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Level E
Acids and
Metals
Level E Science Topic Book
Contents
Topic Outline
Investigations
Homework Sheets
Glossary
Pupil Checklist
Learning Outcomes
TOPIC: Acids and Metals
Level E
Stage S1/S2
Changing Materials.
Learning Outcomes:
By the end of the unit the pupils should be able to:
Level
State that the lower the pH of an acid the greater the acidity; the higher the
State that when an acid neutralises an alkali, a salt and water is formed.
State that more reactive metals can displace less reactive metals from their solutions.
Topic Outline
The following topic outline suggests activities and examples of ongoing assessments to take forward the Learning
Outcomes listed for this study. To suit their own classes and situations, teachers may want to add to, or adapt some of
these. The main aim, however, is to ensure that children are given the opportunity to overtake the learning outcomes
listed.
Assessment
---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Identify acids,
alkalis and
neutral solutions
from the pH
values.
Resources
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Measure the pH of E
common
solutions.
Learning Activities
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Level
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Learning
Outcomes
Assessment
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Resources
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Learning Activities
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Level
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Learning
Outcomes
Assessment
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Resources
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Learning Activities
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Level
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Learning
Outcomes
Assessment
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Give examples of
how reactivity
relates to uses
and sources of
metals.
Resources
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List metals in
E
order of reactivity
with oxygen,
water and acid.
Learning Activities
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Level
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Learning
Outcomes
Describe the
effects of
electroplating.
Give examples of
how some metals
are extracted.
Assessment
---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
E
State that
electrolysis can be
used to obtain a
metal from a
solution.
Resources
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Learning Activities
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Level
---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Learning
Outcomes
Solutions of copper
chloride and nickel
sulphate, power pack,
leads, carbon electrodes,
steel nails, beakers,
crocodile clip.
Activity Support Sheet 14.
Support Sheet
Name
Measuring pH
Use the table here to record your values for the pH of the solutions you
tested. Write the name of your solution in the left hand column the first
two have been done for you.
solution
pH
Hydrochloric acid
Sodium hydroxide
Support Sheet
Name
acid
alkali
universal indicator
Volume of alkali
10 ml
pH
2
4
6
8
10
Use the words in the word bank to complete the sentence about adding acid to alkali.
Wordbank
neutral
decreases
alkali
Support Sheet
Name
acid
alkali
universal indicator
Volume of acid
10 ml
pH
2
4
6
8
10
Use the words in the word bank to complete the sentence about adding acid to alkali.
Wordbank
neutral
increases
acid
Support Sheet
Name
Making salt
acid
alkali
acid + alkali
a salt + water
Support Sheet
Name
1.
2.
3.
4.
Support Sheet
Name
Trying it out
Collect some dilute hydrochloric acid in a test tube and add a few drops
of Universal Indicator.
Crush an indigestion tablet. Add the crushed tablet bit by bit to the acid
(stirring all the time) until the acid is neutralised.
Use the space below to plan out your experiment.
Support Sheet
Name
name of metal
fresh
magnesium
iron
tin
gold
zinc
copper
less reactive
more reactive
Glasgow 5-14 Science Programme Education Improvement Service 17
Support Sheet
Name
name of metal
Place the metals below in order of how reactive they are in water.
magnesium
potassium
less reactive
iron
sodium
caesium
zinc
calcium
more reactive
Glasgow 5-14 Science Programme Education Improvement Service 18
Support Sheet
Name
name of metal
Place the metals below in order of how reactive they are in acid.
magnesium
copper
less reactive
iron
aluminium
tin
zinc
lead
more reactive
Glasgow 5-14 Science Programme Education Improvement Service 19
Support Sheet
10
Name
Reactivity Series
Complete the table below using the following metals:aluminium, zinc, potassium, sodium, clacium,
magnesium, gold, slver, iron, tin, lead. copper, caesium.
metal
Support Sheet
11
Name
1.
2.
3.
4.
Support Sheet
12
Name
copper
zinc
Support Sheet
13
Name
Splitting up
Use this sheet to record your observations of the electrolysis
of copper chloride.
Power Pack
DC Supply
positive electrode
negative electrode
copper chloride
250 ml beaker
Support Sheet
14
Name
Electroplating
Use this sheet to record your observations of electroplating
a steel nail with copper.
Power Pack
DC Supply
positive electrode
steel nail
copper sulphate
Support Sheet
15
Name
1.
2.
3.
4.
pH Scale
A good way to help pupils remember what they are measuring is to call the
pH = 4
pH scale the Power of Hydrogen scale. Values of pH less than 7 indicate the
pH = 5
pH = 6
pH = 7
pH = 8
pH = 9
pH = 10
Neutralisation
Acids and alkalis can cancel each other out in a process called neutralisation. This has many useful applications which
include:
Treating bee stings (venom is acidic) with sodium bicarbonate and wasp (venom is alkaline) stings with vinegar.
All neutralisation processes move the pH of an acid or alkali towards 7. The products of all neutralisation reactions include
a salt and water. (With a carbonate the gas carbon dioxide is also formed.) To name the salt, use the metal from the alkali
for the first part and the name of the acid for the second part, e.g. reacting sodium hydroxide and Hydrochloric Acid
together would give you sodium chloride. Testing the pH of salts will show that not all salts are neutral.
Reactivity Series
The reactivity series is a list which places metals in order of their readiness to take part in chemical reactions. Metals at the
top react faster with water and dilute acid and burn more vigorously in oxygen. See the table below for the reactivity of
common metals.
Calcium
Magnesium
Aluminium
Iron
Tin
Lead
FORM OXIDE ON
SURFACE ONLY
Nickel
Zinc
Mercury
Gold
NO REACTION WITH
WATER
Silver
NO REACTION WITH
OXYGEN
Copper
REACTION WITH
ACID
REACTION WITH
COMPOUND
IN GENERAL EACH METAL CAN DISPLACE ANY METAL BELOW IT FROM ONE OF ITS COMPOUNDS
Lithium
Sodium
WATER
Potassium
REACTION WITH
OXYGEN
REACTION WITH
METALS
Metals higher up the table can also push out lower ones from compounds. This is called displacement.
When a metal higher up the reactivity series is added to a solution containing a metal lower in the series, the lower metal
is forced out of the solution and is deposited the higher up metal replaces it in solution.
The reactivity series affects how metals are used. Metals like
lead and copper are used for roofs and piping because they
do not react easily.
Iron is common and is used to make many things, but it has
to be protected from corrosion (electroplating).
Very unreactive metals like gold and silver are used for
jewellery because they stay shiny.
The Glasgow Science Centre has a titanium roof.
Electroplating of Metals
Electroplating is the coating of an object (which must be a conductor) with a metal. The object to be coated is attached to
the negative electrode. The positive electrode would be the coating metal (otherwise the coating metal comes out of solution).
These would then be placed in a solution of the coating metal. An electric current passes through the solution due to the
movement of electrons and ions in the solution. This is also the basis of the operation of a battery.
Extraction of Metals
Electrolysis is a method of extraction using electricity to split up a metal ore. This method of extraction is only used to
extract the metals from the top of the reactivity series. The metal always forms around the negative electrode during
electrolysis (because metal ions are positive).
Less reactive metals are extracted using heat and carbon (coke) usually in a furnace. The extraction of iron is carried out in
a blast furnace using this method. The very unreactive metals such as gold and silver have been known since earliest
civilisation and are often found in their metallic state.
METAL
EXTRACTED ORE
USE
chalcopyrite
Electrical wiring
good conductor
of electricity
aluminium
bauxite
zinc
smithsonite
magnesium
magnesium chloride
Fireworks; flares;
medicines
tin
cassiterite
copper
iron
haematite
Solder; anodising
steel
Investigations
Although investigating is an activity that crosses the curriculum, it has special significance for
science. First-hand investigations are central to the way in which young children learn science,
providing opportunities to plan fair tests, make observations, hypothesise, predict, collect
evidence, research, survey and discuss. Through such means, opportunities arise to infer,
deduce, calculate, draw conclusions from evidence, make judgements and debate important
issues. Characteristics such as curiosity, responsibility, perseverance, cooperation, attention
to detail and divergent thinking are also encouraged.
Environmental Studies 5-14 National Guidelines (2000)
Open-ended investigations are proven to increase pupil motivation, thinking skills and knowledge and understanding.
The investigative skills of planning, fair testing, observing, measuring, recording, reporting and evaluating are best promoted
through investigative work and to this end, this topic includes a topic investigation.
By the time pupils reach S1/S2, they will have, with the support of their teachers, developed a range of investigative skills.
If the Glasgow Science Programme has been used throughout the primary stages, almost all pupils will have achieved skills
at level C by P7 and most will be working at level D. During S1/S2, therefore, pupils should concentrate on the skills at D to
F. The teacher will decide which level is most appropriate for each pupil. The progression in S1/S2 from Level D to Level F
is reflected in the difficulty of the planning and recording sheet for the topic. However, to ensure differentiation, the I am a
Scientist sheets from topics at other levels can be used.
This section of the booklet offers teachers advice on developing the skill areas of
Planning
Predicting
Fair testing
Recording
Level D
Level E
Level F
Standard Grade
hypothesis
Level D
Level E
measurements
Level F
Standard Grade
outcome variables
Level D
Level E
appropriate illustrations
knowledge
Level F
Standard Grade
Make a hypothesis.
Draw a conclusion
Drinks with acid give a low pH. Milk is alkaline, although if it is left out for a few
days its pH decreases. This is a possible alternative investigation.
Write a report.
What I
will change
(Input variable)
What will be
measured?
(Outcome variable)
How will it be
measured?
(Description of apparatus)
What do I think
will happen?
(Hypothesis)
What I will do to
keep the test
fair?
(Control of variables)
A graph of my results
Assessment Sheets
The topic outline offers suggestions for ongoing assessment. The following sheets are provided to aid summative assessment
of pupils knowledge and understanding. They can be copied and used during the topic or at the end of the topic if the
teacher prefers.
The pupil evaluation sheets ask pupils to think about how much they have learned and what areas they enjoyed. These
sheets give the pupils an opportunity to give feedback to the teacher and provide some evidence for the teacher on the
pupils developing attitudes.
Evaluation Sheet
I have completed a topic about:
Shade in the box to show how much you enjoyed the Topic.
very poor
very good
Comment:
Sheets
Name
Use this page to record things you want to get off your chest!
Find out some information about the acid content in drinks. Revise what you know about teeth and
tooth decay.
Give your opinion on the issue below.
Some dentists would like to see fizzy drinks banned because they damage teeth. Others want
the acid content reduced or the drinks to cost more. The makers dont want the drinks banned.
They are also worried that changing the acid content will affect the taste. What do you think?
KU
Sheet
Name
KU
Sheet
pH
less than 7
more than 7
13
pH
pH
GROUP
14
11
12
pH
pH
10
pH
pH
8
pH
pH
6
pH
pH
pH
pH
2
pH
groups:
pH
Name
Group B?
Group C?
KU
Sheet
Name
Taking indigestion remedies to cure acid indigestion is an example of neutralisation.
What two things are always made when neutralisation takes place?
Rearrange the following metals in order of reactivity; putting the most reactive on top.
METAL
ORDER
zinc
copper
calcium
tin
sodium
aluminium
potassium
magnesium
iron
KU
Sheet
Name
Gold and silver have been used to make jewellery
since the earliest times.
Other metals such as calcium and aluminium were
unknown until approximately 200 years ago.
Explain why gold and silver were among the first metals to be discovered.
Explain why calcium and aluminium were not discovered until recent times.
Some metals were added to solutions as shown below. In the box provided state which metal is left
after the reaction takes place.
METAL FORMED
KU
Sheet
Name
Describe what happens when copper
chloride is electrolysed.
Remember to describe what happens at the
electrodes.
Screws, which are to be used outside, are often electroplated with zinc.
Describe how a steel screw can be electroplated.
KU
Sheet
Name
Describe two different extraction processes
for any metals you have studied in this
topic.
Method 1:
Method 2:
PS
Sheet
Name
Jeff added dilute potassium hydroxide slowly to dilute sulphuric acid. After he added each drop, he
tested the pH of the solution and recorded the results in a table.
NUMBER OF DROPS
pH OF SOLUTION
10
12
PS
Sheet
Name
Name the acid and alkali which could be used to prepare solutions of each of the following salts.
magnesium sulphate
sodium chloride
calcium nitrate
Experiments were set up to investigate the rate of reaction of six metals, A, B, C, D, E and F with dilute
hydrochloric acid, oxygen and water. The results are shown below.
METAL
no reaction
no reaction
no reaction
vigorous reaction
slow reaction
slow reaction
slow reaction
slow reaction
no reaction
explosive reaction
vigorous reaction
slow reaction
no reaction
no reaction
vigorous reaction
fast reaction
quick reaction
Place the six metals in order of reactivity. (Start with the least reactive.)
less reactive
more reactive
Homework Sheets
Improving Science Education 5-14 (1999), section 2.3 makes the following statement about homework:
Science homework was rarely given in primary schools and was not sufficiently purposeful or challenging in
secondary schools.
The following homework sheets are designed to address this need. The questions are intended to offer the opportunity for
pupils to think, write extended answers and try some simple practical tasks. Teachers should ensure that pupils are given
any necessary safety advice in relation to the practical tasks (e.g. do not drink the water after adding salt, if the tumbler
breaks, ask an adult to help clean the broken glass).
Although entitled Homework Sheets, these questions can be used to check pupils understanding and can be used in
class as well as at home. The material supplied here is not exhaustive. Teachers can and should use other sources for
homework in the course of their teaching.
Sheet
Name
neutral
slihtly alkaline
beige
yellow
lime green
green
dark green
turquoise
pale blue
blue
dark blue
violet
purple
red
pH 1
10
11
12
13
14
very alkaline
slightly acid
orange
very acid
pink
The table below was copied from Universal Indicator paper (pH paper).
Sheet
1a
Name
neutral
slihtly alkaline
orange
beige
yellow
lime green
green
dark green
turquoise
pale blue
blue
dark blue
violet
purple
pH
10
11
12
13
14
very alkaline
slightly acid
pink
very acid
red
The table below was copied from Universal Indicator paper (pH paper).
Sheet
Name
The following is a report given by SEPA to a fish farmer.
Describe how you would use Universal Indicator or pH paper to measure the pH of the water.
If you were stung by a wasp what would you use to neutralise it?
Sheet
Name
The table below shows how long it takes 1g of each of the five metals to react completely in
hydrochloric acid.
METAL
TIME
copper
years
iron
600s
magnesium
35s
sodium
15s
zinc
180s
The reactivity of calcium is mid-way between those sodium and magnesium. How long might 1g of
calcium take to dissolve in the acid?
Explain why copper rather than magnesium is used to make water pipes.
Concentrate on reactivity in your answer.
Sheet
Name
As a homework exercise, pupils were asked to find the pH values of a number of substances found in
the home. One pupil wrote down her results as follows:
lemon juice 3
washing up liquid 8
indigestion tablet 10
vinegar 4
coffee 5
window cleaner 12
sugar solution 7
bicarbonate of soda 9
cola drink 5
salty water 7
Make a table to show whether these substances were acid, alkali or neutral.
ACIDS
NEUTRAL
ALKALIS
Draw and label a diagram to show how copper can be obtained from the electrolysis of copper
chloride.
Name one neutral substance, one laboratory acid and one laboratory alkali.
Acids
and
Metals
Glossary
Name
WORD
MEANING
acid
alkali
neutralisation
pH scale
pH paper
Universal Indicator
solution
reaction
Reactivity Series
metals
displacement
electrolysis
electroplating
corrosion
extraction
electrode
ore
blast furnace
Acids
and
Metals
Glossary
Name
WORD
MEANING
Acids
and
Metals
Pupil Checklist
Name
Resources
Universal indicator.
Variety of common solutions e.g. lemon, lime, orange and grapefruit juices, vinegar, citric acid, cream of tartar, coffee,
tea, deionised water, salt solution, Epsom salts, milk, milk of magnesia, washing up liquid, bicarbonate of soda, weak
ammonia solution.
Safety glasses.
HCl, H2SO4, CH3CO2H (ethanoic acid), NH3OH, NaOH (all solutions are 0.1M).
Evaporating basin.
Stirring rods.
Indigestion tablets/powder.
Measuring cylinders.
Safety screen.
Samples of fresh and partially corroded magnesium, zinc, iron, tin, copper.
Tongs.
Samples of metals for reactions: potassium, sodium, calcium, magnesium, aluminium, zinc, iron, tin, copper.
Copper sulphate solution and nickel sulphate solution for displacement reactions.
Copper (II) chloride, carbon electrodes, power pack and leads for electrolysis.
Safety Issues
(Advice taken from Be Safe)
Chemicals
The substances suggested for use in this topic can be used safely by pupils with the correct precautions but remember that
any substance, even salt can be harmful if taken in sufficient quantity. Be aware that any substance in a fine powdery or
dusty form can be inhaled and thus harm health.
When transferring solid chemicals use small spoons kept for this purpose, and not fingers. For liquids, use droppers
always taking great care to avoid cross contaminating the chemicals.
Only dispense small quantities so that it is never necessary to return excess chemical to the container.
Prevent contact with the eyes. This can happen when chemicals spit out of a tube during heating or when fingers are
contaminated with chemicals. Wear safety goggles/spectacles for such activities.
Avoid skin contact and use protective gloves if the information on the substance indicates it is corrosive or irritating to
skin or is poisonous by skin absorption.
It may be dangerous to mix chemicals. Even inadvertent mixing in a sink, etc. of household chemicals, such as bleach
with other cleaners or acid can produce a toxic gas. Warn children of the dangers.
Always store chemicals in containers securely labelled with the name of the chemical, and with a hazard warning
symbol if appropriate. It is best to use the original containers.
Be aware of the risk of confusion and avoid using food or drinks containers for the storage of chemicals.
Store all chemicals in a locked cupboard or room away from heat sources and separate from those intended as foodstuffs.
Store flammable liquids separately from other chemicals. Where there is more than half a litre of any one flammable, it
must be locked in a flame-resistant cupboard or store.
Disposing of chemicals
Consult the Technician Resource Service (TRS), 135 Westmuir Street, Glasgow G31 5EX (or David Lawson, Adviser in Science
0141 287 4126) if you wish to dispose of any chemicals.
Metals
When testing the more reactive metals (Alkali metals) this should be done as a teacher demonstration.
The Multi Media Science School on the schools network has some nice video clips of the more reactive metals which you
can show. It also has a nice but very short clip of the electrolysis of molten lead bromide which you could show.
When heating the magnesium ribbon remind the pupils not to look directly at the magnesium as it can damage their eyes,
a beaker of cold water could be used to drop the copper in to after heating it.
When collecting the hydrogen gas for testing remind the pupils not to touch the bottom of the test tubes containing the acid
and metal as they will be warm, in some cases very warm!
Electrolysis
When carrying out the electrolysis experiments remember to ventilate the room to prevent a build up of chlorine gas, and
do not exceed 6V on the power pack when doing the experiment.
Electroplating
When carrying out the electroplating experiments remind the pupils to be careful with the electroplating solution and to
rinse it off immediately if they spill it on themselves. Remember to switch off the power packs before handling the electrodes.
Further information
Consult Technician Resource Service (TRS), 135 Westmuir Street, Glasgow G31 5EX, 0141 554 6322 (or David Lawson, Adviser
in Science, 0141 287 4126).