of the

W!-.ich
following curves

(c)

IllliY n;prc.>ent the

"f

a
in
electron
hydrogen atom as
a funcnon of the
principal qnar.n1m
numbo:r n 1

\2.

(a)

A small oource of sound moves o~ a circle as

shown in figure orul an observer is sittin~ at 0.

Let v1 v 2 v 3 be the frequCilcies heord when
at A, lJ and C r"'PecnV>"l)
the

'"""'"is

(b)

13. A >Ulitl >vhere lkll momw1L uf inerlia [about

ony <>fit< dim<ter. If t~e '""l"""ture nf bndy
is increa9ed by ,J.J". then its moment of inertio
10ill increase by
(c)2rt"\Txl

(h) laAT
(d) 4 i~T

xa

(a) no mc,..,sc

\'."hen two particle> q orul- q ore plac"d at a

d"t<tl!CC r, then Coubmb"> force of artrdc1lun
be!\0-een them ha' magnmtdc F. If another
charge pa!ticle ho;Ulg .::barge ~ 3q is placed
near to - q, then the force exerteC by - q on q
will b-e
(b) 21'. attraclfve
(a) 4F. repulsive
!d) 21'. repuls!re
l<l 1', attratti.e
15. Find the equi,alent thermal ,.,,;,;""".., of
tomhinarion ot rod> a> >b.own On ti1;11re. Every
rod has Silme lengch land cross seononal area
A T~enn.1l oonducuvi<ies arc mcalioned in
figure.

w
w

.e

I~

'

'"
;,

' "

, ') ,'?,!'!.Q

,,

u'R

Q"""""

(a) 20(h-l)

v,~v,>v,

(d) v,>v<>v,

1GM

'"\12R

No. 17 ;,o Ia_., ba...l <m !he.

,.. l'it"e<li<lir :
ft!/I<Jwi"ll Pf"'=api!.
A ain'("'l<m of f~"'illlth ;!0 <'1rl EJi!d ~ ~ len of
.fhd.J~ 10 "'! ~-1'1!".~ .w '"' ~ lli.l>ei)<eeii
h= "".oil;<"'"! #co~ ot dl<tan<e ~ ~~ <lit ron;n,~<n.. :
17. What is the yaJue of x (in om) so that imagC>
formed by bo1lo the lenses coincide?

m
ra

"
..... ,
0,
'

(b!

11GM

. 1,'eM
(C}"\
R

(d) D

(a) v 1 >v,,,.,.,
(c) v,>v,>v,

'

(d) l2K"A

12K"A

"\ 4R

lbl

"

"

16. A particle is kept>t rest at a d.istane< R (eartll'o

rocliu') ,bniT the earth's sLUface. The
mirumum speed with which it >b.ould be
projected so that it d0s not return lS

rhe

(a) ''
(<)

0)

<M

om

sped

(:(1

.c

1!.

il>l 2099.33 J
(d) 2019.65 J

ce

(a) 2268 J
(c) 2000 J

OJ

'

w
-=

"

c~J10h"3-u

What will'-'"" the lineor mgnificatiun pruduc-.d

lry "<'llVI'"X I'"" a11d concave lens lndtvidually.
(a) U3+l)and....;,

(b) -f:land 1_

"

"

(cj (,.'3+1) and(,.-3-1)

(d) ,'" and (2~"3 - 3)

A 20 g bullet i< fired horizontally with a ,;pee.d

of600 w,/s intQ" 7 kg hl<J<k sming on a tahle
top; the bullet (b) lodges in the bloclc (BJ. If
the ,.,.fficient of kinen< fnction between the
block and the table

h"lp i.< 0.4. wh>t is

the diStance the
block will slide ?
(n) O.S m
(h) l.Zm
(c) 0.37 m
(d) 0.1>5 rn
A uniform,..,ttangulor marble slab is 3.4m long
and 2.11 mwid~. Tt ha< am>" of lBO i<g.lt1t ;,
on&rnally tyrng on the fla: ground. bow much
work i> needed to >tand it on an end ?
(b) 3.0J
(a} 2.0 kJ
(d) 3000 kJ
(c) 3.0 kJ

'I

(OJ Zero

26. A paroliol beorn ~r light ha"'-"8 intensity

lO m WI om' is in"'dcnt on a ;-phere of mdtus
2t-m. 30% of tho light hit> /
been ahor"bccl by >ph<'"' ( \
1
been rcfie('ted_ \
ond re~
-------L_ ~
l'lml lhe fm-c eJtcned by
l:g\11 bean: on sphere_
(a) 4-19 ,. 10- 04 N Ql) 5-45 x 10 "N

relea,od. then nr the ;:in,c ,, Je,,gd>)' of the "Ope

hoc fa.lcn, the Ioree on the table"' equivalent
Lo the ;<Cight of the kn~tb Ky olthc mpe.
Fmc! tbc val no ,.flf.
(b) ~

(<) l

(d) 3.5
Con<i<1ct rhe >It_t,tllon <h<>wn ht ftgure. 'fht
swnch -, dos,xJ ott -0, when the capoc-imrs
>--- __ : : ]
nre umh"r~od
c, ,.
c,
find the d'-"-go
~
on the capadto
~,~'
R
E
C1 >< a fttmcioo>
\Cl

23

ol timet.
(R)CF[l-e'''-'-

c, : c,

(cJ +~.Sr11

(u} Que,don io 1crevalon:

w
w

zs_ '--' ,hown in figue. d Llllitonn solhl oph e tolls

on rl hur v.nntal surfo< e at 20 m/> Tt then rol\3

SttU'"""'

<if wh.l. ~ '"'-''" Y"" """"

!),"'"k' (1(!, (l,l, (c) M<1 (d)~ tlow;
,rom

ta s.l"'' <li<.rom<t "'""''

- '. _

(a)

'"'"""""1 <> lru<. ~m<n(/! ~ tl"'m ~(u!Cmffl(fi~

""'~ """""'PI""""'"'~ Sfut<~ I.

Stat<mmtf l! tm<i -~><>r<""'M 11 !S fol,._Slm'"'''"' Il!f<li.!e, Sro""""' n ~ ""' _ , , ,

s"'"'"l"""' '"''; S<tt""'""II ~,,.,..~II i

Statcmem I

m
ra

.e

="""'-.() 0.45 m
lhl II~ rn

xa

~'

"' 29 ill'f Amlrion-

Ac<eleratio~

due to mnon'<

gravJiyon moon\, '"'lace i> S,;. A<<deration due

l(i'""

~/m

/;Q, ~7

Rroc<i<m 'YP'- l'lrlL if '"'"" "'"''""' ""' Jtdtern<nl<I (A.mi"'J, 3raummr l1 (l&mw_l.. """'" <f
'"""" <;""-'"''~ d.'" ha' foura!;emooi'< cll,ol!,>, o>l{r mtl'

27.

J'lte ti>O lllorlol >hOWJ in tgutc ),,,,.._ equal

mae> ";;J J.,-~. ~~n for both l>ioclol.
"'llial
w.,dge W;, fi<r_d and block It is
''1''-''d of I mh ~own rhe plane. Tlow fur wtl! "
mOI'e before comto,; to n:>t if indi~os ond
2
;trill3' ""' quite l<>ng ' [1ak< ;; ~ I0 1ll/s l

(d) r;onc uf tl>e'e

""-' ""'""' <zyllirnt!1onf<>r Bta(<""-"t /,

_c,t,~
co,-"""'"""''" (-,-1.,

,,

w-' N

,.. (llrocn<>m Q,..Hw.-

'<')
(<ll

(o) Ct[!-.---"- 1whcreC- ~LL_

24.

(cJ 7.14 x

(I!)

(bi c,E ll- ,-'-"' 'l

Cdl

h"'

om

II. uniform mpe, ol m m per """ len,o;th.

l~ '""'"illy !r<Jm a suppor: so th" the
loweo' <'nd jusr tollchel che tat>le mp lf it h

.c

22.

(d1 18.5 m

(e) b m

ce

[c) 6 W

to

earth'' gr"'"'Y on moorls surface

is....&,-(60)

Stat=tent II : The distance (I[ moon from

earth's <entrt is approximatcly equ,.] to
60 -,nes the radius of earth.

28. S"'tcmcru: I : f.qual mas>M of aelium """

oxyg>n gase; ar< given equal quantitie' ofhedt.
!here will be grcawr n..., i> tC.LUJft'laturo of
helilnn compared to that of oxygt'1"'Stlllemcnt II : Mc>hubt weight of oxygen ;,
more thot n:olerular Noight of he!J~m2~. StaieiJt"'" l : Wdtcr '" a u-ntbe c,ecutes SHM,
dte moo petiocl fur n1ercury filled up w th~
same betght in the li-tube l>e gr~""' than ilia!
in ''"'" of water.
Sttoment II : Clte omplitu<lc of an oscillating
~cndulum gue' on decrea:.m~

31. A bod)' of mo<S m io placed nn the earth''

sufrtce. It LS taken from earth".< ""'""'" o a
heJghL h <lR. The change in gra1<alional
potonb' energy of the body [;
(a)

' nrtR

mgl{
(c) 2

(hJ

' 0J&R

mg,R

(d)~,~

32.

'

(o) AND

II

Chemistry

O>J KA'lD
(d) KOR.

xa

'
(a) OR.

.e

36. feri"O<.enc is an example ot

(o) s.mdwiched oomplcx
(h) pr bonded oomp]eJ<
(t) a complex in whrch all the """ carbon
aroms cof cydoprnt adiene anion .re
bo~ded to rh~ metal
(OJ Allofthe ohow
Chloretono is used os
(a) :m'""Lhanc
(hi hypnotic
(e) annbiotk
(d) anC:<OJ""
rhe 01Mt<1gnetk mok<ules are
(a) B,, c,, N,
(I>) o,, .~,, r,

w
w
w

t,. (omI

'"

m
ra

TI1e only proper!\' po.<.<es>ed b~ ferTomagneuc

substan'e ;,
(a) hy>tcrcsil
{b) susoepllbility
(c) diroctiornll propcrrf
(d) aarncring magnetic rubs<a"'" '
33. \Vhici logic gate if rqresente d hy the
following cor:rbination of IOI!l<" gate' '

om

(b) 141\
(d) 18 l\

.c

(o) 28 N
(o) 501\

34. 1he in<erroal re'i.ltll!l<:e of a cell is measured by

~ P"'""tiom Ncr. Which of th<: followUrg
;,atemem is not true for the mternal resistance
ofthe<>'l l?
ra) lr.temol rcsi>tance depends betwoen the
twO ele<<rode p1ates
(b) 1utcrn.:J resis<ancc doe not depend on the
a1e.a of the pl"'es immer=l in 1l>e
e]eotl olyL<'
(o) Jntemol res,t.mce depends o~ the natore
nl the electrolyte
(d) lntcma.l resi.ltanO doj><'Ilds on the nature
of the eleclrode>
3S. Consider the follo,"ing u-v digr= regarding
' hc ,,perillle nt to dctcmrine the foeallerw h of
"convex len<

ce

30. The force rrquwd to >epor>tc '"'" gla,, plates

nf rra !0 2 m' with" fi~n of water 'IJI'i mm
Lbicl. between thm, JS (<uriace tension o!
wmcr is 70 x JW 3 N/m)

(c) c,. N 0 F,
tdl a,, o~,!',
The olemC"Tit with dre deCITomc configum lio"
[Xe) 54 4/ 1'"Sd &'i>"

At the pomt A, the ,dines afu and v a....,

eojUal. The local length of the lens is
(a) 10 em
(b) 20""'
(c) 10 em

(d]IS""'

(n) rcp!sentat>;e element

Co) ''"""';"n el=ent
(c) lonthanid e
(d) acriTiide
WhJcft of th< followmg show' b(>tld; in silicones ?

(al s,-s,-s ,- .s;

(!J)

~;-C-Si--0-Sl

(c) Si--C-S i-C-Si

(d) -Si-0- Si--0- Si

The type of l>yOridisation and po.mble
geometry uf te<ronuoride of ;nembers of
OX)')(<" farnil) are
(a: sp'J. liT<'gular ret~hcdral
(b) sp'. <et<ah<"dT;ti
lcl d.</, square planar
(d) ol's~', uctahcd" ]

isomer orc,H 50?

(a) Prop-2-en-1-o!

(b) l, 2-e['(lxy pro~ane

[d) Prup- 2-one

In dte photoelec~nc eff"'" the n<1mher of
plwtoolectron< omitte d rcr unit time depen d'

n!
0

cct " wmcc ~'"''"'"""" fut """''" '"' I

11
s""'"'""'' '" "'"''
S'"""''''" 1 i c_fat.,_- s = <l1t rr tr '"'~

""""''n' ''fal'"

"""
(,iJ lmm,cn[f~ true; "'"''~<o<)/t<""" ~""""
J.
dw '"'"'"""- '-')'Jona<iunfiot

'ruwr'"'

oddin g Zn d11t
StFtcn><llt II , Zincis
g')id.

xa

lei I kJ

""'thposltj,-o cl:ary,e
(a)

(],) negaric ci"IJ! "

(c) 'orne posirite, :.ume L!egative
id) oo acrnti>Jiinn of clwrg e
Tl.c freevn g point of a soluti on O'l1Tlpo.,;ed of
10.0 g of KCI m 100 g of 1'0Tei is 4.5T
, r for this
~alulare rhe ,.,, Hofi factor

.e

w
w
w

(c) 17%

is
of :1-.c wn is

..,rn,. .dlon ,: Q>resoi>"' -~e. r.o "' 53 "'" "'-'"r i=

,

solunon.

wu>t\1~

(d) 2\l%

' "'~ '"""" ''"

"""'"" " typ~ Eo<h, <f "'""' "'""""
SW"""'"-' /.(A<w o!Wn) , 5'""""""' ll ~R<cwn) liru:JJ yf

(<1) 0

Whc" ."@<0 , " treate d wirh ex< ess of Kl. Agl

pnt1p Jtate; ""~ Whkh forms c'Oilnidal sohl!i on

{e) 2.0 M

om,

ehL> pos:n ve tl:on

One mnlo of'J 2 "' 'lOOICwoi I arm preu re b

heareJ '" o o!o"'" ;es,d so rhat tempe rature
l'eoarne SOOK and P"" = 5 atm. 1hffi, it i1;
cooled so that tonperanu<' falls w 300K .,d
jlfessurc 1 atm. Chang e in i~te1-n~l energy of
1be g.lS "
(b) 2.5 kJ
Ia) 2.2 k.J

rndiat ions
The numb er of mole> Ml-TLI (p~r-:oenruge p;mrv
of
60% by we1ghtl in a 200m \ of"'-' ]"'""'
'Pedf ic gra>ity Ll2 is
{~) 2.24m ol
(a) 3.6Sm ul
{J) l.l2 mnl
(c) 3 i mol
mL
46. A zinc rOO weigh ir.g 25.0 g "'"' kepr iu 100
ofl.O {M) CuSO , olmi on. After a rmi n nmc
2
the molality nlCu + in tl>e sollln nn was 0 0
The moloncy of so;- is
(b1Q ..IM
(a)l.O M

F<;, 9,0 1, . Wnat ~ercenta~c

Jlre>e.Ht ;, the forn1 ofre
(b) 15.05 %
(a) 14%

tnm~

52. S""'" ''"nt 1 'Acid rein llas a ~1-1 of 5.6.

sulph w
~urement lJ . Oxides of nil!og en and
rain.
acic
cc
p.odu
w
c,mbm c with rair) wa<a:

llpon the
(a) energ y of inCJOen<rdJ<rLions
(b) ire4ueocy of indde nt ro<'iot:ions
(c) intensity of in<idont '"l1aliOL1S
(d) both frequency and inlcn,it:v "f inotdent

(dJ 0.25/A
'19. The compo<!tlon ol sarnpic of

ll.,;

I ' The fhot tnernber of a ~rou? of

Clement> comp ared "'LOa ; ur the sub,e quent
me,nber> ir r:1e same group shm,~ Oifferent
ckmi ca\ behavcour.
Stmem ent II : The fmr ro~mber of a group iJO<
highc"'' immatio1, energ ym the ~roup.
51. SLatemc-nt I: C,old i> reoo>,..-cd from its
soio.lttc-1\ oor.r.>Hhng "'""'1 'anidc c.omplex by
~Moment

OG.

m
ra

(c) Propa MI

"""""""'II "

II

om

44. The reacti on of g]uco<e with ore-;c anh)'<lride

and Tollen'' reagent '"W" \ that ids
ll a pental lydrox )' aldeh yde
(b) hydrn w o( carOOn
(c) a polyh ydrox y kerone
(d) an alcohol
45. 1'>1\ioh of :he followtll8 is not " fur.tu onol

oj ,,.;,,; '' mmcr Yon """" to >tort d"' '""""

}"Om t.\e :od-< (a), (b), fc) ami (Q! d=> l!o(ow
(ai <tor>.-neo r r ~ !rut; &tamW1 ;;< tru~

.c

I
rn,

o1re
'hes' quon.o'o! nbo h" [0"' a!"'"" ""' rO= , ;mtf' rho~"

ce

ReacM ilof Br, on ethyle ne in pre;en cc of 'laC]

gives the comp ound as major pn1ducL ;,
(o) Br-0 1 2 --CH~-Br
{b) Cl-C H,--- CH,- Br
{c) C!CH 2- CH,Cl
(d) 1\'aCH =CHh :a
"'
43. Bosic cham No' of ,.-hich of the fnllow;ng
maxim um in aqu"" "' medm m
(b) CH 3-NH -CIJ ,
(a) CH,- NH,
(d) CH,- -N--- CH,
(c) NaNH 2

'\~.

(a) 2.>0
(c) .2
5~.

[b) 1.8
{d) :.3

lhc tempc tmure at wilid1 nim>gen undo;

l.(lO ac:n ~<e<su,.., t..< tl;e '"'"" root moan
sqtwn ' <poeG " thar of e>o],ondioxile "' STP, i>
{nJ we
(c) - 99'C

zn::

(b)
(d) - 211U"C

ttl) ""Jt

2 :Fc[CNJ,r-- ' 2H,O

T

J-L,O

0"

-co ,

Mn,._ + 2H,o --o,,

.e

xa

1he boot af comb ustio n of bcnz.<ne a! C<m;-,aLll

''Olume ""'-' fuund rn be 3263 .9 kJ mol-: at
2S'C Tflton, hem of combustion of bon,c nc ot
const ant press ure "
(a) ---S2&."l.9 I<J moC 1
(b) ---3263. Y x (~/ 2)RT k.J mol
(c) -326 3.0- (3!2 )RT k.Jmo l- 1
(d) -3263.~ + (3/ 2)RT kJ mor'

w
w

Majo r prcdon1ino''' ,-udu cr o[ the reacr ion ca.~

"

om

."' tOe ba~s '" tins assumption. '"''" ' me f"ll""-i

"-!!
que..ciOO.'

Lylmd~r ">iil retaift 1!1 odgin a[ iorm

if
(a l <h~ temp e"'"" e i"nc'" -<>ed from 300 K
ro
450 K ar oonsw nt pre.>Sure
(b) the pC10>Sille i< iHue:J.Sed from l
a<.n <o
2 ~tm" cunst am<e mpem tuo<
(c) ~,e,emperamreis decrc<>scd from Wn
K ro
~00 K aod the l"e;su re 1< decre ased from
3 OIIlllO 2 aiC"
(oil the tempcrrll'.lle ;, inrre''-'<l from LOll K rr,
~00 K ond rhc P'"'" It' i> decren;cJ from
3
to 2 "'"'
M. Tcm?fml~r< of one wole of n ideal
2"'
con,a ined mit" increa<e<l from 300 K ro 301
](_ P"'-oore-vo:u'"" worl( obtoi ned ;,
>ol8. 3J4.1
(b)2. 494k J
(c)0 83l'I J
tdJH 114J

fi3.

m
ra

rcJ ~a,co, + H,O, ------. -~",n,

(d) Mn0 2 + Tl_p, + 21-t ______,

=l'l

.c

59. An eleme nt (X') torrru <>.>mpound' of

chc
fnrmula XCI, ,Xp ond Ca,X . but does not
5
2
form XC! 5_ WllKh of ""' foilowi' is the
clernenr X?
f J B
(h) A!
(c) N
(d) p
60_ Which ono of rho foilowing 1eao11
ou>
demonstrnres ~'"' H,O, oct:; as a:1 m:idisffig
agent in the h.a<>< medi um?
;a) Mn" THj ) 2 T20H -----'>Mn0 +2H
,Q
2
(b) 2 [fe(cr-;J,;J'
Hp, + 201r- ----->

""Dir ection ' <)<"'"""" ~'o, G3 ,nu M or< i><.<o:t

0<1 !h<
fbiJ&wins P'""!lforic
As!lli110 '"'~ W>IJ " ' " ' o
4 g,., io qliuO et wit!-. o
<M.:O>ic r,9too. "' >ho"'-" lu ~" bUow~lg dr>Wi
ng

ce

DriUge proiitOtec< '"t<rid _IUnrtion

powu Ul
5R_ T~ acom bina! lon of NO-;, Bt- <'fld [' pre;e
nt in
a mi<tute, Be- ,mdr illterfcre in d1e rlllgre stlot
NO;. Tile.<;< .uere rnow U byad dmg a soluti o" u'
(a) AgNO ,
(b) _~~g,su,
(c) .~og,co,
(d) Nunenft~e>e

'"n

cH,- -cH= CJI- CI!, - N0

2

'

~CH"-cH 2 -CH 2-CJT"-~u 0

I"----> CH,-CH=CH-CH~-NH"

.l, ~ mld Care "'l"'U ::t\'el y

(d)

~1

Ran-.yNi,H,,B~Sn;!-JC.',

r:~~l<,

KH,, H,0 2

(b) A

NH2- -Nl-1 2, HJl 2 B

Raney N1_. H2

~ ~nl

HC:I

(t) A~Sn/HCI,B~Raneyl\J,Il 2

c-NH,-1-IH,,Hp,
rm 2-NH 2, H,O,,B -]l.aney Ni, H,

A~

Sn(HCI

6-6. Aqueous sol111inn of sodmm bH:arbonatc can

fairly be useful to ~i>linguish aliphalic
'-"' boxylic aud from

(,) o-COOH (!rOll

Y
r;;o,
Jv
(b)

(c)

OC!l,

_)_~ 011

fOOH

(d)

61!. Levelinf l>uih IS u;ed du1ing expmment to

stud)' k\lletic> uf lhe dissocia11on of hydroge"
peroxide to ensure
(a) mriium1 pressure Mference bw-.een the
L1 the S'.>tem
room and the
(b) p1essurc wirhin ;he rccLion ve,eliS "'me
as that m the room
(c) same temperature as thatuf room

Z"""'

...

COOH

N01

o,N

(d) /'.one oi the al>ove

om

ov-~
~

H-Cf-1--<::00H

xa

I>>

"

0~

ln rhe reaction of a A + b B + ,-c ------7 prod<Jct>

(1) if mncentra!ion of A i> doubled, ke~piug
concenrrauon of B arul C oon<tant, rht Me

m
ra

0
Prodn,t ;, purple complex having ,tn.Jcmre
0

(<I) None of the above

of IC"-<tion becomt< dnubie.

(iiJ if con,..,otration ul JJ ~ hah'Cli, '<eeping
cor.centration ul A and C corntnnt, the ratt
of 1 eactiun renain' unafk'"ed.
(1ti) if conccntra<ton of C i> made 1.5 time,, d!e
rate of reaction bc,omc< 2.25 time,_
The order of reatnon "
(b) 2.5

67. 2 ' * UH +R-GH-COOllpnducr

I
Oil

"'

.c

ce

(d)

'"

"1-k-0

(d) 3 5

A hydrogen ga:, ck<l<ude hn> poLerttial of

- 0.118 V whcuH, gas is bub~led at 298 K and l
a[JU. in ]-;CI solution. llc pll of HCI solu:ion i<
(b)l
(a)2
(d) 2 7

.e

(c) 7

w
w

I Mathematics
l.

Jf:J'"(x+tvl-

+ '

13 '- 100

-ij

k ;,
(a)

'

-3

(bi

I3

"nd.<l;r,then

2.

Jf log (~~'log ~J and log ( g, a<O in AP,

'"

_Sc

,.~--~

where a, b, c ore m GP, then a, 1, c are the

length; of sk!cs of
tal an ;,'"''"-los <ria.ngle
{b) an equilattrai tflall~le
(c) a ><alene niangle
(d) No11e clthe abo)Ve

11.

I 0 'Pries are Ji;nibULecl ar random omOIJll 6

persons_ Tho probabJlity that at least one of
rhcrn w1ll ""'"'"" non<, is
"c
() 0
~

Cen:r<' of dtde' = (4,0) >nO =U;, = J '"'hen <ny two

Mn-pqrall<llW<-Houclilitjr Cll'cle, tt,.., <entre of circle

4. If lbm' -81- l = 0, then eg~<ation of 1he circle

hnng U< ~ m_v <- 1 ~ 0 i< a t.!l>&~n~ :s
(a} x'+x' -8x= U
(b) x'+y'- 8_r= O
(c) x'+y' +Sx= fl

'"' "c'

'"

'

(c)

"

B7

"'

CO) """" of those

-x'-S x'>4

,iTx- o:x-2 ) 1'

Lei j(xl~'l

o
u

(tl) <'+x'+B.v~o

s_ If x T 2y = 3 aJld 2x + _v = 3 touche s a <'IIT],

whme ceniTC lies on " line 3x+ 4y ~ 5; tllen
pos.>ible ""'""" ' of drcl< ""'

(<)

(aj R
(c) 11-(2 j

13.

- (

6_ It R "'"I 1<.' ore symrnetnc relanons (no!

di\iOhlt) on a''' A, thenllw reladon R nK is
(a) refl<eliYe
(b) <;lllillc>tric
(t} rranSltiW
(d)"~"' nfthes e

- 0,-,-,r
~- ;.en
'

'

'"

>sin(<X+~~~)

xa

,;sln(a-e~-rl

.e

_,,--.r. T--,\

then Ihe value ofF (x) <11 x

'

w
w

._,4 -x!

= () ;,

(b)i

rdj [l.;one of tho;e

- ~log I x + 21 + ~d!en

idJ "~w.b=s

l'he slope of rhe rangent at (x, y) ro a "".TVe

pasring through
1, ~ J "' J(iven by

'

S. If j(x)-l log ~" "u1 x)(log~" cotx) 1

(aJ

''" "--w"~s

-~ -

(b) qjn(a+~+Y)
(c}=>in(a+~t7l

(dJ

lx+2) (-""+l )

I
2
Cal a--w.D~--,2 (b) a- l ,b--s
10
I
2
1
2
1

14.

lu:t,~.7'= (

(a)

'
IIJ-- '"-,--alng O+x' J+bta n-1 x

m
ra

7.

sc~

(b) 11-{[
{d) R {1,2)

.c

C")

Then, /(.<_I i; c-ominuuu> on the

ce

I'7''1/
'I I4,-4') (b) .,
' (3,-J)
l3'0),
'I 3_-l)
1,3'0).,4,-43-) (d) r;.y_,f

om

lloi "-'' -.ng]o ;;,..,,,;, of lin"'

ros 2

( ".

,I!.' ,then the equation of the curve i<

'")
(a) y~t:m- 1 [iog,i''IJl

_ 'X
lb) Y=xta n- rj IQ"l'I'J
L <)
I

(c)

y~x"n-'llo/~11
"

'"') J

(d) /\one of the. above

15. lithe distance of a giw'n point (n, ~)from e.l<h
of two <mtighr ''""' throug h the ongin i> rl,
then rl1c value or {o:y - ~<j' is equal to

~~- "'~"

(c) d'Cx+y)

(d) !<one of Lle>e

a' c~ _,_ .v"l

~""'"'"' '''"'"tri'-:""'
Wttt8~n<n<t
1 tA<IrniorU, ot~ $10m,.,ffi) Fool. oft/,e,<e q1fe.<ti""'al>ni= /ouT ~lt<.,tln
cJ.m'is.
of -him 4 W ~t wt~< !\," o,;.,_ to
Uldl of (lu!>.

="""'!!

'"1"'""'

;dectdl; '""""W,t<t"in "!<e =fps(~), (bJ, (0

-th<sivmMOw

no

.,;,JJ<l);m,.

. --.Sta"'""~' ' " <nre, sta=t !14 .. ~~- 'sta."'""R' !l ;.

"'"" -

-'1)
[:7 ~ '

~.

8-<+14y.l3z+37~o

(d) None of \he abuve

The AM of ''"'c 0,

,_,C 1 ""'c,, ...... , '"''c,

"

'i"'
'"-"
(a) --

)'+X,

' '
" ,_,
"' '"

" 1 +I<" -11=<"

Tho number of real ..-,)utions of

to"- 2lis

(a) U

(h) 1

(cl 2

(d) 4

m
ra

17. Statemffit 1
The hne 2.x+y >6~0 i5
pcrpIldiculat Lo the !me ~ - 2y + 5 = 0 <1ml
Soond line pae< tbruugh (1, 3)_

ce

tan'[')+ <an-'[y-:<J'4'
Statement II :Product of the slop<> uf the lines
"'ocu,,) w-1.

! ''e~xdx-i...

18. St...teme.nt

(J)S

(b) 8x-14y+13z+37~0
(c) 8x+l4y-1~+37~D

St.tement 11 : Fot x >- 0, y >- 0

Y

(b)3

(c)~

(a)

""""""'""''"'' ,jt"""'""'!

W ~'nrfi:fo~~SW<mmriiLimr~ , - _- _
[,j] S>ot<mMl1"~ ~!lu'iOn]or.s.&!t.~if_

(a)2

22. The equallon of the plane throu3h the point

{2, -1, -:f) and parallel w the line<
x-1 y+2
x y-1 z- 2
2 ----1ond2~----::::f~-2 11
3

. (bl """''""' J.is =~ Stan,'""'" ,fi1o<.,

16. State<nentl : tan-1(-~,I - :an
4

The three roots of the eqll<Uion

'

f:~u '""'dx = 200~.

j[a+x)~J(xl

. ' j(x)jx,oEiond

f{:t)~nj

'

xa

Stntementll:j

.e

P(x)
tuen .':!':. Q(x)
,.

c_,

''

a'""'" non->x,oco

11

w
w

3x-l 4y

nmnuers, u

+S~Ois

(a) 3.< +B;c'+JO:ry+l~x~22y~n

Cbl 3.>:' +

21.

{rl

sy'

"
sx~sy

' .,

JOzy +'4x + 22y + 7 ~o

>y+l4x+22_y+7~o

(d) 3x 2 I He''~ 10:ry + 14.< F 22y ~ 7 = 0

-~

'"
(a) -9,2,7

(bJ9, .. z,7

(c) 9,2,-7

(d) Koucufthese

~i

GP coruim nfan even number uftenn,_ If the

sum uf all die "'rn" lS 5 umes the mm of tho

(bi t
(d) None of the>e

(0) '

(c) r

,.

20. Theequ"Lion of the hyperl>ola possing through

the point ll,- I) ""d having <S)'ln:''"''"
1- 3~0and

equal to

degree of P(x) and Q(x) are equal

x+ 2y

~~ ~ :1= G

lf t and r deno>e a tautolozy arui comradictwn

respectlve;y, then for any statemem p, p A r i<

Statement 11: lfl'(x jand Q(:.-J~"' polynondals,

c

terms ocrnpying odd place.<, tho common rario

Will i>e equal to

.;.O;re<!iol>S : ""~'~'""'>io. 1Q"' t~ or<Antf;,:~"'""

~ ~"'

'.,, "

om

CbJ

.c

[o) d 2 (x'- y')

"

The gceatest value e>f x 2y 3, when 3x + 4)" ~ 5,

"(a;
(c)

"

''

2
lflm ( " + ;

(d~ None of these

= -

2, then the lorus ofthe point

'"' ''
representing < 111 th complex plane;,
(a) a mcle

(b) a straight line

(c) rl pHrabola
(d) None of Lhe above

i,j,kar.db=i-j+ :lkoncl

vccLO.:i

0'"

(a) 7
(<:)

(a)

dtulc ;mgk will! ohe ve<J.-.o

.J 26

,~
"'3

'h'2
'''4

(c)

,2(, (41 - j + :lk)

l
el
c 3

, 4
c'd''~

(d)

Non~

6 L4i
.

of che above

Tho probability that out of 10 ~cr<uns, II boon

in Apnl, at least two ],.,,., the same bmhdaf, is

fcJ

"c

"c-'~

(h) 1- - - "

30!

(30)'"

go"---"'c-"

.c

(o)

ce

(c)

m
ra

(0)

(c)

)c)

~.

)).

MATHEMATICS

' "''"' ...

'"'
"' "' "
"

"
(a)

w
w

(<)

(;)

(cj

(0}

(c)
(c)

(b)
(o)

(o)

(c)
(c)

,,,
"''"

:c)

,,,
'
'
"'" ,,, "'" '" "'"
"
..."

.e

).

(c)
()

xa

~.

(a)

(tl) None nf Lbe3e

(:lld'

, ,,, ' (C) n.'

'"
"'
"
"" ,,,'' '"
"" ,,,'" "" '" "" ,,, ""'" ,,, ""w
"
"u. "' " ',.,"' ..." "' " '"' ""
'
"
'
,,,
"
...
...
"
'"
'"
"'
'"
..." "'"' '"'"' " ''"" ... ,,, """ '" "'"
(c)

j :Jii)

om

/7. -

PHYSICS AND CHEMISTRY

(b)
'c'

"''" '"

(d)
(b~

!,_ "

-~(4i-j-3k)

,'~

(a) (2+,'2J<qunit
(b) (2- ,'2J sq unit
2) sq unit
(c) (
(d) None of Lhe above

(b)

1>

32. The orea of one tunlliueor tl iangle f01med by

the CUP;<>) = ,in X, J = O(}.U and NIXi' i:;

).

lio>n;h,J 111 o
~iWJ\ spill e, then ratio ofheipt of tho wne 10
diaaeter ot the >-phere ;,

A cone of maximum volmne

31.

makin~ .m

(d) None o! th"""

1~

(d)

(c;
(c)

(c)

~.

(a)
(c)

:c)
(a)
~o)

~c)
.:~-)

(t)
(')

""'
"
...""
"

,,, " '",,,,,,

'",,, ...
..." '"

(b)

(C)

~.

(c)

',,,'""'
...
'"
56.

(o)

(c(

,,,
>l
,,,
'
"'
'
,
"
"
"
"'
"...
" '"' " '"CO)
(d)

~.

(o)

(c)

(o)

Physics
will pru<lua: mogneti< lidtl ""oudo il ur'J-00'''
Lhe ong;,.,) mognet1c field m aroordance >~ith
Le:u's law_ n.u,_ currem i induced in the loop

1. p-type or n-type 'emiCnnductms are unchat](d

the dopants are donating or acceptin); the

'e("tn}n>, hu> acquiring negotive or ;>osil1W
cl>arge_

Q~:_'!t

in antidO<kwise du:ettion.

om

Charge of capacir01 is the charge on facing

,-urface> of the plat> of capatitor.

10. rn.><e% ;, Jsobm1c su.'JW

~1.01 X JO' 0671 -1) X lO-o

/'J

= 168.6' J
IIQ-Ix540x4.2J
~ 2268 J
AL' ~ .l.Q - AIV = 2099.33 1

)10-(-7))

= 6itC

'

_,

Potemioldifferene< across the caf"dtor- l2V

so.

~
3.

l \~o-")
(G

C-v

JF

~ pLW

~ O.S~F

Due w the proce <J! rrnognetit hlu<thm

v- *so tho cntw ;s rcctaJlgular hyporl>ola.

12. Fr<UHJ(:"<Y heaoJ by oh<crvcr (8'-"' 1onaoy) will

he "'"'mllm if <Olltce" mm'lng mwarch; rlle
ob<e;Ver, "'hidl is the co"" when tile 'our<:eis otR
Frf'l!uency heard by observer (sco<10nary) will
he mioimuro, il;oun-<; ;, moving Hwoy fcnm the
ob~etvec, wh1ch L< Lhc oa<o when Lhc wurcc i'
oLA

m
ra

ma&net can allract non- magncUzcd substances.

11.

.c

~-

ce

4. The needle will stoy in any direcUon it is

relea..,d_
S- Dire(tly !rom theory.

--o

6. The rota! averoge enetll)' of SHM in o~e time

2

. mw A
0

penOO "' - -- -

r decrease. frequency incrtd'"" o

""'ek"s''' k< '~"'e'6. l.N parnde is projected l'ito sped u, >a total
Af;

xa

7.

rirr:e of fli~hc
,_

;(

.e

"

"Jand<=2x ma~imumhe>ght

~' "'
=2x~=g

w
w

T=

n rheTe i> no zrdv:icy then>'

=" T
2u'

~--~2>

'

H gravit)' is not there, it will ne>-er fall kck.

9. At th< locanon of loop_ magnetlc Held ,,
i>"tpendicular to plane of P"P"' and going inm
i, wlri<-h h im;ru.,ing wilb lime d5 current i>
increasm.5. Therefore. emf will be :nduced in
tbe loop m such a way ;o that induced current

For point C. JreqLtency llean:\ is origmal

fr"'" ue;rc y.

I-~MR'
l.li=_;Mil 20 > :le<.'JT_l
0
~I+

Ia x 2.>.T

Force between two charge particle is

iodepenclem vf presence of >n;- orher charge,
(superposition plindple)

'

'

R 1 -K4,R 2 ~2K4.,R 3

'I

4KA

"

f R 1+R
R,
R,,~!,R
+R,_ ~12KA
' .
.
[e> rods 1 ond 2 ""'in pa"illeland equivalent
is 1n "''"'with :<J

'

Tmg< formed by roncove lens is"'"""! fur all

b!O<k where s " the dlSt:mce rraver>e<l by

block-bullet >)>leou on the !able top.
From work-ne.rgy theorem.

t.K =WI

pos!lions of ob)e<tre, llllag Oyccme>lve lens lies

~"'''""'' the ""' len.les_ For both the im"l,'tS to
col!lcide, image bv mnvex lens should also lie

j_j

rui>ed.
W = (180 kg] (9.8 rn/.< 1) (I 7 m) = 3.0 kJ

having em! E JS I A, while

through 12 V bmery is

For convex len>

'

_,
... (i)
For oo:ncave lens

'
~alvin~

'

'

'

Llus equorion, we get

20(,'3-lj
x
..
em

"

'=20(~'3-l)c-m

w1d

Ma~uilicolion

v1

-v

'

-W

-(20-x)

by ronvex !em
v
20(>~'3-l)

-./3

.e

-~"'~'~"'"

19. By cou>rvation of momentum, the momenhlm

of the block bullet sy<tem JUst after the
interaction is p ~ r;w,

w
w

=> '=3A
wh~cc i "

.
=(2-/3-3)
20-?~U~ I)
,-'3

E,1!l

current flowlnz through tmonob

l2V batle<:)'
From Km:hhoff's circ"Uit I"" al !L C\lrrent
rhrough rechargeable
islA_
Net power ('<JOilHnCct
=VX!=6xl=6W
22. The descendirlz pari ofrhe mpe is in !tee fall; It
cunwu!iu~

Magruficanon Dy roncove lens

v2 -{20_-,) 20-v
"' -(20-x) 20 x

1'hi> can be ('"k"la.-.d a

follows.
Potential difteren<' acm
12VbaucryJS
fl"U-1~2

... (ii)

xa

m, =;;;-=X= X ~ zo(./3-l)t ,13 =

"'--

"

m
ra

'

(20 v)

.c

C'urrent throLOgh harrery

1_.,_< - - 1 - 20-< ._..I

ce

'=0.37 m
20. 'Jhe work dor_r by gravity is the "ark done. as
if all the rna" were con,entrared at the <enuc
of mass. 1he work <H'Ce<sary to lift tbe ob_iec~
am be thol'ghi ol " the work done >gaul't
gravitv ond is just W = m,i[h, where " is the
heigll: through which tbe centre of m= is

om

in betweffi <be ;,_o I011<e< the rwa lens or

ima!;e b~ c-unvc< lens should also be >irtual.

0-K=-~.(m+MJg<

!las speed v =,.'2p;y

"""''l'

"'the'""""' alit" point>

~~'

'nc~Tr'' ?lieF~~

lw>c de>cemled a disra~cc y. lhe length of the

OlJ

intf!>VI dt tollowing tim inmnt lS vdt. The

increment of momentum imparted to <ho table
hy tlri> length in rommg m teSt is m(vdt)v.
Thuo, the rate or whrcO momentum is

"""''enctl w the table;,

e~ert>

dp = Pt- p,
dt
!Jt

a Ioree on it.

(P/<)LI!
~'

=!'_=4.i9xlO"-~

'

2.7. Acceleration due to moon's gtm1ty on moon';

surfa<e is
because

"

~-'" ~.!: M,

and thi.1 1S t~e force arising from topping the

downward !'>II of the rope. Since, a lengtf, of

R~

6R:

(g

Gm).
R'

While oce<lerannn dHe to e<mh'' grnvity on

moon's surface isdpproxirnately(~i' or 3~0u

I2 + Jw'
2)
2

=(Mgh) 0J

~'

.e

M>

2Mr'

For a <olirl sphere, 1 = -,-- Al<o, lO = r' Then

ahovc cquatlon oecome<

(~Mr'1i.")'
=M h
r
o

w
w
or

2\5

1 ,

:!'' - 5 v

=(9.8)0

U<.ing ''~20m;~ gi,es h =2&6 rn

Note' rh, '"""'"0''- "" dcceoc ""'" '"' "'"" ,.

'"' b'll " " '

ce
eo

'"i"" '-'" "" '"-

Rote at which ene'l)y is mddent on >phe"',

P = intensny ~ projec-tion area of sphere

= 10 x 10 ' x

x (2x lo->f

This energy incident on sphere impam some

Moon

m
ra

xa

The """nona! and tramlauo,al Krl of the ball

at the bottom wrll i>e c.hdnged to gravirational
potendal Oll"'lfi, whrn <he ophere stops. We
therefore ;nite

can X undc,..tood from d:te f.gure

g,, ~+/-

\ 60 R.

\,_.(--/ ___

2mc. = mg sin 53" W"& cos 53

- mg sin 37' -IJJ"g 0<><37
'!'hen u<e v' ="' + 2as, v= G, u= 1 m/s

,,

00 times the TI\dius of earth ""d g- --!,.This

,.'

Find acccleranan

_!_M-t'+ l

Thi is because chsLance of rnoor_ from the

eorth's <>'ntte is appmximalcly e4ual to

c, ~c,

'

.c

rope y, of the WeJght(n()' )g olro,dy he< nn the

mbletop, lhc tut.J force on the ra\llecop Is

(2my Jg + {m_v)g ~(C>try)g, or the weight of"
length :\y of rope.
So,
J{-3
The charge on bmh the cap>dtors C 1 and c,
would be same " hoth m l'-"lllected in series,
tllen equivalent circuit
can be dfdw~ &s and
q=CE!l-< r/>X'l

whe~eC- _5_,C,

it, whicll.

gJ

o,p-m> 2 -(Zmy)g

"

mornentum

the tob!e during ""

om

rope which lnd<

,,_

"

"--~.~)

~/

g1 =

rf~)' whiles, = ,;-

Ilelium is monoatomic gos. while M)"Ken is

dmromic. Therefo,-.,, the h<'<lL ~iYen to helium
will b< totally cc~ed u~ i< increa;in.<l the
translational kinetic eucr;,-y of it> rnoleruk<;
whereas the h""t giV<"n to ox)"gen will be uoeJ
up lD incr.,.sm~ the nan.slatioal kinetic
energy of the molecule and al"' is 'llUCO>in):
the kine"c energy of rotlltioto oncl ibration.
lienee, there will be g:"eatcr rise in the
tcm!"""tllr<O of heliwn _

The pcriOO of Lhc liqutd ex<cuting SliM in ,

U -tube de>es not dcp<nd upon the delL<oi ( y nl n, e

liquid. Th""'fure, time period will be tho <arne,

when merrill}' is filled up to the same oei~ht "'
the water in the ~-:ub<.
Now, as the pendulum oodllate,, it Jroz:; air
with it_ Therefore, its kinetic L"nCIJ,"Y il
dis<.ipated m owreorning visoom drag due to
air and hence, its ampl!tude goes on
alon~

docreasin&.

35_ Clear!)' the courdmates o! A are ()J, 2/ l

f ~ 40
=

'

20 e-n

ll Chemistnj

42

"'
m 2~Cl-1, ~ cw<~rn,
N1

'

Cl

""'''l"o-ee

.e

"f""

"' "

01-l

w
w

H
"

'

CH

ClJ,OH

'

xa

43- NaNl-1,--------> Na Nft,

Solo NH; is much I""' mong base.

me

"'

-------'> CII 2-CH.

~~;"'

,I

c
0

o -- C ----<.;H,

om

01-IC-+ CH----+4 CH,

~C-C!! 1

.c

P'"'""''Yl substituted gluCOIC COJlftrms the

p.-eseru:e of five hydroxy group. Tollen\ rted)(l'IIt
;hows the existence of aldd;d;,_ group.

ce

Propmol (CH,CH,Cll,OH), c,H,O e<ll not he

1he ~omer of C 1!-i 60.
N~mber of plwroehtmm emitted Jepc,ds
UJ>Oll i~tensit) cf inddcJL( 1<d '"Lions_

112 g contamed hy l mL_

then 200 rnLcontOlilS

~I,

\2x 200= 2:!4 go!

HCJ,olulioo
Actual w<ight o' HCI = 60'% of 224 - 134.4
1344
:-lumber o! moles = :lb'i - 1.M mol

m
ra

36. Ferro<"<'ne ,, o .<andwJCh complex comrmm<l m

which all the five corbon attnns of
cyclOjlentadiene "nion ""'1m ked ro the metal
1hrnugh p1 loonds.
37. FcLuaL
38. All arc hav'ng paired electrons only inC,, K,
<Lrnl F,.
39. After achleving 4/" Sd 0 fu-'' confi~urdLiuu, lh<
next electron goc1 to 5d and this is the taso of
Lu (Z = 711 wlmh is the last element uf
lonthanide serie5.
40. Silicones oom"ir- --,S-0-Si- bond.
41. The member\ of oxygo~ family formMF4 type
tenafluoride> (where M -O,S.Se, Tel, in
whkh the central awm ;, .<r'd hybrid!!ed with
" '""'gulor tetrahednd g<'<>meory due to
presncc of one lane pair o! el<'"""'-

Ac<tk anhydrJde

Cl

Pmcess is ciispL,cement ,;,nply

'>yZn o.- bm the concrntra<ion
of so:;- with both jons ,-,rn,.,~ oott<tant

cu'~ is dbp).,ed

e 093 Ouo
O"dllott number of Fe 0_,
--2(0.93molpo,cssnd 1 2chorge)

Suppose x mol- 2charge.

then 0. 93- .t po;,;e' + :l charge

1-lentt, ,. x 2 3(0.93- x)~+ 2
X

0.79 Fe 0; Fe ' = 0.14

~ ,~,,
_ U.l4 'l"l _,~.von
_ , ~-"'
re
,.---X><

0.93

;m;ll

,;,.

and

bigb

group bas ooly tour valence

orbil~\>

expa!lS!Ol' of the yaJence shell ro ocoonunodate

:nore than fuur pairs of e:ect~m>.
l'be iorili;auon cn"'l!}' decrea""' oo moving
~own the group.
This method i< known os Mac-Arrhor Fnrest
q=ide process. Gold par:1clcs di,olYe in
dilute .<oit<tion of sodium cyonidt in pre>ence
of OJ[)'S<n of the ,;,-form co~lph c-yanides.
4Au

+ Agl + ~o,

{2s :md

2p) ,-,,,[able for bonding 1e, ,.,....., "' no

~1.

NOi + ~r- + r + Ag,S0 4 -------'> AgBr(ppt. )

+ 8NaC"-- + 21-{_p I 0 2
-----+ 41-<arAu(CKhJ + 4NaCN
sodium <mru">'"ide

~u is recovered trom the >oludon by the

tlditiun of more eleccropositwe metal.
2!\a[Au(CN) ,], Zn____, Na 2[Zn(o-;) ) + 2.Au 1
4

ooluble

C 5H,(I)+ 15/20 2[i j--------. 6C0 2(g)

+ 31-ljJnJ

''

!JJi =L!E - M,RT ~- 3263.9- (3/ l)RT

lnrernal aldol cor.deosa\ion.

""""

xa

m
ra

52. The norrnil rom w"tcr has a pH of S.6 duo to

dissohrdon ofCQ 2 in it, but the pl-l of acid rain
isle than 5.
In atmospl'~'~ the mddes of nitrogen and
sulphur combnc5 v.ith warer to gw.- ~olphwic
acid and nirrir ac1~ which makes the rain
acidk.
53. lmrl>l.<rate (30UK, I atln)
F:innl "-'"" (300](. I atrnl
bin<>' milia! and final .ltntc are same and
internal energy is ' sta:o ~LnCtlon. ;o !>li - II.
.>4. >'.f:NO, - KI -------> A!!"l + KNO,

w
w

.e

Our of "'"'"" Kl. 1-, wh1ch is common

con,'rituent to soluuun, ge" "l>sorhed over ,\gl
nnparts nezanve char2e.
55. Al'; =iK 1m
_ _!_!!{lg/~gH20 _
m- 74.55 g:rnol - '--14 "'
i_!>Ty=-

- K,m

4--'~C

(;.86Ciml (I.34mj

lB

56. Lot 1\MS speed of nitro3en at TK be> ond is

equal to tloat or co, at STP

- i'gk'f = 13R_~ 273

V-~ 26
\ 1 44
28
27
'f 7
17:!.7:JK--9 9.:l7C
4

'J

57. Salt bndg< i> used purp<><<'~:~lly to reduce

liqmd junction potentinl.

+ ~o:

fi&,CO, dues not dissolve m wat.,-,.

The
elemenT
;,
r-;
wluch
NCI ,, r-; ,0 5 , ea,r-;, but not NC1 5.
Here Mn 2" is oxidi>ed to MnO, llt lo>k
l!ledium by H,0 2.

om

i!S

.c

Besides

decrronegadvi[}', the fir.<rr memf.er uf each

ce

~0.

63. 'f ~ T, \'Oiume decreases ro

ou dec""'-'ing

tomperature from 300 K to 200 K

lf-

T,, Yohm>e incroa>e~ further to ~value nn

decO'ea<lng presSllre from 3 otm ro 2 atrn, thus

original form i< retained .

64. pV ~ Rf' attempermor c T

!(

p (V ~I!. I')= R (T + l) ar remperature (T + l) !(

p\'-j),l'f=R l'+R

:.pM'-R

Since mech.anical
worl(j =pi'>'!

wurk

,,

(pressure-volume

.pAV~R=8.314J

<

Reduttrun
double bond ortly

"

ReJu,on
Mly

'

KH 2-NH,, H,O,

"""'!"
Oydrogeoation.

ono,

Reducdon of both

Sn/HCI
~ney

Ni;H,

>trong" on.

66. Benzoic a<id, o>-..lic aciU and picnc aoid are

suffici"1!t' acidic to evolve CO, but (h) is
oompRmuvely les-s acidic tl!ar' why <il.,r,'t
evolve co,.

vy yv
c

0
1'\UJ>k violet complex

6S. The main Plll1'ose of using leve~ng bulb is to

assure that pres.mre within the r<action ve.se\
lS same ., that in the room.
69. Statemem

om

(J) 511&&"''-' nrdo" with r"-'Fecr to A is l_

(til StiAAOstS order with respecr ton is 0.
(ili) Suggests order with resp<cr to C ;, 2-

Hence, rate law eKpre,;ion <on IN written as

2
0
1
c= klflJ lB] [C]
Order ulre,cMn = 1 + 0 + 2 = 3
)

H,

0., 1;=P""

o.059llog~

v= 0 + 0.0.'>9:

ce

"

-,

.c

"

7 _ ,--, +e.

- 0.118

log

ur-:

- o. ns v =- 0.0591 (- log [1-r+])

-0.118 v~- o 0591 pH

Mathematics
1. Since,

I'

m
ra

H= U.l18 = 2
0.0591

0 ~''"
'
,X+\)'- +
,""'')-~~2
2

'

But

~ [u3 r ~ 011"'

xa

l -

I~

3' (< + lY} = ;"'' 3' 0 (-

m}"''

3"" (x- iy)=3'"-"' = 3'" 1'-~+ i

--!})

~-

Since. log

X=-

)
c;;Yo

,,

x = J;y

k=--L
,-'3
.:'1. log'~~-!
I' 5u_,
oc,

and

log[~.)
""

arc in

g,f3 '

.e
3

'

x+\)'=-z+-,-

w
w

:;.,.'3
3
x=- 2'y-,.. (i)

(x+

b, care in GP.
b2 ~or

_(li)

"

On 'olving E.qs. (i) and (iii), we

9/5

b+c<a.
Since, sum of two stdes of a triangle is smaller
than the th11 d "d.
.-. Tr:ian~le i> not dellned.
3. Let f(.<J=.< 2 -2(a-l)x+(2o+H Then,
f(x) = 0 will have both ""'" positive, If
l_ Discriminant;, 0

2.<umofthere>o">O 3.j(0)>0
I. Discrimir..mt l

"'

4{o-lJ'-4(21HlPO

"' (i)

2. Stun of the roots > o => 2f_a -ll > o

___ (ii)

3.f(0)>0-'->(2<Ii 1)>0

=
-

'

- (lii)

a>- 2

xa

,.. Solutiom for(/_ No. 4 to 5.

16m' ~Bl+ 1

?;

oos 1_-

21 l,

1"_,_~-~

<m - , - ,

~"~SLn
_ ("+~')[ co; ("-')- co\la+~+Z7'I]
;
2

- 1"-')'
2
'"\('''I,
2 :ill ("")
'2

" ~ '"'.,

Since,a,~,rc(o. ~)

="

16Cl'~m'J~(41+1) 2

=>

c---, ~141+11
4;'!"+m

=;

.e

l6(1'-m')-J61'+m+t

1~=4

,r, m'

~~
~+"{ "/+<>
2'2'2

w
w

5. Given t~uations oi lines x + 2,v- 3 ~ 0 and

:be+ y- 3 ~ 0 "'" non-p<lr.Uel.
Bisecror d lines
(_:<+2y-3) +(2.\'+y-3)

/5

=>

E(O -'""
-~~)

_yl

sin I <!__:1-__ll: sin r!)_~

sin p:_:i--"] ' 0
,2)'
,2'
,2

=>4,in

Since, u:ntre = (4, 0) md radius = 4.

,",Equation of circle is c~ -4l' + lY - o)' = 4 2

,~-T~+

'"''

=>

=>

~ 2>in ("; ~) ~ 2>in ("; r; >in::~; Y)]

Hcncc. the lcosr intc311tl value of" is 4.

,. ,

su\

'

From Eqs. (i), (i1) and (11i), W< get a~ 4-

4. Given that,

><>hing E.qs. (10 and (iil), w~ gor (3, -\).

Since, R n R' """ ;:~t dis,ioint, there is at least
one ~ ~ered pir, "i (c, OJ in R n R'_
But(", b], R n R' '--"(", b)'= R ru,j {>- I;) o R' .
Since,Randl!' are 5)-Inmetric relatione, we g<t
(b. ah R
and
(b,o)ER"
and comeqoentiy(b, a) ERn R'.
Similarly,
onr
other
oro.,!
pcir
{<-, d) e R n R', then we mtc! al.lo haVE
(d. c) El-: ,-, 1-:'.
Hence, R ~ R' 15 symrnen< relation.
7. !>low, >inu +sin~- si, y-sin (ct + ~ + 7)
(<:<-~)'
' +~\

6.

m
ra

a>l

g<{?-, ;) and

.c

"

[lmm Eq. (i)J

ce

"

5~5<-~~

-(2<+ y-3)

x+y "2
... (il)
Sinoc, conlrc of drclc lies on angle bisector of
lines.
Abu, centre hes on d lute
3x-14y -S
.. (ii!)

From E.q,, (i) >nd (til, we get

9ac ~ 25< 2 => 9a ~ 25r

Zy-3)~

om

Also~.

(HO'loin

.2;

'"'"+.<in~

,;, a-

s!n lpl
:
>0
I"'']
,2
2

+>ill y- >ill (o

+~

6. AI X " 0, log"~ , "1U X and Jog,"' x 00{ X IS llOI

Jcf.ncJ_ Sn, we do not determined ;he j' {x)a(

x=O
9. TI1e equation or g:v"n """'""

___ (i)

x-y~,;<-

On differentiacing w_u_ x, we get

(x+2y-3)&(2.\'+y-3)
- (i)

+ Tl> 0

siJ1 ll +sin y> >iH (u + ~ + y)

"

"'

I+ d.<~<"' y.xd.<)

-;!,.

lf It touche>, x' = 4ay. then

"'!"'"""
.
v ' = 4< [mx + -" ' ha> equal roots
1

'"'

:. 11c~ 2 -4<1m 2x - 4o 2 = 0 I'"' e<ludl wut>.

= 16a"m' + l6a0m = 0 (: discrimi.,ant = 0)
m1 =-1
m=-1
On puct;ng m =-1 my= mx- -;!,,we geL
y=-x-~

=
n.

So _f(x)i' not conTinuous at x ~ l.

Similor)y, _ftxl 1s not conllnuous at x = 2.
Heru.,, it is mn6nuau' for R - {l, 21Smce,

~ 1----=o
'
1 (X 2}(x
t-Il

+/,.,,-,_,-, llo~lx+2l+c
0

On dil'fcrcrrtiating both sid.,, we get

1
btan- x+

.c

10ax(x+ 2)+ Sb(x + 2)+1 + x'

5(x+2lU+>-'l

1t(S)

The required pmbabll;ty

'' 'c ,_,

'"'''c,_,
6

=I

137

= 1 -141=14.~

'c

__ _l_

"c,

for ony x" l, 2 we find tlm f(x) is d>e

quouent of two polynomials and a f'Olynomial<

xa

12.

;, everywhere continuou<. Therefore, J'(>)"

rontinuou.< for oil~-~ I 2,
C011tlnull:y at x

~ 1,

.e

LHL= lim f(x)=lirnj(l-h)

,_,' a
= lm (1-h-2)(1-h; 2_1(1 -h + l)(J -h_-1)
.1-o
10-h 1)(1 h 2JI

w
w

=lirnl3-ltl(2-hlhU+U
6
IHO
h(h+!)
-

(x+2)(1+x'J
(l+lO.>)x 2 l (%~20a):<+1i10b
'i(x-2)(1+x 2)
=< (I < IOol x 2 ~(50+ 20u) ,, +I+ lOt=:;

m
ra

"""h

ce

the number of integral <olu.,on< or

g1v., "(E) ond the r.umh<.T ul mtegral>olutioos

of x,+.<,>+-<,--'",='n
iha'
x 1 20_x 2 l0, . . ,x,_~Og""'-'"(S}

tJ

2axb11
l+x' l+x 1 5 (XI-2)

I - probab!ley of each receiving ar least one

-1-n(l::)
=

x 1 +x 2 +x,-x4 1 X ; i X 0 olD
sud1 thatk 1 ~I, x, ?1, .... , ~ 0 21

~ loglx 1 21>

----------

The "'quircd pob.>bili!y

-l-

d r
,
"'['alqdl + x)
"-'

1
(x+2)(x'+l)

x+y~a=O

-~ow,

'

o~(l+x)

om

y = mx +

On compar;ng the roe(flc.ent of x'. x aTid

<;OTI>(>:Tit ttmO> on both sides, we get
1 +lOa ~o, .'ilo- 20<1- o, lOb-4
j
2
""
a~-10,b~5

14. Gi,..,n 1har, dy = r_ - cus' (']

Pu'

d:<

X,

~=1--">_'f~xl~:t~r+x~~
l+x-t=l-cos't

..

'ec"t dt =- ---

0.. im.-grnti[l)l, we get

'

t:mt=-l<>g(x)+c
----;

tm :

I.J =-log (x) + c

'

,,

:0 ' I,

,,
l
I'
tanl;, )~log,:;:_)logc
tan(fJ=lo<;J
Lan

"4)=-log(ll+c

c=l=loge

x' x'

3+0-0+0

4+0 -0

Statemem T.
~U.

Lenhe oquoMn of any line through the ongin

(O,Q)boy-mx"O.
... (iJ
It is gi;cn that th< length of t11e porpcndK1~or
from rn, Pl LO liuc (i) il d.

We know that equanon of the ll)'ll('tiv>l' d!ffei>

l'om tile oqution uf the O'J'-rnptme only in

.c

oon<tonl term<.

ce

Equallon of "'")mpto<e is
(x + 2y + 3)(3x- 4y- 'ij = 0
:_ Fquarion ofhypcrbola i;
(x+2y<-3)(3x<-4~+5l+A-O

lt

__ ,(i)

P"''"' tl!rough the poim {I, - 1).

[l

+ 2(-1)-

~][3(1)- 4(- 1)

+ 5] + ~

~ Q

m
ra

l~t-+~=J
'
l_Jt-+:-J ' ~d'

4+_2__2

-_ S!Otommt I is n11e ili~ Statement IT is true

bur ir is n~t a mrrecr "-"Planation of

y=xton'llog(fJ]
15.

~ + 9)
l 3+~'x'x'

= hm---

om

Al puint I,

!'rom Eq. (D,

l>::o 2y_,_ 3)(3_,_, -'-y + 5)-8~u
'43x' + e-J ' , IO>y+ l4x- 22y >7 ~o

N\lW, lH

.e

16.

xa

21.

Let the c''"" number of tefil'-'l in GP be 2n, w1ti1

' ' " ' t(!fm o ond oomrrtGn ratio r_ Then,
~urn ~~ oil rerm< ~ ') (Sw:n of odd terms)

=a,_

+ -c, 0 " .'i(<l., I "J + ... + <t,,_Jj

a+ ar~ a:r2 _ . +ar'"-'

02

~sea'
"{'" -1)

-(r-1)

Statement II l< th< wrroa axplantion of

Statement L

w
w

17. Slopeofim2xfy+ 6=0i.-2"m!

(sav)

and slope of line x- 2,v- 5 = 0 is~ ~ m, (say)

m,m,

Also. Ll,

2
--1

J,'" e'"'"dx~200,\
.SMcmontl"' false and

Stor~me"' T1 i;

,,r

y-1

----=3

5-:I(r'" -I)

c "

r +I= 5
r= 4
x-1
" and
lme> ore , - =y+2
2- = ~
Z

~-2.

f.quo!lon ol plane pa,ing thmt~gh {2, -1, -3) is

a(x-2)+h:y+l)+c(+.1)~0
___ (j)
!-<ow, giwn line5 are pam lid to"3a+2h-4<--0
... [ll)
and
Ja- 3b + 2< 0
... (Iii)
Elimination of" ba:nd cfiorn Eqs_ (i), (>i) and

~)lies

on x-2y+ 5 = 0
H.nce, option (d) is correct.
18. Since, P"''iV<I of."'' is 21t.

Eouauon

ar'+ ... ~ar~~'l

true.

(iii),

we get

"'0 -

"'~~quolm.r

,_

Now,

""'c +'"'c ' +.

~--'

2;3x'i, 3(4y"l=5

'c,., ...
1
'" C, = ' " 'c ,,_, 1

"' 'C 1 = '-""

(nt-1)

+""' 1C

,_2)

3x 3>: 4y 4y
2+2+3+3

z'"

Umg we1gl1Ced AM
3.<
4v

------" =---

n+l

22~ 33

21. Gillen, 1 +II" -11 ~<" (c' -2)

e"-11~2

('"le'-lloc-1)

d"-1=2,-2
e' =3;-1
(:<f;<-1)

_. The Tiumber ofreai ;ulull<ln ,; l.

lx

Givel:tthat,
Appl)'in~

b
~

3 7

6 -"

R,---> R1 < R,. 1 R 3 and

:7

'' '

2 =0

'

w
w

.e

Appl)'ingc, .... c,-c,a~dc,--->c,

2(x+(y)+l_<'~';:"~'jl+i(2y)
y)+i(i)

taking

xa

i'

(Xt-9)12

~[(>;)'[4;)')'

L<>lZ=X+IJ
2ot-l

rommon from R~

G'<l inequality

.. tz+l =i(x+[vl+l --(1

2=0

...

m
ra

<"=3

4y
3= 5

.c

-'--'

2+1<"'-ll=,""-2o'ol
2+le' -IHe' -tl'
le' -II' -le' -11- 2=0
lie' -l-2HI e' -11 + 11= o
le'-li=2.-l

ce

=0

,3,

om

'"''Co '"+ 1C 2 "_ 1,

Jx+4y=S

c
,_,
"
_, 0 '=O
x-7:

c,

~(2< 1 1)(1 v)+ 2..w

]
_.
+i{2y(l y) :.:(:1.>:<1)}
---(! y)'+x'

l2z+l) --2
Smce,
Tm-,\'-"+ 1
(-2x 2 Ly' Y+2y)

2y+x'y'

Weha;"C sinA_~ms_=,;,~
c
b
' a
45
>in
30"
sin
Slll i 05

--,-

,'3+1

-J3 +I

b~ 2sin 105'
,13 + l
, 12 sin lOS"

om

c-~

___ (!)

x'=y (2r-y )
VO!Wlle of cone,

V~

j """'y

.c

~~ny(21"-_Y)y

[fromE .q.(i)]

~" (2Jy'- y')

ce

On differentiating w.r.r. y, we gor

Area ~I!> ABC "

b< sin

A~~ be sin 100"

[,.'3 + ll'
2 uz,in (60t 45'J

1'1

(,13+ ll'

AgaJ!l differe nnatlng w.r.t. y, we gee

tan [.!]

xa

2(./3+ 1)

~~(./3;

y[4r-3 y)=O

2~2-!22

l)

x" -tan r- ''lx

1
o'v
Jy,= rr(4r- Oy)

sfii.2 X

.e

ax'

tan7x '+tan
--<in' x -'m
~o
-

[:7<e 2 <8)

w
w

'

=-ve
Volume of cone is maximum at y ~ ~ rNow,

7+8

Heigl1t of oone

Ra ,

no =Diameter of -<phere
~1_

,,"

'

-,;

31. Let t.':tc diomo: er of the sphere_ AE ~ 2r.

Let the r!idius of en no " _, and beight is y.

Smce,

=0

~~(4ry-3r'J~o

..,

(,'3 I l f

4.'21''3 ~

For maxima and minima. put :

m
ra

:=~ff(4ry-3y 2 )

AD= YBD'-A D-DE

"3

"

''

<---cor'"F'I"t-1~.
X

tt/2

'

I "" rosxdx

sin-<dx +

"14

~-[cOil

,.

llixbi=-Ji6+1+Y
- ../26

.-. Unit Y<ctor porpendiculdr toil and b

il.xb
,, __

x]f' - Ism xJ:;.j

~-(Ji--tJ+(t- 1)

1.1 xDI

1J~(2-..

~-2)

/2)squnil

[l(x) [f'(x)+ p(xl (!'' (xJ

xa

-[f(x)p "(.<)

w
w

.e

=Plxl-f /"(x)

35. There 11re 30 daf' in April.

n(S) =the number of way> in which !0 perwns
can have birthd"}~ in the month of Apnl
= 3Ux 3U x ____ ''' 10 times= 30 0
(because each person can have bin!><lay in any

of 3(] ways).

m
ra

"'2y':;=p[x)p"(x)-~fp'(x))'
=

.c

~ =p"{x)-2($)'
2y'~~=y'p'(r)-2y'(~)'
2y

dx')

2(~)' + 2y ~ = p"(x)

dx

"'

,,

On ogain diffe,.nn ating, '"" get

, ~ (r' d'~ 1

Roqurred vector is -- -,- ( 4i - j - 3k).

On again different iating, we get

But- -,-- (4i- j- :lk)mak es au acute angle

,26
with the ve<:ror k.

33. Since, y' = p(x)

On dllferent iating w.r.t. x, wo get
2 1 dl=p'(x )

,.

l-r41 .,J-3i<J

=i

ce

,,(!-

'

om

> =></<!

'

=4i-J- 3k

n(E) = n(S)

the number of wayo in whkh

10 per""n' C>ln haw. different
birthd;,y s

=3o'"-""c"

:. P(E)~ 30"

C,

3o"