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Chemistry
Kertas 2
Oktober
2010
2 jam
BAHAGIAN PENGURUSAN
SEKOLAH BERASRAMA PENUH DAN SEKOLAH KECEMERLANGAN
KEMENTERIAN PELAJARAN MALAYSIA
CHEMISTRY
Kertas 2
Dua jam tiga puluh minit
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Section A
[60 marks]
Answer all questions.
40
19
Diagram 1.1
(i) What is the proton number for Y?
...........
[1 mark]
(ii) What is the number of neutrons in atom V?
..
..
[1 mark]
(iii) Write the electron arrangement for an atom of element X.
............
[1 mark]
(iv) Which of the atoms above are isotopes of an element? Explain your answer.
..
.
[2 marks]
(b) Table 1 shows the melting point and boiling point of substances P, Q, R and S.
Substance
P
Q
R
S
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Substance Q
Substance R
S
[2 marks]
Time(s)
t2
t1
Diagram 1.2
S
DIAGRAM 2
Diagram 2
Using the letters in the Periodic Table of the Elements in Diagram 2, answer the following
questions.
(a) State the position of T in the Periodic Table of the Elements.
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[2 marks]
(b) W is chemically inert. Explain.
[1 mark]
(c) (i) Which element is a transition element?
(ii)
[1 mark]
State one special characteristics of transition elements.
[1 mark]
(d) Arrange P, U and V according to increase in atomic size.
....
.
[1 mark]
..
[2 marks]
(f) The electron arrangement of M2- ion is 2.8. In Diagram 2, mark M in the box
for the location of M element in the Periodic Table of Elements.
[1 mark]
3
Carbon electrode X
Carbon electrode Y
0.0001
Dilute
moldm-3
sodium
sodium
chloride
chloride
solution
solution
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Diagram 3
(a) (i) What is meant by anion?
....
[1 mark]
(ii) Write the formulae for all anions present in the sodium chloride solution.
[1 mark]
(b) What is the energy change that occurs in the electrolysis process?
..
[1 mark ]
(c) Based on Diagram 3,
(i) Which electrode is the cathode?
.
[1 mark ]
(ii) Write the half equation for the reaction at the cathode.
....
[1 mark ]
(iii)
(d) The experiment is repeated by using 2 mol dm-3 sodium iodide solution.
(i) Name the product of electrolysis at electrode Y.
...
[1 mark]
(ii) Explain how does the product is formed.
...
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[2
marks]
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Diagram 4 shows three test tubes contain dry glacial ethanoic acid, aqueous solution of
ethanoic acid and dilute hydrochloric acid.
Dry glacial
ethanoic
acid
Blue
litmus
paper
Aqueous
solution of
ethanoic acid
0.1 moldm-3
Dilute
hydrochloric
acid
0.1 moldm-3
Blue
litmus
paper
Blue
litmus
paper
Diagram 4
(a) (i) State the colour change of the litmus paper in test tubes R.
................................................................................................................................
[1 mark]
(ii) Write the formula of ion which caused the colour change of the litmus
paper.
................................................................................................................................
[1 mark]
(b) Is there any changes of colour of the litmus paper in test tube P? Explain why.
.....................................................................................................................................
.....................................................................................................................................
[2
marks]
(c) Table 4 shows the pH value of aqueous solution of ethanoic acid and dilute
hydrochloric acid of the same molarity.
Type of acid
Molarity
pH value
aqueous solution of
ethanoic acid
dilute hydrochloric
acid
0.1 moldm-3
0.1 moldm-3
2.9
1.0
Table 4
Explain the difference in the pH value of aqueous solution of ethanoic acid and
dilute hydrochloric acid.
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[3
marks]
Diagram 5 shows set-up of apparatus in the preparation of two different type of salts.
Experiment
Method
II
10 cm3 of 1.0
mol dm-3
lead(II) nitrate
solution
Excess potassium
chloride solution
Precipitate X
Diagram 5
(a) Based on Experiment I:
(i) State the name for the reaction.
......................................................................................................................................
[1 mark]
(ii) State the colour change in the conical flask at the end point.
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[1 mark]
(iii) Calculate the volume of hydrochloric acid used to neutralise 25.0 cm3 of 0.2 mol
dm-3 potassium hydroxide solution.
[2 marks]
(b) Based on Experiment II:
(i) Write the chemical equation for the reaction.
....................................................................................................................................
[2 marks]
(ii) How can you separate precipitate X from the mixture.
....................................................................................................................................
[1 mark]
(iii) Calculate the number of moles of lead nitrate in the solution.
[1 mark]
(iv) Determine the maximum mass of precipitate X formed.
[Molar mass of precipitate X = 278]
[2 marks]
(iii)
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Process P
Reaction R
Compound S
Hydrogen gas
Process Q
Ammonia
Nitrogen gas
Diagram 6
(a) (i) Sulphuric acid is produced in mass quantity through Process P. Name Process P.
[1 mark]
(ii) State two raw materials needed for Process P.
[2 marks]
(iii) A waste gas is produced during the manufacture of sulphuric acid. Explain briefly
how this gas can cause environmental pollution.
..
..
[2 marks]
(b) (i) Write the chemical equation for the formation of ammonia in Process Q.
[2 marks]
(ii) Name the catalyst used in Process Q.
[1 mark]
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Section B
[20 marks]
Answer any one question.
2+
Q
Diagram 7
(a) Based on Diagram 7, write the electron arrangement for atoms of element R and Q.
Explain the position of element Q in the Periodic Table of Elements
[6 marks]
(b) Based on Diagram 7, explain how the compound is formed.
[7 marks]
(c) Element R can also react with carbon, C to form a compound.
[Proton number of carbon = 6]
(i) Write the formula of the compound formed.
(ii) Draw the electron arrangement of the compound formed.
[3 marks]
(d) The compounds formed in (b) and (c) have different physical properties.
Compare the two compounds based on:
Melting point
Electrical conductivity
[4 marks]
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Crucible lid
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Diagram 8 shows the apparatus set-up for two methods to determine the empirical
formula of two compounds.
Method I
Method II
Chemical substance
Chemical substance
heat
heat
Diagram 8
(a)
(ii)
(b) A student plans to determine empirical formula of magnesium oxide in the laboratory.
Based on Diagram 8, describe the method. Your answer must include
procedure of experiment
tabulation of result
calculation of the result obtained for the experiment.
[Relative atomic mass: O = 16, Mg = 24]
[11 marks]
CH2O
By using glucose as an example, compare and contrast empirical formula and
molecular formula.
[5 marks]
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Section C
[20 marks]
Answer any one question.
(a)
Salts play an important role in our daily life. Salts can be classified according to its
solubility in water. State the meaning of salt.
[2 marks]
(b) The following are three examples of sulphate salts that can be prepared in the
laboratory.
(i) From these examples, classify the salts into soluble salts and insoluble salts
[4 marks]
(ii) State the reactants for the preparation of one of the soluble salts in 9(b)(i).
[2 marks]
(c) Describe how to prepare a dry sample of salt in 9(b)(ii) in laboratory. Your answer
should consists of the following :
Procedure of the preparation
Chemical equation involved in the reaction
[12 marks]
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(a)
(b)
Experiment
II
Set-up of
apparatus
Silver nitrate
solution
Silver nitrate
solution
Observatio
n
Grey deposit
Colourless solution
Grey deposit
Light blue solution
Diagram 10.1
(i) Based on the Experiment II in Diagram 10.1, suggest the identity of metal Q used in
this experiment.
Explain the observation.
[5 marks]
(ii) If metal P is zinc, arrange the three metals in order of increasing electropositivity.
[1 mark]
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Diagram 10.2 shows a voltaic cell. Metal R is situated higher than copper in t he
electrochemical series.
Metal R
Copper
Copper sulphate solution
Diagram 10.2
Explain how the cell work in Diagram 10.2. In your explanation, include the
following
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If you wish to change your answer, cross out the answer that you have done. Then write
down the new answer.
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