Académique Documents
Professionnel Documents
Culture Documents
via electrohydrogenesis
Shaoan Cheng and Bruce E. Logan*
Department of Civil and Environmental Engineering, Pennsylvania State University, University Park, PA 16802
www.pnas.orgcgidoi10.1073pnas.0706379104
Author contributions: S.C. and B.E.L. designed research; S.C. performed research; S.C.
analyzed data; and S.C. and B.E.L. wrote the paper.
The authors declare no conflict of interest.
This article is a PNAS Direct Submission.
Freely available online through the PNAS open access option.
Abbreviation: MFC, microbial fuel cell.
*To whom correspondence should be addressed. E-mail: blogan@psu.edu.
2007 by The National Academy of Sciences of the USA
SUSTAINABILITY
SCIENCE
Edited by James M. Tiedje, Michigan State University, East Lansing, MI, and approved September 17, 2007 (received for review July 9, 2007)
4.0
1.5
3.0
1.0
2.0
0.5
1.0
-1
0.0
0.0
100
80
B
Efficiency, W+S or
0.0
0.2
0.4
0.6
0.8
Applied voltage (V)
1.0
800
600
60
40
400
R_H2
_W+S
_W
20
0
0.0
0.2
0.4
0.6
0.8
1.0
Efficiency, W (%)
-3
2.0
-1
H 2 rate, QH2 (m m d )
200
Table 1. Hydrogen production using cellulose, glucose, or five different volatile acids at an
applied voltage of 0.6 V
Substrate
Glucose
Cellulose
Acetic acid
Butyric acid
Lactic acid
Propionic acid
Valeric acid
RH2, %
Production rate,
m3d1m3
, %
WS, %
8.55
8.20*
3.65
8.01
5.45
6.25
8.77
71
68
91
80
91
89
67
1.23
0.11
1.10
0.45
1.04
0.72
0.14
266
268
261
285
283
248
263
64
63
82
77
82
79
66
obtained from Mallinckrodt (Hazelwood, MO) except that sodium acetate anhydrous (99.2%; Sigmacell Cellulose type 20)
was obtained from Sigma (St. Louis, MO); glucose anhydrous
was obtained from Fisher Scientific (Hanover Park, IL); and
propionic (99.5%) and valeric acid (98%) were obtained from
Chem Service (West Chester, PA). All solutions were prepared
in deionized water.
Analytics. Volumetric gas production in the cathode chamber was
SUSTAINABILITY
SCIENCE