Académique Documents
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Culture Documents
1956
Short communication
A new mathematical model for thin layer drying of fruits
Lemuel M. Diamante,1* Reiner Ihns,2 Geoffrey P. Savage1 & Leo Vanhanen1
1 Department of Wine, Food and Molecular Biosciences, Lincoln University, Lincoln, Canterbury, New Zealand
2 Department of Agriculture and Food Technology, Hochschule Neubrandenburg, Neubrandenburg, Germany
(Received 25 March 2010; Accepted in revised form 11 June 2010)
The aim of this study was to t a new mathematical model on the thin layer drying curves of fruits. Thin
layer drying studies at dierent temperatures (60, 80 and 100 C) were carried out on two varieties each of
kiwifruit and apricot. The new model was compared statistically with three other drying models (Henderson
and Pabis, Page and logarithmic) published in the literature. The proposed equation gave the highest
coecient of determination for both varieties of kiwifruit and apricot and closely followed by the Page
equation. Statistical evaluation of the experimental and predicted moisture ratio showed that the proposed
equation consistently gave the lowest reduced Chi-square, root mean square error and mean relative
percentage error. The results indicate that the proposed equation has the best curve tting ability for both
fruits. However, there is no theoretical basis oered for the good curve tting ability of the equation.
Summary
Keywords
Introduction
doi:10.1111/j.1365-2621.2010.02345.x
2010 The Authors. Journal compilation 2010 Institute of Food Science and Technology
Materials
Table 1 Regression analyses results of the different thin layer drying equations for green and gold kiwifruits
Temperature
(oC)
Thin-layer drying
equation
60 R1
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
60 R2
80 R1
80 R2
100 R1
100 R2
Pabis
Pabis
Pabis
Pabis
Pabis
Pabis
Green kiwifruit
Constants
d = 1.5749
g = 0.00213
p = )17.7553
a = )5.5341
d = 1.6418
g = 0.00189
p = )11.5627
a = )5.5955
d = 1.6349
g = 0.00286
p = )8.3541
a = )5.7311
d = 1.6920
g = 0.00286
p = )14.0267
a = )5.8443
d = 1.6878
g = 0.00305
p = )2.7067
a = )5.6465
d = 1.6901
g = 0.0335
p = )2.1513
a = )5.4073
f = -0.0165
h = 1.3451
q = )0.0008
b = 1.0504
f = )0.0166
h = 1.3655
q = )0.0011
b = 1.0423
f = )0.0253
h = 1.4002
q = )0.0023
b = 1.3309
f = )0.0282
h = 1.4260
q = )0.0016
b = 1.4181
f = )0.0393
h = 1.5299
q = )0.0086
b = 1.4295
f = )0.0386
h = 1.5001
q = )0.0098
b = 1.2992
r2
r = 18.0797
c = 0.0335
r = 11.8674
c = 0.0368
r = 8.6323
c = 0.0090
r = 14.3801
c = 0.0010
r = 2.9021
c = 0.0156
r = 2.3138
c = 0.0313
0.980
0.996
0.983
0.997
0.981
0.996
0.986
0.997
0.976
0.997
0.982
0.998
0.978
0.997
0.982
0.997
0.966
0.999
0.989
0.999
0.962
0.998
0.991
0.999
d = 1.8600
g = 0.00184
p = )3.0499
a = )4.8878
d = 1.7910
g = 0.00171
p = )5.4485
a = )4.5282
d = 1.1852
g = 0.00358
p = )2518.766
a = )6.8477
d = 2.0346
g = 0.00312
p = )4.5110
a = )5.3765
d = 1.5162
g = 0.0382
p = )5.6267
a = )5.6591
d = 1.3636
g = 0.00405
p = )16.8726
a = )5.8431
Gold kiwifruit
Constants
r2
f = -0.0173
h = 1.3666
q = )0.0032
b = 0.6904
f = )0.0167
h = 1.3740
q = )0.0021
b = 0.4914
f = )0.0251
h = 1.3793
q = )9.95E)06
b = 1.9916
f = )0.0317
h = 1.4168
q = )0.0041
b = 1.2164
f = )0.0345
h = 1.4439
q = )0.0044
b = 1.5070
f = )0.0321
h = 1.4384
q = )0.0017
b = 1.6706
0.969
0.996
0.997
0.999
0.971
0.992
0.983
0.997
0.938
0.982
0.937
0.985
0.959
0.997
0.981
0.997
0.977
0.998
0.987
0.998
0.974
0.997
0.976
0.998
r = 3.1965
c = 0.0773
r = 5.7249
c = 0.1007
r = 2518.9346
c = )0.0736
r = 4.6652
c = 0.0243
r = 5.8401
c = )0.0097
r = 17.1136
c = )0.0365
Henderson and Pabis equation is MR = d exp(-ft); Page equation is MR = exp((-gth); logarithmic equation is MR = p exp(-qt) + r; Proposed equation is
ln(-ln MR) = a + b(ln t) + c(ln t)2, where r2 = coefficient of determination; MR = moisture ratio; t = time.
2010 The Authors. Journal compilation 2010 Institute of Food Science and Technology
1957
1958
Table 2 Statistical results of the different thin layer drying equations for green and gold kiwifruits
Temperature
(oC)
60 R1
60 R2
80 R1
80 R2
100 R1
100 R2
Thin-layer drying
equation
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Pabis
Pabis
Pabis
Pabis
Pabis
Pabis
Green kiwifruit
RMSE
v2
0.022032
0.000238
0.010311
0.000109
0.028914
0.000273
0.009425
0.000123
0.028144
0.000157
0.007349
0.000129
0.031540
0.000140
0.012204
0.000134
0.033057
0.000160
0.003271
0.000115
0.034220
0.000225
0.002212
0.000128
0.014123
0.002270
0.095734
0.001611
0.016413
0.002464
0.091308
0.001748
0.016004
0.001838
0.081328
0.001698
0.016145
0.001677
0.104802
0.001655
0.016719
0.001676
0.054683
0.001466
0.017298
0.001998
0.044970
0.001556
P (%)
v2
Gold kiwifruit
RMSE
P (%)
21.77628
15.42070
20.01595
14.60727
21.39923
14.61264
18.72008
13.38242
23.36698
12.40153
40.55048
12.03612
24.37413
14.98433
21.27113
15.01172
22.39701
7.75572
11.31370
7.07465
23.53720
8.54605
9.73451
6.53331
0.054546
0.000381
0.001953
0.000067
0.046911
0.000682
0.008542
0.000193
0.007770
0.000341
0.008268
0.000681
0.086242
0.000159
0.002780
0.000100
0.025197
0.000163
0.005558
0.000194
0.012168
0.000096
0.007128
0.000170
0.021860
0.002731
0.041569
0.001256
0.021436
0.003880
0.086926
0.002028
0.014117
0.003399
0.083005
0.004424
0.029264
0.002095
0.048129
0.001742
0.018822
0.002029
0.070290
0.002158
0.014116
0.001620
0.079407
0.002072
27.12660
13.79168
8.37137
5.35465
26.71808
19.41563
19.58052
13.28155
44.10940
38.03985
44.11896
37.23407
43.53949
20.91764
22.36914
18.34801
19.71611
7.95032
13.15920
8.14228
16.80913
7.42705
15.15859
8.63018
v2 = reduced chi-square; RMSE = reduced mean square error; P = mean relative percentage error.
MR d exp ft
Mathematical models
M Me
Mi Me
MR exp g th
2010 The Authors. Journal compilation 2010 Institute of Food Science and Technology
Table 3 Regression analyses results of the different thin layer drying equations for apricot Southern Red and Moorpark varieties
Temperature
(oC)
60 R1
60 R2
80 R1
80 R2
100 R1
100 R2
Thin-layer drying
equation
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Pabis
Pabis
Pabis
Pabis
Pabis
Pabis
d = 1.1304
g = 0.00170
p = )5.5985
a = )6.7371
d = 1.4547
g = 0.00123
p = )6.6064
a = )6.2170
d = 1.4490
g = 0.00177
p = )4.6761
a = )6.2104
d = 1.4730
g = 0.00171
p = )5.1124
a = )6.1983
d = 1.3713
g = 0.00278
p = )3.7557
a = )5.4846
d = 1.30884
g = 0.00224
p = )2.6881
a = )6.0719
Southern
Red apricot
Constants
r2
f = )0.0054
h = 1.1818
q = )0.0008
b = 1.3532
f = )0.0060
h = 1.2230
q = )0.0007
b = 0.9962
f = )0.0115
h = 1.3047
q = )0.0017
b = 1.2420
f = )0.0115
h = 1.3106
q = )0.0016
b = 1.2222
f = )0.0156
h = 1.3062
q = )0.0029
b = 1.0873
f = )0.0161
h = 1.3501
q = )0.0037
b = 1.3349
0.995
0.999
1.000
1.000
0.989
0.998
0.996
0.999
0.987
1.000
0.997
1.000
0.987
0.999
0.995
0.999
0.989
0.999
0.997
1.000
0.981
1.000
0.999
1.000
r = 5.6361
c = )0.0190
r = 6.7478
c = 0.0239
r = 4.8036
c = 0.0074
r = 5.2592
c = 0.0104
r = 3.8621
c = 0.0279
r = 2.7741
c = 0.0019
d = 1.2319
g = 0.00176
p = )6.8169
a = )6.1609
d = 1.2923
g = 0.00153
p = )5.1483
a = )6.4646
d = 1.4051
g = 0.00232
p = )7.9390
a = )5.9532
d = 1.5055
g = 0.00181
p = )3.4368
a = )6.0915
d = 1.4780
g = 0.00176
p = )2.0450
a = )6.3030
d = 1.5440
g = 0.00214
p = )5.6145
a = )6.1805
Moorpark
apricot
Constants
r2
f = )0.0054
h = 1.1566
q = )0.0006
b = 1.0693
f = )0.0058
h = 1.1949
q = )0.0008
b = 1.1849
f = )0.0112
h = 1.2529
q = )0.0010
b = 1.1904
f = )0.0119
h = 1.3035
q = )0.0010
b = 1.1757
f = )0.0161
h = 1.3956
q = )0.0045
b = 1.3734
f = )0.0179
h = 1.3732
q = )0.0023
b = 1.3939
0.990
0.999
0.997
0.999
0.980
0.999
0.997
0.999
0.977
0.997
0.993
0.998
0.969
0.999
0.994
0.999
0.990
0.999
0.999
0.999
0.987
1.000
0.996
1.000
r = 6.8905
c = 0.0097
r = 5.2229
c = 0.0012
r = 8.0631
c = 0.0079
r = 3.5616
c = 0.0165
r = 2.1344
c = 0.0030
r = 5.8041
c = )0.0028
Henderson and Pabis equation is MR = d exp(-ft); Page equation is MR = exp((-gth); Logarithmic equation is MR = p exp(-qt) + r; Proposed equation is ln(ln MR) = a + b(ln t) + c(ln t)2, where r2 = coefficient of determination; MR = moisture ratio; t = time.
2010 The Authors. Journal compilation 2010 Institute of Food Science and Technology
N
P
v2
MRexp MRpre 2
i1
Nn
N
P
B MRexp MRpre
B
RMSE Bi1
@
N
11=2
C
C
C
A
N
100 X
MRexp MRpre
P
N i1
MRexp
10
11
1959
Table 4 Statistical results of the different thin layer drying equations for apricot Southern Red and Moorpark varieties
Temperature
(oC)
60 R1
60 R2
80 R1
80 R2
100 R1
100 R2
Thin-layer drying
equation
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Henderson and
Page
Logarithmic
Proposed
Pabis
Pabis
Pabis
Pabis
Pabis
Pabis
v2
Southern
Red Apricot
RMSE
P (%)
0.001485
0.000029
0.000072
0.000036
0.013465
0.000158
0.001377
0.000033
0.013750
0.000042
0.001051
0.000029
0.014951
0.000067
0.001490
0.000044
0.009066
0.000050
0.000751
0.000011
0.007045
0.000030
0.000410
0.000028
0.037691
0.005267
0.008210
0.005819
0.115274
0.012501
0.036736
0.005652
0.114842
0.006311
0.031406
0.005241
0.119852
0.008019
0.037453
0.006446
0.092607
0.006902
0.026264
0.003206
0.081634
0.005295
0.019400
0.005100
5.69463
1.33661
1.33722
2.23682
15.08181
9.65092
7.65439
5.02821
13.75727
3.69427
5.83040
3.22651
14.30228
4.94618
7.35035
4.23509
10.04645
3.33604
4.58995
2.25614
14.10143
2.19603
3.05371
2.03167
v2
Moorpark
Apricot
RMSE
P (%)
0.005211
0.000081
0.000486
0.000060
0.006468
0.000040
0.000323
0.000040
0.010513
0.000152
0.000977
0.000128
0.017364
0.000103
0.000985
0.000061
0.010755
0.000052
0.000263
0.000047
0.015122
0.000040
0.001920
0.000046
0.071919
0.008990
0.021929
0.005652
0.080214
0.006341
0.017897
0.006268
0.102108
0.012286
0.031070
0.011250
0.131188
0.010084
0.031191
0.007774
0.103197
0.007169
0.016092
0.006801
0.122394
0.006294
0.043509
0.006714
11.06022
5.76505
4.83358
5.02821
11.59257
3.65356
3.30441
3.51621
14.93524
7.06224
6.58926
5.90738
17.89420
6.67755
5.97629
4.32313
13.19603
3.31268
2.74063
3.00115
15.14682
4.44879
8.01350
4.60358
v2 = reduced chi-square; RMSE = reduced mean square error; P = mean relative percentage error.
700
Experimental 60 C
Experimental 60 C
600
600
Predicted 60 C
Predicted 60 C
1960
Experimental 80 C
500
Predicted 80 C
400
Experimental 100 C
Predicted 100 C
300
200
Experimental 80 C
500
Predicted 80 C
400
Experimental 100 C
Predicted 100 C
300
200
100
100
0
0
50
100
150
200
250
300
350
400
Time (min)
50
100
150
200
250
300
350
400
Time (min)
2010 The Authors. Journal compilation 2010 Institute of Food Science and Technology
800
Experimental 60 C
700
Predicted 60 C
600
Experimental 80 C
Predicted 80 C
500
Experimental 100 C
400
Predicted 100 C
300
200
100
0
0
100
200
300
400
500
600
700
Time (min)
900
Experimental 60 C
800
Predicted 60 C
700
Experimental 80 C
600
Predicted 80 C
500
Experimental 100 C
400
Predicted 100 C
300
200
100
0
0
200
400
600
800
1000
1200
Time (min)
2010 The Authors. Journal compilation 2010 Institute of Food Science and Technology
1961
1962
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2010 The Authors. Journal compilation 2010 Institute of Food Science and Technology
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