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COAL GASIFICATION
TECHNOLOGY DEVELOPMENT
Prepared for:
Alberta Innovates Energy and Environment Solutions
2.0.
Introduction .............................................................................................................. 5
2.1.
2.2.
3.0.
Project Description................................................................................................... 8
3.1.
3.2.
3.3.
3.4.
3.5.
4.0.
4.1.
4.2.
5.0.
Page 3 of 93
Use of standard oilfield equipment, and well design, drilling, and completions
using technology readily available;
Production of synthetic gas rich in methane and carbon dioxide content, with
relatively little hydrogen and carbon monoxide (indicative of effective
gasification coal conversion and methanation occurring in-situ, as to be expected
under relatively high pressure and modest temperature gasification conditions);
Production of very clean synthetic gas, with very little quantity of entrained coal
conversion byproducts or other contaminants;
Process control variables gave good control over synthetic gas manufacture rates
and gas composition;
The composition of the synthetic gas produced over an extended time frame, with its bias
towards methane and carbon dioxide content, bodes well for the processing of this gas in
commercial-scale ISCG developments to remove (capture) carbon dioxide costeffectively on a pre-combustion basis using established natural gas processing
technologies and processes.
On the basis of the operational experience developed in the course of the project
operations, Synfuels considers deep ISCG at Swan Hills ready for replication-based
deployment in commercial project developments.
Page 4 of 93
2.0. Introduction
2.1.
Project Background
Page 5 of 93
Technical the high pressure ambient environment provided by the deep ISCG
setting facilitates the manufacture of clean synthetic gas rich in methane and CO2
content (with comparatively little H2 and CO), which simplifies surface gas
processing and utilization in applications such as power generation.
The Demo facilities were constructed over the winter of 2008/2009, and operated on both
an intermittent and continuous, extended run basis, over the 2009-2011 period.
Figure 1.
Demo Facilities
Page 6 of 93
2.2.
Project Objectives
The Project Research Plan set forth a set of specific project technical objectives regarding
the Demo performance and testing:
(i)
To be able to ignite, in a fully controlled manner, coal at any point along the inseam length of the injection well and thereby initiate the formation of a gasifier
reactor/cavity at that location;
(ii)
(iii)
(iv)
(v)
To be able to operate in a stable manner at oxygen injection rates within the range
of 5 to 30 metric tonnes/d, with an expected normal operating injection rate of 20
metric tonnes/d.
(vi)
(vii)
To be able to control the water/oxygen ratio and mixing such that stable operation
and thorough mixing can be achieved at any operating point within the specified
ranges for water and oxygen injection.
(viii) To determine the maximum sustainable operating temperature of the syngas at the
production wellhead (subject to metallurgy limitations with the production well).
(ix)
To be able to fully withdraw the injection string at any time during the life of the
well pair, and then reinsert it such that the burner/injection head reaches at least
the location of the most recent gasifier reactor/cavity ignition point.
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(x)
(xi)
To be able to recover produced water to the extent practical from the produced
syngas, and recycle this water for both injection, and production well sparging
use, so as to minimize makeup water requirements
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No coal mine, coal production, storage or handling. This greatly reduces land
surface disturbance, and eliminates issues associated with coal dust, along with
the significant methane emissions to atmosphere that result from surface coal
mining (a potent greenhouse gas agent).
Ability to tap coals too deep to be economical to mine and extract, thus unlocking
the energy potential of these deep, economically stranded coals. With the in-situ
conversion of coal into a synthetic gas, the range of economic possibilities with
respect to the usage of this coal energy is greatly expanded, including both
traditional clean combustion use (e.g., power generation in either traditional
Rankine cycle facilities or combined cycle plants), as well as chemical conversion
opportunities of the synthetic gas into advanced fuels, chemicals, fertilizers, or
other products.
Ash, char, and other solid residual materials from the gasification process remain
behind in the original coal seam, thus eliminating the need for solid waste
handling and disposal that is common in surface gasification operations. In deep
ISCG applications, the high pressure environment favors efficient gasification
conversion of coal pyrolysis products into synthetic gas, thus further reducing the
entrainment of residual materials in the gas flowed to surface.
Historically, ISCG dates back to first postulation in the 1800s, with initial deployments
in Europe and Asia in the 1930s. Most of the older ISCG projects were developed in
relatively shallow coals (< 200 m beneath the surface), largely due to the accessibility of
such coals with well drilling technologies that existed at the time. In the last decade or
so, advances in deep horizontal and directional drilling technology have now allowed
access to deep coals for ISCG; this has resulted in game-changing economic and
environmental improvements for modern ISCG development.
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In-Situ Coal Gasification
Technology Development
The advantages of practicing ISCG in deep (>1000 m depth) coals are summarized as
follows:
In deep ISCG, the process takes place in saline aquifers, and thus the process can
use saline water for makeup purposes. This avoids the use of fresh water in the
deep ISCG process.
The high pressure natural environment in deep coal seams (pressure increases
with coal burial depth) is strongly beneficial to the gasification process, resulting
in more thorough and efficient conversion of coal into clean gas that is produced
to the surface. Generally in packed-bed type gasifiers (closest conventional
gasification process analogue), the synthetic gas produced is a mixture of
methane, carbon dioxide, hydrogen and carbon monoxide. High pressure and
modest temperature generally favors methane and CO2 formation, and disfavors
hydrogen and CO formation. The opposite is true for low pressure (e.g., shallow)
ISCG, particularly at higher temperatures.
The depth of the coal makes it economically and technically unattractive for other
purposes (e.g., coal bed methane development), thus minimizing the potential for
conflict with other development forms. In particular, coal bed methane (CBM)
development could be a potential conflict/competing use for these deep coals.
However, in the Swan Hills are Mannville coals, multiple CBM pilots conducted
in these coals over the last decade have found that the coal permeability is simply
too low at this depth, which, combined with the significant need to dewater these
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coals prior to CBM production, makes CBM development clearly uneconomic for
these coals.
Further, ISCG development of these coals stands to extract a significantly greater amount
of energy per given area of land, compared to CBM extraction. Synfuels has calculated
that per-section (square mile) of Mannville coal in the Swan Hills area, ISCG
development stands to extract more than thirty (30) times more energy than CBM
extraction would from the same land area.
3.2.
Prior to selecting the Swan Hills region for the location of the ISCG Demo, Synfuels
conducted a thorough investigation of various coal zones in Alberta for their suitability
for ISCG, applying a number of technical and environmental screens. Almost all of the
coal zones (including the Ardley, Drumheller, Carbon-Thompson, Lethbridge, Taber,
Mackay, Daly-Weaver) failed the primary environmental screen that of depth of coal
seam and isolation from freshwater aquifers, to mitigate groundwater contamination risk.
In this investigation, the Mannville coals in Alberta emerged as the clear choice for
suitability for ISCG development, offering the following advantages:
wet nature of the Mannville coals presence of saline water in the coal is not
detrimental (in fact, is beneficial) to the ISCG process, in terms of reducing the
amount of saline water which must be injected from the surface to meet the
stoichiometric needs of the ISCG process
This analysis guided Synfuels to secure a project site near Swan Hills, Alberta to host the
ISCG Demo, targeting a Mannville coal seam at about 1400 m depth.
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Page 12 of 93
Figure 2.
3-28-65-11W5
14-23-65-11W5
11-19-65-11W5
8-19-65-11W5
3-21-65-11W5
10-17-65-11W5
1A B /16-9-65-11W5
4-16-65-11W5
1A A /16-9-65-11W5
2-10-65-11W5
9-9-65-11W5
1A A /16-4-65-11W5
4-10-65-11W5
11-36-64-12W5
12-25-64-11W5
6-25-64-12W5
5-22-64-11W5
Synfuels well
Core well
The PDA
Stratigraphy
The Medicine River Coal Seam of the Upper Mannville coal measures is found in the
Falher Member of the Spirit River Formation that belongs to the Lower Cretaceous
Upper Mannville Group. These coal measures, recognized throughout Central Alberta,
contain up to five coal seams and have a thickness of some 70 m in the Swan Hills area.
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While the Demo is focused on the Medicine River Coal Seam, the subsurface geology
and stratigraphic interval of interest involves rock formations from the surface to the
Upper Devonian Ireton shale, Figure 2. Overburden strata above the coal seam are
subject to anticipated subsidence caused by reduction of coal seam volume due to
gasification; at depth parts of these strata will be a source of influx of saline water into
the gasifier cavity while at shallow depth the upper most overburden strata contain fresh
groundwater, and certain parts of the overburden will act a caprock over the ISCG zone.
In general these strata are clastic sediments, sandstones, mudstones and shales in the
upper part of the stratigraphic column, and carbonates, limestones and dolomites as well
as shale in the lower part of the column, Figure 3.
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Figure 3.
Stratigraphy and Coal Measures with the Medicine River Coal Seam
modified from Hitchon et all (1989) and Plains (ERCB, 2009)
Sandstone
Immediate
roof
mudstone and
claystone
Coal
measures
of interest
7.9 m
MEDICINE
RIVER
COAL
SEAM
with two
partings
Immediate
floor
claystone and
sandstone
Coal seam
Shale
Sandstone
Siltstone
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Structure
Regional Structure
The geological structure, both at regional as well as at local scale, is relatively simple.
Within the Demo area the formations dip at about 0.5 degrees to the south west as
illustrated by structure contour map Figure 4 and cross-section Figure 5.
Figure 4.
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Figure 5.
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Figure 7a.
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Figure 7b.
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Figure 7c.
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Figure 8.
The most revealing observation of the seam's local structure is the well-path of the
injection well, Figures 9a and 9b, drilled along the eastern border of section 9. Over most
of the well-path the seam gently undulates from 0 to 1.2 degrees and then rises at 2.5
degrees in the last 100 m of the well in the very NE corner of section 9. Between the
well's intersection of the seam in the build section and the penetration of it in the
production well, a distance of approximately 1200 m, the seam floor rises from an
elevation of -404.5 m to -402.1 m, an overall southerly dip of 0.2 degrees.
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Figure 9a.
Figure 9b:
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Page 23 of 93
Table 1.
Swan Hills Synfuels Wells
Year drilled, Well name and UWI
Depth Purpose and Status
[m]
2007:
SYNERGIA SWAN HILLS 9-9-65-11
100/09-09-065-11W5/00
1460
TVD
2008:
SH SYNFUELS 102 SWANHS 16-965-11
1AA/16-09-065-11W5/0
1344.5
TVD Horizontal injection well
2833
MD
2008:
SH SYNFUELS 100 SWANHS 16-965-11
1AB/16-09-065-11W5/00
1427.5
TVD Production well, vertical and partly slanted
with a 19.4 m core.
2012:
SH SYNFUELS SWANHS 4-16-65-11
100/04-16-065-11W5/0
1431
TVD
Evaluation/Observation well
with 120 m of core.
These wells provided geological data in form of cuttings, geophysical logs and core of
the roof rock, coal seam and of floor rock.
The evaluation wells are the two core wells 9-9 and 4-16. A core of roof rocks of the
Medicine River coal seam was also cut in the 20 slanted bottom section of the
production well 16-9. Only a small amount of coal core was recovered in this well.
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The secondary purpose was installation in the well of microseismic and thermal
monitoring instrumentation for observation of the behavior of strata in the area of coal
gasification.
An interval 29 m in length was cored in this well; the core was cut in two core runs:
CORE 1: 1357-1372 m - 15 m core, 14.72 m recovered (98 %)
CORE 2: 1372-1386 m - 14 m core, 10.23 m recovered (73 %)
Core 1: 14.4 m sample of the coal seam's roof rock. The immediate roof is 20 cm of
coaly claystone with 2-4 mm thick lenses of bentonite, 90 cm of coarsely fissile and
slickensided carbonaceous claystone and 1.6 m thick mudstone with two, almost vertical,
joints. The main roof is 9.8 m of medium to coarse grained sandstone thin laminated
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In-Situ Coal Gasification
Technology Development
with carbonaceous dust. Further up is 2 m thick sandstone interbedded with siltstone and
minor shale. Siderite is common throughout.
Core 2: coal and floor rock. The coal seam is 8 m thick: 3.4 m of coal, 0.5 m parting, 1.2
m coal, 0.9 m parting and 1.6 m coal. Only 2.5 m of coal was recovered; most of the core
was lost from the top 3.6 m part of the seam. The core of the immediate floor is 0.4 m
thick slickensided and moderately carbonaceous claystone with a vertical joint. It is
underlain by 2.5 m of coarse grained, clayey salt-and-pepper sandstone. The core
includes a 1 m coal seam at 4.3 m below the main seam.
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Page 27 of 93
Figure 10.
Name
UPPER SEAM
3.4 m
Upper Parting
0.5 m
MIDDLE SEAM
1.4 m
Lower Parting
0.8 m
LOWER SEAM
1.9 m
Marker 0.1 m
Total Th = 8.0 m
The Medicine River Coal Seam maintains similar structure and thickness throughout the
eastern part of section 9 as illustrated by correlation of Synfuels' three wells and the
nearest offset well located along the eastern edge of section 9 , as shown in Figure 11.
Page 28 of 93
Figure 11.
16-9-65-11W5
Med. R.:
7.7 m thick
9-9-65-11W5
8.0 m thick
16-4.16-9-65-11W5
7.8 m thick
4-10-65-11W5
7.9 m thick
Within the Demo general area the seam ranges in thickness from 7 to 8 m, as shown in
Figure 12.
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Figure 12.
Seam Characterization
Macro-petrographic composition of the Medicine River Coal Seam presented below
combines data from the 2007 core well and description of cuttings from Synfuels'
injection well.
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The Upper Seam is from 3.4 to 5.2 m thick in Demo area. It contains a band of slightly
higher gamma, probably a band of volcanic ash that allows informal subdivision as
follows:
Top ply approximately 1 m thick, dull to dull banded coal, dominated by durain
and clarain, less than 50% of vitrain and minor fusain; 0.5 m thick band of higher
ash coal;
Bottom ply 2 to 4 m thick, clean, low ash coal, banded coal of clarain and
vitrain.
The sample of the Upper Seam recovered in well 9-9 is 20 fragments of coal (9%
recovery). They are dull and dull banded coal with vitrain bands up to 6 mm thick. It is
unknown what part of the 3.6 m Upper Seam they represent. Since dull coal is harder
than bright coal it is probable that most of the brittle bright and bright banded coal was
part of the lost core.
The Upper Parting is 0.5-0.7 m thick; it is soft, dark gray coaly claystone;
Middle Seam is 0.6-1.0 m thick in PDA. The core (62% recovery) was of dull banded to
banded coal with vitrain up to 30 mm thick. Cleat is present as some of the core
fragments were broken along cleat. Cuttings indicate dull coal (durain and clarain) with
only 20% of vitrain in the upper part of the seam grading downward into dull banded to
banded coal in the lower part of the seam.
Lower Parting is 0.7-1.2 m thick. It is medium to dark gray blocky claystone with coaly
traces, the rock is slickensided and soft.
Lower Seam is 1.6-1.9 m thick. The core of the top ply of the Lower Seam was mainly
banded and dull banded coal with minor bright banded coal, as shown in Figure 13.
Based on samples of cuttings the coal is dull to banded coal with varying amounts of
bright and brittle vitrain, glossy clarain and dull durain lithotypes. Cuttings with microbanding are common, indicating the presence of bands of clarain or clarodurain with thin
(< 1mm) bands of vitrain. The vitrain content in cuttings ranges from 30% to 80%. The
thickness of vitrain bands, measured on coarse chips, ranged from 1 mm to 15 mm, and
rarely up to 20 mm while in solid core the thickest band of bright coal, pure vitrain, is 40
mm thick.
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Figure 13.
Fusain is omnipresent but only as small amounts in the form of commonly occurring thin
bands. It is up to 5 mm thick in cuttings which rarely exceed 10 mm in size.
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Geophysical logs of the Lower Seam and geosteering experience of drilling the injection
well support subdivision of the Lower Seam into two coal plies separated by a volcanic
ash marker:
Top Ply lower gamma (15-40 API units), lower ash coal
Volcanic Ash Marker high gamma bed (45-95 API units)
Bottom Ply higher gamma (40-80 API), higher ash coal
The injection well moved between both plies and most of the horizontal length of the
well was drilled following the volcanic ash marker, either in it or just above or just
below.
Volcanic Ash Marker is a 10 cm thick layer of "dirty" coal, mainly durain contaminated
with dust, grains and globules of volcanic ash altered to kaolin and kaolinic clay. The
coal is of gritty and of rough texture with white and beige kaolin particles ranging in size
from 60 to 100 microns in the drilled coal chips sampled in the injection well. Because
of its high gamma (50-80 API) and small thickness the Marker was used as a reference
layer in geosteering the injection well.
Generally, the Bottom Ply of the Lower Seam appears to contain less of bright coal than
the Top Ply; it is mainly dull to dull banded coal. The Top Ply is richer with vitrain in its
lower half, dominated by banded coal. The 2007 core of this part of the seam includes
the two thickest bands of vitrain observed in the core: a 4 cm and a 2 cm band of bright
(pure vitrain) coal. The upper half of the Top Ply it is mainly dull banded coal.
Cleat
The seam is moderately to poorly cleaty. The Middle and Lower seams are
predominantly dull and dull banded coal with average face cleat spacing of 2 to 2.5 cm in
the Lower Seam and 2 cm in the Middle Seam. Very little butt cleat has been observed.
Part of the core of the Top Ply of the Lower Seam was split along an almost 40 cm long
face cleat and 3 to 4 face cleats were distributed at 1-4 cm spacing across the 10 cm core
diameter; as shown in Figure 14 below. Cleat in core of the thin seam below the
Medicine River Coal Seam is similar.
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Figure 14.
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Figure 15.
From this graph Mannville coal at depth of 1350 to 1400 m would have a permeability of
about 0.7 mD.
The Lower Seam of the Medicine River Coal Seam recovered in the core well 9-9 was
mainly dull banded lithotype with poor cleat; average face cleat spacing of 2-2.5 cm and
very limited, if any butt cleat.
Partings
The Medicine River Coal Seam contains one to two claystone partings. The partings
represent from 8% to 19% of the coal seam's gross thickness, Table 2.
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Table 2.
Well:
Seam Thickness:
Upper parting:
Lower parting:
Partings share:
8-19
10-17
3-21
4-16
16-9
9-9
16-4/16-9
7.2
0.7
10%
7.7
0.6
8%
7.8
0.6
8%
7.2
0.4
0.8
17%
7.8
0.5
0.8
17%
7.9
0.6
0.9
19%
7.9
0.5
0.7
15%
The Upper parting, as observed on core form 9-9-65-11 evaluation well, is a soft dark
gray claystone with moderate abundance of plant debris, coalified leaves and small stems,
and with thin bands of vitrain ranging in thickness from hairline to 1 mm. The quantity
of the vitrain bands is greater near the bottom of the parting. The core of this rock
fractures easily along bedding into coarse, 2-4 cm thick, poker-chip plates. Slickensided
fracture was present above the parting's base. The Upper parting is present in the eastern
part of the Demo area, in sections 9 and 16. It ranges in thickness from 0.6 to 0.4 m in
wells where it was intersected and thins to 0 m along its projected depositional edge, as
shown in Figure 16.
Ash content of the Upper parting is 83%, VM=7.2%, FC=1.7% and HV=586 kJ/kg. Ash
fusion temperature in oxidizing atmosphere is 1461C.
The Lower parting, ranging in thickness from 0.6 to 0.9 m, appears to be present
throughout the Demo area, as shown in Figure 17. The combined thickness of the
partings is illustrated by Figure 18.
The parting, in 9-9-65-11 evaluation well, is a soft, medium to very dark gray coaly
claystone with frequent lenses and bands of vitrain mainly 1 to 4 mm thick and
exceptionally over 20 mm thick. The bottom third to half of the parting is of lumpy
texture, the rock slickensided and partly turbated that breaks down easily into small to
tiny slivers. A nearly vertical (80 deg) joint was observed in the upper part of the core.
The rock breaks down easily along bedding planes or along slickenside fractures.
Ash content of the Lower parting is 78%, VM=10.2%, FC=7% and HV=3500 kJ/kg. Ash
fusion temperature in oxidizing atmosphere is 1461C.
Both partings are considered weak, soft interburden expected to break down and collapse
easily into the active gasifier. Non-slagging character of both partings indicated by high
ash fusion temperatures will not interfere with partings breakdown. Although the Lower
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parting is somewhat thicker than the Upper parting, its carbon content and weaker, partly
slickensided structure will facilitate its collapse under ISCG process conditions.
Figure 16.
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Figure 17.
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Figure 18.
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between the Medicine River Coal Seam and overlying Joli Fou Formation and Viking
Formations.
Figure 19.
These strata will be affected by localized subsidence, caving and settling of the roof
rocks, and, to a lesser extent, strata below the seam by heaving of the floor due to
extraction of approximately 4.7 m of the seam thickness by in-situ gasification.
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Roof Characterization
Figure 20.
Roof Characterization
The immediate roof is a thin 0.4 to 0.9 m thick layer of claystone or coaly claystone
above the coal seam. It is a dark gray to black, carbonaceous or coaly, coarsely fissile
and partly slickensided rock that crumbles easily. It contains an abundance of plant
debris. It is classified as a weak immediate roof. In all three cores its RQD is 0. An
analysis of a 30 cm sample of this claystone in well 9-9 indicated 20% carbon content
and calorific value of 9330 kJ/kg.
The claystone roof is generally present in the Demo area.
In the core of well 9-9 the immediate roof is a 20 cm bed with five very thin (2-4 mm
thick) lenses of bentonite and traces of coal. The coaly claystone grades upwards into 0.9
m thick, coarsely fissile and slicken-sided carbonaceous claystone that is overlain by 1.6
m thick mudstone with two, almost vertical, joints.
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Figure 21.
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Figure 22.
This main roof extends into a zone dominated by multiple sandstones of variable
thickness interbedded with siltstones, mudstones and minor shales. It also includes few
thin coal seams or coaly stringers.
In core of well 9-9 the core that includes the main roof is a 9.8 m thick medium to coarse
grained sandstone thinly laminated with carbonaceous dust. Further up is 2 m sandstone
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interbedded with siltstone and minor shale. Siderite is common throughout. No joints
were encountered in this vertical core. Sandstone beds range in thickness from less than
to 2 meters to almost 30 m thick channel sandstone in well 8-9-65-11W5 just north of the
Demo area.
In core of the production well 16-9-65-11W5 the lithology of 9 m of core was practically
all siltstone and at 20 angle of the hole the core encountered tree vertical joints spaced at
0.2 and 0.4 m.
The sandstones within the "cave zone" range are fine grained kaolinic salt & pepper to
fine or very fine grained, frequently laminated and often bioturbated, rocks. They consist
of subangular to subrounded grains of silt-size, very fine to fine quartz and varying
amount of dark gray to black chert with kaolinic or calcareous cement and varying
amounts of carbonaceous dust and plant debris. The sandstones occur as beds ranging in
thickness from more or less one meter to fluvial channel sandstones up to 13 m thick
within the project area or 28 m thick north of the project area in section 18.
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Figure 23.
Floor isopach
Caprock
In oil and gas geology the caprock is defined as shale or other impervious, sealing rock
that acts as a barrier to the movement of oil and gas and so it forms a reservoir trap.
Usually it is shale overlying the hydrocarbon bearing formation.
The concept of caprock integrity has become critical in the recovery of heavy oil and
bitumen by SAGD (steam-assisted gravity drainage) where the caprock must remain
undisturbed to prevent reservoir fluids escaping into shallow groundwater or to the
surface as the result of reservoir modifications by the recovery process and technology.
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In case of the ISCG the integrity of up to over 200 m of the overburden above the coal
seam may compromised by localized subsidence. Therefore the function of caprock, the
sealing stratum, must be assigned to 500 m thick shales of Colorado and Lea Park
formations. These shales are the lower part of the zone without significant fracturing.
They are the caprock formation in the SHS project area, Figure 24. Figure 25 is an
isopach map of the Lea Park-Colorado caprock.
The shale is generally composed, in order of decreasing abundance, of mixed-layer
illite/smectite, quartz, kaolinite, potassium feldspar, siderite and pyrite with minor
muscovite, chlorite and biotite, Leckie et al., 2012.
Figure 24.
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Figure 25.
Isopach of combined Lea Park and Colorado shales (top of Lea Park
Formation to top of Viking Formation)
Coal Quality
The Medicine River Coal Seam is a high volatile B bituminous coal with vitrinite
reflectance Romax ranging from 0.64 to 0.69 for the three sub-seams.
Average values of Proximate and Ultimate analyses of the core of Medicine River Coal
Seam from well SYNERGIA SWAN HILLS 9-9-65-11 are shown in Table 3 below.
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In-Situ Coal Gasification
Technology Development
Table 3.
Table 4.
Ultimate Analysis
Parameter
Moisture Free
Ash [%]
9.7
Carbon [%]
74.4
Hydrogen [%]
3.58
Nitrogen [%]
1.1
Sulphur [%]
0.4
Oxygen [%]
10.7
3.3.
As discussed in the previous section, at this coal seam depth, the permeability of the coal
is very low. This required the selection of an ISCG process (well pair configuration) that
provided a mechanical linkage between the wells, rather than rely upon coal permeability
to flow gas and fluids between the wells of an ISCG well pair. Thus, the CRIP
(controlled retracting injection point) ISCG approach was chosen, which uses a
horizontal injection well paired with a vertical production well, as the ISCG well pair, the
principal building block of an ISCG development.
The ISCG process drives coal gasification to occur by creating the right process
conditions (pressure, temperature, presence of required reagents) to encourage
gasification chemical reactions to take place.
The oxygen injected into the active gasifier chamber combusts coal volatiles and a small
portion of the manufactured syngas at temperatures over 1000C in the vicinity of the
teardrop-shaped coal face within the gasifier. The heat from this combustion serves to
boil water present in the system, generating steam, which is an important reagent in the
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gasification chemical reactions. The heat also penetrates the coal to some degree (several
cm), driving coal devolatization, pyrolysis, and finally gasification to occur at the coal
face. Figure 26 below illustrates the coal conversion process which occurs in the skin
layer of coal at the coal face:
Figure 26.
Heat
Coal Volatiles
Unaffected
Coal
Zone
Coal
Devolatization
Zone
Coal
Pyrolysis
Zone
Coal Char
(Gasification)
Zone
Gasification
Zone
Coal
Pyrolysis
Volatiles
Combustion
Zone
Oxygen
Syngas
Water
(Steam)
As coal is gasified at the coal face, the remaining coal char and ash spalls off of the face
and falls to the bottom of the gasifier, building a bulk pile of this unconsolidated material.
The spalling results in an eating away of the coal face, thus exposing fresh coal to the
process. In this manner, the ISCG process continuously erodes the coal face as coal is
converted, thereby growing the active gasifier chamber in all dimensions.
At all times a pressure draw is maintained via the production well, thus drawing the raw
syngas produced towards the production well. This elongates the gasifier chamber into a
teardrop shape as it grows; if no pressure draw was maintained, the gasifier chamber
shape would be spherical. Normal operating pressure of the gasifier chamber is in the 1012.5 MPag range.
Oxygen and saline water injected into the gasifier at the injection point (point where the
coiled tubing burner was used to initiate gasification in this chamber) flow outwards
towards the coal face, where the oxygen is consumed in the combustion zone. The
Final Outcomes Report
Page 49 of 93
In-Situ Coal Gasification
Technology Development
injected water (together with any natural formation water present) is converted to steam
by the high temperatures near the combustion zone, thus providing steam for
participation in the gasification chemical reactions as the principal source of hydrogen for
these reactions.
As the gasifier chamber continues to grow laterally and vertically, with char and ash
rubble accumulating as spalling occurs, the top of the coal seam is eventually reached.
At this point, the gasifier chamber continues to propagate laterally into the coal seam, but
some of the heat generated in the reactor serves to cause the immediately overlying rock
to crack, break apart and fall into the reactor, contributing to the ash/char pile. As the
gasifier chamber grows, this roof spalling continues, until the bulking of the
unconsolidated roof pieces fills the chamber (though with major interstitial spaces) and
prevents further roof spalling.
Theoretically, a gasifier chamber could continue to propagate laterally in the coal seam
indefinitely, but in practical terms, pressure drop considerations, as well as potential falloff in syngas quality (due to heat loss to the overlying strata in disproportionate quantities
to the heat that is actually working coal), will prescribe an arbitrary limit to the practical
extent of lateral chamber propagation. Synfuels has chosen this limit to be ten times coal
seam thickness (or a total gasifier channel width limit of about 80 m) for the Project.
When this chamber growth limit is reached, the coiled tubing/burner is retracted a
distance towards the heel of the injection well, and a new chamber is initiated in fresh
coal. The previous chamber(s) are then used as the now high-permeability flow path to
flow the raw syngas from the active gasifier chamber to the production well. Figure 27
shows a schematic of the well pair configuration is shown below:
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Figure 27.
The horizontal injection well is used to inject oxygen and saline water into the coal seam.
The oxygen supports a limited amount of combustion, which heats up the coal and boils
both the natural formation water present along with injected saline water, to generate
steam. The resultant conditions (high temperature, high pressure by virtue of the
formation depth, and the presence of steam) cause a number of chemical reactions to
occur whereby the coal is converted into a gas, which consists primarily of synthesized
methane, carbon dioxide, hydrogen and carbon monoxide. This gas is then conducted up
to the surface via the vertical production well, where the gas can then be processed in a
conventional gas processing facility to remove the CO2 component in an efficient, costeffective capture process (using standard natural gas processing techniques) for further
utilization (enhanced hydrocarbon recovery) and storage. The remaining clean gas
stream (methane, hydrogen, carbon monoxide) can then either be burned as fuel for heat
and power generation, or can be further converted in a facility into other products such as
liquid fuels or chemical products.
A typical mass balance for a well-pair (gasifier) under normal conditions is shown in
Figure 28 below:
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Figure 28.
Oxygen 45 t/d
Formation Gas Losses
19 t/d
Injection
Water 45 t/d
Coal 118 t/d
Sparge
Water 150 t/d
Gasifier
Chamber/
Reactor
Natural Free
Water Influx 5 t/d
As ISCG progresses along the axis of each horizontal injection well from the toe back
towards the heel of the well, the syngas manufactured in the active gasifier has more
opportunity to cool along the flow path back to the production well. As such, over time
the temperature of the syngas arriving at the production well is expected to decrease,
ultimately to approach the saturation temperature of steam at the system pressure,
approximately 325C. As this cooling progresses, the need for sparge water in each
production well will diminish, with a corresponding decrease in water production tonnage
with the raw syngas.
Synfuels experience with the Demo has shown that under the operating conditions
anticipated for the Projects well-pairs, the expected raw syngas composition is as
follows:
Table 5.
Component
CH4
CO2
CO
H2
C2 +
37%
41%
5%
15%
2%
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Figure 29 below illustrates the main input and output flows for the each gasifier:
Figure 29.
Non-fresh
free
water
influx
Possible
gas
losses
Gas
produced
Control
Volume of
In-Situ
Gasifier
Injectants
(O2, water,
N2)
The gasifying agents injected from surface via the injection well. The two main
gasifying agents are (i) oxygen and (ii) water
The char and ash remaining within the chamber after gasification
The in-situ gasifier natural water influx including (i) the moisture content of
gasified coal and (ii) non-fresh free water from surrounding strata
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The position of the injection point in the horizontal in-seam section of the
injection well
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Page 55 of 93
Figure 30.
Page 56 of 93
Figure 31.
Figure 32.
Water and N2 pipelines are routed between the Injection and Production Sites. A
dedicated 6 km, 4 pipeline also provides natural gas to the Production Site. An access
road connects the two sites with existing road infrastructure to the east of the project site.
.
Page 57 of 93
Figure 33.
The Demo facilities, inject oxygen and water to nominally manufacture 113 e3m3/d of
wet, sour raw syngas from about 75 t/d of coal gasified. The primary purpose of the
Injection Site facilities is to provide oxygen and non-fresh water to support the
gasification process, and nitrogen for well control as well as O2/N2 blending for ignition.
The primary purpose of the Production Site facilities is to collect and cool the produced
syngas, recover condensed and produced water, and analyze the syngas prior to its
disposal by flaring or incineration. The raw, wet syngas mainly contains methane, carbon
dioxide, hydrogen, carbon monoxide and small amounts of H2S.
Plot plans for both the Injection Site and the Production Site are included as Figure 34
and 35 respectively.
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Figure 34.
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Figure 35.
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The injection and production wells within a single ISCG well pair are separated at the
surface by approximately 1.6 km.
Figure 36.
Surface Csg
Surface Csg
Production tubing
Intermediate Csg
Sparge Line
Intermedate casing
Burner
The injection well is approximately 2800 meters in length and is composed of a ~1400
meter vertical section, and a ~1400 meters horizontal section connecting to the toe of the
paired production well. The injection well uses a bi-centric Coiled Tube (CT) injection
string, installed within a 114mm casing. The CT allows the intermittent injection of
ignition fluid and fuel, and the continuous flow of oxygen.
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Figure 37.
The annulus between the CT and the 114 mm casing is used for water injection (Water
Annulus). The annulus between the intermediate casing and the 114 mm casing is
continuously purged with nitrogen.
Water and oxygen are injected via the injection well to support the in-situ gasification
process. The resultant manufactured syngas flows toward the production well where the
gas is quenched with sparge water before flowing up the production tubing string. As the
coal is converted, the CT is retracted inside the 114mm casing, back into unreacted
portions of the coal bed.
The production well is completed with two tubing strings, the syngas production string
and the sparge water injection string, with the sparge water injection string installed
inside the syngas production string. The intermediate annulus between the syngas
production tubing and the casing is continuously purged with nitrogen.
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Figure 38.
Production Wellhead
The wells are designed to meet the operating conditions of ISCG which include high
pressures and temperatures, as well as corrosive fluids including CO2 and H2S. The
wellbore and Coil Tubing (CT) were designed to meet API standards, as per the
following:
Casing
API 5CT
Wellhead
API 6A. PSL 1 PR1
BOP's
API RP 53
CT
API 5CLP
HP oxygen is supplied from the Injection Site to the injection well. The oxygen is routed
on flow control to the CT at the injection well head, and from there, it is injected into the
gasification chamber.
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HP nitrogen is supplied from the Injection Site to the injection well. Nitrogen supply to
the oxygen annulus within the CT is included for control purposes as well as for start-up
where ignition is initiated with a controlled blend of oxygen and nitrogen. Nitrogen is
also used to maintain a casing purge on both wells.
Injection water is supplied from an injection water tank located at the Injection Site. This
water is pressurized and flowed down the injection well via a dedicated annulus to the
gasification chamber.
Reaction chamber pressure for the well pair is controlled at the production well using a
back pressure control valve. Bottom hole pressure at the production well is measured
using a bubble tube assembly. Bottom hole pressure at the injection well is calculated by
measuring surface pressure in the CT and adjusting as required for density and flow
losses.
After reaching the surface of the production well, the hot, wet, raw syngas is routed to the
Production Site facilities.
Injection Site Process Description
The Injection site includes the following equipment:
Injection wellhead, Coil Tubing assembly and associated facilities
Injection Manifold Skid
Oxygen and Nitrogen Skid
Water Storage and injection system
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Figure 39.
20,000 kPag
20 C
30 Tonnes/d
20,000 kPag
20 C
15 Tonnes/day
1379 kPag
20,000 kPag
14,000 kPag
90 Tonnes/d
Page 65 of 93
O2 and N2 Skid
Both liquid nitrogen and liquid oxygen are trucked in and stored in tanks at cryogenic
temperatures. Liquid nitrogen feeds the nitrogen pump where the pressure is increased
before flowing to the nitrogen vaporizer. The tanks are vertical siphon cryogenic liquid
storage tanks with a design that maximizes efficiency by reprocessing the heat of
pumping. All tanks have their own ambient vaporizer for tank pressure control. The
oxygen pump and both of the liquid nitrogen pumps are reciprocating plunger pumps
Final Outcomes Report
May 2012
Page 66 of 93
with variable frequency speed control and are designed for cryogenic operation. The
oxygen vaporizer is a water bath electric heater utilizing an inhibited ethylene
glycol/water mix as the heat transfer medium. This solution will prevent freezing down
to -40 oC. The nitrogen vaporizer is a direct electric heater, with the heating coil cast into
an aluminium block. Both of the vaporizers are designed to take the cryogenic liquids at
high pressure and heat them to 20 oC. Since the operating pressure in both systems is
well above the critical points of the respective fluids, the fluids do not change phase, but
rather undergo a density shift as they are warmed. A low temperature shutdown on the
downstream side of the heaters prevents any liquid carryover.
Figure 41.
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Figure 42.
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During the ignition sequence, ignition fluids consisting of a pyrophoric liquid (triethyl
borane) and a fuel (propane) are injected down the well through the ignition string. This
ignition fluid sequence is only used to initiate gasification and is not required during
normal operation of the facility. The pyrophoric fluid is first injected followed by the
liquid fuel. Nitrogen is used to push the ignition fluids down the well.
The ignition fluid liquid slug is pushed down injection fuel line to the burner tip at the
end of the coiled tubing string. The oxygen and ignition fluids slug launches are timed
such that the ignition fluid arrives very shortly after the oxygen. The pyrophoric fluid
autoignites in the presence of oxygen and as a result ignites the ignition fuel. The
resultant burner flame melts through the injection well liner and initiates the combustion
of volatiles in the near burner area, thus commencing the gasification process.
Figure 43.
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Page 70 of 93
Figure 44.
Figure 45.
Page 71 of 93
Figure 46.
Utility Nitrogen
Utility nitrogen, which is used for blanket gas, instrument gas and low pressure purging is
generated by vaporizing low pressure liquid nitrogen using a nitrogen utility vaporizer.
This is an electric heater which increases the nitrogen temperature to about 20 oC.
Page 72 of 93
Figure 47.
113.3 e3m3/d
9,100 kPag
300 C
Page 73 of 93
Figure 48.
Figure 49.
The condensed water is level controlled in the inlet separator and routed to the Flash
Separator for further separation.
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Syngas from inlet separator is pressure controlled to either the flare or the incinerator.
Prior to disposal via flare or incineration, the syngas is metered and analyzed using a gas
chromatograph.
All critical flows, pressures and temperatures for the syngas and recovered water are
continuously monitored and trended in the control system historian.
Figure 50.
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Figure 51.
Water Handling
Water removed in the inlet separator is reduced in pressure and routed to the flash
separator. In the flash separator, gases liberated by the drop in pressure are removed and
sent to the high pressure flare header. Water from the flash separator is filtered and sent
to the sparge water storage tank, back to the sparge pumps or routed to the injection site
via buried pipeline for use as injection water. The site water balance and water quality
dictate where the water is routed.
A fuel gas blanket is maintained on the sparge water tank to prevent air ingress. Any
vapours released from the water are routed to low pressure flare header.
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Figure 52.
Flash Separator
Figure 53.
Flare System
There are two separate flare systems at the production site. Although both operate at low
pressure, they are referred to as the high pressure and low pressure flares in reference to
the operating pressures of the systems that connect to them.
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Vessel pressure safety valves, control (blow down) valves, and the sales gas to flare
valves from main processing equipment are tied into the high pressure flare system. The
high pressure flare system contains the high pressure flare knock-out drum and flare
stack. The flare header is continuously purged with a small volume of fuel gas. The flare
stack is kept lit with a continuous-spark ignition system. Liquid collected in the high
pressure flare knock out drum is removed by level switch activation of the high pressure
knockout pump. The liquid, which is primarily water, is pumped to the sparge water
storage tank.
Low pressure venting from analyzers, glycol surge drum, and atmospheric storage tanks
are tied into the low pressure flare system, which contains the low pressure flare knockout drum and flare stack. The low pressure flare header is also continuously purged with
a small volume of fuel gas. The flare stack is kept lit with a continuous-spark ignition
system. Liquid collected in the low pressure flare knock out drum is removed by level
activation of the low pressure knockout pump. The liquid, which is primarily condensed
water from tank vapours, is pumped to the water storage tank.
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Figure 54.
Incinerator
Syngas from the inlet separator is sent to an incinerator, which is a forced draft thermal
oxidizer designed for destruction of 99% of contaminants in the syngas stream such as
H2S and aromatic compounds. Destruction efficiency is maintained by controlling the
incinerator top temperature. An integral knock-out drum in the base of the incinerator
captures any condensed liquid in the feed line before gas enters the main burner.
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Figure 55.
Incinerator
Fuel Gas
Fuel gas is pipelined to the production site from an area supplier. Upon entering the facility,
the fuel gas is routed to the fuel gas scrubber to remove any condensed liquid before feeding
the fuel gas supply header. In addition to vessel blanket gas and sweep gas for the flare
headers, fuel gas is added to the flare system as required to increase the energy content of
the overall gas mixture during flaring events.
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Instrument Air
Air is used to power and operate many of the instruments on the production site. This
instrument air is provided by two duplex screw air compressor packages with dry air
storage. Critical instruments have nitrogen cylinders that backup the instrument air in the
event of a loss of air compression.
3.5.
One of the key features and successes of the Demo is the use of standard oil and gas
equipment, materials, design codes, and operating and maintenance practices generally
throughout. The capabilities and depth of experience available with respect to
engineering, supply, construction, operation and maintenance from the Alberta oil and
gas industry was found to be suitable for conducting ISCG operations in Albertas deep
coals.
The Demo results, vis--vis the technical objectives set forth in section 2.2 above, were
as follows:
(i)
To be able to ignite, in a fully controlled manner, coal at any point along the inseam length of the injection well and thereby initiate the formation of a gasifier
reactor/cavity at that location;
The Demo achieved this objective. Synfuels developed and refined an ignition procedure
which is based on starting the ignition process at low energy levels, and then step-wise
incrementing energy levels in a controlled manner if previous ignition attempts are
unsuccessful.
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(ii)
The Demo achieved this objective and repeatedly demonstrated this capability.
(iii)
The Demo achieved this objective, although given the early stage of life for the well pair
(i.e., first few years, as against a 15+ year planned well pair operational life), operations
were necessarily restricted to the far end of the injection well length.
(iv)
The Demo partially achieved this objective, with operation at well below reservoir
pressure (i.e., low end of the range specified in the objective) planned for future
operations.
(v)
To be able to operate in a stable manner at oxygen injection rates within the range
of 5 to 30 metric tonnes/d, with an expected normal operating injection rate of 20
metric tonnes/d.
The Demo has achieved a portion of this objective, with operations conducted over a
wide range of oxygen injection rates, and confirmed expected gas manufacture rates at
varying levels of oxygen injection. Further testing in this regard is planned.
(vi)
The Demo achieved this objective, and demonstrated the influence of water/oxygen
injection ratio on syngas composition, notably the relative fraction of methane and CO2
manufactured at varying water/oxygen injection ratios.
Final Outcomes Report
May 2012
Page 82 of 93
(vii)
To be able to control the water/oxygen ratio and mixing such that stable operation
and thorough mixing can be achieved at any operating point within the specified
ranges for water and oxygen injection.
To be able to fully withdraw the injection string at any time during the life of the
well pair, and then reinsert it such that the burner/injection head reaches at least
the location of the most recent gasifier reactor/cavity ignition point.
To be able to recover produced water to the extent practical from the produced
syngas, and recycle this water for both injection, and production well sparging
use, so as to minimize makeup water requirements
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The Demo has achieved this objective, including use of saline water for makeup water
purposes, with such saline water being considerably higher in total dissolved solids than
saline water from the coal seam itself, with no effects on the ISCG process.
4.2.
Over the course of the program, several important learnings have been garnered with
respect to deep ISCG facility design, operation and system performance. A summary of
these key learnings is provided as follows:
Lack of Far-Field Effects: as predicted prior to the start-up of the ISCG Demo,
operational results have shown that temperature, pressure and gas flows associated with
the ISCG process are confined to a very-near gasifier area in the coal seam, i.e., within a
few meters of the outer envelope of the gasifier at any given time, including elevated
temperatures. The low permeability of the coal, along with the maintenance of pressure
gradients into the gasifier (i.e., operation of the gasifier at slightly below reservoir
pressure) during normal operation ensure that ISCG have no detectable effects removed
from the gasifier zone in any direction (laterally or vertically).
Gas Containment
Gas containment and losses are an important consideration in ISCG. The gasifier
chamber is bound by impermeable cap rock above, base rock below, and coal and
overlying strata on either side. It is the low permeability of the surrounding rock and coal
that will prevent syngas migration beyond the chamber, together with operation at system
pressures which do not support any widespread gas migration or loss from the
gasification chamber.
Containment of hydrocarbons within rock formations by the overlying strata is a naturally
occurring geological feature that has existed for millions of years, which has allowed for
the safe production of oil and natural gas resources in the province for many decades. In
addition, coals are well known for their ability to adsorb gases such as methane and
carbon dioxide, two of the principal gases manufactured in in-situ coal gasification.
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Lateral Containment
Others previous experience with coal bed methane extraction tests in the Swan Hills
region has shown that the coal in the Mannville formation does not produce gas readily
and is indicative of a very low permeability. Synfuels geologists have estimated that the
permeability of the Mannville coal is less than 1 mD in the Demo area.
Operation of the Demo during the February to April 2011 timeframe provided insight
into the impermeable nature of the coal. During that run, SHS tested the ability of syngas
to flow through a restricted-path coal system, to assess the ability of syngas to flow
through coal boundary layers in an in-situ gasifier. During this test, the coal between the
injection and production well, which was acting as a barrier, was estimated to be
approximately 54 thick. Synfuels used a hydraulic rotary system with a small drill bit on
the end of a 6 long flexible drill string to drill a small (approximately 3/4 diameter) hole
from the bottom of the production well, through the coal seam to the end of the injection
well, to improve the flow path (see Figure 1 below). After penetration through the coal,
flow tests were conducted to prove that connection was made between the two wells.
Once operation commenced, however, the syngas flow from the gasification chamber at
the end of the injection well to the production well was significantly restricted, which
limited the amount of oxygen that could be injected. Figure 56 shows a plot of the
injection and production well bottom hole pressures during the February to April 2011
timeframe. As shown, the pressure differential averaged 8.2 MPa, which is in contrast to
an expected differential pressure of approximately 2 MPa or less for design conditions in
a mature gasifier. During this period, the average gas flow rate to the production well
was approximately 1% of the flow anticipated in a mature gasification cavity with an
open flow path. Most, if not all of the flow that was measured during this period likely
travelled to the production well through the 3/4 flow path. The fact that the injection
chamber seemed to hold a pressure and that flow to the production well was greatly
restricted despite a significantly increased pressure driving force clearly illustrates the
coals ability to act as a natural barrier.
Under normal ISCG gasifier chamber operation, the driving force (delta P) across the
lateral coal barriers at the boundaries of the gasifier are significantly lower than those
tested during the operation described above. Additionally, these coal barriers will be in
Final Outcomes Report
May 2012
Page 85 of 93
virgin state from a mechanical integrity standpoint (i.e., no holes drilled into them,
etc.). Thus it is apparent from the above test discussion that under any conceivable
operating scenario for deep ISCG, the prospect of any significant gas migration through
the coal seam is negligible.
Figure 56.
4 1/2
PRODUCTION WELL
P1
3/4
P2
54
COAL SEAM
INJECTION WELL
CHAMBER
Page 86 of 93
Figure 57.
20
16
Average P
= 8.2 Mpa
12
4
Injection Well BHP
Average BHP
0
23/02/2011
05/03/2011
15/03/2011
25/03/2011
04/04/2011
14/04/2011
Vertical Containment
Previous ISCG projects have determined that the process is expected to affect rock strata
(fracturing of rock) overlying the ISCG coal seam for a height of up to about 5 times the
coal seam thickness above the top of the coal seam. At the Demo site, the affected
zone of rock overlying the coal seam is expected to extend from the top of coal, at a
depth of 1370 m KB (as referenced to the 00/09-09-65-11 W5/0 core well drilled in
November 2007), up to a depth of 1343 m KB (27 m above the coal seam) in the worst
case. As such, the unaffected strata above this will provide containment/cap rock
function for the gasifier.
Logs from the 09-09 core well also indicate that from 1343 m KB up to 1325 m KB (27
to 45 m above the coal seam), inter-bedded strata of tight siltstone, shale, coal, sandstone,
and some carbonates are present. According to geological assessments conducted on
these core samples, the strata in this interval, particularly shales and coals, will provide
effective seal in and containment of the gasifier. At 1287 m KB (56 m above the coal
seam), the Joli Fou shales are encountered. These tight shales are well developed in the
area and will constitute a final backstop means of containment of the gasifier.
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The characteristics of the base of the gasifier are of less significance from a containment
perspective, due to the general upward tendencies of the gasification process (heat
transfer, gas buoyancy). In addition, previous ISCG projects have not observed the
mechanical breakage and/or displacement of rock in the gasifier chamber floor that has
been observed in the strata overlying the coal seam. Nonetheless, the approximately 10 m
of tight shales that underlay the coal are expected to provide base containment as
required, particularly as the mechanical integrity is not expected to be influenced by the
ISCG process.
Temperature Effects
From published data, the thermal conductivity of coal is very low and comparable to that
of the surrounding rock strata (shales, claystone, siltstone, sandstone). Temperature
gradients of 5450 C/m have been derived from observation of previous ISCG trials
(Wang et al 1982; Covell and Thomas, 1996). Thus, with expected maximum
temperatures in the active gasifier cavity of up to 1200 C, the zone of thermal effect
around the gasifier is very limited in thickness, at less than 1 m.
During the Demonstration facility operations between February and April 2011,
temperature measurements were taken at various locations surrounding the high
temperature (ignition) area at the burner tip. The locations are illustrated in figure 57.
During this run, the chamber temperature was estimated to be close to 1000 C. The
thermocouple at the burner tip (T2) shows maximum readings of approximately 300 C
due to cool water flow and other factors. As can be seen in the figure 4, there was no
significant far-field temperature effect observed at the heel (T1), observation well (T3), or
production well (T4), all of which measured consistent temperatures between 50-60 C,
which is the temperature of the formation at the depth of the coal seam.
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Figure 58.
700 m
Injection Well
Observation Well
Production Well
1395 m
T4
70 m
5m
3m
T1
T2
T3
Page 89 of 93
Figure 59.
400
350
Temperature (oC)
300
250
200
150
100
50
0
20/02/2011
02/03/2011
12/03/2011
22/03/2011
01/04/2011
11/04/2011
21/04/2011
Page 90 of 93
thermal insulation properties of the rock and coal forming the gasifier boundary layers,
and also in line with the experience of other ISCG operators world-wide.
Metallurgy: Synfuels choice of hot gas path metallurgy in the production well has
proven to be effective as a lower cost alternative to expensive high-nickel alloys.
Corrosion management remains a go-forward operations and maintenance area of focus
for ISCG.
Generally, the ISCG Demo was very successful in demonstrating the use of standard
oilfield equipment, metallurgies and processes to safely and reliably effect the ISCG
process. Notable in this regard is the use of carbon steel in high pressure oxygen service
at the injection site. With proper cleaning and commissioning procedures, carbon steel
was shown to be effective in high pressure oxygen service and suitable for use in ISCG
operations.
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Sustained, steady production of high quality syngas (rich in methane and CO2) ,
largely due to the high-pressure operating environment inherent in working coal
at this depth
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