a
3

PART B PHYSICS
31.

31.

resistor is :

(1)

0.13 A, from P to Q

(1)

0.13 A, P

(2)

1.3 A, from P to Q

(2)

1.3 A, P

Q U

(3)

0A

(3)

0 () A

(4)

0.13 A, from Q to P

(4)

0.13 A, Q

In the circuit shown, the current in the 1V

32.

Distance of the centre of mass of a solid

32.

uniform cone from its vertex is z0. If the


radius of its base is R and its height is h
then z0 is equal to :

3h 2
8R

(1)

3h 2
8R

(2)

h2
4R

(2)

h2
4R

(3)

3h
4

(3)

3h
4

(4)

5h
8

(4)

5h
8

SPACE FOR ROUGH WORK /

U
U z0 U
R h z0
UU ?

(1)

C/Page 12

1V U

33.

Match List - I (Fundamental Experiment)

33.

with List - II (its conclusion) and select


the correct option from the choices given

- I ( ) - II ( U)
() U

below the list :


List - I

34.

- I

List - II

(A)

Franck-Hertz
Experiment.

(i)

Particle nature
of light

(A)

(B)

Photo-electric
experiment.

(ii)

Discrete energy
levels of atom

(B)

(ii)

(C)

Wave nature of
Davison - Germer
(iii)
electron
Experiment.

(C)

U U

(iii)

(iv)

Structure of
atom

(i)

(iv)

- II


SU
U U

U U

(1)

(A) -(iv)

(B) - (iii)

(C) - (ii)

(1)

(A) -(iv)

(B) - (iii)

(C)- (ii)

(2)

(A) - (i)

(B) - (iv)

(C) - (iii)

(2)

(A) - (i)

(B) - (iv)

(C) - (iii)

(3)

(A) - (ii)

(B) - (iv)

(C) - (iii)

(3)

(A) - (ii)

(B) - (iv)

(C) - (iii)

(4)

(A) - (ii)

(B) - (i)

(C) - (iii)

(4)

(A) - (ii)

(B) - (i)

(C) - (iii)

The period of oscillation of a simple


pendulum is T 5 2p

34.

L
. Measured value
g

of L is 20.0 cm known to 1 mm accuracy


and time for 100 oscillations of the
pendulum is found to be 90 s using a wrist

U ,
L

20.0 cm

the determination of g is :
(1)

5%

(1)

5%

(2)

2%

(2)

2%

(3)

3%

(3)

3%

(4)

1%

(4)

1%

SPACE FOR ROUGH WORK /

L
g

100
90 s , 1s ,
g U
1 mm

watch of 1s resolution. The accuracy in

C/Page 13

T 5 2p

35.

the diode is :

U ..U. ( UU)
0.1 U U, U
UU 1 m U U, l

(1)

7.75 V/m

(1)

7.75 V/m

(2)

1.73 V/m

(2)

1.73 V/m

(3)

2.45 V/m

(3)

2.45 V/m

(4)

5.48 V/m

(4)

5.48 V/m

A red LED emits light at 0.1 watt uniformly

35.

around it. The amplitude of the electric


field of the light at a distance of 1 m from

36.

and are not to scale)

U , C 1mF 3mF
U , 2mF U U Q2
U C M Q2
? (
S U U S U )

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

In the given circuit, charge Q2 on the 2mF


capacitor changes as C is varied from 1mF

36.

to 3mF. Q2 as a function of C is given


properly by : (figures are drawn schematically

C/Page 14

SPACE FOR ROUGH WORK /

37.

37.

U I U U
L lU U
mU U
u S , U S
U U
l g L U , I

Two long current carrying thin wires, both


with current I, are held by insulating
threads of length L and are in equilibrium
as shown in the figure, with threads
making an angle u with the vertical. If
wires have mass l per unit length then the
value of I is :
(g5gravitational acceleration)

plgL
tan u
m0

(1)

38.

(2)

sinu

(3)

2sinu

(4)

plgL
m0 cosu
plgL
m0 cosu

pgL
tan u
m0

A particle of mass m moving in the

plgL
tan u
m0

(1)

38.

x direction with speed 2v is hit by another


particle of mass 2m moving in the
y direction with speed v. If the collision is
perfectly inelastic, the percentage loss in

(2)

sinu

(3)

2sinu

(4)

x-

plgL
m0 cosu
plgL
m0 cosu

pgL
tan u
m0
2v m

, y- v 2m
, UU UU (UU)
S , UU U
()

the energy during the collision is close to :


(1)

62%

(1)

62%

(2)

44%

(2)

44%

(3)

50%

(3)

50%

(4)

56%

(4)

56%

C/Page 15

SPACE FOR ROUGH WORK /

39.

39.

U (U) A U B
U 20 N 100 N ,
F mU U U U
, A B 0.1
B U U 0.15 , U mU
B U

Given in the figure are two blocks A and B


of weight 20 N and 100 N, respectively.
These are being pressed against a wall by
a force F as shown. If the coefficient of
friction between the blocks is 0.1 and
between block B and the wall is 0.15, the
frictional force applied by the wall on block
B is :

40.

(1)

150 N

(1)

150 N

(2)

100 N

(2)

100 N

(3)

80 N

(3)

80 N

(4)

120 N

(4)

120 N

Consider an ideal gas confined in an

40.

isolated closed chamber. As the gas


undergoes an adiabatic expansion, the
average time of collision between
q

molecules increases as V , where V is the


volume of the gas. The value of q is :
Cp

g 5

Cv

( ),
() (U)
Lc U U, UU
() Vq U ,
V q :
Cp

g 5

Cv

(1)

g 21
2

(1)

g21
2

(2)

3g 1 5
6

(2)

3g 1 5
6

(3)

3g 2 5
6

(3)

3g 2 5
6

(4)

g 11
2

(4)

g11
2

C/Page 16

SPACE FOR ROUGH WORK /

41.

figures below :

5 cm U
() l U, I 5 12 A, U
U U U
(S) U

(a)

(a)

(b)

(b)

(c)

(c)

(d)

(d)

If there is a uniform magnetic field of

equilibrium and (ii) unstable equilibrium ?

0.3 T
, z l ,
, () (i) S
(ii) S , ?

(1)

(b) and (c), respectively

(1)

(b) (c)

(2)

(a) and (b), respectively

(2)

(a) (b)

(3)

(a) and (c), respectively

(3)

(a) (c)

(4)

(b) and (d), respectively

(4)

(b) (d)

A rectangular loop of sides 10 cm and

41.

5 cm carrying a current I of 12 A is placed


in different orientations as shown in the

0.3 T in the positive z direction, in which


orientations the loop would be in (i) stable

C/Page 17

SPACE FOR ROUGH WORK /

10 cm

42.

Consider a spherical shell of radius R at

42.

temperature T. The black body radiation


inside it can be considered as an ideal gas
of photons with internal energy per unit
volume

u5

U
; T4
V

and

() R U
T U c U U

U ,

pressure

1 U
p 5 . If the shell now undergoes
3 V

p5

1 U

3 V

u5

U
; T4
V

Lc

U , T R

an adiabatic expansion the relation


between T and R is :

43.

(1)

T;

(2)

(1)

T;

T ; e2R

(2)

T ; e2R

(3)

T ; e23R

(3)

T ; e23R

(4)

T;

(4)

T;

1
R

R3

1
R

hydrogen - like atom/ion :

U, U U /
S S
U

(1)

(1)


, S

(2)

h S

(3)

, S

(4)

, S
U U

As an electron makes a transition from an

43.

excited state to the ground state of a

kinetic energy and total energy


decrease but potential energy
increases

(2)

its kinetic energy increases but


potential energy and total energy
decrease

(3)

kinetic energy, potential energy and


total energy decrease

(4)

kinetic energy decreases, potential


energy increases but total energy
remains same

C/Page 18

SPACE FOR ROUGH WORK /

44.

that as it travels, the light beam :

c U , - U,
U -
, -U-
U , h
U ,
-U

(1)

bends upwards

(1)

U U

(2)

becomes narrower

(2)

()

(3)

goes horizontally without any

(3)

,
U

(4)

On a hot summer night, the refractive

44.

index of air is smallest near the ground and


increases with height from the ground.
When a light beam is directed horizontally,
the Huygens principle leads us to conclude

deflection
(4)

45.

bends downwards

From a solid sphere of mass M and radius


R
R, a spherical portion of radius
is
2
removed, as shown in the figure. Taking

45.

gravitational potential V50 at r5:, the


potential at the centre of the cavity thus
formed is :
(G5 gravitational constant)

U
R

2 2GM
R

(1)

2 2GM
R

(2)

2 GM
2R

(2)

2 GM
2R

(3)

2 GM
R

(3)

2 GM
R

(4)

2 2GM
3R

(4)

2 2GM
3R

SPACE FOR ROUGH WORK /

, U
2
U U r5:() U
L V (V50)
, U UU (U) U,
L
(G5 L SU )

(1)

C/Page 19

46.

Monochromatic light is incident on a glass

46.

prism of angle A. If the refractive index of


the material of the prism is m, a ray,
incident at an angle u, on the face AB
would get transmitted through the face AC

A U
,
m , AB
U, u U,
AC U

of the prism provided :

(1)

1
u < cos21 m sin A 1 sin21
m

(1)

1
u < cos21 m sin A 1 sin21
m

(2)

1
u > sin21 m sin A 2 sin21
m

(2)

1
u > sin21 m sin A 2 sin21
m

(3)

1
u < sin21 m sin A 2 sin21
m

(3)

1
u < sin21 m sin A 2 sin21

(4)

1
u > cos21 m sin A 1 sin21
m

(4)

1
u > cos21 m sin A 1 sin21
m

C/Page 20

SPACE FOR ROUGH WORK /

47.

Two stones are thrown up simultaneously

47.

from the edge of a cliff 240 m high with


initial speed of 10 m/s and 40 m/s
respectively. Which of the following graph
best represents the time variation of
relative position of the second stone with

240 m U U ,
U U U ,
U 10 m/s 40 m/s , ,
() U
U U S U
(U) ?

respect to the first ?


(Assume stones do not rebound after
hitting the ground and neglect air
resistance, take g510 m/s2)

( , U UU
U U U U
, g510 m/s2)

scale)

( S U U S
U )

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

(The figures are schematic and not drawn to

C/Page 21

SPACE FOR ROUGH WORK /

48.

(graphs are schematic and not drawn to scale)

U , S d
U S d
S
() ?
( S U U S
U )

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

For a simple pendulum, a graph is plotted

48.

between its kinetic energy (KE) and


potential

energy

(PE)

against

its

displacement d. Which one of the


following represents these correctly ?

49.

A train is moving on a straight track with

49.

speed 20 ms21. It is blowing its whistle at


the frequency of 1000 Hz. The percentage
change in the frequency heard by a person
standing near the track as the train passes
him is (speed of sound5320 ms21) close
to :

U (U) UU U 20 ms21
U U U
1000 Hz
320 ms21 , UU U
U U U, mU
U U

(1)

24%

(1)

24%

(2)

6%

(2)

6%

(3)

12%

(3)

12%

(4)

18%

(4)

18%

C/Page 22

SPACE FOR ROUGH WORK /

50.

An LCR circuit is equivalent to a damped

50.

pendulum. In an LCR circuit the capacitor


is charged to Q0 and then connected to
the L and R as shown below :

If a student plots graphs of the square of

2
maximum charge ( QMax
) on the capacitor

with time(t) for two different values L1 and

L2 (L1>L2) of L then which of the following

represents this graph correctly ? (plots are


schematic and not drawn to scale)

(1)

LCR U U
Q0 , U U U
U L R

l L , , L1 L2
(L 1 >L 2 ) , t U U
2
QMax

?
(U S U S U
)

(1)

(2)

(2)

(3)

(3)

(4)

C/Page 23

LCR (..U) U

(4)

SPACE FOR ROUGH WORK /

51.

A solid body of constant heat capacity

51.

1 J/8C is being heated by keeping it in


contact with reservoirs in two ways :
(i)

Sequentially keeping in contact with


2 reservoirs such that each reservoir
supplies same amount of heat.

(ii)

Sequentially keeping in contact with


8 reservoirs such that each reservoir
supplies same amount of heat.

In both the cases body is brought from


initial temperature 1008C to final
temperature 2008C. Entropy change of the

U U (S) SU c U
1 J/8C c (c UU)
UU U ,
(i)
M 2 c
U UU c
c ,
(ii) M 8 c
U UU c
c ,
S U U 1008C
2008C , S U
U U ,

body in the two cases respectively is :

52.

(1)

2ln2, 8ln2

(1)

2ln2, 8ln2

(2)

ln2, 4ln2

(2)

ln2, 4ln2

(3)

ln2, ln2

(3)

ln2, ln2

(4)

ln2, 2ln2

(4)

ln2, 2ln2

An inductor (L50.03H) and a resistor

52.

(R50.15 kV) are connected in series to a


battery of 15V EMF in a circuit shown
below. The key K1 has been kept closed
for a long time. Then at t50, K1 is opened

and key K 2 is closed simultaneously.


At t51ms, the current in the circuit will
be : (e5@150)

U , U (L50.03H)
U (R50.15 kV) 15V l
(..) UU
K1 U
t50 U, K1 U
, K2 t51ms
U, U l U (e5@150)

(1)

0.67 mA

(1)

0.67 mA

(2)

100 mA

(2)

100 mA

(3)

67 mA

(3)

67 mA

(4)

6.7 mA

(4)

6.7 mA

C/Page 24

SPACE FOR ROUGH WORK /

53.

R has potential V0 (measured with respect

U
cU V0 (: )

equipotential surfaces with potentials

A uniformly charged solid sphere of radius

53.

to :) on its surface. For this sphere the

3V0 5V0 3V0


,
,
2
4
4

V0
4

V
3V0 5V0 3V0
and 0 have radius R1,
,
,
4
2
4
4
R2, R3 and R4 respectively. Then

c U ,
R1, R2, R3 R4 ,

(1)

(1)

(2)
(3)
(4)
54.

2R < R4
R150 and R2 > (R42R3)
R1 0 and (R22R1) > (R42R3)

(2)
(3)
(4)

R150 and R2 < (R42R3)

A long cylindrical shell carries positive

54.

surface charge s in the upper half and


negative surface charge 2s in the lower
half. The electric field lines around the
cylinder will look like figure given in :
(figures are schematic and not drawn to scale)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

SPACE FOR ROUGH WORK /

R150

R2 < (R42R3)

U U
cU s cU
2s (UU) U
U l -U,
U ?
( U S U U S
U )

(1)

C/Page 25

2R < R4
R150 R2 > (R42R3)
R1 0 (R22R1) > (R42R3)

55.

resolve at 500 nm wavelength is :

0.25 cm, U
ScU U 25 cm ,
500 nm U , S
U
U ?

(1)

300 mm

(1)

300 mm

(2)

1 mm

(2)

1 mm

(3)

30 mm

(3)

30 mm

(4)

100 mm

(4)

100 mm

Assuming human pupil to have a radius

55.

of 0.25 cm and a comfortable viewing


distance of 25 cm, the minimum separation
between two objects that human eye can

56.

signal is/are :

()
2 MHz U U U
, U ()

(1)

2000 kHz and 1995 kHz

(1)

2000 kHz

(2)

2 MHz only

(2)

2 MHz

(3)

2005 kHz, and 1995 kHz

(3)

2005 kHz,

(4)

2005 kHz, 2000 kHz and 1995 kHz

(4)

2005 kHz, 2000 kHz

A signal of 5 kHz frequency is amplitude

56.

modulated on a carrier wave of frequency


2 MHz. The frequencies of the resultant

C/Page 26

SPACE FOR ROUGH WORK /

5 kHz

1995 kHz

1995 kHz

1995 kHz

57.

Two coaxial solenoids of different radii

57.

carry current I in the same direction. Let

F1

be the magnetic force on the inner

F2

solenoid due to the outer one and

U , I U
U , U U
U, U U U

F1

be

U U U, U U

the magnetic force on the outer solenoid

F2

due to the inner one. Then :

(1)

F1 is radially outwards and F2 50

(2)

F1 5 F25 0

(3)

F1 is radially inwards and F2 is

(1)

58.

F1

A pendulum made of a uniform wire of

(4)
58.

cross sectional area A has time period T.


When an additional mass M is added to
its bob, the time period changes to TM. If
the Youngs modulus of the material of the
1
is equal to :
Y
(g5gravitational acceleration)

wire is Y then

(2)

TM

2
A

1
2

Mg

(3)

TM

2
Mg

21

(4)

T
1 2 M
T

C/Page 27

Mg

Mg

SPACE FOR ROUGH WORK /

F1

U U U () U
U U U
U U U

F2 50

U SU
A
T U M
U
U TM U
Y
(g5L

(1)

F2 50

(3)

F1 5 F25 0

F2

F1 is radially inwards and F2 50

T
1 2

TM

U U U

(2)

radially outwards
(4)

F1

1
Y

U)
2

(1)

T
1 2

TM

(2)

TM

2
A

21

Mg

(3)

TM

2
Mg

21

(4)

T
1 2 M
T

Mg

Mg

59.

From a solid sphere of mass M and radius

59.

R a cube of maximum possible volume is


cut. Moment of inertia of cube about an
axis passing through its center and
perpendicular to one of its faces is :

60.

U M
R
() U
, , -,
U $U
U ?

(1)

4MR 2
3 3p

(1)

4MR 2
3 3p

(2)

MR 2
32 2p

(2)

MR 2
32 2p

(3)

MR 2
16 2p

(3)

MR 2
16 2p

(4)

4MR 2
9 3p

(4)

4MR 2
9 3p

When 5V potential difference is applied

60.

across a wire of length 0.1 m, the drift


speed of electrons is 2.531024 ms21. If
the electron density in the wire is
831028 m23, the resistivity of the material

0.1 m

U U 5V UU
U U U
2.531024 ms21 U U
831028 m23 ,
U ,

is close to :
(1)

1.631025 Vm

(1)

1.631025 Vm

(2)

1.631028 Vm

(2)

1.631028 Vm

(3)

1.631027 Vm

(3)

1.631027 Vm

(4)

1.631026 Vm

(4)

1.631026 Vm

C/Page 28

SPACE FOR ROUGH WORK /

C U

PART C CHEMISTRY
61.

The vapour pressure of acetone at 208C is

61.

185 torr. When 1.2 g of a non-volatile


substance was dissolved in 100 g of acetone
at 208C, its vapour pressure was 183 torr.
The molar mass (g mol21) of the substance

208C U

U c 185 torr
208C U, 1.2 g c 100 g
U , c 183 torr
U (g mol21 )

is :

62.

(1)

488

(1)

488

(2)

32

(2)

32

(3)

64

(3)

64

(4)

128

(4)

128

adsorbed (per gram of charcoal) is :

S 0.06N U 50 mL
3 g cU
U U U S
0.042 N U
(cU- U)

(1)

54 mg

(1)

54 mg

(2)

18 mg

(2)

18 mg

(3)

36 mg

(3)

36 mg

(4)

42 mg

(4)

42 mg

3 g of activated charcoal was added to

62.

50 mL of acetic acid solution (0.06N) in a


flask. After an hour it was filtered and
the strength of the filtrate was found to be
0.042 N.

63.

64.

The amount of acetic acid

possible excited state of hydrogen ?

U S
?

(1)

16.8 eV

(1)

16.8 eV

(2)

113.6 eV

(2)

113.6 eV

(3)

26.8 eV

(3)

26.8 eV

(4)

23.4 eV

(4)

23.4 eV

Which of the following is the energy of a

Which among the following is the most

63.

64.

reactive ?
(1)

ICl

(1)

ICl

(2)

Cl2

(2)

Cl2

I2

(4)

(3)
(4)
C/Page 29

Br2

(3)

SPACE FOR ROUGH WORK /

Br2
I2

65.

66.

of paints and lacquers ?

U
?

(1)

Poly vinyl chloride

(1)

UU

(2)

Bakelite

(2)

(3)

Glyptal

(3)

(4)

Polypropene

(4)

Which polymer is used in the manufacture

The molecular formula of a commercial

65.

66.

resin used for exchanging ions in water


softening is C8H7SO3Na (Mol. wt. 206).
What would be the maximum uptake of
Ca21 ions by the resin when expressed in

U$ C8H7SO3Na
( U = 206) U$ Ca21
(
U$) ?

mole per gram resin ?

67.

(1)

1
412

(1)

1
412

(2)

1
103

(2)

1
103

(3)

1
206

(3)

1
206

(4)

2
309

(4)

2
309

In Carius method of estimation of

67.

halogens, 250 mg of an organic compound


gave 141 mg of AgBr. The percentage of
bromine in the compound is :

U 250 mg
141 mg AgBr
:
(U Ag5108; Br580)

(at. mass Ag5108; Br580)


(1)

60

(1)

60

(2)

24

(2)

24

(3)

36

(3)

36

(4)

48

(4)

48

C/Page 30

SPACE FOR ROUGH WORK /

68.

Assertion : Nitrogen and Oxygen are the

68.

main components in the


atmosphere but these do not

U U U
U U U
U U

react to form oxides of nitrogen.


Reason :

The reaction between nitrogen


and oxygen requires high
temperature.

(1)

Both the assertion and reason are

U U

(1)

(2)

U U
ScUU

(3)

U U
ScUU

(4)

incorrect
(2)

Both assertion and reason are


correct, and the reason is the correct
explanation for the assertion

(3)

Both assertion and reason are


correct, but the reason is not the
correct explanation for the assertion

(4)

The assertion is incorrect, but the


reason is correct

69.

The following reaction is performed at

69.

298 K U

298 K.

2NO(g) 1 O 2 (g) 2NO 2 (g)


The standard free energy of formation of
NO(g) is 86.6 kJ/mol at 298 K. What is
the standard free energy of formation of
NO2(g) at 298 K? (Kp51.631012)

2NO(g) 1 O 2 (g) 2NO 2 (g)


298 K U NO(g)


86.6 kJ/mol 298 K U NO2(g)
? (Kp51.631012)

(1)

0.5[2386,6002R(298) ln(1.631012)]

(1)

0.5[2386,6002R(298) ln(1.631012)]

(2)

R(298) ln(1.6310 12)286600

(2)

R(298) ln(1.631012)286600

(3)

866001R(298) ln(1.6310 12)

(3)

866001R(298) ln(1.631012)

(4)

86600 2

(4)

86600 2

C/Page 31

ln (1.6 3 1012 )
R (298)
SPACE FOR ROUGH WORK /

ln (1.6 3 1012 )
R (298)

70.

greater than its lattice enthalpy ?

U U

?

(1)

SrSO 4

(1)

SrSO 4

(2)

CaSO 4

(2)

CaSO 4

(3)

BeSO4

(3)

BeSO4

(4)

BaSO4

(4)

BaSO4

Which one of the following alkaline earth

70.

metal sulphates has its hydration enthalpy

71.

72.

73.

exist for square planar [Pt (Cl) (py) (NH3)

(NH2OH)]1 is (py 5 pyridine) :

[Pt (Cl) (py) (NH3) (NH2OH)]1


(py 5 pyridine)

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

The number of geometric isomers that can

71.

accomplished by :

UU
U

(1)

Swarts reaction

(1)

SU

(2)

Free radical fluorination

(2)

(3)

Sandmeyers reaction

(3)

UU

(4)

Finkelstein reaction

(4)

SU

The synthesis of alkyl fluorides is best

The intermolecular interaction that is

72.

73.

dependent on the inverse cube of distance

U-
U U U ,

between the molecules is :


(1)

hydrogen bond

(1)

(2)

ion - ion interaction

(2)

(3)

ion - dipole interaction

(3)

- m

(4)

London force

(4)

C/Page 32

SPACE FOR ROUGH WORK /

74.

In the context of the Hall - Heroult process

74.

for the extraction of Al, which of the

-UU c
?

following statements is false ?


(1)

Na3AlF6 serves as the electrolyte

(1)

(2)

CO and CO2 are produced in this


process

(2)

(3)

Al 2O 3 is mixed with CaF 2 which


lowers the melting point of the

(3)

mixture and brings conductivity


(4)

Al31 is reduced at the cathode to

(4)

form Al
75.

Which of the following compounds will

76.

77.

1, 1 - Diphenyl - 1 - propane

(2)

1 - Phenyl - 2 - butene

(3)

3 - Phenyl - 1 - butene

(4)

2 - Phenyl - 1 - butene

The ionic radii (in ) of N32, O22 and F2

l U U

CO CO2

CaF2 Al2O3 U
U

U U Al31 U Al

75.


?
(1) 1, 1 - U - 1 -
(2) 1 - - 2 - U
(3) 3 - - 1 - U
(4) 2 - - 1 - U

76.

N32, O22 F2

exhibit geometrical isomerism ?


(1)

Na3AlF6

are respectively :

(1)

1.71, 1.36 and 1.40

(1)

1.71, 1.36

(2)

1.36, 1.40 and 1.71

(2)

1.36, 1.40

(3)

1.36, 1.71 and 1.40

(3)

1.36, 1.71

(4)

1.71, 1.40 and 1.36

(4)

1.71, 1.40

From the following statements regarding

77.

H2O2, choose the incorrect statement :


(1)

It has to be kept away from dust

(2)

It can act only as an oxidizing agent

(3)

It decomposes on exposure to light

(4)

It has to be stored in plastic or wax


lined glass bottles in dark

C/Page 33

SPACE FOR ROUGH WORK /

H2O2

( )

1.40
1.71
1.40
1.36

,

(1) U U
(2) U
(3) U
(4) SU U U

U

78.

Higher order (>3) reactions are rare due

78.

U (>3)

to :
(1)

loss of active species on collision

(1)

UU S$

(2)

low probability of simultaneous

(2)

UU

(3)

U U
h

(4)

U UU U U
SU

collision of all the reacting species


(3)

increase in entropy and activation


energy as more molecules are
involved

(4)

shifting of equilibrium towards


reactants due to elastic collisions

79.

Match the catalysts to the correct

79.

processes :
Catalyst

80.

U
U
U

Process

(A)

TiCl3

(i)

Wacker process

(A)

TiCl3

(i)

(B)

PdCl2

(ii)

Ziegler - Natta

(B)

PdCl2

(ii)

-^
UU

(C)

CuCl2

(iii)

Contact process

(C)

CuCl2

(iii)

(D)

V 2O 5

(iv)

Deacons process

(D)

V 2O 5

(iv)

(1)

(A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)

(1)

(A) - (iii), (B) - (i), (C) - (ii), (D) - (iv)

(2)

(A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)

(2)

(A) - (iii), (B) - (ii), (C) - (iv), (D) - (i)

(3)

(A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)

(3)

(A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)

(4)

(A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)

(4)

(A) - (ii), (B) - (iii), (C) - (iv), (D) - (i)

polymerization

Which one has the highest boiling point ?

80.

(1)

Xe

(1)

Xe

(2)

He

(2)

He

(3)

Ne

(3)

Ne

(4)

Kr

(4)

Kr

C/Page 34

SPACE FOR ROUGH WORK /

81.

In the reaction

81.

NaNO /HCl
0258 C

CuCN/KCN
D

NaNO /HCl
0258 C

D E 1 N 2

CuCN/KCN
D

D
E 1 N2

the product E is :

82.

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

colored yellow ?

U
?

(1)

BaCrO 4

(1)

BaCrO 4

(2)

Zn2[Fe(CN)6]

(2)

Zn2[Fe(CN)6]

(3)

K3[Co(NO2)6]

(3)

K3[Co(NO2)6]

(4)

(NH4)3 [As (Mo3 O10)4]

(4)

(NH4)3 [As (Mo3 O10)4]

Which of the following compounds is not

C/Page 35

82.

SPACE FOR ROUGH WORK /

83.

Sodium metal crystallizes in a body centred

83.

cubic lattice with a unit cell edge of 4.29.


The

radius

of

sodium

atom

is

U
SU U 4.29
U U

approximately :

84.

(1)

0.93

(1)

0.93

(2)

1.86

(2)

1.86

(3)

3.22

(3)

3.22

(4)

5.72

(4)

5.72

300 K for the reaction 2A B 1 C is

U 2A B 1 C
$ 2494.2 J

2494.2 J. At a given time, the composition

The standard Gibbs energy change at

of the reaction mixture is [A] 5

84.

1
, [B]52
2

1
. The reaction proceeds in
2
the : [R58.314 J/K/mol, e52.718]

300 K

[B]52 U [C] 5

1
2

[A] 5

and [C] 5

[R58.314 J/K/mol, e52.718]

(1)

reverse direction because Q < Kc

(1)

U Q < Kc

(2)

forward direction because Q > Kc

(2)

Q > Kc

(3)

reverse direction because Q > Kc

(3)

U Q > Kc

(4)

forward direction because Q < Kc

(4)

Q < Kc

C/Page 36

SPACE FOR ROUGH WORK /

1
,
2

85.

Which

compound

would

give

85.

5 - keto - 2 - methyl hexanal upon

$ U U
5 - U - 2 - ?

ozonolysis ?

86.

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

Which of the following compounds is not

86.

an antacid ?
(1)

Ranitidine

(1)

UUU

(2)

Aluminium hydroxide

(2)

UU

(3)

Cimetidine

(3)

UU

(4)

Phenelzine

(4)

C/Page 37

SPACE FOR ROUGH WORK /

87.

In the following sequence of reactions :


KMnO

SOCl

87.

H /Pd
BaSO 4


KMnO

4
2
2
Toluene
A
B
C,

SOCl

H /Pd
BaSO 4

4
2
2
Toluene
A
B
C

the product C is :

88.

(1)

C6H5CHO

(1)

C6H5CHO

(2)

C6H5COOH

(2)

C6H5COOH

(3)

C6H5CH3

(3)

C6H5CH3

(4)

C6H5CH2OH

(4)

C6H5CH2OH

Which of the vitamins given below is water

88.

U

(1) U K
(2) U C
(3) U D
(4) U E

89.

KMnO4

soluble ?

89.

90.

(1)

Vitamin K

(2)

Vitamin C

(3)

Vitamin D

(4)

Vitamin E

The color of KMnO4 is due to :


(1) s 2 s* transition

(1)

(2)

M L charge transfer transition

(2)

(3)

d 2 d transition

(3)

(4)

L M charge transfer transition

(4)

Two Faraday of electricity is passed

90.

through a solution of CuSO4. The mass of

copper deposited at the cathode is :

U U
s 2 s*
M L SU
d 2 d
L M SU

CuSO4

, UU l
U U :
(Cu U 563.5 amu)

(at. mass of Cu563.5 amu)


(1)

127 g

(1)

127 g

(2)

0g

(2)

0g

(3)

63.5 g

(3)

63.5 g

(4)

2g

(4)

2g

-o0oC/Page 38

SPACE FOR ROUGH WORK /

-o0o-

SPACE FOR ROUGH WORK /

C/Page 39

SPACE FOR ROUGH WORK /

Read the following instructions carefully :


U U S U U (D -1) U U
U / U U
U D-2 U U / U
/ U U
3. U S/U U U S U
R
4. U

5. U U
- () U
U U ,
U
6. U S U U
US ( U S U
S UU), U U S
U
7. U U U U
, U S
U U mU
, U D U U U
S D U (D 39)
8. U, U / U U
U U
U S
9. U U U
10. U U
S U
11. U U U S
U U SU U U U
U U U S U SU
U U
U
U S S U

12. U/S U , U
U U
13. U U U .../U
U mU
.../U
U
14. S U S U

15. U mU U / U
U U , S,
, U, U
U U U
U

1. The candidates should fill in the required particulars 1.


on the Test Booklet and Answer Sheet (Side1) with
Blue/Black Ball Point Pen.
2. For writing/marking particulars on Side2 of the 2.
Answer Sheet, use Blue/Black Ball Point Pen only.

3. The candidates should not write their Roll Numbers


anywhere else (except in the specified space) on the
Test Booklet/Answer Sheet.
4. Out of the four options given for each question, only
one option is the correct answer.
5. For each incorrect response, onefourth () of the total
marks allotted to the question would be deducted from
the total score. No deduction from the total score,
however, will be made if no response is indicated for
an item in the Answer Sheet.
6. Handle the Test Booklet and Answer Sheet with care,

as under no circumstances (except for discrepancy in


Test Booklet Code and Answer Sheet Code), another set
will be provided.

7. The candidates are not allowed to do any rough work


or writing work on the Answer Sheet. All calculations/
writing work are to be done in the space provided for
this purpose in the Test Booklet itself, marked Space
for Rough Work. This space is given at the bottom of
each page and in one page (i.e. Page 39) at the end of
the booklet.
8. On completion of the test, the candidates must hand
over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to
take away this Test Booklet with them.
9. Each candidate must show on demand his/her Admit
Card to the Invigilator.
10. No candidate, without special permission of the
Superintendent or Invigilator, should leave his/her
seat.
11. The candidates should not leave the Examination Hall
without handing over their Answer Sheet to the
Invigilator on duty and sign the Attendance Sheet
again. Cases where a candidate has not signed the
Attendance Sheet second time will be deemed not to
have handed over the Answer Sheet and dealt with as
an unfair means case. The candidates are also required
to put their left hand THUMB impression in the space
provided in the Attendance Sheet.
12. Use of Electronic/Manual Calculator and any
Electronic device like mobile phone, pager etc. is
prohibited.
13. The candidates are governed by all Rules and
Regulations of the JAB/Board with regard to their
conduct in the Examination Hall. All cases of unfair
means will be dealt with as per Rules and Regulations
of the JAB/Board.
14. No part of the Test Booklet and Answer Sheet shall be
detached under any circumstances.
15. Candidates are not allowed to carry any textual
material, printed or written, bits of papers, pager,
mobile phone, electronic device or any other material
except the Admit Card inside the examination
room/hall.

C/Page 40

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