Académique Documents
Professionnel Documents
Culture Documents
Paper 2
From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students from Classroom
/Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
FIITJEE
Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1.
2.
3.
4.
5.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Parts.
Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
Each part is further divided into three sections: Section-A, Section-B & Section-C
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
Enrolment No.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
Useful Data
PHYSICS
2
g = 10 m/s
Planck constant
Charge of electron
e = 1.6 1019 C
Mass of electron
me = 9.1 1031 kg
Density of water
Atmospheric pressure
Pa = 105 N/m2
Gas constant
R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant
Avogadro's Number Na
Plancks constant h
1 Faraday
1 calorie
1 amu
1 eV
=
=
=
=
=
=
=
=
=
=
8.314 J K1 mol1
0.0821 Lit atm K1 mol1
1.987 2 Cal K1 mol1
6.023 1023
6.625 1034 Js
6.625 1027 ergs
96500 coulomb
4.2 joule
1.66 1027 kg
1.6 1019 J
Atomic No:
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Physics
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
PART I
SECTION A
Single Correct Choice Type
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1.
the bottom of container. The velocity v of the particle relative to the box
after time t is
(A) u cos i + (u sin gt) j
(B) (u cos gt sin ) i + (u sin gt cos ) j
(C) u cos i + (u sin gt cos ) j
(D) u cos i + u sin j
2.
3.
T3
5 kg
T2
50 kg
50 kg
1 = 0.3
2 = 0.9
T1
D
50 kg
A simple pendulum of bob of mass m and length has one of its ends fixed at
the centre O of a vertical circle, as shown in the figure. If = 60 at the point P,
the minimum speed u that should be given to the bob so that it completes
vertical circle is
(A) g
(B) 2g
(C)
5g
2
(D)
P
m
3g
2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
4.
A rod of mass m and length is lying along the y-axis such that one of its ends is at the origin.
Suddenly an impulse is given to the rod such that immediately after the impulse, the end on the
origin has a velocity v0 i and the other end has a velocity 2v 0 i . The magnitude of angular
momentum of the rod about the origin at this instant is
3
2
(A)
mv0
(B)
mv0
3
2
5
7
(C)
mv0
(D)
mv0
6
8
Multiple Correct Answer(s) Type
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE or MORE are correct.
5.
6.
y
Am
D
O
v0
11 2
(B) kinetic energy of the system is
mv 0
4
(D) | v C vB | = | vB vD |
Consider one dimensional collision between two identical particles A and B. B is stationary and A
has momentum P before impact. During impact, B gives impulse J to A. Choose the correct
alternative(s)
(A) the total momentum of the (A + B) system is P before and after the impact and (P J) during
the impact.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
7.
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
rd
R1
3
R2
3
R3
2
R4
2
R5
2
st
8.
Energy liberated in the deexcitation of hydrogen atom from 3 level to 1 level falls on a photo
cathode. Later when the same photocathode is exposed to a spectrum of some unknown
nd
hydrogen like gas, excited to 2 energy level, it is found that the deBroglie wavelength of the
fastest photoelectrons, now ejected has decreased by a factor of 3. For this new gas, difference
of energies of 2nd Lyman line and 1st Balmer line is found to be 3 times the ionization potential of
the hydrogen atom. Select the correct statement(s) :
(A) The gas is lithium.
(B) The gas is helium.
(C) The work function of photocathode is 8.5 eV.
(D) The work function of photocathode is 5.5 eV.
9.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
SECTION - B
Matrix Match Type
Longitudinal waves are produced in five identical rods in different situations. Their mode of
vibration and fixed points (with bold point) are shown in the column II, and their frequencies are
given in the column I, match the frequency in the column I with the appropriate situation in the
column II. Each of the rods has length 1 m youngs modulus of elasticity, 2 1012 N/m2 and
density 5 103 kg/m3.
Column-I
Column-II
(A)
10 KHz
(p)
Second overtone
(B)
15 KHz
0.5 m
(q)
Fundamental mode
(C)
25 KHz
0.5 m
(r)
First harmonic
(D)
45 KHz
(s)
2/3 m
Fundamental mode
(t)
2/3 m
Third harmonic
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2.
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
Medium I
( 1)
Medium II
( 2)
C (R, 0)
Positive
X-axis
Spherical
interface
(p)
Column II
Image may be real
(q)
(r)
(s)
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
SECTION C
Integer Answer Type
This section contains 8 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown.
1.
S1
9 10 m
, where, is the wave length in meter. A beam of light
2
S2
Two particles A and B are located at points (0, 103) and (0, 0) in xy plane. They start moving
3.
4.
L = 3mH
B = 0.1T
R = 0.01
= 2 rad/sec. Find the magnitude of this torque (in N-m) at t = (0.3 ln2) second.
Space for Rough work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
5.
Two sound waves of frequencies 100 Hz and 102 Hz and having same amplitude A are
interfering. A stationary detector, which can detect waves of amplitude greater than or equal to A,
So, in a given time interval of 12 seconds, find the total duration in which detector is active.
6.
Two identical metallic sheets each behaves like a black body are kept parallel to each other with
small separation between them in vacuum. Thermal energy is generated at a constant rate P in
one of the sheets by a passing electricity in it. In steady state, temperature of the other sheet is
found to be constant is 300K. Find the value of P in Kilo-Watt.
(Given area of the plates A =
7.
8.
17
103
2
m and =
108 w/m2K4)
17 27
3
In the adjacent figure, ABCD are four points in a smooth horizontal plane
representing the four corners of a square of diagonal 20 cm. A very small
object of mass 14 gm placed at the centre of the square connected to
points A, B, C and D by four elastic strings of same dimensions but of
different moduli of elasticity as shown in the figure. Natural length and
cross-sectional area of each string are 10 cm and 2 106 m2 respectively.
The mass is slightly displaced from equilibrium and then released to
perform SHM along the diagonal AC. (Y1 = 9Y, Y2 = 4Y, Y3 = 16Y and Y4 =
4Y, where Y = 4.9 109 N/m2). The time period of oscillation of object is k
millisecond. The value of K is
Two identical equi-concave lenses made of glass of reflected index 1.5,
placed in contact has power P. When a liquid of refractive index is filled in
the gap between the concave lenses, the power becomes of initial value(P/3).
K
The value of is . Find the value of K.
3
B
Y1
Y2
Y4
Y3
C
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
Chemistry
10
PART II
SECTION A
Straight Objective Type
This section contains 4 multiple choice questions numbered 1 to 4. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
1.
The correct order of reagents required to bring the following change is:
COOH
CH3
OH
+
2.
3.
4.
1 mole of a gas AB3 present in 10 lt container at pressure 2.5 atm and 273 K temperature. On
increasing the temperature to 546 K, AB3 dissociates into AB2(g) and B2(g). If the degree of
dissociation of AB3 is 80%, then final pressure at 546 K is :
(A) 5 atm
(C) 10 atm
1 mole of each of CaC2, Al4C3, Mg2C3 reacts with excess water in separate open flasks work
done during dissolution shows the order :
(A) CaC2 = Mg2C3 < Al4C3
In which of the following pairs the two species are not isostructural?
(A) PCl4+ and SiCl4
(B) PF5 and BrF5
3
(C) AlF6 and SF6
(D) CO32 and NO3
Rough Work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
11
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
Which of the following reactions are correctly matched with products (major)?
O
C
Ph
(A) PhMgBr
(i)
ii
H3 O
Ph
Ph
OH
(i) CH3CN
(B)PhMgBr
(ii) H3O
(X)
(i) CH3Li
(ii) H 3O
Ph
CH3
CH3
O
(C) PhMgBr
(i) H
CH3
(ii) H3O
(D) PhMgBr
Pure enatiomer
CH2
CH2
(i)
O
(ii) H3O
6.
PhCH2CH2OH
(C) Fe + I2 Fe + 2I
7.
(B) ZnCl2
(C) HgCl2
(D) AgCl
Rough Work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
8.
12
O
||
NH2 CH C NH CH2 CO2H
|
CH3
9.
(A) Glycine
(B) Phenylalonine
(C) Alanine
(A) NH 4 ClO4
H
(B) KIO 3 N 2 H 4
(C) HN 3 HNO2
(D) NH 2 OH CuO
Rough Work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
13
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
SECTION-B
(Matrix Type)
This section contains 2 questions. Each question contains statements given
in two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as
illustrated in the following example:
2.
NaCl
CsCl
CaF2
S 2 O3 2
BF3
H 2 C SF4
(p)
(q)
(r)
(s)
(t)
Frenkel Defect
Crystallographic C.N = 4
Insoluble in water
8 nearest neighbours of the cation
(p)
Column II(characteristics)
sp 2
(q)
sp 3
(r)
(s)
Back bonding
sp 3 d
(t)
Coordinate bond
Rough Work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
14
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
SECTION C
Integer Answer Type
This section contains 8 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown.
1.
The total number of cyclic, structural isomers for a compound with molecular formula C5H10
is______.
2.
The equivalent weight of Zn(OH)2 in the following reaction is equal to its M/x :
Zn (OH)2 + HNO3 Zn(OH) (NO3) + H2O
X is equal to ___________.
3.
The number of ions formed when cuprammonium sulphate is dissolved in water is _______.
4.
How many visible lines are emitted during transition from 5th orbit to ground state in hydrogen
emission spectrum?
5.
The half life of two samples of a substance is 50 sec and 200 sec at 0.4 M and 0.1M
concentrations, respectively the order of reaction is __________.
Rough Work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
15
Et
6.
Ph
CH3
HO
OH
Et
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
HO
OH
H2SO 4
CH3
Ph
Ph
Ph
The total number of pi-bonds in pyrene responsible for its aromatic behaviour are:
O
OH /H2 O
O
Double bond equivalent of final product is ...............
Rough Work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
Mathematics
16
PART III
SECTION A
Straight Objective Type
This section contains 4 multiple choice questions numbered 1 to 4. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.
1.
2.
3.
Tangents PA and PB are drawn to the circle x 2 + y2 = 4 from an external point P lying on the line
2
y = x such that the angle between the tangents satisfies
3
3
(C) (2, 2)
4.
(A)
2i
in the straight line z(1 + i) = z (1 i) is
3i
2 i
(B)
3 i
2i
(D)
3 i
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
17
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
Two players A and B toss a coin which has a probability p of showing head (0 < p < 1), in the
cyclic order A, A, B, A, A, B, .. till a head appears. Let x denotes the probability that A gets the
head first and y that of B, then
(A) x + y = 1
(B) x > y for all p
1
1
(C) x >
for all p
(D) y >
for all p
2
2
6.
7.
A plane meets the co-ordinates axes in A, B, C such that the centroid of the triangle ABC is the
point (1, r, r2). If all such planes must pass through the point (t, t, t) for all r R {0}, then t can
satisfy
(A) 0 t 4
(B) 1 < t 4
(C) 2 < t < 3
(D) 0 < t 4, t 3
8.
The value(s) of satisfying the equation [sin(cot1 cos tan1 x)] = sin , (where x R and [.]
denotes the greatest integer function) is/are
(A) 0
(B)
2
3
(C)
(D)
2
9.
Let f(x) = (ax + b)cos x + (cx + d)sin x and f(x) = x cos x for all x R, then
(A) a = 1
(B) b = 1
(C) c = 1
(D) d = 1
Space for rough work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
18
SECTION-B
(Matrix Type)
This section contains 2 questions. Each question contains statements given
in two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as
illustrated in the following example:
(B)
(C)
(D)
2.
Column I
Two sides of a triangle are given by the roots of the equation
Column II
(p)
12
(q)
15
(r)
3
7
(s)
1
5
(t)
2
3
Column I
The coefficient of two consecutive terms in the expansion of (1 + x)n
will be equal, then n can be
n
n
If 15 + 23 is divided by 19, then n can be
10
C020C10 10C118C10 + 10C216C10 .. is divisible by 2n, then n can
be
If the coefficients of Tr , Tr 1, Tr 2 terms of (1 + x)14 are in A.P., then
Column II
(p)
9
(q)
(r)
10
11
(s)
12
(t)
14
r is less than
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
19
AITS-FT-IV(Paper-2)-PCM-JEE(Advanced)/14
SECTION C
Integer Answer Type
This section contains 8 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The appropriate bubbles below the respective question
numbers in the ORS have to be darkened. For example, if the correct answers to question
numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening of
bubbles will look like the as shown.
1.
If the function f(x) = 2x 3 9ax2 + 12a2x + 1 has a local maximum at x = x 1 and a local minimum at
x = x2 such that x2 = x12 , then a is equal to _____
2.
xy
yz
is equal to
2y x 2y z
_____
3.
The number of odd proper divisors of 24300 is N + 11, then N is equal to _____
4.
5.
The number of normal(s) to hyperbola which can touch its conjugate is equal to _____
6.
7.
logex2
For y cot 1
2
loge / x
8.
For real valued function f(x), f(x) + f(x + 4) = f(x + 2) + f(x + 6), g(x) =
d2 y
1 3 2ln x
, the value of
at x = 1, is equal to _____
tan
dx 2
1 6ln x
x8
equal to _____
Space for rough work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com