1.

2.

If the ionization enthalpy and electron gain enthalpy of an element are 275 and 86 kcal mol 1 respec
tively, then teh electronegativity of the element on the mulliken scale is
1) 2.8
2)0.0
3)4.0
4)2.6
In which of the following arrangements ,the order is not correct according to the property
indicated against it: (AIEEE-2005)
1) Increasing size

3.

Al 3+ < Mg 2+ < Na + < F

2)Increasing

IE1 : B < C < N < O

3) Increasing

EA1 : I < Br < F < Cl

4) Increasing metallic radius : Li < Na < K < Rb

The ionic mobility of alkali metal ions in aqueous solution is maximum for:
1) Na +

2) K +

3) Rb +

4) Li +

5.

If the energy necessary to remove an electron from the krypton is 1350.7 KJ mol-1, then the

7.

for the highest energy electrons in krypton is

1) 2.22 2) 4.05 3) 3.62 4) 5.01
Which is not arranged in the correct sequence:

Zeff value

1) d 5 , d 3 , d 1 , d 4 __increasing magentic moment

8.

29.

2)

Mo, M 2O3 , MO2 , M 2O5 ___decreasing basic strength

3)

Co 2+ , Fe3+ , Cr 3+ , Sc 3+ ____ increasing stability..

4) Sc,V,Cr,Mn____ increasing number of oxidation states

Give the name of the inert gas atom in which the total number of d-electrons is equal to the difference
in numbers of total p and s-electrons.
1) He
2)Ne
3) Ar
4)Kr
In the anion HCOO the two carbon - oxygen bonds are found to be of equal length. What is the
reason for it ?
1) Electronic orbitals of carbon atom are hybridised.
2) The C=O bond is weaker than the C-O bond
3) The anion HCOO has two resonating tructures

31.

4) The anion is obtained by removal of a proton from the acid molecule.

Specify the coordination geometry around and hybridisation of N and B atoms in a 1:1 complex of

BF3 and NH 3
1) N : tetrahedral, sp 3 ; B : tetrahedral,

sp3

2) N : pyramidal, sp 3 ; B : pyramidal, sp 3
3) N : pyramidal, sp 3 ; B : planar,, sp 3
4) N : pyramidal, sp 3 ;B : tetrahedral, sp 3
19.

In

PO43 , the formal charge on each oxygen atom and the P-O bond order respectively are

1) -0.75, 0.6
3) -0.75, 1.25

2) -0.75, 1.0
4) -3 , 1.25

10.

Which of the following has p d bonding ?

1) NO3

11.

SO2

2)

OH 2

3)

The vapour pressure of

1) Dipole moment
4) Lattice structure

13.

3) BO33

4) CO32

Which one of the following compounds has the smallest bond angle in its molecule?
1)

12.

2) SO32

SH 2

4)

NH 3

is higher than

2) Dipole - dipole interaction

3) H - bonding

Trimethylamine is a pyramidal molecule

and formamide is a planar molecule

the hybridisation of Nitrogen in both is

1) sp 2 , sp 2
3.

2)

sp 3 , sp 2

3)

4)

sp 2 , sp

Which statement is correct about HCHO?

1) It has

sp 2 hybridized carbon

2) The bond angles HCH and HCO

3) It involves multiple bond pair
11.

sp 3 , sp 3

The correct stability order for

1)

N 2 N 2 N 2 N 22

2)

N 2 N 2 N 2 N 22

3)

N 2 N 2 N 2 N 22

4)

N 2 N 2 N 2 N 22

are 116 and 122 respectively

bond pair repulsion

N 2 and its given ions is :

4) All of these