Paragraph

1

FePO4 stands out from the rest of the -quartz. This is due to the fact that its A
cation is a transition metal. When the experiment is carried out at a temperature of
294K, a tetrahedral structure is created, which is similar to the structure of -quartz.
At 980K, it undergoes a transition process. At this stage, the bridge angles Fe-O-P
increases and angles of the tetrahedral tiles increases. As the discontinuous shift
moves along, the phase will be formed. As temperature increases, they will increase
at a faster rate. The low temperature the structure will be at will result in a P3121
space group. On the other hand, at high temperatures, it will become P6422. An
octahydro structure will be formed when there is a good indication of a very high
temperature. The intensity of the vibrations will largely increase, resulting in a very
large disorder and the tilt angle falls to an estimate of zero. FePo4 has a larger angular
and size difference, which suggests that there is no stability in the -quartz. The
phase will not experience any expansion due to thermal reasons as it does not have the
mechanisms present in -quartz. There are two important variables that decide the
thermal expansion, of which will be discussed in further detail. It is proven that there
is a correlation between O1 and O2 since their coordinates for the atoms is similar to
a great extent. The hydro structure is also disposed of and there is a distortion from
SiO2. The research paper also provides a formula for the - transition that shows
that the tilt angle is a determinant for the temperature, which is as follows:
!

! = ! ! [1 + (1 (T T! / T! T! )] !/! ]
where ! denotes the fall in tilt angle at 980K, where the first transition occurs, and
T! is the temperature where the second transition occurs.
Paragraph 2
Following from the previous paragraph, when the temperature rises, specifically from
294K to 980K, the - transition will occur. When this happens, there will be a
Trigonal -FePO4 unit cell structure. Going into detail, in the lattice parameters, a, b,
and c are exactly the same. When temperature rises, specifically from 980K to 1073K,
the lattice parameter is such that a = b at 90 degrees, but inherently, b c as is equal
to 120 degrees. It thus becomes and adopts a hexagonal FePO4. Subsequently, there
will be an increase is the volume of the call and this is due to the increase in
temperatures. The rising temperatures will cause the crystal structure to grow and
expand and such a phenomenon is more distinct and attractive in the c direction.
Furthermore, there will be an extremely huge drop in the Fe-O bond distance at the
phase, and this is largely attributed to the fact that the fast rigid-unit modes are
directly linked and correlated to the dynamic disorder. Providing reasons for the
stability, we will need to calculate the distance and attribute it to other reasons other
than the reasons as stated below. This research paper tests the limits of ones very
high endurance and perseverance to constantly paraphrase and produce a paper that
meets the necessary word count. Moreover, the - transition is closely linked to ,
which is the tilt angle as mentioned earlier. When the bridging angles of Fe-O-P rise
dramatically, it is vital to note that there are future discontinuities in its structure that
is almost similar to the first transition, as mentioned in paragraph 1. Tables and trends
ought to be included to substantiate this idea. At the second transition of -FePO4, it

is known that the bond distance compression is the most abundant in this area. Other
factors that explains its stability will need to be further discussed in the next section to
ensure that there is a holistic approach to this idea.
Paragraph 3
As mentioned earlier, there will be a - transition at the temperature of 980K.
Comparing the tilt angles, it is largely similar to AlPO4 since the values will likely
come together before the phase of transition and that the smaller tetrahedron has a
much wider tilt angle than that of the larger one. Moreover, the tetrahedral Fe-O
distance is negatively related to temperature, which means as temperature increases,
the distance decreases. This is largely due to the fact that as temperature rises, the fast
movements of the atoms to its maximum point yet its low energy, which will
ultimately result in an extremely large deviation and distortion. It is also largely due
to the fact that the bond distance results in high vibration to the atoms amplitudes and
it falls to a minimum for the length and angle. The paper is again vital for any
manifestation in angles and there is absolutely no good fit to the tetrahedral distortion
in writing this. The dependence is the total neutron that scatters in a tetrahedral
format. In addition, the distortion is caused by tetrahedral tilt, which is measured by
the symmetrically-independence of the two atoms. Results have also shown that there
is a quick and immediate reaction due to the scatter such that the distance between the
two atoms will be expected to rise, especially in SiO2. As a result, we bring in the
above formula again, which quantifies the correlation between the temperatures of the
two angles. The formula is shown below:
!

! = ! ! [1 + (1 (T T! / T! T! )] !/! ]
where ! denotes the fall in tilt angle at 980K, where the first transition occurs, and
T! is the temperature where the second transition occurs. This has specifically shown
that the stability of the inter-tetrahedral bridging angles where the transition of the cell
parameters will be closely related to the maximum capacity of expansion.