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Product code
: 527
Product description
: Hardener.
Other means of
identification
: Not available.
Product type
: Liquid.
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Uses in Coatings - Industrial use
Uses in Coatings - Professional use
Supplier's details
Emergency telephone
number (with hours of
operation)
: 1-800-424-9300
(Staffed 24/7)
Coatings: Hardener.
1,2
527
^(ValidationDate).
Signal word
: Danger.
Hazard statements
: Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause damage to organs through prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Date of issue
: 26.05.2015.
1/11
Response
Storage
Disposal
Hazards not otherwise
classified
: Wear protective gloves. Wear eye or face protection. Wear protective clothing. Avoid
release to the environment. Do not breathe vapor or spray. Do not eat, drink or smoke
when using this product. Wash hands thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace.
: Collect spillage. Get medical attention if you feel unwell. IF INHALED: Remove victim
to fresh air and keep at rest in a position comfortable for breathing. Immediately call a
POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON
CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair):
Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash
contaminated clothing before reuse. Immediately call a POISON CENTER or physician.
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER or physician.
: Store locked up.
: Dispose of contents and container in accordance with all local, regional, national and
international regulations.
: None known.
: Mixture
Other means of
identification
: Not available.
: Not applicable.
Product code
: 527
Ingredient name
CAS number
aminepoxyadduct
benzyl alcohol
3-aminomethyl-3,5,5-trimethylcyclohexylamine
2-methylpentane-1,5-diamine
50 - <75
25 - <48
10 - <25
3 - <5
1075254-00-0
100-51-6
2855-13-2
15520-10-2
Inhalation
Date of issue
: Get medical attention immediately. Call a poison center or physician. Immediately flush
eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns
must be treated promptly by a physician.
: Get medical attention immediately. Call a poison center or physician. Remove victim to
fresh air and keep at rest in a position comfortable for breathing. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
: 26.05.2015.
2/11
Ingestion
: Get medical attention immediately. Call a poison center or physician. Wash with plenty
of soap and water. Remove contaminated clothing and shoes. Wash contaminated
clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for
at least 10 minutes. Chemical burns must be treated promptly by a physician. In the
event of any complaints or symptoms, avoid further exposure. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
: Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do
so by medical personnel. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs. Chemical burns must be treated promptly by a physician.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Inhalation
Skin contact
Ingestion
: Harmful if swallowed.
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
Unsuitable extinguishing
media
: None known.
Date of issue
: 26.05.2015.
3/11
: In a fire or if heated, a pressure increase will occur and the container may burst. This
material is toxic to aquatic life with long lasting effects. Fire water contaminated with
this material must be contained and prevented from being discharged to any waterway,
sewer or drain.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
: Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities. Collect spillage.
Large spill
: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
: Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Date of issue
: 26.05.2015.
4/11
: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
: Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
Exposure limits
benzyl alcohol
Appropriate engineering
controls
Environmental exposure
controls
: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Body protection
Respiratory protection
Date of issue
5/11
: Liquid.
Color
: Various colors.
Odor
Odor threshold
: Characteristic.
: Not available.
pH
Melting point
: Not available.
: Not available.
Boiling point
: Not available.
Flash point
Evaporation rate
: Not available.
: Not available.
: Not available.
Vapor pressure
: Not available.
Vapor density
Relative density
: Not available.
: 1.02 to 1.05 g/cm
Solubility
: Not available.
Auto-ignition temperature
: Not available.
Decomposition temperature
: Not available.
Viscosity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: No specific data.
Incompatible materials
: No specific data.
Hazardous decomposition
products
: Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Result
Species
Dose
Rat
Rat
2900 mg/m
1690 mg/kg
Exposure
1 hours
-
Irritation/Corrosion
Product/ingredient name
Result
Species
Score
Exposure
Observation
Rabbit
Rabbit
0.1 Mililiters
0.5 Mililiters
Sensitization
Date of issue
: 26.05.2015.
6/11
Category
Route of
exposure
Target organs
2-methylpentane-1,5-diamine
Category 2
Inhalation
Not determined
Aspiration hazard
Not available.
Information on the likely
routes of exposure
: Not available.
Skin contact
Ingestion
: Harmful if swallowed.
Ingestion
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
: Not available.
effects
Potential delayed effects
Long term exposure
Potential immediate
effects
Potential delayed effects
: Not available.
: Not available.
: Not available.
: 26.05.2015.
7/11
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
ATE value
Oral
Dermal
Inhalation (vapors)
513 mg/kg
7857,1 mg/kg
37,16 mg/l
Result
Species
Exposure
aminepoxyadduct
Algae - Pseudokirchneriella
subcapitata
Daphnia - Daphnia magna
Fish - Oncorhynchus Mykiss
Daphnia - Daphnia magna
72 hours
Algae
72 hours
3-aminomethyl-3,5,
5-trimethylcyclohexylamine
48 hours
96 hours
48 hours
Test
Result
Dose
Inoculum
aminepoxyadduct
Product/ingredient name
Aquatic half-life
Photolysis
Biodegradability
aminepoxyadduct
benzyl alcohol
3-aminomethyl-3,5,
5-trimethylcyclohexylamine
Not readily
Readily
Not readily
Bioaccumulative potential
Product/ingredient name
LogPow
BCF
Potential
benzyl alcohol
3-aminomethyl-3,5,
5-trimethylcyclohexylamine
1,1
0,99
<100
-
low
low
Mobility in soil
Soil/water partition
coefficient (KOC)
Other adverse effects
Date of issue
: Not available.
8/11
TDG
Classification
Mexico
Classification
ADR/RID
IMDG
IATA
UN number
2735
2735
2735
2735
2735
2735
UN proper
shipping name
Polyamines,
liquid,
corrosive, n.o.s.
(3-aminomethyl3,5,
Polyamines,
liquid,
corrosive, n.o.s.
(3-aminomethyl3,5,
Polyamines,
liquid,
corrosive, n.o.s.
(3-aminomethyl3,5,
Polyamines,
liquid,
corrosive, n.o.s.
(3-aminomethyl3,5,
Polyamines,
liquid,
corrosive, n.o.s.
(3-aminomethyl3,5,
Polyamines,
liquid,
corrosive, n.o.s.
(3-aminomethyl3,5,
5-trimethylcyclohexylamine)
5-trimethylcyclohexylamine)
5-trimethylcyclohexylamine)
5-trimethylcyclohexylamine)
5-trimethylcyclohexylamine)
5-trimethylcyclohexylamine)
Transport
8
hazard class(es)
Packing group
III
III
III
III
III
III
Environmental
hazards
No.
No.
No.
Yes.
Yes.
No.
Additional information
DOT Classification
: -
TDG Classification
: -
Mexico Classification
: -
ADR/RID
IMDG
IATA
Special precautions for user : Transport within users premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
Date of issue
: Not available.
: 26.05.2015.
9/11
: Not listed
: Not listed
: Not listed
: Not listed
: Not listed
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ
: Not applicable.
SARA 311/312
Classification
Fire
Sudden
hazard release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
aminepoxyadduct
benzyl alcohol
3-aminomethyl-3,5,
5-trimethylcyclohexylamine
2-methylpentane-1,5-diamine
50 - <75
25 - <48
10 - <25
No.
No.
No.
No.
No.
No.
No.
No.
No.
Yes.
Yes.
Yes.
No.
No.
No.
3 - <5
No.
No.
No.
Yes.
Yes.
State regulations
Massachusetts
New York
New Jersey
Pennsylvania
International regulations
: 26.05.2015.
10/11
: Not determined.
Canada
: Not determined.
China
: Not determined.
Europe
: Not determined.
Japan
: Not determined.
Malaysia
: Not determined.
New Zealand
: Not determined.
Philippines
: Not determined.
Republic of Korea
: Not determined.
Taiwan
: Not determined.
Justification
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
Calculation method
History
Date of printing
: 26.05.2015.
Date of issue/Date of
revision
Date of previous issue
Version
: 26.05.2015.
Key to abbreviations
References
: 26.05.2015.
: 1.01
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
: Not available.
Date of issue
: 26.05.2015.
11/11