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CONTENTS
Fundamental Aspects of Plant Nutrition
Introduction 1
Absorption of Nutrients
1
Essential Macro-Elements 3
Trace or Micro-Elements 5
Water Status and Quality for Crop Production
Introduction 7
Water Status 8
Water Potential
8
Water Quality
10
Water Treatments 13
Fertilizer Management
Introduction 14
What are the Essential Elements for Plant Growth?
What do these Numbers on Fertilizer Bags Mean?
What are Parts Per Million?
15
Any Formulas to Calculate PPM? 16
Solubilities of Fertilizers
18
Different Sources of Fertilizers
19
Preparing a Fertilizer Program
20
Making Stock Solutions from Trace Elements
Principles of Mixing Fertilizers
27
pH, Your Water and Fertilizer?
27
What is Electrical Conductivity. . . 29
Sample Fertilizer Programs30
.
27
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ABSORPTION OF NUTRIENTS
Plants use carbon, hydrogen and oxygen from the air and water in general from the
growing medium to make simple foods by the process of photosynthesis. These
substances are needed to make amino acids, proteins and protoplasm. Other elements
are taken up by plants through the roots. Moderate amounts are also absorbed through
the leaves and stem tissues. Quite often trace element deficiencies can be corrected
through foliar feeding.
Absorption through roots is the major route of nutrient uptake. If the root system is
damaged by disease, insects or higher levels of soluble salts in the growing medium,
the nutrient uptake is reduced.
Roots can absorb organic salts or ions, which are formed as a result of interaction
between root respiration and soil water. Inorganic salts applied as fertilizers are broken
apart by a chemical process called dissociation.
At any time, both molecules and separate ions of the salt are present. A molecule
consists of two or more ions. For example, potassium chloride (KCl) supplied as a
fertilizer is dissociated in the soil solution into potassium (K+) and chloride (Cl-) ions.
Ions with positive (+) charges are called cations. Ions with negative (-) charges are
called anions. The ions are then absorbed by the roots through a special membrane.
This semi permeable membrane surrounds each cell within the root and allows the ionic
exchange..
Cation-Exchange Capacity
The actual process of nutrient uptake by plants is controlled by the cation-exchange
capacity (CEC) of the growing medium. This action is associated with the clay particles
of a mineral soil. Organic materials such as peat moss also have a cation exchange
capacity. The clay particle has a negative (-) surface charge and attracts cations (+
charge). Hydrogen ions are released when carbonic acid is formed from the
combination of hydrogen from the soil water and the carbon dioxide resulting from root
respiration. These hydrogen ions, which have a positive charge, exchange their
positions in the soil solution for positively charged cations held on the surface of the clay
particles. These cations are then absorbed by the roots.
The cations are calcium, potassium, magnesium, sodium, and ammonium ions. The
roots have to release a hydrogen ion to take up one ion of potassium, magnesium,
sodium and ammonium while two hydrogen ions will be required to obtain one calcium
because of its two positive charges.
Anion-Exchange Capacity
Plants also need anions for good growth. Nitrates (NO3-), chlorides (Cl-) and sulfates
(SO4-) are examples of anions. Negatively charged anions are not attracted by the
negative charge of the clay particles. Thus, they are not held like cations. They remain
in solution unless absorbed by the plant or lost through leaching. If leaching is not
adequate, anions can build up in the soil solutions and cause an increase in the
electrical conductivity of the root zone medium. The practical implications are that
nitrates are easy to leach with over watering and thus deficiency in plants can occur
rather quickly.
pH Effect on Nutrient Absorption
Uptake of nutrients is strongly affected by the pH of the growing medium. Our
experience is that the pH of the growing mix should be between 5.5 and 6.5. Below that
value the uptake of manganese, iron and boron increases considerable and can cause
tip burning and toxicity problems. Enough dolomite lime should be added to raise the
pH to around 5.5. Dolomite lime can be replaced with potassium bicarbonate because
calcium is supplied through calcium nitrate and magnesium through magnesium sulfate.
Many growers have reported difficulties with pH adjustments while plant seedlings are
being grown. It takes a long time to change pH from a lower to a higher value or vice
versa. Since the pH scale is based on logarithms, a growing medium with a pH of 6 is
10 times more acidic than a medium with a pH of 7. Similarly, a growing medium with a
pH of 5 is 10 times more acidic than one with a pH of 6.
By the law of logarithms, a growing medium with a pH of 5 is 100 (10 x 10) times more
acidic than a medium of with a pH of 7. This factor of 100 is the reason it is more
difficult to raise the pH from pH 5 to 7 than it is to raise from pH 6 to pH 7. This means
that if 10 pounds of lime are required to raise the pH from 5 to 6, then 100 pounds are
required to raise the pH from 5 to 7. In actual situations, other factors influence the
ratios to change the values.
ESSENTIAL MACRO-ELEMENTS
Nitrogen (N)
Nitrogen is very important to plant growth and is usually found in the largest amounts in
the leaves. On a dry weight basis, two to six percent of a healthy leaf is nitrogen.
Plants cannot absorb the elemental form of nitrogen (N). Primary absorption occurs as
nitrate (NO3-) while ammonium (NH4+) and amino (NH2+) can also be absorbed. In soil
based media there are a group of bacteria present which can convert ammonium
nitrogen to nitrate nitrogen. These bacteria are not present in soilless media used by
growers. Consequently ammonium nitrogen can quickly become toxic to roots. When
bacteria convert ammonium nitrogen to nitrate nitrogen, there is an intermediary step
involved. That is the formation of nitrites, which are normally very short lived radical but
fairly toxic to roots. This can happen under low temperature and water logged
conditions. If you detect nitrite in your medium, you know there is water logging.
Nitrate nitrogen, while inside the roots, is converted to ammonium and to amino forms
and used to make proteins and other chemicals needed by the plants. That is why
fertilizers containing nitrate nitrogen like calcium nitrate and potassium nitrate will
produce slow and steady growth. Ammonium and urea based fertilizers can produce
soft and lush growth in plants.
Ammonium nitrogen can be used if plant growth is slow but it should be used when the
growing medium temperature is above 16oC and the light is good. Use of ammonium
fertilizers should be avoided until the end of March. Where pH is alkaline, use of
ammonium fertilizer is an advantage because it can help to bring down the pH. Urea is
a good source of nitrogen for foliar feeding. Wherever plants are slow and need a
growth boost, urea should be applied to the leaves. Nitrogen is mobile within the plant,
so it can be transported from lower to upper leaves. That is why deficiency symptoms
will first appear on the lower leaves.
Measurement of nitrogen in tissue is a useful tool to manage the growth and bud set in
plants, especially tree seedlings. It should be monitored on a weekly basis after week
16 of the growth. Bud set in conifer species will be difficult if tissue nitrogen is over two
percent.
Phosphorus (P)
Phosphorus has several important functions. It must be available in sufficient quantities
early in the life of the plants to assist in cell division and differentiation. It is also
required for root growth and formation of buds. Both the respiratory and photosynthetic
processes require phosphorus for high energy phosphate bonds. Most of the
phosphorus is taken up in the form of the primary orthophosphate ion ( H2PO4--).
Smaller amounts of secondary orthophosphate (HPO4--) and organic phosphorus
compounds are also absorbed.
Two facts should be remembered about phosphorus:
* If you are using phosphoric acid to neutralize the carbonates and bicarbonates in
water, do not assume that phosphorus from phosphoric acid will be available for
plant use. Add an additional 40 to 80 ppm of phosphorus based on the need of
plant growth period.
* A pH of above 6.8 in the growing medium can tie up phosphorus with calcium and
it may not be available to the plant. We have seen phosphorus deficiencies in
plants because of pH related problems.
Because of the negative charge of orthophosphate, it is not attached to clay particles
and can easily tie up with aluminum in the growing mix. Phosphorus deficiency results
in stunting of plants and deep green or purple leaf colour with poor root development.
Phosphorus uptake is reduced at a growing medium temperature of below 12oC.
Phosphorus is slightly mobile within plant tissues. Phosphorus and iron levels in plant
tissues act in opposition to each other. At a high level of phosphorus, an iron deficiency
may develop. Similarly, a high level of iron may cause a phosphorus deficiency.
Potassium (K)
Potassium is absorbed by plants in its ionic form (K+). It plays an important role in the
regulating of the opening and closing of stomata and in water retention. It promotes the
growth of meristematic tissue, activates some enzymatic reactions, aids in nitrogen
metabolism and the synthesis of proteins, catalyses activities of some mineral elements
and aids in carbohydrate metabolism and translocation. Potassium is found in plant
tissues as a soluble, inorganic salt, while nitrogen and phosphorus are converted into
complex compounds. It is absorbed by the plants in large amounts without becoming
toxic.
Potassium is highly mobile within the plant. High potassium as compared to nitrogen is
used by growers in Alberta. This is to exert an antagonistic effect on the uptake of
nitrogen so that the growth is slowed down. Nitrogen to potassium ratios can be
changed to obtain faster or slower growth. N:K ratio of 2 to 1 will result in fast,
vegetative growth of plants. An equal ratio will maintain good growth while a ratio of 1
to 2 will harden the growth. That is why hardening fertilizer regimes contain an N to K
ratio of 1 to 2.
Calcium (Ca)
Calcium is absorbed in the ionic form (Ca++). Most of the calcium inside the plant is in
the form of calcium pectate in the middle lamellae of the cell walls. In tree seedlings it is
part of the lignin and tannin complex as well. The calcium prevents the leaching of
mineral salts from the cells. Much of the stiffness of plants is due to calcium. Calcium
is immobile and is not translocated from older to younger leaves. It's uptake from the
growing medium is dependent on the active water transport. If plants are not
transpiring, then calcium movement will be minimal. Slow or poor development of
terminal and side bud shoots is generally related to a lack of calcium in the tissue. In
cucumbers, poor development of side shoots is an indication of calcium deficiency while
in tomatoes; blossom end rot is due to poor calcium translocation. Most growers supply
enough calcium through their feeding program but it is the poor uptake which causes
problems. Make sure that the moisture deficit is in the range of 3 to 7 g/m3.
Magnesium (Mg)
Magnesium is absorbed as Mg++. It is the only mineral element contained in chlorophyll.
Magnesium appears to be related to phosphorus metabolism. A number of enzyme
systems require magnesium to work properly. Magnesium is mobile within the plant
tissues. Thus, symptoms of a lack of magnesium show up first on lower leaves. The
symptoms could appear later, on the entire plant as yellowing of interveinal areas with
veins remaining green.
Magnesium deficiencies have been noted in many crops and is likely due to the higher
potassium we use in our fertilizer programs. Foliar feeding of magnesium has given
satisfactory results.
Sulfur (S)
Sulfur is taken up from the soil in the form of sulfate ions (SO4--). Small amounts of
sulfur may be taken in through the leaves as sulfur dioxide. Sulfur seems to be involved
in the formation of chlorophyll but it is not a component of the chlorophyll molecule.
Nitrogen and sulfur deficiencies may look alike. As long as enough sulfur is supplied
from magnesium sulfate, its deficiency is unlikely to occur.
TRACE OR MICRO-ELEMENTS
These elements are as important as major elements but they are required in small
amounts. Their deficiency or toxicity can occur readily.
Iron (Fe)
Its deficiency has been noted in plants primarily due to alkaline pH in the growing
medium. It is taken up by the plant in the form of ferrous ions (Fe++) or complex organic
salts. Iron may also be absorbed as ferric ion (Fe+++) form. Plants may contain large
amounts of ferric ion but still show severe iron deficiency symptoms. Thus, a tissue iron
test cannot be used as a diagnostic test for confirming iron deficiency.
Iron acts with certain enzyme systems that carry on respiration. It is also required in the
formation of chlorophyll. Unlike magnesium it is not a component in the chlorophyll
molecule. Iron is immobile. Thus, a deficiency of iron appears first in the youngest
leaves as a chlorosis. If the deficiency is not corrected, the leaves may turn light yellow
and then almost completely white. Iron chelate is commonly used by many growers in
their fertilizer programs.
Manganese (Mn)
Plants absorb manganese in the form of the manganous ion (Mn++). It is used in the
active growing parts of plants and is involved in certain enzyme systems that oxidize
other elements such as iron. An excess of manganese may cause iron deficiency.
Manganese is immobile. Thus, a deficiency appears first in the new growth.
Manganese and iron deficiencies may be confused because symptoms are similar.
Manganese toxicities are more common in tree seedlings. This is because of a
tendency to grow them at acidic pH values. The uptake of manganese is several times
higher at pH values below 5. The damage appears as browning of needle tips
progressively moving inwards. The entire needle may turn brown. The damage is
generally irreversible. Toxicity has been seen in tomatoes and cucumbers where
manganese containing fungicides like Manzate have been used.
Copper (Cu)
Plants absorb copper in the form of the cupric ion (Cu++). It is needed for the proper
function of many enzyme systems. It stabilizes chlorophyll and delays its breakdown.
Thus, copper helps to increase the effective life of leaves. It is immobile, an enzyme
activator in respiration, seed formation and root growth. Organic growing media like the
one used by growers can tie up copper to a considerable degree. That is why copper
deficiencies are frequently noticed in many plants. We recommend the use of relatively
higher levels of copper in our feeding programs. A lack of copper in tree seedlings can
easily be confused with boron deficiency because symptoms are similar. Terminal
shoots may die back and witches' broom symptoms appear. It is best to monitor tissue
copper levels on a regular basis. Both copper chelate and copper sulfate are suitable for
plant use.
Zinc (Zn)
Zinc is an intermediately mobile nutrient. It is required to regulate consumption of
sugars essential for early growth and plant maturity. It plays an important role in
photosynthesis. Zinc deficiency is well known as small or tiny leaves disorder. Roots
absorb the zinc ion (Zn++). Zinc is also absorbed through leaves so one has to be
careful with the use of zinc based fungicides. Its deficiency has not been noticed in
Alberta grown plants but toxicities are possible due to the high zinc content in some
water supplies. Watch for higher zinc levels when you are collecting water from
greenhouse frame. Galvanized gutters may contribute significant amounts of zinc.
Molybdenum (Mo)
This element is required in the smallest amount of all trace elements. It appears that
molybdenum is used in the nitrogen cycle in the formation of nitrogen compounds and
the breakdown of nitrates. The leaves lose their good green colour and become more
dark blue in colour. When molybdenum is lacking in the plant, nitrates are not absorbed
from the growing medium even if it is present in large amounts.
Chlorine (Cl)
Chlorine deficiency is not well documented in plants. Its importance has been
recognized in plants such as tomatoes. Enough chlorides are present in our water
supplies. Too much chloride in the growing mix causes more problems than a lack of
chloride. Needle tip burning is the major symptom of chloride excess in spruce and
other conifers.
Other Elements
Sodium, aluminum and silicon are found in the tissues of many plants. Sodium levels
over one percent of the dry matter should be a cause of concern. Aluminum is found in
root tissue and ties up phosphorus in large amounts. Silicon increases the cation
exchange capacity of the growing medium and is used by many growers when
manganese toxicity is suspected.
High fluoride levels, over 1 ppm, has caused problems with tip burning in spruce
needles.
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Under high deficit situations the transpiration rate is high and if roots cannot meet the
demand of water then stomata start closing which slows down the photosynthesis. It is
suggested to use a deficit range of between 3 and 7 grams/m3.
WATER POTENTIAL
Water potential of a plant is a measure of energy status of water that is usually
expressed in pressure units and is composed of the following:
WP = OP + PP + MP + GP
OP = Osmotic Potential - the component produced by dissolved solutes.
PP = Pressure Potential - the component produced by the inward pressure of cell
walls in plants or due to water weight or air pressure in soil.
MP = Matric potential - the component produced by the adhesive attraction of water
molecules to surfaces or adhesion and cohesion in small capillaries.
GP = Gravity Potential - the component produced by the force of gravity.
Plant Water Potential (PWP) - the energy status of water within the plant. MP is small
in well watered plants. GP is negligible in small plugs and seedlings. PWP = OP + PP.
Growing Medium Water Potential (GMWP) - the energy status of water within the
growing medium. PP and GP are negligible in small containers. GMWP = MP + OP.
Plant Moisture Stress (PMS) - a way of describing plant water status.
Plant Water Potential is dynamic and changes with time as soil moisture and
atmospheric demand change. On a typical sunny day in a well-irrigated growing
medium, a plant begins to transpire as soon as the sun comes up, assuming that the
relative humidity is not very high. Once transpiration begins, PWP decreases until the
stomata close at which point the PWP levels off. Towards sunset, the PWP begins to
increase as atmospheric demand declines and the plant replenishes its moisture
content from the water in the growing medium.
Under high evaporative demand and a moderately dry growing medium the PWP is low
to start with because the plant is unable to completely recharge its moisture supply
overnight. PWP declines further at noon and continues in the afternoon. If this pattern
continues, over time, young seedlings can show moisture stress resulting in growth
damage.
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WATER QUALITY
Most Alberta growers have access to good quality water but some growers rely on "dug
out water". When we talk about quality, it means different things to different people.
This is because the quality is dependent on intended use. For irrigation purposes water
quality is determined by two factors:
1. The concentration and composition of dissolved salts.
2. The presence of suspended particles, pathogenic organisms, algae, pesticide and
herbicide contamination.
Effects of salts on irrigation water quality
A salt is defined as a chemical compound that releases charged particles called ions
when dissolved in water. For example, potassium nitrate (KNO3) releases two ions, one
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a positively charged cation (K+) and the other is negatively charged anion (NO3-). Salts
can be either beneficial or harmful depending on the characteristics of the specific ions
involved, as well as the total salt concentration. KNO3 is a fertilizer salt and both K+
and NO3are nutrient ions needed by the plant for growth. Salts such as sodium chloride (NaCl),
consist of harmful ions (Na+ and Cl-) that can damage or kill plant tissue.
Water analysis generally provides the concentration of following major ions.
ION NAME
CHEMICAL SYMBOL
EQUIVALENT WEIGHT
Calcium
Ca2+
20
Magnesium
Mg2+
12
Sodium
Na+
23
K+
39
Bicarbonate
HCO3-
61
Carbonate
CO32-
30
Cl-
36
Sulfate
SO42-
48
Boron *
CATIONS
Potassium
ANIONS
Chloride
* Boron occurs in several different ionic forms in irrigation water and therefore a
specific ionic formula cannot be given.
In addition to specific ion concentrations, a water quality test should provide
measurements of Electrical Conductivity, pH and Sodium Absorption Ratios (SAR).
Electrical Conductivity
EC is a measure of total dissolved solids in water. It is reported in millimhos or
millisiemens. As EC increases, the quality of the water decreases. It is a useful tool to
monitor plant development. EC and SAR are taken into consideration to make a
decision on quality. SAR reflects the relationship between sodium, calcium and
magnesium. The higher the ratio of sodium to calcium and magnesium, the higher the
danger of sodium toxicity. This is how the quality is judged:
*
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*
*
*
EC of 0.8 mmhos or less is considered suitable for irrigation of crop plants under
normal conditions.
EC between 0.81 and 2.2 mmhos. The water is considered marginal in quality
but can be used if special management practices are followed.
Water with an EC above 2.2 mmhos is not suitable for crop production.
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Zinc
Excessive levels of zinc have been found in water supplies where the water is collected
from galvanized metal. Excess zinc may cause problems with copper uptake.
pH
pH of Alberta water supplies is generally over 7 and this can cause problems in several
ways. pH of water over 6.8 can cause calcium to react with phosphorus and thus
precipitate out in the solution. When you are irrigating with water of pH over 7, even
though the medium pH is around 4, iron and manganese deficiencies are possible.
Adjust pH of water to around 6.
WATER TREATMENTS
Dug Out Water
Many Alberta growers collect water from a large run-off area. The water is generally of
good quality. In winter we have seen problems with low water levels and consequently
sucking mud with water. This can cause two problems: 1. Silt and clay may be
deposited in the growing medium and change the porosity and drainage characteristics
of the medium. 2. The fungus Pythium, can accompany this water and cause serious
damping off problems.
In one case where the dug out was located in a clay area, a large number of suspended
particles were delivered to the crop causing water logging. Herbicide contamination is
another potential problem. Treatments are available to remove suspended particles. In
the case of herbicide contamination, installation of charcoal filters should be considered.
In Saskatchewan 38% of growers use well water as the source for greenhouse crop
irrigation, followed by 31% from municipal sources, 26% from dugouts, and 5% from
rivers and creeks.
Hard Water from Wells
If calcium levels are over 100 ppm, then growers must use acid to neutralize carbonates
and bicarbonates. Hard water can be chemically softened but such water is not suitable
for plant growth. The quantity of acid needed to neutralize bicarbonates depends on
their amount present in water supply. Phosphoric, nitric, sulphuric and citric acid can be
used for this purpose although commercially, the first three acids are more commonly
used. Neutralizing 60 ppm or one milliequivalent of bicarbonates require 7 litres of 85%
phosphoric acid, 13.8 litres of 37% nitric acid and 3 litres of sulphuric acid for 100,000
litres of water. A level of 60 ppm of bicarbonates should be maintained in water to have
enough buffering capacity and maintain a pH of around 6.0.
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pH is logarithmic so it can drop very rapidly after a certain point. So dont depend on
the calculation alone. Check the pH after the desired amount of acid has been added
and then make corrections accordingly. We have seen cases where the pH dropped to
a level of 3 and grower did not realize until the damage was done.
Following table provides a summary of amounts of acid required to neutralize 60 ppm of
bicarbonates. A level of between 30-60 ppm of bicarbonates should be maintained in
the water supply.
Acid
13.8
8.4
8.0
7.0
3.0
Acids are corrosive so proper care should be taken in handling them. When diluting the
acid, add acid into the water not water into the acid. Wear proper clothing, gloves and
safety glasses. Calibrate pH meter frequently and obtain new buffers every year.
High Sodium Water
Some growers have no choice but have access to soft water.
reverse osmosis to make their water usable.
FERTILIZER MANAGEMENT
INTRODUCTION
All plants need sixteen elements to grow properly. These are called essential elements.
Any one of these elements can become the limiting factor in the growth of plants. This
is important to understand because many times growers get upset that a fertilizer
program is not working. When you look closely you will find a limiting factor which may
or may not relate to fertilizer elements. For example, in a recent situation with a tomato
grower it was found that plants were not growing properly and fruit was not sizing up. All
the fertilizer elements were being supplied in adequate amounts. It was found that the
carbon dioxide generator was not working properly and the plants were starving for
carbon. Thus, a lack of carbon became a limiting factor for these tomato plants.
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N:P2O5:K2O
N:P:K
20-10-20
20-10-20
20-4.3-16.6
10-52-10
10-52-10
10-22.3-8.3
20-20-20
20-20-20
20-8.6-16.6
28-14-14
28-14-14
28-6.02-11.6
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For example, the formula calls for 200 ppm of nitrogen from 20-10-20 fertilizer. Using
the above formula:
ppm desired = 200
Grade of fertilizer = 20 percent nitrogen
multiplication factor 0.62
200
20 x 0.62 = 16 ounces/100 gallons of water
You can multiply 16 ounces with 20 percent nitrogen and 0.62 and get your ppm from
there. It means that if you know the ounces per 100 gallons of water you can calculate
ppm concentration. You can also establish a simple rule for quick mental use.
One pound or 16 ounces of a fertilizer in 100 imperial gallons of water will give
you ppm 10 times the value of the fertilizer grade. For example one pound of 2010-20 fertilizer in 100 gallons of water gives you 20 x 10 ppm of nitrogen, 10 x 10
ppm of phosphoric acid and 20 x 10 ppm of potash.
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If you use U.S. gallons then use a multiplication factor of 0.75 instead of 0.62 If you like
metric units to calculate parts per million of an element then use the following formula:
*
OR
Example
I want to make a nutrient solution containing 130 ppm of nitrogen using potassium
nitrate which is 13-0-44.
- ppm desired 130 ppm of nitrogen
- amount of water 100 litres
- grade of fertilizer 13 percent nitrogen
Using the above formula: 130 x 100 = 100 grams
13 x 10
I also have 44 percent potash with the fertilizer I used. I want to find out how much
potash I have. Using the formula:
-
We can use the same rule for quick mental calculation as we did for imperial gallons.
One hundred grams of a fertilizer in 100 litres of water will give you parts per million
equal to 10 times the grade of the fertilizer.
Example
-
One hundred grams of 13-0-44 in 100 liters of water will give you 130 ppm of
nitrogen and 440 of potash.
REMEMBER: 100 grams/100 liters of water is the same thing as one pound in 100
gallons of water. This is because one pound weighs 450 grams and 100 gallons
equal 450 liters of water.
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SOLUBILITY OF FERTILIZERS
Solubility of fertilizers differs in cold and hot water. That can play an important
role when you are preparing a fertilizer program in a stock tank. That is, you
have to prepare a fertilizer solution several times stronger to go through the
injector. Here are the solubilities of various fertilizers:
Solubility of Fertilizers in grams/100 mL of water
Fertilizer
Formula
Cold
Hot
Urea
46-0-0
78.0
Ammonium nitrate
34-0-0
118.0
871.0
Ammonium sulfate
21-0-0
70.0
103.0
Calcium nitrate
15.5-0-0
102.0
376.0
Potassium nitrate
13-0-44
13.0
247.0
Potassium chloride
0-0-60
34.0
56.0
Potassium sulfate
0-0-50
12.0
24.0
Monoammonium phosphate
11-52-0
22.0
173.0
26.0
73.0
1.6
14.0
31.0
203.0
105.0
111.0
Ferrous sulfate
15.0
48.0
Sodium molybdate
56.0
115.0
Magnesium sulfate
Borax
Copper sulfate
Manganese sulfate
80-0-0
46-0-0
34-0-0
34-0-0
21-0-0
15.5-0-0
21
Potassium nitrate
Sodium nitrate
13-0-44
15-0-0
Phosphorus
Monoammonium phosphate
Diammonium phosphate
Monopotassium phosphate
11-52-0
21-63-0
0-53-34
Potassium
Potassium nitrate
Potassium sulfate
Potassium chloride
Monopotassium phosphate
Potassium bicarbonate
Potassium silicate
13-0-44
0-0-50
0-0-62
0-53-34
0-0-46
0-0-12
Calcium
Calcium nitrate
Calcium chloride
Calcium carbonate
Calcium hydroxide
Dolomite lime
15.5-0-0 + 19 percent ca
18 percent ca
38 percent ca
54 percent ca
22 percent ca
Magnesium
Magnesium sulfate
Magnesium nitrate
Dolomite lime
10 percent mg
9 percent mg
9 percent mg
Fe 21 percent
Fe 13.2 percent + 68 percent EDTA
Fe 7.0 percent + 48.6 percent DTPA
Manganese
Manganese sulfate
Manganese chelate
21
Mn 29.5 percent
Mn 13.0 percent + 68 percent EDTA
22
Copper
Copper sulfate
Copper chelate
Cu 25 percent
Cu 14 percent + 63 percent EDTA
Zinc
Zinc sulfate
Zinc chelate
Zn 35 percent
Zn 14 percent + 62 percent EDTA
Boron
Boric acid
Borax
B 17.5 percent
B 15.0 percent
Molybdenum
Sodium molybdate
22
Mo 46 percent
23
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1) If you have a large tank in which you mix fertilizer then you will know how
many gallons or liters the tank is. Sometimes the tank capacity is indicated in
U.S gallons.
2) If you are using an injector system then know the size of the stock tank and
dilution rates. For example if you have a 200 L stock barrel and dilution rate is
1 to 200, then you will multiply 200 with 200 and that will give you a volume of
40,000 liters of water.
3) New irrigation systems have a very small mixing tank and water is added
based on the demand by the irrigation area. Fertilizers are added by a
computer using electrical conductivity as a guideline. In such cases proper
fertilizer mixing is done in stock tanks where you choose the concentration.
Once in a while the nutrient solution should be analyzed to make sure you are
delivering to the plant what you think you are.
Now we are ready to design a fertilizer program with following nutrient
concentrations at plant delivery point:
Nitrogen
Potassium
Magnesium
Iron
Copper
Boron
200
350
70
3.0
0.15
0.25
ppm
ppm
ppm
ppm
ppm
ppm
Phosphorus
Calcium
Sulfur
Manganese
Zinc
Molybdenum
40 ppm
150 ppm
100 ppm
0.8 ppm
0.2 ppm
0.12 ppm
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40,000 liters in the formula or multiply the 100 liters figure with 400 to get the final
amount of calcium nitrate to be used. That will equal to 31.6 kg. This amount
will be dissolved in 200 liters of stock tank.
Step 4
Find out how much nitrogen you got by using 79 grams of calcium nitrate in 100
liters of water. The formula is:
grams of fertilizer x grade x 10 = ppm
Amount of water in liters
79 x 15.5 x 10 = 122 ppm
100
So calcium nitrate contributed 150 ppm of calcium and 122 ppm of nitrogen. We
still require 200 - 122 = 78 ppm of nitrogen.
Step 5
Get all your phosphorus from mono potassium phosphate 0-53-34. Remember
53 percent is phosphate and we have to convert it to phosphorus by multiplying
53 percent by 0.43 and that will equal 22.8. That is the figure we will use for our
phosphorus calculation.
Using the ppm desired formula:
40 x 100 = 17.5 grams
22.8 x 10
Make adjustments for the amount present in your water.
Step 6
Calculate the amount of potassium you got from 17.5 grams of 0-53-34 in 100
liters of water. Remember 34 percent is potash not potassium. Multiply 34 with
0.83 to get potassium which equals 28.2.
Thus ppm of potassium = 17.5 x 28.2 x 10 = 49.3 ppm
100
Step 7
Take the balance of nitrogen, that is 78 ppm, from potassium nitrate which is 130-44.
78 ppm x 100 litres = 60 grams
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13 x 10
How much potassium is obtained from 60 grams/100 liters of potassium nitrate
13-0-44? Remember 44 percent is potash and it will be 36.5 percent potassium.
60 grams x 36.5 x 10 = 219 ppm
100 liters
Total potassium from steps 6 and 7 is 268 ppm. Total required is 350 ppm.
Thus we still need 82 ppm of potassium.
Step 8
Take this potassium from potassium sulfate 0-0-50 which is 41.5 percent
potassium (50 x 0.83). Using the formula:
82 ppm desired x 100 litres of water = 19.7 grams
41.5 x 10
Now we have satisfied our requirements for nitrogen, phosphorus, potassium and
calcium.
Step 9
Take all your magnesium from magnesium sulfate which is 10 percent Mg.
50 ppm desired x 100 litres of water = 50 grams
10 percent mg x 10
Step 10
Calculate how much sulfur you got from potassium sulfate and magnesium
sulfate. Potassium sulfate has 18 percent sulfur while magnesium sulfate has 12
percent sulfur.
Sulfur from 19.7 grams of 0-0-50:
19.7 x 18 x 10 = 35.4 ppm
100 litres
Sulfur from 50 grams of magnesium sulfate:
50 x 12 x 10 = 60 ppm
100 liters
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Thus total sulfur is 35.4 + 60 = 95.4 ppm which is close to our 100 ppm of
requirement.
Step 11
Iron required is 3 ppm and will use 13 percent iron chelate:
3 ppm required x 100 liters = 2.30 grams
13 percent iron x 10
Step 12
We need 0.8 ppm of manganese from manganese chelate which is 13 percent
manganese.
0.8 ppm desired x 100 liters = 0.61 grams
13 percent mn x 10
Step 13
We need 0.15 ppm of copper from copper chelate, which is 14 percent copper.
0.15 ppm desired x 100 liters = 0.10 grams
14 percent cu x 10
Step 14
We need 0.2 ppm of zinc from zinc chelate which is 14 percent zinc.
0.2 ppm desired x 100 liters = 0.14 grams
14 percent zn x 10
Step 15
We need 0.25 ppm of boron from borax, which is 15 percent boron.
0.25 ppm desired x 100 litres = 0.16 grams
15 percent b x 10
Step 16
We need 0.12 ppm of molybdenum from sodium molybdate which is 46 percent
molybdenum.
0.12 ppm desired x 100 liters = 0.026 grams
46 percent mo x 10
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This completes our requirements for all nutrients. You may have noticed that
trace elements are required in very small quantities and it will be difficult to weigh
them. You make strong solutions called stock solutions.
What is pH?
pH is a measurement of the acidity or alkalinity (base) of a solution. When
substances dissolve in water they produce charged molecules called ions. Acidic
water contains extra hydrogen ions (H+) and basic water contains extra hydroxyl
(OH-) ions. pH is measured on a scale of 0 to 14. Neutral water has a pH of 7.
Acidic water has pH values less than 7, with 0 being the most acidic. Likewise,
basic water has values greater than 7, with 14 being the most basic. A change of
1 unit on a pH scale represents a 10 fold change in the pH, so that water with pH
of 6 is 10 times more acidic than water with a pH of 7, and water with a pH of 5 is
100 times more acidic than water with a pH of 7. That is the reason why It takes
longer time to adjust the pH of the growing medium. pH constantly changes
during the crop duration and must be monitored regularly. Also growers must
know the optimum ranges of pH for the crops they are growing.
Why it is important?
It is important because the uptake of nutrients depends on proper pH in the
growing medium.
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5.5 - 6.5
Soil-based mixes
6.0 - 6.8
Rockwool
5.8 - 6.4
Nutrient solution
5.5 - 6.5
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the growing medium. Many irrigations may be required. Rinse leaves after
application. If pH is on alkaline side then adjust the pH of the fertilizer solution to
around 5.5 or start using fertilizers with higher ammonium nitrogen.
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Plants like Petunias, Bacopa, Scaveola and Calibrachoa are iron inefficient
groups of plants and if pH goes over 6.5 they will show Iron deficiency. Plants
like Geraniums and New Guinea Impatiens are iron efficient group of plants and
will show iron toxicity at pH below 5.5. Availability of trace elements like iron,
manganese, copper, boron and molybdenum is up to 4 times higher when pH
moves to acidic side and lower when pH moves to alkaline side.
EC
Distilled water
not measurable
Edmonton water
Well water
Fertilizer solution
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= need fertilizer
= maintain feed
= caution
A higher EC can be maintained if plants are vigorous and demand more fertilizer
but you have to keep the growing medium moist.
Once the seedlings are planted in the final container then EC will be managed
based on light conditions. Higher the light, lower will be the EC.
Here are couple of examples where very high EC affected the growth of crops.
This grower grows spinach and lettuce for farmers market in winter with some
supplemental light in bedding plants trays. Once the harvest is completed, the
growing medium is reused. The plants are very dark green in color and very
compact. They are not stretching.
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Notice the leach E.C. Below 3.0 millimhos is normal for winter production. The
grower mixed the old growing medium with the new one without leaching and
that is the result.
Growers must invest in a good pH and E.C meter and monitor the crop regularly
especially crops like petunias and geraniums.
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