P13-14a (segregation model)

Calculated values of the DEQ variables

Variable
t
xs
x
K
Ca0
E1
E2
E

initial value
0
0
0
0.5
2
0
2
0

minimal value
0
0
0
0.5
2
0
0
0

maximal value
2
0.476756
0.6666667
0.5
2
2
2
0.9986356

final value
2
0.476756
0.6666667
0.5
2
2
0
0

maximal value
2
0.4669203
1
0.5
2
2
2
2
0.9954514

final value
2
0.4669203
1.168E-06
0.5
2
0
0
2
0

ODE Report (RKF45)

Differential equations as entered by the user
[1] d(xs)/d(t) = x*E
[2] d(x)/d(t) = K*Ca0*(1-x)^2
Explicit equations as entered by the user
[1] K = 0.5
[2] Ca0 = 2
[3] E1 = t
[4] E2 = 2-t
[5] E = If (t<=1) then (E1) else (E2)

P13-14a (maximum mixedness model)

Calculated values of the DEQ variables
Variable
z
x
f
K
Ca0
lam
E1
E2
E

initial value
0
0
1
0.5
2
2
2
0
0

minimal value
0
0
1.168E-06
0.5
2
0
0
0
0

ODE Report (RKF45)

Differential equations as entered by the user
[1] d(x)/d(z) = K* Ca0*(1-x)^2-(E*x/(1-f))
[2] d(f)/d(z) = -E
Explicit equations as entered by the user
[1] K = 0.5
[2] Ca0 = 2
[3] lam = 2-z
[4] E1 = lam
[5] E2 = 2-lam
[6] E = If (lam<=1) then (E1) else (E2)

P13-14b (segregation model)

Calculated values of the DEQ variables
Variable
t
ca
cb
cc
cabar
cbbar
ccbar
E1
E2
E
S

initial value
0
2
0
0
0
0
1.0E-10
0
2
0
0

minimal value
0
0.5799685
0
0
0
0
1.0E-10
0
0
0
0

maximal value
2
2
1.0759432
0.1720441
0.9952971
0.838566
0.083065
2
2
0.9943237
259.9553

ODE Report (RKF45)

Differential equations as entered by the user
[1] d(ca)/d(t) = -0.5*ca^2-0.12*ca*cb
[2] d(cb)/d(t) = 0.5*ca^2-0.12*ca*cb
[3] d(cc)/d(t) = 0.12*ca*cb
[4] d(cabar)/d(t) = ca*E
[5] d(cbbar)/d(t) = cb*E
[6] d(ccbar)/d(t) = cc*E
Explicit equations as entered by the user
[1] E1 = t
[2] E2 = 2-t
[3] E = if (t<=1) then (E1) else (if (t>=2) then (0) else (E2))
[4] S = cbbar/ccbar

final value
2
0.5799685
1.0759432
0.1720441
0.9952971
0.838566
0.083065
2
0
0
10.095294

P13-14b (maximum mixedness model)

Calculated values of the DEQ variables
Variable initial value
z
0
Ca
2
Cb
0
Cc
1.0E-09
F
0.999999
Selectivi
0
k1
0.5
k2
0.12
lam
2
E2
0
E1
2
E
0
Ca0
2

minimal value
0
2
-157.21264
1.0E-09
4.936E-07
-402.47408
0.5
0.12
0
0
0
0
2

maximal value
2
55.964394
0
51.624121
0.999999
0
0.5
0.12
2
2
2
0.9953463
2

ODE Report (RKF45)

Differential equations as entered by the user
[1] d(Ca)/d(z) = k1*Ca^2+k2*Ca*Cb-(Ca-Ca0)*E/(1-F)
[2] d(Cb)/d(z) = -k1*Ca^2+k2*Ca*Cb-(Cb*E)/(1-F)
[3] d(Cc)/d(z) = -k2*Ca*Cb-(Cc*E)/(1-F)
[4] d(F)/d(z) = -E
Explicit equations as entered by the user
[1] Selectivity = Cb/Cc
[2] k1 = 0.5
[3] k2 = 0.12
[4] lam = 2-z
[5] E2 = 2-lam
[6] E1 = lam
[7] E = If (lam<=1) then (E1) else (if(lam >=2) then (0) else (E2))
[8] Ca0 = 2

final value
2
55.964394
-157.21264
51.624121
4.936E-07
-3.0453329
0.5
0.12
0
2
0
0
2

P13-14c (segregation model)

Calculated values of the DEQ variables
Variable
t
xbar
x
R
Ca0
E1
E2
E
T
Ea
K

initial value
0
0
0
8.314
2
0
2
0
300
4.184E+04
0.5

minimal value
0
0
0
8.314
2
0
-1
0
300
4.184E+04
0.5

maximal value
3
0.9758307
0.9986277
8.314
2
3
2
0.984945
449.79415
4.184E+04
133.40292

ODE Report (RKF45)

Differential equations as entered by the user
[1] d(xbar)/d(t) = x*E
[2] d(x)/d(t) = K*Ca0*(1-x)^2
Explicit equations as entered by the user
[1] R = 8.314
[2] Ca0 = 2
[3] E1 = t
[4] E2 = 2-t
[5] E = If (t<=1) then (E1) else (if (t>=2) then (0) else (E2))
[6] T = 300+150*x
[7] Ea = 41840
[8] K = 0.5*exp(Ea/R*((1/300)-(1/T)))

final value
3
0.9758307
0.9986277
8.314
2
3
-1
0
449.79415
4.184E+04
133.40292

P13-14c (maximum mixedness model)

Calculated values of the DEQ variables
Variable
z
x
F
R
Ca0
lam
E1
E2
T
Ea
K
E

initial value
0
0
0.99999
8.314
2
2
2
0
300
4.184E+04
0.5
0

minimal value
0
0
-5.312E-06
8.314
2
0
0
0
300
4.184E+04
0.5
0

ODE Report (RKF45)

Differential equations as entered by the user
[1] d(x)/d(z) = K*Ca0*(1-x)^2-(x*E/(1-F))
[2] d(F)/d(z) = -E
Explicit equations as entered by the user
[1] R = 8.314
[2] Ca0 = 2
[3] lam = 2-z
[4] E1 = lam
[5] E2 = 2-lam
[6] T = 300+150*x
[7] Ea = 41840
[8] K = 0.5*exp(Ea/R*((1/300)-(1/T)))
[9] E = If (lam<=1) then (E1) else (E2)

maximal value
2
0.9813837
0.99999
8.314
2
2
2
2
447.20756
4.184E+04
125.04351
0.9956036

final value
2
0.9813837
-5.312E-06
8.314
2
0
0
2
447.20756
4.184E+04
125.04351
0