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53
REPORT
ECUMED PETROLEUM
1
0
21/06/2013
Issued For
approval
18/06/2013 Issued For
Review
001/AR11/12
SANAMCH
MCH
MLI
SANA
MCH
MLI
04/10
NO.
R1112-RPT-PR00-001
REV.A
PAGE: 2 / 63
PROCESS REVIEW
REQUIRED MODIFICATION REPORT
REV
DATE
Designation
NAME
VISA
Prepared by
NAME
VISA
Verified by
NAME
VISA
Approved by
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Revisions report:
Revision No
0
1
002/AR11/12
Revision Description
Issued For Review
Issued For Approval
NO.
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0
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TABLE OF CONTENTS
1.
INTRODUCTION........................................................................................6
1.1
GENERAL................................................................................................................. 6
1.2
1.3
DOCUMENT SCOPE..................................................................................................... 7
1.4
1.4
DEFTINO.S ............................................................................................................................ 7
21.4
ABREVOITNS............................................................................................................................. 8
1.5
UNITS OF MEASUREMENT............................................................................................ 8
2.
DESIGN DATA..........................................................................................10
2.1
ENVIRONMENTAL DATA.............................................................................................. 10
12.
MCLATINDMEORG ITNS........................................................................................................................... 10
2.1
GROUNDASILCT........................................................................................................................... 11
2.2
WELLS LOCATION................................................................................................... 11
2.3
12.3
WELHADRMPT.S .......................................................................................................................... 11
2.3
COMPSITN........................................................................................................................... 12
2.4
CPFDESIGNAMRT........................................................................................................................... 12
2.5
GASREQUDISPCFOTNTE(IA.) .......................................................................................................................... 12
3.
4.
CALCULATION METHODS.........................................................................13
3.1
3.2
THERMODYNAMICS................................................................................................... 13
3.3
13.
DFLUIRESVO........................................................................................................................... 13
23.
WELHADS........................................................................................................................... 14
3.
PIENL........................................................................................................................... 14
43.
FIRSTSEPAO.N .......................................................................................................................... 14
53.
NAMEIT.U .......................................................................................................................... 14
63.
GLYCODEHRATNI.U .......................................................................................................................... 14
73.
CONDETSARMLV.UI .......................................................................................................................... 15
83.
INJECTOGASCMPR........................................................................................................................... 16
93.
CONDETSASLBIZ........................................................................................................................... 16
AND
ASSUMPTIONS...............................................13
4.2
CO2 SELECTIVITY................................................................................................. 20
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KINETICS
4.4
CORROSIVITY.......................................................................................................... 21
4.5
AMINE
4.6
THERMODYNAMICS
4.7
14.7
DETRMINOAFWL........................................................................................................................... 21
24.7
NSIZGOFCO2ABRE........................................................................................................................... 22
34.7
NAMEIRGTO........................................................................................................................... 23
4.7
LEANMICRUTOPS........................................................................................................................... 23
4.8
NSIZGOFHEATXCR........................................................................................................................... 24
14.8
NSIZGOFLEAMRC........................................................................................................................... 24
24.8
NSIZGCOFRH/LEAMTXNG.R .......................................................................................................................... 24
34.8
NSIZGOFRETACD........................................................................................................................... 25
4.8
NSIZGOFRETALB........................................................................................................................... 25
54.8
NSIZGOFAMELHDRU........................................................................................................................... 26
5.
6.
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OF REACTION WITH
CO2..............................................................................20
CO2..................................................................21
REVISION OF TEG
5.2
15.2
GLYCOFASHTNKPERIDMOSN........................................................................................................................... 28
25.
THECAXNGRSIPUD........................................................................................................................... 29
25.1
AIR/GLYCOHETXN.E320 .......................................................................................................................... 29
25.
GLYCO/HEATXNR........................................................................................................................... 29
25.3
GLYCOREN/DASMIZ........................................................................................................................... 29
5.3
GLYCOPUMS........................................................................................................................... 30
5.4
CONDESRILXHAG........................................................................................................................... 30
5.
REGNATOILB........................................................................................................................... 30
5.6
LGPSTRNIUCOM........................................................................................................................... 30
5.7
LGSTICOUM.N: .......................................................................................................................... 31
5.8
15.8
PSTRNIGAFLOWE........................................................................................................................... 32
25.8
PSTRNIGAUCOMLDE(TR.) .......................................................................................................................... 33
CONTACTOR
DESIGN..................................................................26
REFRIGERANT
6.2
PROPANE RECEIVER................................................................................................. 34
6.3
PROPANE COMPRESSOR............................................................................................ 35
6.4
PROPANE CONDENSER.............................................................................................. 35
6.5
6.6
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FLUID SELECTION..................................................................................34
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6.7
6.8
6.9
COLD SEPARATOR.................................................................................................... 37
7.
NITROGEN SKID......................................................................................38
8.
SIZING OF PIPELINE................................................................................39
9.
CONCLUSION..........................................................................................42
10. APPENDICES........................................................................................... 44
10.1
APPENDIX 1:
RECIRCULATION RATE OF
10.2
APPENDIX 2:
10.3
APPENDIX 3:
10.4
APPENDIX 4: GPSA
10.5
10.6
10.7
10.8
10.9
STANDARD FOR
DEA
TEG
SOLUTION..................................................44
CONTACTOR SIZING........................................45
10.10 TIE-IN PROCEDURE TO ADD AMINE FLASH VAPOR TO STRIPPING GAS PROCESS
58
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1. INTRODUCTION
1.1GENERAL
El-Bibane offshore wells are located at about 18 km far from the CPF (the
onshore central processing facility) situated on the town of Zarzis.
Presently, El-Bibane field is operating as described below:
-
The production is handled to the CPF through an 8 sea line and the treated gas
is rerouted from the CPF to be re-injected through 6 sea line.
Prepare the required simulations to sell 4-5 MMSCFD and inject 9-11
MMSCFD of gas in order to recover condensate.
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Based on the recovered condensate quantity and the gas sales, develop
the first phase economic analysis.
Based on the gas sales develop the second phase economic analysis.
The present report is devoted to the first phase; the feasibility study for
selling 1/3 of gas production and injection of the remaining quantity.
1.3DOCUMENT SCOPE
The objective of this document is to check the operability and the adequacy of
the existing facilities and to size required additional equipments on both CPF
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and other units relevant to El Bibane Field Development Project. This study has
been carried out for a total gas production of 15MMSCFD, case of selling 1/3 of
gas production and injecting the remaining quantity in order to recover
condensate.
1.4DEFINITIONS & ABBREVIATIONS
1.4.1DEFTINOS
For the purpose of this document the following definitions shall apply:
Owner/Client
ECUMED Petroleum
Contractor
EPC contractor
Engineering company
Engineering
Procurement
and
Project
Management (EPPM)
Project
Supplier/ Vendor
The
party
(s)
supplies
which
manufactures
equipment,
and/or
technical
:
:
:
:
:
:
:
:
:
:
:
Bottom-Hole Pressure
Central Processing Facility
El Bibane Wellhead number
Equation of State
High Pressure
Higher Heating Value
Joule Thomson
Low Pressure
Pressure Control Valve
Process Flow Diagram
Electricity Company of El-Bibane ( Socit dElectricit El-
STEG
Bibane )
Tunisian Company of Electricity and Gas ( Socit Tunisienne
TEG
dElectricit et de Gaz)
Tri Ethylene Glycol
1.5UNITS OF MEASUREMENT
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In general, SI units will be used. However, there are recognized exceptions and
preferred units that are used in the Oil & Gas industry.
Table 1: Units of Measurement
Measured Quantity
Corrosion Allowance
Preferred Unit
Millimeters
Designation
mm
Density
kg/m3
Ampere
milli-ampere
mA
Volt
Watt
Kilowatt
kW
Megawatt
MW
Electric Resistance
Ohm
Ohm
Enthalpy
kJ/kg
Force
N or kN
Frequency
Hertz
Hz
Head
Meters
Heat Loading
Heat Transfer
Coefficient
Latent Heat
Kilowatts
watts per square meter per
degree Celsius
kilo Joules per kilogram
kW
Length
mm, m, km
Luminance
Lux
Lx
Mass
Kilogram
kg
kilogram/hour
kg/h
Mechanical Power
kilowatts, megawatt
kW, MW
Diameter
In
Stress
Inches
bar gauge, bar absolute,
Kilopascal
revolutions per minute
kilocalories per Standard cubic
meter
kilojoules per kilogram degree
Celsius
Newton per square meter
Temperature
degree Celsius
Thermal Conductivity
W/m C
Time
y, d, hr, min, s
Vessel Dimensions
Volume (actual)
cubic meters
m3
SCM (Note 1)
Electric Current
Electric Potential
Electric Power
Pressure
Rotational Speed
Lower Heating Value
(LHV)
Specific Heat
Velocity
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W/m2 C
kJ/kg
m/s, m/h
m, mm
Measured Quantity
Volume Gas Flow
Volume (liquid)
Pipe/Nozzle sizes
Dynamic Viscosity
Kinematic Viscosity
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Preferred Unit
meter /day (per hour)
Million Standard cubic feet/day
Cubic meter
Cubic meter/ hour
Cubic meter/ day
Barrel/day, Barrel Oil/day, Barrel
Water/day, Barrel
Condensate/day
Inches
Designation
SCMD (SCMH)
MMSCFD
m3
Centipoises
cP
Centistokes
cSt
m3/h
m3/day
BPD, BOPD,
BWPD, BCPD
In
Rainfall:
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2.1.2GROUNDALSICT
The offshore soil properties are investigated by pressure-metric survey, the main
results could be summarized in the following table:
Table 2: El-Bibane Offshore Soil Profile
Depth
Soil Type
Effective
Limit
Pressure
Sub-Grade
Modulus
Friction
Angle
Sandstone +
35 bars
700-1000
30-35
Hard
Silt
40 bars
1000-1100
35-40
12m-20m
sandstone
Statu
s
UTM x
(m)
UTM y
(m)
EBB#3RE2
(Horizontal)
None
713942
3702310
Same
as
unknown.
EBB#4
(Horizontal)
Inject
or
713570
3702746
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Remarks
EBB#3RE.
Deviation
EBB#5
Produ
cer
714321
3703214
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(after
choke
valve) (barg)
Injection pressure(barg)
Temperature (C)
Design
Flow
rate
(MMSCFD)
EBB#5
EBB#4
wellhead
wellhead
36
64
158
-
10
10
2.3.2COMTPSIN
EBB#5 fluids compositions inlet and outlet HP separator are detailed in process
simulation reports
2.4CPFDESIGNARMT
The design parameters of the CPF are illustrated in the following table:
Table 5: CPF Design Parameters
Parameter
Equipment
HP
Separator(V1001)
V-100
V-101
Glycol Contactor (T710)
Gas/Gas Heat
Exchanger (EJ-4001)
Cold
4001)
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Separator
(VJ-
Design
Pres. (barg)
Design
Temp. (C)
100
50
41.4
46
100
97.5
-29 to 65.5
Shell/Tube
Shell/Tube
Tubes: OD, 14
75.8/75.8
121.1/121.1
BWG, Length=40 ,
69.98
-45.5 to 51.6
Capacity/Dimensio
ns
60 OD 20
Length
36 OD 28
Length
22 Shell Diameter
No. 350
40 OD 120
Length
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Equipment
Compress
or (K-400
A/B)
Parameter
First
Stage
Second
Stage
Design
Pres. (barg)
Suction/discha
rge
30/84.5
Suction/discha
rge
84.2/228
Heater (H-102)
Design
Temp. (C)
Capacity/Dimensio
ns
2.5GASREQUDISPFCTON(TEGIA)
The required sales gas specifications are summarized in the table below:
Table 6: Required Gas Specifications
Parameter
Unit
Value
Higher Heating
Value
kcal/Nm3
9300 10228
Wobbe Index
kcal/Nm3
11961 12640
Water content
(ppm)
<= 80
H2S content
Sulfur content
Gas temperature
CO2 content
H2
and
content
O2 content
N2
mg/Nm
<2
mg/Nm
< 50
10 50
% mol
< 0.5
% mol
<6
% mol
3. CALCULATION METHODS
3.1PROCESS DESIGN TOOLS
The software HYSYS (version 7.3) is used for the process simulation under
steady state conditions.
Schlumbergers PIPESIM modeling Software version 2009 is used for process
calculation and hydraulic simulation for the study at steady state for the pipeline
connecting the piping outlet the CPF with the tie-in point on the STEG gas
network.
3.2THERMODYNAMICS
The simulations have been performed based on Amine package in amine unit
simulation and Peng/Robinson EOS using the binary coefficient data provided
by HYSYS.
3.3MODEL DESCRIPTION, BATTERY LIMITS AND ASSUMPTIONS
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3.3.1FUIDLRESVO
The gas and oil compositions (Appendix 2) respectively inlet and outlet the HP
separator are recombined and reintroduced as a feed stream. Hence the
separated gas composition is given in the table below:
Table 7: Estimated separated Gas composition
COMPONENTS
CO2
Nitrogen
Methane
Ethane
i-Butane
n-Butane
i-Pentane
n-Pentane
n-Hexane
Propane
Benzene
Cyclohexane
2-Mpentane
3-Mpentane
2-Mheptane
Toluene
n-Heptane
n-Octane
n-Nonane
2-Mhexane
MOLE FRACTION
0.0177
0.0172
0.8256
0.0783
0.0067
0.0098
0.0037
0.0031
0.0015
0.0336
0.0002
0.0002
0.0007
0.0003
0.0001
0.0001
0.0007
0.0001
0.0001
0.0002
3-Mhexane
0.0001
3.3.2WELHADS
The wellhead stream from EBB#5 conditions are as follows:
o
An automatic/electric choke valve is used to adjust the well stream flow rate and
the pressure which will define the optimal CPF inlet pressure.
The injected gas in EBB#4 is at pressure 158 barg.
3.3.3PPELIN
A roughness of 45.7 m (Carbon steel) will be used for the pressure loss
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calculations.
A thermal conductivity of the pipe material of 45 W/m.K will be assumed.
3.3.4FRSTISEPAON
The CPF inlet production is carried into the HP three phases separator (V-1001)
as a first removal of water and condensate. This separator has a design pressure
of 100 barg which can limit the CPF inlet pressure. The gas at the inlet of
separator is considered at 31 barg and 31C.
3.3.5AMINEUT
In order to remove carbon dioxide from inlet gas, an amine unit is foreseen
downstream HP three phase separator (V-1001).
The Amine unit will be designed to treat 16 MMSCFD of gas with 1.77 mol %
CO2, by circulating lean amine solution (30 wt% DEA) through the contactor to
remove carbon dioxide from inlet gas and satisfy the customers requirement of
0.5% CO2.
approximately 32 bara to 5 bara through a level control valve and sent to the
Amine Flash Drum to separate the hydrocarbon gas from DEA solution. The rich
DEA is heated to approximately 75C by the Rich/Lean Amine Exchanger and
then fed to the Amine Regenerator. The lean amine is cooled through the
Rich/Lean Amine Exchanger and pumped via the Amine Booster Pumps to the
Lean Amine Air Cooler and then through lean amine filters. The lean amine is
cooled to approximately 40C and routed back to the Amine Contactor after
adjustment of amine solution flow rate and composition by the water make-up.
3.3.6GLYCODEHTRINAU
In order to prevent hydrate formation, a TEG contactor unit is foreseen
upstream of the J-Thomson condensate removal unit.
In order to prevent hydrate formation, a TEG contactor unit is foreseen
upstream of the J-Thomson condensate removal unit.
The sweet gas from the Amine Contactor is routed to the Glycol contactor (T710) near its bottom and flows upward through the bottom tray to the top tray
and out at the top of the column. Lean glycol is fed at the top of the column and
its flows down from tray to tray, absorbing water vapor from gas. The Contactor
operates at @ 50 C and 30 bara with a lean TEG. Dehydrated gas from the
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Wet Gas
Heat Exchanger
Gas/Gas
Dry Gas
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The HYSYS flowsheet of the CPF considering the new configuration is shown in the following figure.
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CO2 Selectivity
Corrosivity
Amine degradation
4.2CO2 SELECTIVITY
Selectivity is a balance between the mass transfer rates of the acid gases competing
for the amine in the solvent. The less reactive the amine, the better the selectivity
MDEA is fairly selective towards H2S removal gases containing both H 2S and CO2
because it does not react directly with CO2. In such case, DEA is the best solution.
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4.4CORROSIVITY
The DEA is more corrosive than MDEA but in this case the corrosion is not an
important factor for the selection of the amine type because the existing facility is
sized for the most corrosive amine type.
4.5AMINE CONSUMPTION AND PRICE
The boiling temperature of DEA is higher than that of MDEA therefore the losses of
amine are greater for the case of MDEA.
The DEA is less expensive than MDEA; therefore the DEA is favored according to
price factor.
4.6THERMODYNAMICS OF REACTION WITH CO2
Both
types
of
amine
solutions
are
almost
total;
therefore
they
are
thermodynamically favored. However, the MDEA does not react directly with CO 2;
therefore its conversion rate is lower compared to DEA conversion rate.
Hence in this case the DEA is thermodynamically favored.
To summarize, as per Selectivity for CO2, Price of amine, Kinetics of reaction with
CO2, Corrosivity, Amine degradation and Amine consumption, and thermodynamics
of reaction with CO2, the performed amine for the gas treatment is the DEA.
The criteria of choice of the type of amine are summarized in the following table:
Table 8: criteria of choice of the type of amine
Choice criteria
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DEA (30)
MDEA (40%)
Thermodynamic
Price of amine
Kinetics of reaction with
CO2
Corrosivity
Amine degradation
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Amine consumption
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DEA (30)
MDEA (40%)
Therefore we have chosen to use the DEA solution for natural gas treatment.
4.7MAIN EQUIPMENTS SIZING
4.7.1DETNRMOAIFLWE
The method to calculate the minimum amine flow rate in case of DEA solution is
shown in Appendix 1.
The main outcomes are summarized in the following table:
Actual Process
scheme
MM
15
Xa
(1.77 0.5)/1.77 =
0.717
8.59
ML
0.3
WT
30
26.73
6.07
For amine solutions with DEA, the minimum capacity of lean amine circulation
pumps for the actual process scheme shall be over than 6.07 m3/h.
Using the chemical reaction, to eliminate the acid gas the amine molar flow shall be
twice of the CO2 flow rate, in this case the DEA circulation rate is equal to 10.47
m3/h using a correction factor of 10%.
4.7.2SZINGOFCO2ABSRE
The method for calculating the diameter of the absorption column is shown in
Appendix 2.
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Value
16
(MMSCMD)
Contactor pressure (kPaa)
Contactor diameter (m)
0.453
3200
0.962
The main HYSYS simulation results for the CO 2 absorber are illustrated in the
following table:
Table 11: CO2 Absorber Main Sizing Results
Parameters
Value
15.95
32
Number of stages
10
0.762
6.1
0.61
10.47
1.772
0.304
Considering the above calculation results, the sizing results of the worst case are
considered:
Table 12: Results of sizing of absorption column
Design Parameter
Diameter of column (m)
Value
0.962
6.1
Number of plates
10
4.7.3AMINERGATO
The method for calculating the diameter of the regeneration column is shown in
Appendix 3.
Tacking in consideration the design capacity of the recirculation pump of 10.47
m3/h; the minimum diameter of the amine regenerator column should be of 517.72
mm.
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The main HYSYS simulation results for the Amine regenerator are illustrated in the
following table:
Table 13: Amine Regenerator Main Sizing Results
Parameters
Value
10.47
outlet
1.62
absorber (mol %)
Regenerator pressure (bara)
1.5
Number of stages
10
0.609
6.1
4.529
0.2
Considering the above calculation results, the sizing results of the worst case are
considered:
Table 14: Results of sizing of regenerator column
Design Parameter
Value
0.61
6.1
Number of plates
10
4.7.4LEANMICRULOTPS
The data of lean amine circulation pumps are summarized in the following table:
Table 15: Data for lean amine circulation pumps calculation
Design Parameter
Unit
Value
m /h
10.47
Suction pressure
bara
1.4
Discharge pressure
bara
32.2
Vapor pressure
bara
Mass density
Kg/m
0.43
3
1009
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Unit
Value
Hydraulic power
kW
8.214
Electrical power
kW
14
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Design Parameters
HMT
Unit
Value
mCE
302
4.8SNIZGOFTHEACXR
4.8.1SZINGOFLEAMRC
The sizing of the lean amine air cooler is performed using the software HTFS.
The data of lean amine air cooler are summarized in the following table:
Table 17: Calculation data of lean amine air cooler
Design Parameter
Unit
Temperature of amine solution inlet air
C
cooler
Temperature of amine solution outlet air
C
cooler
Amine solution flow rate
Kg/h
Air cooler inlet pressure
Value
80
40
9623.16
bar
32.2
Unit
Value
45
Tube passes
4
2
Area required
Tube length
745
9.74
4.8.2SZINGOFCRH/LEAMTXNGR
The sizing of the rich/lean amine heat exchanger is performed using the software
HTFS.
The data of rich/ lean amine heat exchanger are summarized in the following table:
Table 19: Calculation data of lean/rich amine heat exchanger
Design Parameter
Unit
Value
40.25
75
112
Kg/h
10055.72
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Design Parameter
lean amine flow rate
Heat exchanger inlet pressure
Unit
Value
Kg/h
9623.16
bar
Unit
Value
2
2
Area required
Tube length
7.1
3.048
Unit
Value
99.5
60
bar
1.2
kg/h
MMbtu/
hr
1525.12
flow rate
Heat duty
2.26
4.8.4SZINGOFREATBL
The data of Regenerator Reboiler are summarized in the following table;
Table 22: Reboiler main design parameters
Design Parameters
Temperature inlet Reboiler
flow rate
Unit
Value
112.5
11598.5
2
1.6
kg/h
bar
MMbtu/
hr
4.472
4.8.5SZINGOFAMELSHDRU
The sizing of amine flash drum is determined by referring to standard DEP.
The data of amine flash drum are summarized in the following table.
Table 23: Amine flash drum input data
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Design Parameters
Mass flow rate
Unit
Inlet vessel
kg/h
9717.08
m /h
Pressure
bara
11.23
3
Temperature
40
Mass density
kg/m3
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Liquid outlet
9661.4
Gas outlet
55.68
1.87
9.36
40
40
1084
1.593
Unit
Value
Diameter
0.75
Length
3.37
Parameter
Unit
Value
Diameter
0.9144
Height
2.286
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Value
23.65
1106
18630
30
Parameter
Value
2835.19
133.93
50.32
0.78
Diameter (m)
0.84
Number of trays
0.61
4.88
A HYSYS simulation performed to model the actual contactor T710 including its
diameter, internals (bubble cap trays) estimate the TEG contactor size considering
the following input data:
Table 28: Glycol contactor main simulation Input data
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Value
30
45
0.8
15.77
0.914
Bubble Cap
Trays
Trays type
Number of trays
4.877
0.61
Water
(kg/h)
Water
(ppm)
Water
(kg/h)
Water
(ppm)
Value
50.17
3235.8
1.71
111.3
The water content downstream the Glycol contactor T-710 is 111.3 ppm, It doesnt
comply with STEG requirement (Wc <80 ppm), for this raison a design review of
regeneration unit with the expected gas flow rate is made available in next
paragraph.
5.2CURRENT TEG REGENERATION UNIT DESIGN
5.2.1GLYCOFASHTNKPERIGDMOSN
The data of Glycol flash drum are summarized in the following table.
Table 30: Glycol flash drum operating data
Design Parameters
Mass flow rate
Volumetric flow rate
Temperature
002/AR11/12
Unit
Inlet vessel
kg/h
873
3.93
80
m /h
C
Liquid outlet
870
Gas outlet
3
0.813
2.577
80
80
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Design Parameters
Mass density
Unit
kg/m
Inlet vessel
Liquid outlet
1070
257.5
Gas outlet
1.168
The dimensions of Glycol flash drum are summarized in the following table:
Table 31: Glycol flash drum dimensions
Diameter
Existing
Value
0.406
Length
1.5
Design Parameter
Unit
5.2.2HEATXCHNGRSIPUD
5.2.2.1
AIR/GLYCOHETXNE320
The data of Glycol air cooler are summarized in the following table.
Table 32: Calculation data of Glycol air cooler
Design Parameter
Unit
Value
187.4
140
Kg/h
897.9
bar
Btu/
hr
1.103
Duty
5.2.2.2
120000
GLYCO/HEATXNR
The data of rich glycol/lean glycol heat exchanger are summarized in the following
table.
Table 33: Calculation data of glycol/ glycol heat exchanger
Design Parameter
Temperature of lean glycol inlet heat
exchanger
Temperature of
lean glycol outlet heat
exchanger
Temperature of rich glycol inlet heat
exchanger
Temperature of
rich glycol outlet heat
exchanger
heat exchanger inlet pressure
5.2.2.3
Unit
Value
199.8
188
70
80
bar
5.5
GLYCOREN/DASMIZ
The data of glycol regen/dry gas economizer are summarized in the following table:
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Value
139
54
48
53.4
bar
30.1
5.3GLYCOUMPS
The data of glycol pumps are summarized in the following table:
Table 35: Data for Glycol pumps sizing
Design Parameter
Unit
Value
GPH
210
Suction pressure
bara
1.1
Discharge pressure
bara
30
138
Suction temperature
Vapor pressure
Mass density
bara
Kg/m
1.18
3
1087
5.4CONDESRCILXHAG
The data of condenser are summarized in the following table:
Table 36: Main Design parameters of Glycol unit condenser
Design Parameters
Type
Heat duty
Unit
Value
Coil exchanger
Btu/hr
47250
5.5REGNTROARBLI
The data of Regenerator Reboiler are summarized in the following table;
Table 37: Reboiler main design parameters
Design Parameters
Type
Heat duty
002/AR11/12
Unit
Btu/hr
Value
Fired heater
exchanger
480000
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The lean glycol downstream the reboiler passes through the Lean Glycol
Stripping Gas Column that contacts the lean glycol with dry gas from flash drum,
further removing water from the glycol to the higher purities required by this
operation, the main design data for the LG stripping gas are summarized in the
following table:
Table 38: LG stripping gas data
Unit
Value
psia
20
Inlet temperature
80
0.273
Column height
1.4
Internals
packed
Packing Type
1 random packing
pall rings
Design Parameters
Inlet pressure
5.7LGLSTICOUMN:
The vapors leaving the glycol reboiler are contacted with cooler liquid on random
packing in the TEG still column and are further cooled by the still column condenser
to provide reflux to minimize glycol losses out of glycol reboiler.
Table 39:LG still column data
Design Parameters
Unit
Value
psia
16
Inlet temperature
80
0.355
Column height
3.81
Internals
packed
Packing Type
1 random packing
pall rings
Inlet pressure
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higher water content in the dry gas stream leaving the contactor. The lower purity is
the higher dry gas water content is.
The next step is to perform the regeneration process trouble shouting as long as
the lean glycol purity is low.
the following regeneration parameters has to be reviewed to improve regenerated
glycol purity:
5.8.1 STPRINGAFLOWE
when increasing stripping gas flowrate
condense the heavier component ( TEG ) in the stream leaving reboiler stage ,and
the water vapour goes back to the still column and will be rejected from the top, as
a result the regenerated glycol purity is improved.
The proposed solution is to add additional amounts of stripping gas coming from
amine flush drum to the existing one coming from glycol flash tank.
The following process scheme shows the glycol purity improvement , to bring it
from 96.2% to 98.65% when increasing stripping gas flowrate.
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The new regenerated glycol purity 98.65% is sweet able decrease the dry gas water
content from 111.3 ppmH2o to 64.4 ppmH2o so that it meets closely the STEG
requirement ( < 80 ppmH2o ).
The following process flow scheme shows the main simulation results using the
improved regenerated TEG purity.
The stripping gas column diameter shall be reviewed since the feed gas flowrate
increased
5.8.2 STPRINGACOLUMDE(TR)
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The stripping gas column diameter is being recalculated via HYSYS software ( tray
sizing utitlity ), the actual stripping gas diameter is 0.27 m , and as per the attached
sizing results the diameter should be 0.3 m.
The following table shows the required stripping gas column design:
1__TS-1
Section End
3__TS-1
Internals
Packed
Section Diameter
(m)
0.3048
Max Flooding
(%)
X-Sectional Area
(m2)
8.45
7.297e002
Section Height
(m)
1.354
Section DeltaP
(bar)
---
DP per Length
(kPa/m)
---
(m3/h-m2)
3320
(m/s)
0.9223
(kg)
47.4
66.30
(m)
0.4514
HETP Correlation
Packing Correlation
Norton
SLEv73
Refrigerant
Chemical
Formula
Molecular
weight
Boiling point
@1bar (C)
Danger
002/AR11/12
Propane
C3H8
44.09
-42
Extremely
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Refrigerant
Propane
flammable gas
Appearance
Skin
Corrosion/Irritati
on
/inhalation
Colorless
Not expected to
be irritating.
Not expected to
be irritating.
No classified
hazard
Protect from
sunlight. Store in
a well-ventilated
place
Eye Damage
Toxicity
Storage
6.2PROPANE RECEIVER
The sizing of Propane receiver drum is determined by referring to standard DEP.
The data of Propane receiver drum are summarized in the following table.
Table 41: Propane Receiver Input Data
Design Parameters
Unit
Inlet vessel
Liquid outlet
Gas outlet
kg/h
5741
0.58
5740
m /h
2514
0.0009
2514
Pressure
bara
1.06
1.06
1.06
Temperature
-39
-39
-39
2.3
585
2.3
Mass density
kg/m
Unit
Value
Diameter
0.98
Height
2.25
6.3PROPANE COMPRESSOR
The main data required for compressor sizing are as follow:
Table 43 : Stage 1 Main Data
Property
002/AR11/12
Value
44.1
Compressibility Factor
0.97
5741
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Property
Value
-37
1.1
4.5
Duty (kW)
143
Table 44 : Stage 2 Main Data
Property
Value
44.1
Compressibility Factor
0.93
5758
24.2
4.5
19
Duty (kW)
165
6.4PROPANE CONDENSER
The sizing of the condenser is performed using the software HTFS (see Appendix8).
The main data required for the simulation are as follow:
Table 45: Propane Condenser Input Data
Inlet
Outlet
19
18.8
Temperature (C)
104
54
Flowrate (kg/hr)
5758
5758
Parameters
Pressure (bara)
Unit
Value
kW
391
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Unit
Inlet vessel
Liquid outlet
Gas outlet
kg/h
5758
3387
2371
m3/h
239.6
12.4
233.2
Pressure
bara
4.7
4.7
4.7
Temperature
-0.4
-0.4
-0.4
24.03
530.1
10.17
Mass density
kg/m
Unit
Value
Diameter
0.45
Height
8.44
Unit
Value
Exchange area
m2
19.5
Heat exchanged
kW
279.9
92
Shell ID
mm
336
Length
3.65
Tube Number
002/AR11/12
Unit
Value
Exchange area
m2
8.5
Heat exchanged
Kw
211.4
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Unit
Value
Tube Number
34
mm
193.68
Shell ID
Unit
Value
Exchange area
m2
2.4
Heat exchanged
Kw
40.8
Tube Number
36
Shell ID
mm
193.68
Length
1.22
6.9COLD SEPARATOR
The sizing of cold separator drum is determined by referring to standard DEP.
The data of cold separator drum are summarized in the following table.
Table 52: Cold Separator Input Data
Design Parameters
Unit
Inlet vessel
Liquid outlet
Gas outlet
kg/h
5616
1105
4511
m /h
30.53
3.26
27.27
Pressure
bara
85.21
85.21
85.21
Temperature
-35
-35
-35
183.9
338.2
165.4
Mass density
kg/m
002/AR11/12
Unit
Value
0.39
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Value
7. NITROGEN SKID
Option 1: Nitrogen injection only for the sales gas only
Table 54: Sales gas Nitrogen Skid main sizing Data
Design Parameter
Unit
Value
Nm3/h
181
Pressure
bar
85
Temperature
< 45
Purity
> 98
Nitrogen flowrate
Unit
Value
Nm3/h
558
Pressure
bar
28.5
Temperature
< 45
Purity
> 98
Nitrogen flowrate
8. SIZING OF PIPELINE
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Property
Value
Difference
(m)
[estimated]
Required Pressure in the tie-in
point with STEG Network (bara)
Pipeline Roughness (mm)
onshore
temperature (C)
Gas Flowrate (mmscfd)
5
76
0.045
25
ground
45
20
5.72
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The results of this simulation for different pipeline diameter are summarized below:
Table 57: Pipeline calculation Results
Diameter
(inch)
4
6
8
10
12
Gas flow
rate
(MMSCFD)
5
5
5
5
5
Pressure
downstre
Loading
Pressure
am PCV
(bara)
85.1
77.3
76.27
76.11
76
at tie-in
point
(bara)
76
76
76
76
76
Velocit
y (m/s)
2.36
1.163
0.664
0.426
0.296
Max
velocity
(m/s)
24
24
24
24
24
Pressure
Max
drop
pressure
(bar/100
drop
m)
(bar/100m)
0.0364
0.0052
0.001
0.0004
0
0.27
0.27
0.27
0.27
0.27
According to NORSOK standard for gas line sizing shown in appendix 5 the selected
pipeline diameter is 4.
9. CONCLUSION
The product streams of Ecumed gas treatment plant are in compliance with STEG
requirements due to the follwoings
Amine unit ( sweetning gas unit ) to remove carbon dioxide (CO2) present in
raw gas.
Increasing the stripping gas flowrate in the dehydration unit in order to
improve TEG purity , as a result the water content removal increases
significantly to reach 31.26 PPMH2O.
A chilling unit is installed to cool down the gas leaving dehydration unit . this
leads to the following :
-additional amount of condensate ( heavy components in the treated gas )
approximately 400 BBl/day.
-decreasing the higher heating value as well as the wobbe index to meet STEG
requirements.
Nitrogen injection into sales gas stream to comply with STEG wobbe index
specification.
The following table shows sales gas specifications versus STEG requirements:
Table 58: Sales gas specifications versus STEG requirements
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Treated Gas
STEG
Specifications
Pressure (barg)
76
75 at tie in point
Temperature (C)
20
10 - 50
5.064
Parameter
Value
9300 - 10228
10,056
11961 - 12640
12,397
81.9
28.01
64.4
< 80
0.3
< 0.5
<2
<6
O2 content (% mol)
Molecular Weight
Actual
Property
volume flow (barrel/day)
50C/1Atm
808.5
0.7269
0.6055
002/AR11/12
Value
684.1
0.3981
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10. APPENDICES
10.1
In case of using the DEA solution the recirculation rate is calculated by the following:
LDEA =
192 MM Xa
WT ML
Where:
LDEA: DEA solution minimum recirculation rate (USGPM)
MM : gas flow MMSCFD
WT : amine solution weight percent circulated
ML : mol loading, moles acid gas/mole
Xa : required reduction in total acid gas fraction.
: Solution density (lb/gal)
10.2
The amine contactor column diameter is determined referring to the given correlation:
Dc=10750
Q
P
Where:
Dc = Contactor diameter in mm.
P = Contactor pressure
Q = gas processed flow rate
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Dr=160 L
Where:
L =
Amine circulation rate (m3/h) = is the design capacity of the lean amine
circulation pump 330-PA-001A/B
10.4
W r =W iW o
The water content of sweet gas respectively inlet and outlet contractor can be
calculated using BUKACEK correlation:
W i=
A1
+ B1
P
W o=
A2
+ B2
P
With:
P:
A1 ,
A 2 , B1 ,
B2
QTEG =
Wo
( E11 )
g (mg/h)
Arm
With:
E:
m
g
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(kg/m.h)
S=
m g
G
With:
m
g
D=
10.5
4S
(m)
In lines where pressure drop is not critical, gas velocity shall not exceed limits which may
create noise or vibrations problems. As a rule of thumb the velocity should be kept below:
0.43
()
V =175
Where:
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10.9
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Section_1
Section Start
1__TS-1
Section End
3__TS-1
Internals
Packed
Mode
Design
Active
Off
Status
Complete
Design Limit
Chanelling
Limiting Stage
1__TS-1
Off
SPECIFICATIONS
Section_1
Section Start
1__TS-1
Section End
3__TS-1
Internals
Mode
Packed
Design
922.6
2.651e-004
----
-144.0
Off
200.9
1.000
SLEv73
HETP (m)
0.4514 *
PACKED RESULTS
Viscosity (cP)
Internals
912.1
2.634e-004
2.607e-004
145.8
147.2
199.4
197.0
Density (kg/m3)
Section End
918.8
80.00
Packing Correlation
Surface Tension
(dyne/cm)
Section Start
VAPOUR PROFILE
3__TS-1
0.4086 kPa/m
Packing Type
2__TS-1
966.9
968.9
971.8
0.5994
0.6072
0.6246
29.49
29.70
29.37
Section_1
(TO TRAY)
1__TS-1
3__TS-1
Packed
1__TS-1
2__TS-1
3__TS-1
Section Diameter
(m)(kg/h)
Mass Flow
0.3048
17.79
13.96
7.215
Max Flooding
(%) (ACT_m3/h)
Gas Flow
20.47 8.45
15.78
8.460
X-Sectional
Area (m2)
Molecular
Weight
7.297e-002
32.14
31.27
21.18
Section Height
(m)
Temperature
(C)
199.41.354
197.0
57.25
Section DeltaP
Density(bar)
(kg/m3)
DP per Length
(kPa/m)
Viscosity
(cP)
Flood Gas
Velocity
(m3/h-m2)
Fluid
Pressure
(bar)
Flood Gas Velocity (m/s)
0.8691
--
0.8849
0.8528
--
1.695e-002
1.212e-002
1.0143320
1.058
1.103
1.615e-002
0.9223
4901
47.4
66.30
HETP (m)
HETP Correlation
002/AR11/12
Packing Correlation
Packing Type
0.4514
Norton
SLEv73
Pall Rings (Metal, random) 1_inch
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PROCESS
Please refer to the piping and instrumentation diagram entitled PROCESS FLOW
GLYCOL DEHYDRATION
PACKAGE , document No R02-06-DWG-PR-00-004.
The Tie in point is located downstream of the ESDV-410 valave and the upstream of
the valve NE- 6008 ( the line in which mounted a restriction orifice RO-410).
The isolation work is guaranteed by closing , the ESDV-410 and valve NE- 6008.
002/AR11/12
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