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Equilibrio de Solubilidad
Muchos proceso naturales dependen de la
K ps [Ca ][C2O4 ]
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reserved.
PbI2 (s)
Pb (ac) 2I (ac)
H2O
K ps [Pb ][I ]
CaC2O4 (s)
H2O
Inicio
Cambio
Equilibrio
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reserved.
K ps [Ca ][C2O 4 ]
5
PbI 2 (s)
Inicio
Cambio
Equilibrio
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reserved.
H2O
Pb (aq) 2I (aq)
0
0
+1.2 x 10-3 +2 x (1.2 x 10-3)
1.2 x 10-3 2 x (1.2 x 10-3)
K sp [Pb 2 ][I ]2
3
K sp (1.2 10 )( 2 (1.2 10 ))
K sp 6.9 10
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reserved.
[Ca ][F ] K sp
(x)(2x) 3.4 10
2
3.4 10
x
4
3
-11
11
2.0 10
78.1g CaF2
solubilida d 2.0 10 mol / L
1 mol CaF2
4
1.6 10 g CaF2 / L
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reserved.
H2O
Ca (ac) C 2 O 4 (ac)
Inicio
0.15
Cambio
Equilibrio
+x
0.15+x
+x
x
[Ca ][C2O4 ] K ps
(0.15 x)(x) 2.3 10
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reserved.
9
2.3 10
2
.
3
10
x
0.15 x
0.15
x 1.5 10
PbCl2 (s)
H2O
La expresin de Qc es:
Qc [Pb
2
]i [Cl ]i
Qc (0.0025) (1.0 10 )
-10
Qc 2.5 10 K sp
-7
Effect of pH on Solubility
CaC2O4 (s)
H2O
H2O
Effect of pH on Solubility
.
Ag (ac) NH 3 (ac)
Ag ( NH 3 ) (ac)
Ag ( NH3 ) 2 (ac)
[ Ag( NH 3 )2 ]
Kf
2
[ Ag ][NH 3 ]
El valor de Kf para Ag(NH3)2+ es 1.7 x 107.
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reserved.
1 [ Ag ][NH 3 ]
Kd
K f [ Ag( NH 3 )2 ]
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reserved.
Ag( NH 3 )2 (aq )
Inicio
Cambio
Equilibrio
0.010
-x
0.010-x
0.98
+2x
0.98+2x
[ Ag ][NH 3 ]
1
Kd
Kf
[ Ag( NH 3 )2 ]
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reserved.
( x)(0.98 2 x)
1
7
(0.010 x)
1.7 10
2
( x)(0.98)
8
5.9 10
(0.010)
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reserved.
Luego
8
x 5.9 10
( 0.010 )
( 0.98 )2
6.1 10
10
Anlisis cualitativo
Anlisis cualitativo involucra la
ure 18.8