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Stoichiometry is the study of the relationship or ratios between the amounts of reactants and products in a
chemical reaction.
Stoichiometric amounts or ratios are the amounts of reactant or product as given by the coefficients in the
balanced equation.
The following laws and ideas underpin our knowledge about the relationships between chemicals involved
in reactions (see PowerPoint):
1. Law of Conservation of Mass: Lavoisier (18th Century) concluded, from studying reactions
involving oxygen, that during any chemical reaction no atoms were destroyed.
2. Law of Definite Proportions: analytical tests showed that any compound consists of the same
elements in definite proportions e.g. in every water molecule 88.88% of its mass is oxygen.
3. Law of Combining Volumes of Gases: Gay-Lussac (1803) concluded that when gases react they
do so in whole number ratios in terms of volume e.g. 3 volumes of hydrogen react with 1 volume of
nitrogen to form 2 volumes of ammonia.
4. Avogadros Theory (1811): Avogadro stated that equal volumes of gases must have equal
number of particles (provided temperature and pressure are the same)
5. Law of Multiple Proportions: in 2 different compounds of the same elements (e.g. CO and CO 2) if
the mass of 1 element is the same (e.g. carbon in CO and CO 2) than the ratio of the mass of the
other element (in our example oxygen) in each compound must be a whole number.
As particles are extremely small chemists measure amounts of substance using a quantity called the
MOLE which stands for 6.02 x 10 23 a number which is know as Avogadros constant.
So 1 mole of a substance = 6.02 x 10 23 units of that substance; these units can be atoms, molecules, ions,
electrons or formula units.
number of particles
number of moles =
6.02 x 1023
Molar ratios in compounds or formula units:
Topic1notes
12.5 hours
Page 1 of 30
Examples:
in 1 mole of Fe2 O3 there are 2 moles of iron atoms and 3 moles of oxygen;
in 3 moles of Na2CO3 there are 3 moles of CO32- and 6 moles of Na+ ;
in 2 moles of (NH4)3 PO4 there are 6 moles of NH4+ and 12 moles of hydrogen atoms and so on
if there are 2 x 10 22 C-atoms in a sample of ethane how many hydrogen atoms are there in that same
sample?
if you have 6 x 1022 atoms of hydrogen, how many molecules of ammonia do you have?
Exercises
1. How many moles of oxygen are there in 2 moles of Al 2O3?
2. How many moles of NO3- are there in 1 mole of Ga(NO 3)3?
3. What is the total number of atoms of 0.05 moles of NH 4NO3?
1.2. Formulas
1.2.1
1.2.2
1.2.3
1.2.4.
1.2.5
1.2.6
Define the terms relative atomic mass (Ar) and relative molecular mass (Mr).
Calculate the mass of one mole of a species from its formula.
Solve problems involving the relationship between the amount of substance in moles, mass and molar
mass.
Distinguish between the terms empirical formula and molecular formula.
Determine the empirical formula from the percentage composition or from other experimental data.
Determine the molecular formula when given both the empirical formula and experimental data.
Page 2 of 30
Example:
The average magnesium atom has a relative atomic mass of 24 which means that a magnesium atom is 2
times heavier than a carbon atom which has a mass of 12 and 24 times heavier than a hydrogen atom
which has a mass of 1.
Complete the following table:
element
Cu
Eu
Ag
isotopes
abundance
69.09%
30.91%
relative
atomic mass
151.9
48.17%
relative molecular mass of Al2(SO4)3 is because (2 x 26.92 ) + (3 x 32.06) + (12 x 16.00) = 342.02
Molar mass
How do we measure 1 mole of a substance?
The mass of 1 mole of a substance = molar mass which is measured in g mol-1.
The molar mass is the mass of 6.02 x 10 23 units of a substance; it is the relative atomic, molecular or
formula mass but expressed in grams as the molar mass is an absolute mass.
12.5 hours
Page 3 of 30
Below are examples of the type of calculations you should be able to solve using the mole concept
Calculate the number of moles (using molar mass) when you are given the mass of the substance
mass of substance
number of moles =
molar mass
mass of 1 atom/molecule
number of molecules
multiply
by 6.02 x 10 23
number of atoms
multiply
by subscript of atom in formula
number of moles
number of particles
multiply by 6.02 x 10 23
Exercises
1.
2.
3.
Topic1notes
12.5 hours
Page 4 of 30
4.
5.
10g of C2H6
10g of C6H6
2g of NH3
2g of CO2
Using the mole concept and molar ratios for analytical purposes: empirical and
molecular formulae.
Empirical formula
To determine the empirical formula (=the most simple molar ratio) of a compound, a chemist needs to find
out how much (a mass or a percentage) of each element there is in a certain mass of the compound.
This raw data (how much there is of an element in a compound) can be obtained in various ways:
This involves combusting a known amount of the organic compound and finding the masses of carbon
dioxide and water (=raw data). Using the percentage composition of hydrogen and carbon in both
compounds allows the chemist to calculate the starting amount of hydrogen and carbon in the compound.
Involves reacting the known mass of one element with a second element, measuring the mass of the
compound and then finding the mass of the second element.
Decompose (usually using heat) a sample with a known mass, measure the mass of the final product and
use this data to
From this mass analysis of a compound the amount in mass of each element or the percentage
composition of the compound can be determined; from this information the most simple whole number
molar ratio can be found and this then gives us the empirical formula of the compound.
Percentage composition of a compound
Experimental analysis usually results in the amount of an element in a compound being expressed as a
percentage composition
molar mass of element x coefficient in compound
% composition =
100
Topic1notes
x
molar mass of compound
12.5 hours
Page 5 of 30
Calculate
1.
2.
carbon
47.98 (74.9%)
47.98/12 = 3.99 mole
(74.9/12 = 6.24 moles)
ratio of moles
most simple ratio of moles
4 (6.25)
1
hydrogen
16.02
(25.1%)
Answer:
mass of element
number of moles
carbon
hydrogen
93.71
6.29
93.71/12 = 7.8
6.29/ 1 = 6.29
6.29/6.29 = 1
empirical formula:
C5H4
C10H8
Exercises:
Calculate
i.
ii.
Page 7 of 30
As seen in 1.1 the stoichiometric amounts or molar ratios for any reaction can be obtained from a
balanced equation.
Example:
Fe2 O3 (s)
+
3CO (g)
2Fe (s)
+
3 CO 2 (g)
This means that
1 particle
of Fe2 O3
3 particles
of CO
2 particles
of Fe
3 particles
of CO
Alternatively this means that there are 3 times as much particles of CO as Fe 2 O3 particles; for the reaction
to go to completion (=both reactants are completely used up) 3 times as much CO is needed as Fe 2 O3.
By multiplying each number of particles by 6.02 x 1023, the above balanced equation states the same
reacts with
3 moles
of CO
to give
2 moles
of Fe
and
3 moles
of CO 2
In the above equation the molar ratio of iron oxide to carbon monoxide is 1: 3 i.e. for the reaction to go to
completion 3 times more moles of CO 2 are needed than Fe2O3
Complete the following table showing other molar ratios in the above equation;
Fe2 O3 : Fe
Fe : CO2
CO : CO2
Fe2 O3 : CO2
:
:
:
:
Balancing equations
In getting an equation to balance, the number of moles of each substance is changed, until there are the
same number of atoms of each element on each side of the equation:
Unbalanced equation:
Balanced equation:
C3H8 +
5O2
--->
3CO2
4H2O
Conservation of mass
When applying the molar mass concept to the equation below the Law of Conservation of Mass can be
proven:
Fe2 O3 (s)
+
3CO (g)
2Fe (s)
+
3 CO 2 (g)
1 x 160 g
+
244 g
3 x 28g
2 x 56 g
12.5 hours
+
244 g
3 x 44 g
Example: How much iron oxide is needed to produce 28g of iron during the reduction of iron oxide by
carbon monoxide?
Step 1: write balanced equation
Fe2 O3 (s)
3CO (g)
2Fe (s)
3 CO 2 (g)
To get 28g or iron, 40g of iron oxide is needed to get the reaction to go to completion!!!
The quantity of product that you should obtain according to the amounts of reactants available and the
molar ratios of reactants is called the theoretical yield.
However, when the reaction is carried out the actual yield is nearly always less than the theoretical yield.
Comparing the actual and theoretical yield by calculating their ratio allows us to determine the efficiency of
a reaction; the ratio is called the percentage yield.
actual/experimental yield
percentage yield =
x 100
theoretical yield
Limiting reagent
1.4.2 Determine the limiting reactant and the reactant in excess when quantities of reacting substances are
given.
Topic1notes
12.5 hours
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If in a chemical reaction the molar ratios of the equation are not followed, usually one of the reactants
becomes the limiting reagent whilst all the others are in excess. The limiting reagent controls or limits the
amount of product that is formed. At the end of such a reaction in which there is a limiting reagent,
besides product, some of the reactants that are in excess will be left.
To determine which reactant is the limiting reagent:
The number of moles of the limiting reagent is the number of moles used to calculate the theoretical yield
of the reaction.
Sample exercise
Consider the Haber process, when 25000 g of nitrogen is reacted with 5000 g of hydrogen to produce
ammonia.
N2(g)
+
3H2(g)
2NH3(g)
Determine which reactant nitrogen or hydrogen is the limiting reactant? Calculate the theoretical yield of
ammonia in grams and the experimental yield as a % of 10390 g of ammonia.
1.
2.
Find the actual number of moles of each reactant from the mass of reactant given.
for N2
m
M
25000
28
892.8 mol
for H2
m
M
5000
2
2500 mol
Find the required number of moles of each reactant from the moles ratio in the reaction.
Required moles of reactant A
3.
Actual
moles of
reactant B
Ratio of A
Ratio of B
Required moles of H2
892.8
3
1
2678.6 mol
Required moles of N2
2500
1
3
833.3 mol
If the:
Topic1notes
12.5 hours
Page 10 of 30
So for H2
833.3 mol
so N2 is not limiting)
Find the mass of one of the products formed (also called the theoretical yield)
Use the actual number of moles of the limiting reagent and compare the mole ratios
e.g.
NH3
2
if the actual number of moles of the limiting reagent H2 = 2500 mol then using the mole ratio in the
equation the actual number of moles of NH3 = 2500 x 2 = 1666.6 mol
3
H2
3
2500
mass NH3
5.
1666.6
17
28332
NH3
2
1666.6
100
10390
28332
100
36.7 %
Exercises
1.
3 I2
2 AlI3
12.5 hours
Page 11 of 30
(a)
2.
(b)
2 SbF3
3 CCl2F2
2 SbCl3
150 g CCl4 (Mr = 154) is combined with 100 g SbF 3 (Mr = 178.8) to give freon-12, CCl2F2
(Mr = 120.9).
(a)
(b)
3.
2 C7H6O3
2 C9H8O4
H2O
(a)
(b)
Calculate the maximum mass of aspirin that could be obtained in this reaction.
(c)
If the mass obtained in this experiment was 13.7 g calculate the percentage yield of aspirin.
1 mark
2 marks
Gay-Lussac noticed that there is always a very simple ratio between volumes of gases that react together.
For instance,
To explain these results, Avogadro proposed that equal volumes of gases (if measured in the same
conditions) must have the same number of molecules.
As a result the above volume observation can also be considered as
1 molecule of hydrogen + 1 molecule of chlorine
Topic1notes
12.5 hours
Question:
Cl2
+ H2
N2 + 3H2
2HCl
Hydrogen and chlorine react according to the equation above. What will be the result of the reaction of 2.0
moles of H2 and 1.5 moles of Cl2?
A. 3.5 mol of HCl
Topic1notes
12.5 hours
Page 13 of 30
You can also use the following simulations to study the effects of the above factors.
http://mc2.cchem.berkeley.edu/Java/molecules/index.html
http://www2.biglobe.ne.jp/%7Enorimari/science/JavaApp/Mole/e-gas.html
pV = nRT
Irrespective of the conditions the gas is in (pressure, temperature, volume), the ratio of pV over nT is
always R!!!
The gas constant can have a different value depending on the units it is expressed in. The value you
chose depends on the units the raw data is expressed in although we prefer to use the SI units!!!
See: http://www.chm.davidson.edu/ChemistryApplets/GasLaws/GasConstant.html for determining the gas
constant.
See http://resources.schoolscience.co.uk/BAMA/16plus/aerosch3pg1.html
When carrying out calculations using the ideal gas equation, we need to ensure we can
cancel units!!! Better to use SI units!!
Therefore:
The ideal gas equation can be used to solve a variety of problems such as:
calculate the p,V or T values of a gas in a particular condition provided 2 of the 3 quantities are known
we need to know the conditions it is in and the mass of the sample of the gas
we can then calculate n and then using n = mass/Mr calculate the Mr
we can also use this calculation to identify an unknown gas experimentally !!!
calculate the new value of either p, V or T provided we know what the other 2 have changed into. If
we are assuming that when we change 1 or 2 conditions and the mass or amount gas stays the same,
then in pV = nRT both n and R are constants and n = pV/T should be the same for both sets of
conditions. So
V1 P1
Topic1notes
V2 P2
12.5 hours
Page 14 of 30
=
T1
T2
Worked example
What volume will be occupied by 0.216 g of CO2 at 21 C and at a pressure of 1.32 atm?
1. Calculate the number of moles of the gas: 0.216g/44.0g = 4.91 x 10 -3 mol
2. Express all temperatures in Kelvin: 21 C = 294 K
3. Convert all other units in SI units: 1.32 atm = 1.32 x 1.013 x 10 5 Pa = 1.34 x 105 Pa
4. Apply pV = nRT
1.34 x 105 x V = 4.91 x 10-3 x 8.314 x 294
Worked example
A gas occupies 127 cm3 at a pressure of 0.830 atm and at 28C.
(a) What volume will the same amount of gas occupy at 1.00 atm and 0 C
(b) How many moles of gas are present
1. Express all temperatures in Kelvin: 28 C = 301 K
P1 V1
2. Apply:
and
0 C = 273 K
P2V2
=
T1
T2
(no need to change the units to SI units!! when using the above formula)
V1 x P1 x T2
V2 =
=
P2 T1
1.00 x 301
3. The number of moles can be calculated by using the ideal gas equation. When using the ideal gas
equation, SI units need to be used
n = PV/RT
8.41 x 104 Pa x 1.27 x 10-4 m3
n=
= 4.27 x 10
8.314 J K
-1
mol
-1
-3
mol
x 301 K
Exercises
Topic1notes
12.5 hours
Page 15 of 30
2. The temperature (in K) is doubled for a sample of gas in a flexible container while the pressure on it is
doubled. The final volume of the gas compared with the initial volume will be
A. the same
B. twice as large
D. half as large
3. When the temperature of a fixed mass and volume of nitrogen is raised from 25C to 50C, the
pressure increases because the
A.
B.
C.
D.
4. For an ideal gas, the variables in one of the pairs below are inversely related to one another (i.e. one
increases as the other decreases). Which pair is it?
A. temperature, kinetic energy
C. temperature, rate of diffusion
5. A 250 cm3 sample of an unknown gas has a mass of 1.42 g at 35 C and 0.85 atmospheres.
Which expression gives its molar mass, Mr? (R = 82.05 atm cm 3 K-1 mol-1)
1.42 x 82.05x 35
A.
0.25 x 0.85
0.25 x 0.85
82.05 x 308
250 x 0.85
6. A sample of gas has a certain volume at a temperature of 60C. What must the temperature be in
order to double the volume if the pressure is kept constant?
A. 120C
B. 333C
C. 393C
D. 666C
7. 125 cm3 of an unknown gas has a mass of 0.725 g at 25C and 0.97 atmospheres. Which expression
will give the relative molar mass of the gas? (R = 82.05 cm 3 atm K-1 mol-1)
0.725 x 82.05x 25
A.
125 x 0.97
B.
0.97 x 125
0.97 x 0.125
0.97 x 125
8. A 1.25 dm3 sample of air at 25C has a pressure of 85.9 kPa (0.85 atmospheres). What is its volume
(in dm3) if its temperature and pressure are changed to 100C and 65.7 kPa (0.65 atm)?
A. 0.76
B. 1.20
C. 1.31
D. 2.05
9. A sample of ethane occupies a volume of 120 cm3 at 30C and 1.0 atm (101kPa). What volume (in
cm3) will it occupy at 40C and 1.2 atm (121 kPa)?
A. 103
Topic1notes
B. 133
C. 149
12.5 hours
D. 192
Page 16 of 30
10. A 225 cm3 sample of a particular gas weighs 0.774 g. What is the approximate molar mass of this gas
if the volume was determined at 98.7 kPa (0.974 atm) and 30C?
A. 120 g mol-1
B. 88 g mol-1
C. 86 g mol -1
D. 77 g mol-1
11. A 0.365g sample of a common anaesthetic has a volume of 225 cm 3 at 35C and 98.6 kPa (740 mm
Hg). What is its molar mass?
A. 42.1 g mol-1
B. 40.8 g mol-1
C. 39.9 g mol -1
D. 4.79 g mol-1
1. 5. Solutions
1.5.1 Distinguish between the terms solute, solvent, solution and concentration (g dm 3 and mol dm3).
1.5.2 Solve problems involving concentration, amount of solute and volume of solution.
H2 O (l)
number of moles
concentration =
(mol/L)
volume (in L)
12.5 hours
Page 17 of 30
A. C2H2
B.
C2H4
C. C3H4
D. C3H8
2. (M07) When excess BaCl2(aq) was added to a sample of Fe (NH4 )2 (SO4 )2 (aq) to determine the amount in
moles of sulfate present, 5.0210_ mol of BaSO4 was obtained. How many moles of sulfate ions and iron
ions were in the sample of Fe (NH4 )2 (SO4 )2?
3. (M07) What volume of 0.500 mol dm-3sulfuric acid solution is required to react completely with 10.0 g of
calcium carbonate according to the equation below?
A.
100 cm-3
5. (M06) A reaction occurring in the extraction of lead from its ore can be represented by this unbalanced
equation:
__ PbS + __ O2
__ PbO + __SO 2
When the equation is balanced using the smallest possible whole numbers, what is the coefficient
for O
A. 1
B. 2
C. 3
D. 4
12.5 hours
Page 18 of 30
What is the maximum amount of methanol that can be formed from 2 mol of carbon dioxide and 3 mol
of hydrogen?
A. 1 mol
B. 2 mol
C. 3 mol
D. 5 mol
7. (N05) The complete oxidation of propane produces carbon dioxide and water as shown below.
What is the total of the coefficients for the products in the balanced equation for 1 mole of propane?
A. 6
B. 7
C. 12
D. 13
8. (N05) The relative molecular mass (Mr) of a compound is 60. Which formulas are possible for this
compound?
A. I and II only
D. I, II and
10. (N06) A 4 g sample of sodium hydroxide, NaOH, is dissolved in water and made up to 500 cm 3 of
aqueous solution. What is the concentration of the resulting solution?
A. 0.1 mol dm-3
B. 25 %
C. 50 %
D. 75 %
12.5 hours
Page 19 of 30
__ Na + __ H2O
__NaOH + __H2
What is the total of all the coefficients when the equation is balanced using the smallest possible
whole numbers?
A.3
B. 4
C. 6
D. 7
What is the amount (in mol) of carbon dioxide formed by the complete combustion of three moles of
butane?
A. 4
B. 8
C.
12
D. 24
14. (M05) Which solution contains the greatest amount (in mol) of solute?
A. 10.0 cm3 of 0.500 mol dm3 NaCl
15. (M05) How many oxygen atoms are present in 0.0500 mol carbon dioxide?
A.
3.011022
B. 6.02 1022
C. 6.02 1023
24
12
D. 1.20 1024
Mg2+ ion?
B. 12
C. 14
D. 22
13O 2(g)
8CO2(g) + 10H2O(l)
How many moles of CO2 (g) are produced by the complete combustion of 58 g of butane, C 4H10 (g) ?
A. 4
B. 8
C.
12
D. 16
18. (N04) 6.0 moles of Fe2O3 (s) reacts with 9.0 moles of carbon in a blast furnace according to the
equation below.
Fe2O3 (s)+3C(s)2Fe(s)+3CO(g)
What is the limiting reagent and hence the theoretical yield of iron?
Topic1notes
12.5 hours
Page 20 of 30
19.
(N04) What volume of 0.500 moldm3 HCl (aq) is required to react completely with 10.0 g of calcium
carbonate according to the equation below?
CaCO3 (s) + 2HCl(aq)
A. 100 cm3
B. 200 cm3
C. 300 cm3
D. 400 cm3
3
20. (M04) What amount of NaCl (in moles) is required to prepare 250 cm of a 0.200 mol dm-3 solution?
A. 50.0
B. 1.25
C. 0.800
D. 0.0500
21. (M02) A compound that contains only carbon, hydrogen and oxygen has the following percentage by
mass:
carbon: 60%
hydrogen: 8%
oxygen: 32%
What is a possible molecular formula?
A. C5H8O2 .
B. C5H4O
C. C6HO3
D. C7HO4
B. 0.6 mol O3
23. (M02) 6.4 g of copper wire is added to 0.10 dm3 of 1.0 mol dm-3 aqueous AgNO3 to form
metallic silver and aqueous copper (II) nitrate. When the reaction is complete,
a.
b.
c.
d.
24. (M02) 2.02 g of KNO3 (Mr= 101) is dissolved in sufficient water to prepare 0.500 dm 3 of solution.
What is the concentration of this solution in mol dm -3?
A. 0.02
B. 0.04
C. 0.10
D. 0.20
25. (M03) What amount of oxygen, O 2, (in moles) contains 1.8 x 10 22 molecules?
A. 0.0030
Topic1notes
B. 0.030
C. 0.30
12.5 hours
D. 3.0
Page 21 of 30
26. (M03) 3.0 dm3 of sulfur dioxide are reacted with 2.0 dm3 of oxygen according to the equation:
2SO2 (g) + O2 (g)
2SO3 (g)
What volume of sulfur trioxide (in dm3) is formed? (Assume the reaction goes to completion and all
gases are measured at the same temperature and pressure.
A. 5.0
B. 4.0
27. (M03)
_ C2H2 (g) +
C. 3.0
_ O2 (g)
D. 2.0
_ CO2 (g)
+ _ H2O (g)
B. 3
C. 4
D. 5
_ HNO3
_ Cu(NO3)2 + _ H2O
_NO
B. 6
C. 8
D. 10
29. (N03) A hydrocarbon contains 90% by mass of carbon. What is its empirical formula?
A. CH2
B. C3H4
C. C7H10
D. C9H10
+ CO2
Li2CO3 + H2O
What mass (in grams) of lithium hydroxide is needed to react with 11g of carbon dioxide?
A. 6
B. 12
C. 24
D. 48
31. (M04) How many hydrogen atoms are contained in one mole of ethanol, C 2H5OH?
A. 5
C. 1.0 x 10 23
B. 6
D. 3.6 x 10 24
H = 12%
O = 16%
B. 1 : 2
C. 1 : 6
D. 6 : 1
33. (M04) What is the coefficient for O2 (g) when the equation below is balanced?
_ C3H8 (g) +
Topic1notes
_ O2 (g)
_ CO2 (g)
12.5 hours
+ _ H2O (g)
Page 22 of 30
A. 2
B. 3
C. 5
D. 7
O2 (g)
2SO 3 (g)
what volume of air (20% O2) is required to react with 10 dm3 of SO2?
A. 2 dm3
B. 5 dm3
C. 10 dm 3
D. 25 dm 3
35. (M03) Which of the following compounds has the greatest empirical formula mass?
A. C6H6
36.
B. C4H10
CaCO3 (s)
C. C5H10
CaO(s)
D. C2H6
+ CO2 (g)
When heated, CaCO 3 (Mr = 100) decomposes as shown above. When 20 g of impure CaCO 3 is
heated, 0.15 moles of CO2 are obtained. What is the % purity of the CaCO 3 ?
A. 15
B. 25
C. 55
D. 75
Paper 2
1. (M07)
(a) Propane and oxygen react according to the following equation.
C3H8 (g) + 5O2 (g) 3CO2 (g) + 4H2O(g)
Calculate the volume of carbon dioxide and water vapour produced and the volume of oxygen
remaining, when 20.0 dm3 of propane reacts with 120.0 dm3 of oxygen. All gas volumes are
measured at the same temperature and pressure.
[3]
(b) State and explain what would happen to the pressure of a given mass of gas when its absolute
temperature and volume are both doubled.
[3]
2. (N05) An organic compound, A, containing only the elements carbon, hydrogen and oxygen was
analysed.
(a) A was found to contain 54.5 % C and 9.1 % H by mass, the remainder being oxygen.
Determine the empirical formula of the compound.
[3]
(b) A 0.230 g sample of A, when vaporized, had a volume of 0.0785 dm 3 and 102 kPa at 95 C .
Determine the relative molecular mass of A.
[3]
(c) Determine the molecular formula of A using your answers from parts (a) and (b).
[1]
3. (M06) The reaction below represents the reduction of iron ore to produce iron.
12.5 hours
Page 23 of 30
Calculate the maximum mass of iron that can be obtained from these masses of reactants.
[5]
4. (N06) An organic compound A contains 62.0 % by mass of carbon, 24.1 % by mass of nitrogen,
the remainder being hydrogen.
(i) Determine the percentage by mass of hydrogen and the empirical formula of A.
[3]
[2]
[1]
[2]
(b) A 1.00g sample of the hydrocarbon at a temperature of 273K and a pressure of 1.01105 Pa (1.00
atm) has a volume of 0.399 dm3.
(i) Calculate the molar mass of the hydrocarbon.
(ii) Deduce the molecular formula of the hydrocarbon.
6.
[2]
[1]
(M03)
(a) The relative molecular mass of aluminium chloride is 267 and its composition by mass is 20.3% Al
and 79.7% chlorine. Determine the empirical formula and molecular formulas of aluminium
chloride.
[4]
(b) Sodium reacts with water as follows.
2Na(s) + 2H 2O (l)
2NaOH (aq)
+ H2 (g)
1.15 g of sodium is allowed to react completely with water. The resulting solution is diluted to
250 cm3. Calculate the concentration, in mol dm-3, of the resulting sodium hydroxide solution.
[3]
7. (N03)
(a) Aqueous XO 43- ions form a precipitate with aqueous silver ions, Ag +. Write a balanced equation for
the reaction, including state symbols.
[2]
(b) When 41.18 cm3 of a solution of aqueous silver ions with a concentration of 0.2040 mol dm -3 is
added to a solution of XO 43- ions, 1.172 g of the precipitate is formed.
(i)
[1]
(ii)
[1]
(iii)
[2]
(iv) Determine the relative atomic mass of X and identify the element.
8.
[2]
(M02) A student was asked to make some copper (II) sulfate-5-water (CuSO 4.5H2O) by reacting
copper (II) oxide (CuO) with sulfuric acid.
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[1]
(b) Calculate the amount (in mol) of copper (II) sulfate-5-water in a 10.0 g sample.
[1]
(c) Calculate the mass of copper (II) oxide needed to make this 10.0 g sample.
[1]
9. (M03)
(a) Write an equation for the reaction between hydrochloric acid and calcium carbonate.
[2]
(b) Determine the volume of 1.50 mol dm -3 hydrochloric acid that would react with exactly 1.25 g of
calcium carbonate.
[3]
(c) Calculate the volume of carbon dioxide, measured at rtp, which would be produced when 1.25 g
of calcium carbonate reacts completely with the hydrochloric acid.
[2]
10. (M01)
(a) An anti-cancer drug called Cisplatin has the following percentage composition by mass:
Pt = 65.01%
Cl = 23.63%
N = 9.340 %
H = 2.020 %
[3]
(b) The molecular and empirical formulas of Cisplatin are the same. Analysis of the molecule shows
platinum to be the central atom, being bonded to four separate atoms; the hydrogen is bonded to
nitrogen. Draw the representation of the molecule.
[1]
(c) 16.20 x 10-3 dm3 of 0.1020 mol dm-3 aqueous AgNO3 is added to 14.80 x 10 -3 dm3 of 0.125 mol
dm-3 aqueous NaCl. Calculate the maximum mass (g) of AgCl which could be obtained from this
reaction.
[4]
11. (N01) Indigo is a blue dye which contains only carbon, nitrogen, hydrogen and oxygen.
(a) 2.036 g of indigo was completely oxidized to produce 5.470 g of carbon dioxide and 0.697 g of
water. Calculate
(i) the percentage of mass of carbon in indigo.
(ii) the percentage of mass of hydrogen in indigo.
[2]
[2]
(b) If the percentage by mass of nitrogen in the indigo sample is 10.75%, determine the empirical
formula of indigo.
[3]
(c) If the molar mass is approximately 260 g mol-1, determine the molecular formula of indigo.
[2]
12. (N02) A balloon, which can hold a maximum of 1100 cm3 of air before bursting, contains 955 cm3 of air
at 5C . Determine whether the balloon will burst if the temperature is increased to 25 C. Assume
that the pressure of the gas in the balloon remains constant.
[3]
13. (N02) An element X reacts with oxygen to form the oxide X 2O3 .
(a) Write a balanced equation for the reaction.
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[1]
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(b) If 2.199 g of the oxide was obtained from 1.239 g of X, calculate the relative atomic mass
of X and identify the element.
[5]
(c) Nitrogen also forms an oxide on reaction with oxygen. This oxide contains 25.9 % of
nitrogen and 74.1 % of oxygen by mass. Calculate the empirical formula of this second
oxide.
[3]
14. (M02) A student is asked to prepare some copper(II) nitrate by reacting nitric acid with copper(II)
oxide.
(a) Write a balanced equation for this reaction.
[1]
(b) The student carries out this reaction by adding 0.0345 mol of copper(II) oxide to 36.0 of cm 3
1.15 mol dm-3 nitric acid solution. Calculate the amount (in mol) of nitric acid.
[1]
(c) Use the information in (a) and (b) to identify the limiting reagent and determine the amount
(in mol) of copper(II) nitrate formed.
[2]
15. The value of X in NaAl(SO 4)2.XH2O can be found by determining the number of moles of sulphate in
the compound quantitatively. A 5.218g sample was dissolved and excess BaCl 2 was added. The
precipitate of BaSO 4 was separated, dried and found to weigh 5.315g. (use integer mass numbers).
(a)
(b)
(c)
(d)
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Mark scheme
PAPER 1
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
PAPER 2
1. (M07)
2. (N05)
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1.
(M06)
2.
(N06)
4.(M01)
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5. (N01)
6.
(N02)
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7. (N02)
8.(M02)
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