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in enhanced chalcopyrite
dissolution
PhD. Cynthia Torres Godoy
TEAM
Cynthia Torres
Maria Elisa Taboada
Tefilo Graber
Osvaldo Herreros
Pa Hernandez
Helen Watling
Denis Shiers
OUTLINE
KEY OBJECTIVE
EXPERIMENTAL EQUIPMENTS
Shaker
Leaching reactors
METHODOLOGY
Mineral phase
Chalcopyrite
74
CuFeS2
Hematite
Fe2O3
Melanterite
FeSO4.7H2O
Bernalite
Fe(OH)3
MgFe3+2O4
Calcite
4.5
CaCO3
Magnesioferrite
Quartz
2.5
SiO2
Siderite
0.5
FeCO3
K-Jarosite
2.5
KFe3(SO4)2(OH)6
Ferrihydrite
0.5
Fe5O3(OH)9
Pentlandite
(Fe,Ni)9S8
Talc
0.5
Mg3(Si2O5)2(OH)2
Rmerite
Fe3(SO4)4.14H2O
Dwornikite
0.5
NiSO4.H2O
Pyrite
FeS2
Magnesite
0.5
MgCO3
Fe
As
Si
24.5
25.9
28.6
0.126 5.19
Na
Al
Mg
Zn
Pb
100
Cu 0.0234 M pH 1
80
Cu 0.0234 M pH 2
60
Cu 0.0391 M pH 1
40
Cu 0.0391 M pH 2
20
0
0
50
100
150
Time [hours]
100
Cu 0.0078 M
80
60
Cu 0.0234 M
40
Cu 0.0391 M
20
0
-20
0
50
100
150
Cu 0.0078 M
adjusted f or
adsorption
Time [hours]
While an initial copper concentration 0.0078 M was limiting, copper extractions were not affected
greatly at higher initial copper concentrations.
Thus the presence of cupric ions is necessary for accelerated chalcopyrite dissolution,
but above the limiting concentration, rates of dissolution are not enhanced for increased copper
concentration.
100
80
60
Cl 0 M
Cl 0.143 M
40
Cl 0.200 M
Cl 0.286 M
20
0
0
50
100
150
Time [hours]
The presence of chloride in the initial leach medium resulted in increased copper extraction,
compared with the chloride-free medium.
However, the rate of chalcopyrite dissolution is not greatly affected by the chloride concentration
G (kJ/mol)
-2.198
K1=2.426
CuCl+ + Cl CuCl2(aq)
6.653
K2=0.068
CuCl3
9.131
K3=0.025
13.142
K4=0.005
Cu2+ + Cl CuCl+
CuCl2(aq) +
Cl
CuCl3 + Cl CuCl42
A model of copper speciation in the experimental range predicted that, increased Cl concentration,
Cu+2 concentration decreased significantly while the chlorocomplex species CuCl+ concentration
increased
Table 4. Copper extraction [%] at pH 1 correlated with predicted copper speciation at different chloride
and copper concentrations.
Total Cl
[M]
Total Cu
[M]
Cu+2
[M]
CuCl+
[M]
Extraction
[%]
0
0
0
0.143
0.200
0.286
0.143
0.200
0.286
0.143
0.200
0.286
0.0078
0.0234
0.0391
0.0078
0.0078
0.0078
0.0234
0.0234
0.0234
0.0391
0.0391
0.0391
0.0078
0.0234
0.0391
0.0058
0.0053
0.0046
0.0176
0.0159
0.0139
0.0295
0.0267
0.0234
0
0
0
0.0020
0.0025
0.0032
0.0058
0.0074
0.0093
0.0095
0.0122
0.0153
16
24
30
39
55
57
60
67
67
57
58
57
ACKNOWLEDGEMENTS
The authors are grateful for the financial support provided by CICITEM R04I1001,
CSIROChile International Centre of Excellence, and CONICYT through Fondecyt
Project 1140169 (Director: Maria Elisa Taboada)