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The scanning tunneling microscope (STM) is a nonoptical microscope that scans an electrical probe over a surface to
be imaged to detect a weak electric current flowing between the tip
and the surface. The STM allows scientists to visualize regions of
high electron density and hence infer the position of individual
atoms and molecules on the surface of a lattice. Previous methods
required arduous study of diffraction patterns and required
interpretation to obtain spatial lattice structures. The STM is capable
of higher resolution than its somewhat newer cousin, the atomic
force microscope (AFM). Both the STM and the AFM fall under the
class of scanning probe microscopes. The STM can obtain images of
conductive surfaces at an atomic scale 2 1010 m or
0.2 nanometer,
and
also
can
be
used
to
manipulate
individual atoms, trigger chemical reactions, or reversibly
produce ions by removing or adding individualelectrons from atoms
or molecules.
In a typical STM, a conductive tip is positioned above the
surface of a sample. When the tip moves back and forth across the
sample surface at very small intervals, the height of the tip is
continually adjusted to keep the tunneling current constant. The tip
positions are used to construct a topographic map of the surface.
For a current to occur the substance being scanned must be
conductive (or semiconductive). Insulators cannot be scanned
through the STM, as the electron has no available energy state to
tunnel into or out of due to the band gap structure in insulators. The
following figure shows the schematic diagram of STM.
Special nanomaterials:
Introduction:
In the previous chapters, we have introduced the fundamentals and
general methods for the synthesis and fabrication of various
nanostructures
and
nanomaterials
including
nanoparticles,
nanowires and thin films. How ever, there are a number of important
nanomaterials not included, since their synthesis is unique and
difficult to group into previous chapters. Examples of such
nanomaterials are carbon fullerenes and nanotubes. In addition,
bulk materials with nanosized building blocks, such as nanograined
ceramics and nanocomposites have not been discussed so far. In
this chapter, we will discuss the synthesis of these special
Property
value
Cage diameter
0.7 nm
1.0 nm
0.1448 nm
symmetry
isosahedral
Electron affinity
2.65 ev
7.58 ev
Cohesive energy
7.4 ev/atom
Synthesis:
There are four methods for the production of fullerenes. They
are radio frequency thermal plasma method, laser vaporization, RFinductive coupled plasma discharge method and flame combustion
method.
Fullerenes are usually synthesized by using an arc discharge
(flame combustion method) between graphite electrodes in
approximately 200 torr of He gas. The heat generated at the contact
point between the electrodes evaporates carbon to form soot and
fullerenes, which condense on the water cooled walls of the reactor.
This discharge produces carbon soot that contains up to ~15%
fullerenes: C60 (~13%) and C70 (~2%). The fullerenes are next
separated from the soot, according to their mass, by use of liquid
chromatography and using a solvent such as toluene. However,
there is no definite understanding of the growth mechanism of the
fullerenes. The following figure shows the schematic diagram of
fullerene soot production chamber.
deactivate the enzyme and kill the virus. Ways of getting the
molecule to the enzyme are under investigation
3. Possible applications of interest to industry include optical
devices; chemical sensors
and chemical separation devices;
production of diamonds and carbides as cutting tools or hardening
agents; batteries and other electrochemical applications, including
hydrogen storage media; drug delivery systems and other medical
applications; polymers, such as new plastics; and catalysts.
Catalysts, in fact, appear to be a natural application for fullerenes,
given their combination of rugged structure and high reactivity.
Experiments suggest that fullerenes which incorporate alkali metals
possess catalytic properties resembling those of platinum.
4. The C60 molecule can also absorb large numbers of hydrogen
atoms--almost one hydrogen for each carbon--without disrupting the
buckyball structure. This property suggests that fullerenes may be a
better storage medium for hydrogen than metal hydrides, the best
current material, and hence possibly a key factor in the
development of new batteries and even of non-polluting
automobiles based on fuel cells.
5. A thin layer of the C70 fullerene, when deposited on a silicon chip,
seems to provide a vastly improved template for growing thin films
of diamond.
Carbon nanotubes:
A promising group of nanostructured materials is the
nanotubes, which are currently fabricated from various materials
such as boron nitride, molybdenum, carbon (carbon nanotube), etc.
However, at the moment, carbon nanotubes seem to be superior
and most important due to their unique structure with interesting
properties, which suit them to a tremendously diverse range of
Properties:
The following table shows selected electrical and mechanical
properties of carbon nanotubes.
Characteristics
Measure
Electrical conductivity
Electrical transport
Ballistic, no scattering
E g (ev)=1/d (nm)
1010 A/cm2
Maximum strain
0.11% at 1 V
Thermal conductivity
6 KW/Km
Diameter
1-100 nm
Length
Up to millimeters
Gravimetric surface
>1500 m2/g
E-modulus
Strength 100 times greater than steel at one sixth the weight,
and high strain to failure.