1.

In the following reaction, correct statement is

K2Cr2O7 + 8H+ + 3S2O3 Cr3+ + K2SO4 + 3S + 4H2O.
(1) Equivalent weight of K2Cr2O7 = Molar wt./3
(2) Equivalent weight of K2Cr2O7 = Molar wt./5
(3) Equivalent weight of K2Cr2O7 = Molar wt.
(4) Equivalent weight of K2Cr2O7 = Molar wt./6

10. x gm of NaOH required to neutralise 15 meq of HCl. To neutralise same meq of H 2SO4 and H3PO4
the weight of NaOH will be
(1) 2x g and 3x g respectively
(2) g and g respectively
(3) x g for each
(4) 3x g and 2x g respectively
.3. Which of the following pair have same number of nucleon?
(1) 6C13, 7N14

(2) 6C12, 6C13

(3)

(4) 8O16, 7N15

20C

40,

40
18Ar

4.

The radius of 4th shell in the Li+2 in

(1) 2.82
(2) 0.282
(3) 0.846
(4) 1.68

5.

Two objects A and B having mass M and 4M respectively and velocity 4v and 2v then ratio of the
wavelength associated with objects A and B is

6.

In the simultaneous measurement of position and momentum of a macroscopic particle, it was found
that x (uncertainty in position) is zero then uncertainty in momentum is
(1) Zero
(2) Infinite

(4) Cannot be calculated from above data

10. Which set is the correct set of quantum number for
?
(1) n = 5, l = 2, m = 2, 1 0, + 1, +2, s = +1/2
(2) n = 5, l = 2, m = 2, s = +1/2
(3) n = 5, l = 0 4, m = +2, s = +1/2

(4) n = 5, l = 2, m = 0, s = +1/2
8.

Choose the correct statement

(1) 6d orbital have 4 radial nodes
(2) The energy of 7d is higher than energy of 7s in case of hydrogen atom
(3) 7 orbital do not have 2 nodal plane
(4) Energy
sequence
of
3s < 3p < 3d < 4s for element Z < 20

the

following

orbital

is

9.

Which of the following is excited electronic configuration and also voilet the Hund's rule?

2.

What fraction of air is expelled out if a flask containing V litre gas is heated from 27C to 327C?
(1) 25%
(2) 50%
(3) 75%
(4) 10%

3.

A 10 litre cylinder contains 0.4 gm x 2 gas 3.2 gm y2 gas and 5.6 gm z 2 gas at 27C. Assuming ideal
gas behaviour of all gases, choose the correct statement. (Given atomic weight of x, y & z are 2, 8 &
14 amu respectively)
(1) Partial pressure of x2, y2 and z2 are identical
(2) Partial
pressure
y2 = partial pressure of z2

of

x2

>

partial

pressure

of

(3) Partial pressure of x2 = partial pressure of

1.

4.

5.

(4) Partial pressure of x2 = 2 partial pressure of z2

A gaseous mixture of O2 and N2 are in the ratio of 1 : 4 by weight. The ratio of molecules of N 2 to O2
is
(1) 32 : 7
(2) 5 : 6
(3) 7 : 32
(4) 6 : 54
Which process is exothermic out of following?
(1) A A+ + e

(2) B + e B

(3) B + e B2

(4) A+ A+2 + e

Which is incorrect statement?

(1) Electron affinity of carbon is higher than silicon

(2) Electron affinity of fluorine is higher than chlorine
(3) Electron affinity of oxygen is smaller than sulphur
(4) Electron affinity of phosphorus is higher than nitrogen
11. The correct order of electronegativity
(1) F > Cl > O > N
(2) Mg < Be < C < B
(3) Mg < Al < S < Cl
(4) B < C < O < N
6.

Which of the following ion have highest polarising power?

(1) Na+

(2) Te+

(3) Cu+

(4) K+

12. If element (A) have oxidation state + 6 and element (B) have oxidation state 2 and (C) have
oxidation
state 1. The formula of compound will be

7.

(1) ABC4

(2) AB3C

(3) ABC5

(4) A2B5C

Which of the following pair of element have zero electron affinity?

(1) K, B

(2) N and oxygen

(3) He and C

(4) Ar and Na

16. Which is amphoteric oxide?

(1) MgO

(2) Al2O3

(4) Cl2O7
(3) SiO2
17. The incorrect order of ionic radii is
(1) Fe+3 < Fe+2 < Fe
(2) O2 < N3 < F
(3) Li < Mg < K
(4) Be < Mg < Na
18. Element of IA group give flame colour due to
(1) Low IE
(2) Low boiling point
(3) Low melting point
(4) All of these
20. An element have atomic number 24. It belong to
(1) 2nd group
(2) 4th group
(3) 6th group
(4) 8th group
3.

No. of bond and bond in P4O10 are

(1) bond 16, bond 4
(2) bond 15, bond 4
(3) bond 10, bond 2

(4) bond 16, bond 8

4.

5.

Which of the following possess distroted octahedral shape?

(1) SF6, sp3d2

(2) [SiF6]2, sp3d2

(3) XeF6, sp3d3

(4) [PCl6], sp3d2

Which of the following species is diamagnetic?

(1) KO2
(2) Na2O2
(3) Fe2O3

0.

(4) ClO2

Choose the correct statement

(1) BCl3 > BBr3 > BF3 (Lewis basic character)
(2) N(CH3)3 is pyramidal while N(SiH3)3 is triangular planar
(3) CH4 > H2O > HF (acidic strength)
(4) BeS > ZnS > MgS (covalent character)

8.

The correct order regarding the relative overlapping power of an orbital

(1) sp3
orbital
p orbital
(2) Pure
s
sp3 hybrid

>
or

sp2

orbital

orbital

(3) sp
hybrid
orbital
3
sp hybrid orbital > pure p orbital
(4) sp3
hybrid
orbital
s orbital > pure sp hybrid orbital
9.

>

sp

sp
orbital

sp2

>
>

>

sp2

orbital
>

sp2

hybrid
hybrid

>

orbital

hybrid

orbital
>

Which of the following is correct match?

(1) Ionic bond Directional
(2) XeO2F2 Xe is sp3d hybrid, 2, 4 bond
(3) Tetraethyl ammonium chloride N is sp3 hybridised, 4, 1 ionic bond
(4) N(SiH3)3 N is sp3 hybridised, pyramidal shape

15. Maximum ionic percentage present in

(1) NaI
(2) NaCl
(3) NaF
(4) NaBr
8.

Maximum bond angle present in

(1) NH3
(2) AsH3
(3) PH3

2.

3.

(4)

SbH3

The compound which act as oxidising agent as well as reducing agent?

(1) H2S

(2) H2SO3

(3) H2SO4

(4) All of these

K2Cr2O7 + aH2SO4 + bSO2 K2SO4 + Cr2(SO4)3 + cH2O. The value of a, b and c are
(1) 4, 3, 5

(2) 2, 3, 2

pure
>
>
pure

(3) 3, 3, 3
4.

5.

(4) 1, 3, 1

Oxidation number of sulphur in S2O32 is

(1) +6, 2

(2) +2.5, +2.5

(3) +6, +2

(4) +6, 6

FeCl3 + H2S FeCl2 + S + HCl

In above reaction
(1) FeCl3 act as reducing agent
(2) H2S act as oxidising agent
(3) H2S act as reducing agent
(4)

7.

Oxidation number of nitrogen in HNC is

(1) 3
(3)

2.

3.

4.

Both act as reducing agent

(4)

Alicyclic compounds are :

(1) aromatic compounds
(2) aliphatic cyclic compounds
(3) heterocyclic compounds
(4) none of these
Alkanols are represented by :
(1) CnH2n+1O
(2) CnH2nO
(4) CnH2n+2O

(3) C

The IUPAC name of Cl3CCH2CHO is :

(1) chloral
(2) 3,3,3-trichloropropanal
(3) 1,1,1-trichloropropanal
(4) 2,2,2-trichloropropanal
The IUPAC name of the following compound is :
CH3 CH2 CH = CH C CH
(1) 1-hexyne-3-ene
(3) 3-hexen-1-yne

7.

(2) +3
2

(2) 5-hexyne-3-ene
(4) 3-hexen-5-yne

Which of the following pairs shows isomerism?

(1) CH4 and C2H6
(2) CHCl3 and CCl4
(3) CH3CH2OH and CH3OCH3

5.

(4) NaCl and KCl

Total number of isomeric alcohols with formula C 4H10O is :

(1) 1 (2) 2 (3) 3 (4) 4

6.

Vinyl alcohol and acetaldehyde are :

(1) geometrical isomers
(2) keto-enol tautomers
(3) chain isomers
(4) position isomers

Cs+ ions impart violet colour to Bunsen flame. This is due to the fact that the emitted
radiations are of
(A) high energy
(B) lower frequencies (C) longer wave-lengths(D) zero
wave number
Q.1

Q.4

The reaction of an element A with water produces combustible gas B and an aqueous
solution of C. When another substance D reacts with this solution C also produces the
same gas B. D also produces the same gas even on reaction with dilute H 2SO4 at room
temperature. Element A imparts golden yellow colour to Bunsen flame. Then, A, B, C and
D may be identified as
(A) Na, H2, NaOH and Zn
(B) K, H2, KOH and Zn
(C) K, H2, NaOH and Zn
(D) Ca, H2, CaCOH2 and Zn

Q.6

The correct statement is/are

(A) BeCl2 is a covalent compound
(B) BeCl2 is an electron deficient molecule
(C) BeCl2 can form dimer
(D) the hybrid state of Be in BeCl2 is sp2
Which of the following carbonate of alkali metals has the least thermal stability?
(A) Li2CO3
(B) K2CO3
(C) Cs2CO3
(D) Na2CO3

Q.8

Q.9

Q.10
Q.11

Q.12

Q.13

The milk of magnesia used as an antacid is chemically

(A) Mg(OH)2
(B) MgO
(C) MgCl2

(D) MgO + MgCl2

The alkali metals which form normal oxide, peroxide as well as super oxides are
(A) Na, Li
(B) K, Li
(C) Li, Cs
(D) K, Rb
The pair of compounds, which cannot exist together in a solution is
(A) NaHCO3 and NaOH
(B) Na2CO3 and NaOH
(C) NaHCO3 and Na2CO3
(D) NaHCO3 and H2O
Mg2C3 + H2O
(A) C2H2

X (organic compound). Compound X is

(B) CH4
(C) propyne

The hydration energy of Mg2+ is

(A) more than that of Mg3+ ion
(C) more than that of Al3+ ion

(D) ethene

(B) more than that of Na+ ion

(D) more than that of Be2+ ion

Q.16

Which of the property of alkali metals is not listed correctly?

(A) the least electronegative metal : Cs
(B) a natural radioactive metal : Fr
(C) the alkali metal with lowest density : K (D) the heaviest alkali metal : Cs

Q.22

Na + Al2O3 X Y; compound Y is
(A) NaAlO2
(B) NaHCO3

Q.26

Q.27

(C) Na2CO3

aq. NaOH + P4 (white) PH3 + X; compound X is

(B) NaHPO4
(C) Na2CO3
(A) NaH2PO2
The correct order of solubility is
(A) CaCO3 < KHCO3 < NaHCO3
(C) NaHCO3 < CaCO3 < KHCO3

(D) Na2O2

(D) NaHCO3

(B) KHCO3 < CaCO3 < NaHCO3

(D) CaCO3 < NaHCO3 < KHCO3

Q.28

The complex formation tendency of alkaline earth metals decreases down the group
because
(A) atomic size increases
(B) availability of empty d and f-orbitals
increases
(C) nuclear charge to volume ratio increases (D) all the above

Q.29

The alkaline earth metals, which do not impart any colour to Bunsen flame are
(A) Be and Mg
(B) Mg and Ca
(C) Be and Ca
and Ba

(D) Be

Q.30

Y CaSO42H2O X. X and Y are respectively

(A) plaster of paris, dead burnt plaster
(B) dead burnt plaster, plaster of
paris
(C) CaO and plaster of paris
(D) plaster of paris, mixture of gases

Q.36

The correct order of basic-strength of oxides of alkaline earth metals is

(A) BeO > MgO > CaO > SrO
(B) SrO > CaO > MgO > BeO
(C) BeO > CaO > MgO > SrO
(D) SrO > MgO > CaO > BeO

Q.40
Then, substances Y and T are
(A) Y = Mg3N2 and T = CuSO45H2O
(C) Y = Mg(NO3)2 and T = CuO
Q.41

(B) Y = Mg3N2 and T = CuSO44NH3

(D) Y = MgO and T = CuSO44NH3

Weakest base among KOH, NaOH, Ca(OH)2 and Zn(OH)2 is

(A) Ca(OH)2
(B) KOH
(C) NaOH

(D) Zn(OH)2

Q.42

If X and Y are the second ionisation potentials of alkali and alkaline earth metals of same
period, then
(A) X > Y
(B) X < Y
(C) X = Y
(D) X << Y

Q.43

The aqueous solutions of lithium salts are poor conductor of electricity rather than other
alkali metals because of
(A) high ionisation energy
(B) high electronegativity
(C) lower ability of Li+ ions to polarize water molecules
(D) higher degree of hydration of Li+ ions

Q.44

Sodium metal is highly reactive and cannot be stored under

(A) toluene
(B) kerosene oil
(C) alcohol

Q.58

(D) benzene

Na2SO4 is water soluble but BaSO4 is insoluble because

(A) the hydration energy of Na2SO4 is higher than that of its lattice energy
(B) the hydration energy of Na2SO4 is less than that of its lattice energy
(C) the hydration energy of BaSO4 is less than that of its lattice energy
(D) the hydration energy of BaSO4 is higher than that of its lattice energy

Q.59

Which of the following is not a anomalous property of lithium?

(A) Hydrated lithium ion is the largest among alkali metals
(B) The melting and boiling points of lithium are comparatively high
(C) Lithium is softer than that of other alkali metals
(D) The ionisation potential and electronegativity of lithium are higher than those of other
alkali metals

Q.62

Be2C + H2O
CaC2 + H2O
(A) CH4, CH4

BeO + X
Ca(OH)2 + Y; then X and Y are respectively
(B) CH4, C2H6
(C) CH4, C2H2

(D) C2H2, CH4