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RFM = 12 + 2 16
= 44
Cu(NO3)2
CuSO4.5H2O
Find the relative molecular mass for each of the following. SHOW your WORKINGS
HCl-36
MgCl2-96
LiOH
CH4
CaSO4
11. CuSO4
12. CuCl2
13. H2S
14. CH4
15. CaO
16. Al2O3
17. Cu(NO3)2
18. CaCO3
19. Mg(NO3)2
20. Al2(SO4)3
-1-
NH4OH
(NH4)2 SO4
IGCSE Chemistry
-2-
IGCSE Chemistry
% by mass of Al = 102
100
= 227 + 316
= 227
= 102
= 54
A common problem with percentage by mass calculations occurs when an element occurs in
two places in the compound.
What is the percentage by mass of oxygen in CuSO4.5H2O?
RFM of CuSO4.5H2O
Mass of oxygen in formula
144
% by mass of O = 250
100
= 64 + 32 + 416 + 5 (2+16)
= 416 + 516
= 144
= 57.6% (3 sig. fig.)
H in H2O=2/16=.125
C in C2H6=24/30=.800
O in CO=16/28=.571
O in CO2=32/44=.727
N in NH3=14/17=.823
Cu in CuCl2
Ca in CaO
S in SO3
Na in NaCl
Cl in HCl
11
12
13
14
15
16
17
18
19
20
Cl in MgCl2
H in H2S
Al in Al2O3
C CaCO3
Na in Na2CO3
O in NaHCO3
K in K2SO4
H in HNO3
S in Al2(SO4)3
O in Cu(NO3)2
Other likely questions are: Which fertiliser has the biggest % of N (nitrogen)?
-3-
= 250
IGCSE Chemistry
a)
N in NH4NO3 28/80 b)
N in KNO3 14/101 c)
-4-
N in NH4PO4 14/98
IGCSE Chemistry
Calculate the percentage element in a compound
-5-
IGCSE Chemistry
Questions: Relative Formula Mass and % Element in a compound
1.
The symbol equation below shows the reduction of iron (III) oxide by carbon monoxide.
Fe2O3
(a)
3CO
2Fe
3CO2
[1]
...............112/16+16+16+36+16+112=244=45.9%...........................................................
(b)
[2]
45.9%................................................................................................................................
.....
.....................................................................................................................................
2.
Calcium carbonate tablets are used to treat people with calcium deficiency.
C a lc ifu ll T a b le ts
C a
A c tiv e in g r e d ie n t:
C a lc iu m c a r b o n a t e
C aC O
( E a c h ta b le t c o n ta in s 1 .2 5 g C a C O 3 )
(a)
(b)
(c)
(d)
-6-
IGCSE Chemistry
...........................................................excess CO2 gas created.......................................
3.
(a)
The formula for ammonia is NH3. What does the formula tell you about each molecule
of ammonia?
[1]
......................................one nitrogen three hydrogens......................................................
(b)
Ammonia is used to make nitric acid (HNO3). Calculate the formula mass (Mr) for nitric
acid. [1]
.....................................................................................................................................
4.
[1]
...........................120...................................................................................................................
5.
Complete the table to show the number of atoms of each element present in NH4Cl.
Element
Number of atoms in
NH4Cl
nitrogen
hydrogen
chlorine
1
(1)
(ii)
[1]
.................................................................53....................................................................
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IGCSE Chemistry
The mole
1.17 understand the use of the term mole to represent the amount of substance
1.18 understand the term mole as the Avogadro number of particles (atoms, molecules,
formulae, ions or electrons) in a substance
Because atoms and molecules are so small, chemists measure or work with them in large
numbers. Chemists measure amounts of substance in moles.
The mole is the chemists counting unit used to indicate a certain number, just like a pair, a
dozen, a trio.
A mole is the number 6.02 x 1023, and is called Avogadro's number.
A mole of any substance contains the same number of atoms or molecules or ions or
electrons or formula units and always equals 6.02 x 1023.
The Avogadros Number or Constant is equal to the number of atoms in 12 g of carbon12,
and is 6 x 1023
Molar mass
1.19 carry out mole calculations using relative atomic mass (Ar) and relative formula mass (Mr)
The molar mass of a substance is the mass of 1 mole of particles of that substance or the
mass of 6.02 x 1023 particles of that substance.
Calculate the relative formula mass (Mr) of a substance, the mass of 1 mole will be the same
number, in g. This is called the molar mass, and its units are g/mol.
e.g. What is the mass of one mole of (a) CO2 ; (b) Cu(NO3)2 ?
(a)
(b)
1 mole of CO2
Relative formula mass of CO2
Molar mass of CO2
= 12 + 216 = 44
= 44 g/mol
1 mole of Cu(NO3)2
Relative formula mass of Cu(NO3)2
= 64 + 2 (14+ 316) = 188
Molar mass of Cu(NO3)2
= 188 g/mol
-8-
IGCSE Chemistry
Calculating moles using molar mass
36
2mols
2mols
NaOH
.4
d. 85g of NH3
5+2/3
f. 0.8g of CH4
1/20
g. 196g of H2SO4
h. 31g of P4
i. 0.56g of CaO
Find the mass of the following amounts of substance show your working:
a. 2 moles of iron
112g
d.
g.
i. 0.1 moles of S8
-9-
IGCSE Chemistry
Number of moles=
mass of the substance
mass of 1 mole of the substance
molmr
mol= m
mr
Example
1
a)
b)
c)
d)
e)
2
a)
b)
c)
d)
e)
3
a)
b)
c)
d)
e)
f) 4g of oxygen molecules
g) 213g of chlorine molecules
h) 254g of iodine molecules
I) 0.8g of oxygen molecules
j) 0.56g of nitrogen molecules
f)
g)
h)
I)
j)
-10-
IGCSE Chemistry
Moles
mol
Therefore:
Mass of substance =
number of moles x mass of 1 mole
which is the same as saying . . .
Mass
= number of moles x Relative Formula Mass
m
molmr
= mol x mr
Example
mol=m
mr
a)
b)
c)
d)
e)
3
a)
b)
c)
d)
e)
f)
g)
h)
I)
j)
-11-
1.25 calculate reacting masses using experimental data and chemical equations
Example
Fe2O3(s) +
3CO(g)
2Fe (s) +
3CO3 (g)
28g
number of moles =
= 0.5 mole of Fe
molar mass
56g
Step 3: find answer in moles using the balanced chemical equation:
2 moles of iron needs 1 mole of iron oxide
0.5 moles of iron needs 0.25 moles of iron oxide
Step 4: convert answer into unit asked for:
unit is mass mass = number of moles x Mr = 0.25 x 160g = 40 g
Exercises
1. How much zinc oxide will be produced when 13g of zinc are heated in an excess of oxygen?
2. How much calcium oxide will be produced when 10g of calcium carbonate are decomposed
by heat?
3. 6.4 g of sulphur were burned completely in air. What mass of sulphur dioxide was formed?
4. How much carbon dioxide is produced when 20 tonnes of carbon are burned in excess of
oxygen?
5. How much oxygen is needed to react with 12 tonnes of iron to form iron (III) oxide?
6. A chemist is investigating a mixture of substances to make an improved type of glass. She
wants the finished glass sample to contain 14.0 g of calcium oxide. She plans to add calcium
carbonate to the mixture before it is melted. Calcium carbonate undergoes thermal
decomposition according to the equation
CaCO3(s) CaO (s) + CO2 (g)
Calculate the minimum number of moles of calcium carbonate which the chemist should
add to the mixture in order to ensure that the final glass contains 14.0 g of calcium oxide.
7. Calculate the mass of copper required to produce 160g of copper oxide when heated in
excess oxygen
2Cu (s) + O2(g) 2CuO (s)
-12-
IGCSE Chemistry
1 Zinc oxide reacts with carbon to form zinc and carbon monoxide. How much zinc oxide do
you need to make 130 tonnes of zinc?
ZnO (s) + C(s) Zn (s) + CO (g)
9. In the thermit reaction, aluminium is used to obtain pure iron. How much aluminium is
needed to obtain 28 tonnes of iron?
Fe2O3(s) +
2Al (s)
2Fe (s) +
Al2O3 (s)
10. What mass of chlorine would be needed to make 73 tonnes of hydrogen chloride?
H2 (g) + Cl2 (g) 2HCl (g)
11. Calculate the mass of nitric acid needed to make 400 tonnes of ammonium nitrate
HNO3 + NH3 NH4NO3
12. What mass of aluminium would be produced from 204 tonnes of aluminium oxide given the
reaction?
13. 2.67g of aluminium chloride was dissolved in water and silver nitrate was added to give
silver chloride
AlCl3 + 3AgNO3 Al(NO3) + 3AgCl
2Al2
O3
(s)
Calculate the amount of chromium produced from 1 tonne of chromium (III) oxide
Calculate the amount of aluminium needed to react with 1 tonne of chromium (III) oxide.
-13-
IGCSE Chemistry
6.
7. Observe the magnesium react as the acid diffuses downwards, wait until all the magnesium has
reacted.
8.
Results:
Mass of magnesium used _____________ g Volume of hydrogen produced ______________ cm3
Safety
Questions
The equation for the reaction is
Mg +2HCl MgCl2 + H2
The equation tells us that 1 mole of magnesium will produce 1 mole of hydrogen.
1. How many moles of magnesium were reacted?
2. How many moles of hydrogen were produced?
3. Calculate the volume of 1 mole of hydrogen.
4. Write a conclusion.
5. How can you make the experiment more valid?
-14-
IGCSE Chemistry
Molar volume of gases
1.20 understand the term molar volume of a gas and use its values (24 dm 3 and 24,000
cm3) at room temperature and pressure (rtp) in calculations
The moles of a gas can be calculated because 1 mole of any gas, at room temperature and
normal pressure, occupies a volume of 24 dm 3 which is called the molar volume of gases at
room temperature.
volume of gas in dm3
number of moles of gas at r.t.p. =
24 dm3
At room temperature and pressure (r.t.p.), one mole of any gas occupies a volume of 24 dm3 (24000
cm3).
Number of moles of gas at r.t.p
as
volume of gas in cm 3
24000
e.g. What total volume of gas at r.t.p. can be obtained from heating 99.3g of lead(II) nitrate?
(Pb=207, N=14, O=16)
2 Pb(NO3)2
2PbO + 4NO2 + O2
(a)
= 331g/mol
99.3g
331 g/mol
(b)
(c)
= 0.75 24
e.g. What mass of sodium hydroxide is needed to absorb 1.00 dm 3 of carbon dioxide gas at
r.t.p.?
Equation: 2NaOH + CO2 Na2CO3 + H2O
(a).
= 0.0417 mol
(b)
(c)
= 23 + 16 + 1
-15-
= 40 g/mol
IGCSE Chemistry
mass of NaOH needed
= 0.0833 mol 40 g/mol = 3.33 g
How many moles of gas are there in (at rtp):
a. 2400 cm3 of chlorine
c. 96 cm3 of nitrogen
d. 24 cm3 of methane
f. 12 dm3 of Cl2
h. 24 000 cm3 of O2
b. 2.05 moles of O2
e. 0.25 moles of He
-16-
c. 7 moles of NH3
f. 0.001 moles of F2
IGCSE Chemistry
-17-
IGCSE Chemistry
-18-
IGCSE Chemistry
Past question
-19-
IGCSE Chemistry
-20-
IGCSE Chemistry
-21-
IGCSE Chemistry
-22-