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Name:
CHEMISTRY
- PAPER 1
INSTRUCTIONS TO GANDIDATES
Write your name, Centre number and candidate number on the answer sheet in the
Spaces provided.
There are forty questions in this paper. Answer alt questions, For each question, there are
four possible answers, AB,G and D. Choose the one you consider correct and record your
choice in soft pencil on the separate answer sheel
' Read very caiefully the instructions on the answer sheet.
Each correct answer will score one mark. A mark will not be deducled for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is printed on page 16.
This Question Paper consists of 16 printed pages including the cover page.
flurn over
1. The best representation of a mixnue of ar_eon and heiium inside a balloon is
shown by diagram:
@@@ffi
Gas X was passed through a U-tube irnrhersed. in an ice mixture. The gas
conciensed into a colourless liquid-
A (D, CID, @)
B (D, @), @)
c (tr), cD, @)
D @), @), CD
se'parated' using paper cbromatography: The cbromatoglams
A
A substance X was
are shown below'
Jeveloped using water and ethanol
solvent front
(al (b)
5.Fivestrrdentseachdissolvedanindigesdonta.'b.letTigoT,ofwater.Theythen
each titrated zio"d-"i,rteir soiutioins
with dilule hydrochioric acid' using the
the table'
same indicator. The results are shown in
A Lrer 1 lL ) l4
Tikation value / ffn' 20.4 I 20.5 7r;120.6 122-0
-Whichstatementcouldexpiaintheresultobtainedbystudentnr:mber5?
acid-
A The burette was washed out vrith hydrochloric
B The pipette was wasbed out with tablet solution'
of the pipefce'
C The student m"^sur"d to the top of the meniscus
DThetitradonflaskwaswashedoutwiththetabietsolution.
6.Wbichoneofthefollowingcorrectlydescribestheparticlesinadilutesait
solution at room temPerature?
Salt ions
I ciose movine at ragdom
A ciose
B close toeethen viblq'u4g sli
*rd"lY seaxarcd: mor-ing at random
\- wideiv ssDarared: not : o1'ng
5 widelv separareq-me1-lgg 3!gg
This is the srable $ructure sf salglrrrn ign.
I
I
I
I
I
I
I
l
L
It follows tbat an atoo of caicir:m contains
A 20protons, 20 electrons and20neutrons.
B 20protons, 18 elecEons aad20neutrons-
C 20protons, 18 electrons and 18 Deutrons.
D 18 protons, 18 electons and 18 neurons-
8- Z is the atomic number of a noble gas in the periodic table and (Z+L) afi(Z-1)
are the atomic numbers of the elements X and Y respectiveiy. If the elements X
au<l Y are to combine, which-willbe the most likel;r formuia of the compouod-
formed?
AXY
B X;Y
C XYz
D X2Y
t1
T I. The tabie below shows the melting and boiling points of.sulphr:r, lead@) bromide
and hydrogen chioride.
:-F-{-:
---------
beaker 1 bcaker 2
(25'C) (4O0'C)
Whicb one of the following correctly describes the substances presentin beakers
L an(l-.L!
are there in
of x molecuies' how manY molecules
L4- If 1i g of carbon dioxide colsist
7 g of nit'ogen gas?
Yzx
B
C
A*
D
1i Whatisthemaximrrmmassofcalcir:moxidetbatcanbeobtainedbyheating15
of li-*oo" which is 80% Prne?
A 6.72 g
B 8.40 g
C 10.92 g
"D r2g
16.Chlorideionsreactwitb'siiverionsaccordingtothefollowingequation:
B3i
c32
D
18'Whichofthefollowingstate,meltsabouteiectrolysisofdilutesulphuricacidwith
platinr.tm electrodes is not correct?.
A Th" OH-;;; ; preferentiallv discbarged at tfe anode'
as electrolysis proceeds'
B The sulphr:ric acid becom", Jor"-"ooclntrated respectivelv are in the
c nt" g.t:;;;i""t"a ot'o th";;;;;d the anode
Ptatinum eiecfodes
d€ar cepp€rtll)
iellY cfiromate
Why is a blue colour observed near the negative elect'ode after some time?
A Copper@) chromate is an electrolyte
B The jeliy conducts elecricity.
C Chromare ions are biue in colour.
D Copper@) ions migrate ro the cathode.
2'1 The following observations were made when nickel and iron were put separately
into solutions of salts of three metals P, Q and R
Solution
\of Salt of P Salr of Q SaIt of R
Metal
Nickel Yes: disolaced Nor displaced Not displaced
Iron Yes; displaced Yes; dispiaced Not displaced
carFn Bleclrodes
=
After each additio3, fre-sol-u-tio4 was s{r-red arrd-&e-4mmelerreading noted.,
Which one of the following gaphs corectly represents the reiationship between
the voiume of acid added and the ammeter reading?
d o o
'A l*"rg
I
I &cr(si
l-f
rl
tt
I,- | ** i=s).+ cl-'("e)
-
3 | "nerg
I
I NcNq, (i{)
lr
tlrl
I
I
| -Na+'6iq1 + Nol-
ll- (cs)
enersr
I -kcrtsr
DT eD.ersrj
I
I *** ,""
IU
25. Which sait can be e$trinsd as the insoiuble product of a reaction beween a dilute
icid and an aqueous salt?
A barium suiphate
B copper@) sulphate
masesiuo sulphate
D silver nitrate
26. The rate of reaction between pieces of zinc foil and- 1 moVdo3 hydrochloric acid
was investigated by_recording the total volume of gas produced every minute over
a period of time. The results are sbown in the graph. The zi''c had completeiy
reacted in the reaction-
*u-"rrr
sas,itit
50.
4B
30
What results would be expected. if the experiment was repeated using the same
mass of zinc (same size lumps) andthe srme volume of 2-0moVdm'hydrochloric
acid at the same te'mPeratr:re?
i1
27. Which starement best explainq wby coal dust forms an explosive mirture with air?
at CDc
B CzD:OD
L CaOD
D DCI
29. The apparatus shown in the diagram was used to investigate the rusting of moist
iron.'Th" tube contained 100 cm3 of air at the start of tbe experimenf
B U D
volrna st gas vottna cC Atrs rclunc cd gns bLEmof !,<
uminirg/ crf rsnainhg ./ drf rstrairir€ / mt unlning/qrf
1O0 {
1 _..-.-
I
'1
.n]
--l
Jt
I
I
oL_"*------
lime
L2
30- Chlorinc is passed.into an aqueous solution of a compormd. Z. At first a brown
colorr is see,r and the,n a blackprecipitate appears- What could Z be?
A ammonir:mhYdroxide
B iron(tr) sulPhate
C Potassir:mbromide
D poussium iodide
32. . Four reactions are given below. In which one is the rmderiined substance acting
as a reducing agent?
A hydrcgen * copoer0toxide') copper + water
B sulphuric acid + magnesium oxide ) magnesium sulphate * watgr
C zinc oxide * carbon monoride ) carbon dioxide + anc
D iron@) chloride + chlorine ) iron(m) chloride
33- The formulae of catalysts used in some important indusuial processes are given in
the table-
13
^,
5+. The stnrctr:ral formulae of three organic compormds &Y,and Z arc shoqrn below.
xYZ
HHH .HHH H HH
lll lll
H-C -C -C-H
ttl
H-C-O-C-C-H
H-O-C-C-C-H
lll
HHH HOH
ttl tlr
H HH
I
35. Propaae gas is cracked to produce two hydrocarbons. One of them is methane sas
and the other gas is Q- Wbat is the stnrctr:re of Q?
HH .B H H
tl
II
H-C-C-H t-t
ttl- I
H-C:'C-H
HH
DHIIH.H.
CFTHH
lrl ltrl
H-C-C-C-C-H
H_C-=C-C_H
ttt trtl
HHHH
HH.H
JO- Olive oil contains oleic acid- Oleic acid. is an unsafirrated acid *U"n has tbe
moiecular formula Cr zHl r COzH. How many carbon-carbon double bouds are
present in one molecule of oieic acid?
A1 B2 t-J D4
1 r'l
l-
37 . bottle of wine or beer is left standing in the air for some time, it becomes
.When a'Which
acidic. equation describes the reaction that takes place?
'What
38. The second mernber of a homologous series has the formula CzHs. is the
formula of the first member of this series?
A C6iJ6
B C6I{8
C CtHs
D CeHro
'Which set contains tbe correct process for converting substance S,to the
40.
product(s)?
End ofpaper
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Candidate
uenre Numoer Numoer
Name:
Ghemistry 5068
_ PAPER 2
PRELIMINA,RY EXAMINA.TION
Section A
Answer atl questions.
Write your ansu/ers in the spaces provided on the question paper.
Section B
Answer allthree questions, the last question is in the form of eitherlor.
Write your answers on the lined paper provided.
At the end of the examination, tie the answers of section A and B together.
The number of rnarks is given in brackeG[ ] at the end of each question or part
question-
A copy of the Periodic Table is printed on page 15
This Question Paper consists of 15 printed pages including the cover page.
ffum over
SectionA(50marks)
A-nswer all the questions in this section in the spaces provided.
(iii) Showing only the vaience electrons, draw a ldot and 6xsss' diagram oftle
compound namsd in (ii) above. [1m]
(iv) If lumps of phosphon:s are left in contact with aA thgy start to burn-
Explain why this is unexpected in the iight of your knowledge of
nitrogen. [2m]
A2 A snrdent prepares a soiution of ethanol as showa below-
(ii) The shrdent wants the process to go frster and heats tbe flask- Explain
u&y this may not be a good idea. . [1m]
(c) After the yeast is removed Aom the solution when the reaction has
stopped, the ethanoi is separared from the solution by disullation.
HH
tl
tl
rH<-+{
' ll
oo
tl
ll
HH
Whe,n one mole of water is added to one mole of epoxyethane, one mole of
gthane-l, 2 - diol is formed as the only producl
(b) Etlane-l, 2 -diol when dissolved in the water in the radlator of a car acts
as an antifreeze. Ethane-1, 2 -diol freezes at -14oC and boiis at 19fC.
When a sample of the liquid taken from a radiator that contained water
and antifreeze was cooled dowg clystais first appear at atenperature
of -21oC and not at -14oC. Give a probable eiplanation forthe
observation. [1m]
A4 An organic compound, W, contains 37.5oA carbon andT25Yohydrogen, by
maqs- The rest is oxygeo-
Electroiysis
sphalerite- [1m]
(ii) Explain why the sulphr:r dioxide fomed should not be allowed to escape
into the air for econornic and environme,ntal reasons. [2n]
.cconouuc reasons:
Environmental reasons :
(iii) Descnbe experiments you could carry out and statetle results you
would obtain to confrm the prese,nce of zinc sulpbate. [4m]
O) Zinc blocks are anached to the steel hulls of ships, as shown in the
diagram-
(ii) What would be the effect of using copper blocks instead of zinc? [hn]
AO The dia-e5am below shows an indusrial ceii forthe manufacture of sodium anA
chlorine by rhe eiecrolysis of noiten sodium chloride.
Moltea Moltea
soorum sodium
--
_
- =_H__l-+-==l
= -:--^ - l--;r r=-l =. Moltcn
oirturc
conuining
----i i-=;-l;i l--.r-- sodium
(a) in the diagram above, labei the elecrodes A, B and C rdth + or - .ls
appropriate inthe circles below the electrodes. [lm]
(b) Write an eqrufion of the reaction that occurs at A-
[1m]
(d) Suggest why the hood does not exrend to the botom ofthe cell.
liml
(e) Why must tbe sodir:m chioride be molten and not solid?
[lm]
(g) why must all the air be excluded from the parts of the ceir iabelled x?[lm]
(h) Electrodes A and c are made of steel but B is made of graphite- Explain
why electrode B is not made of steel [1m]
A1
nt This question is mainly concerned wiih air pollution
What is the protective part of the earth made of and explain why this parr
is important? [2n]
(b) Vehicles are fined with catalytic converters which change exhaus gases
such as carbon monoxide and nitrogen monoxide into a more acceptable
form of emission
To
atnosphere
EXHAUST
G45ES -J
TO
ATilOSPHERE
CATALYTIC CONYEFTER
(a)'State the colotr cbange you wor:ld see when ]vfnO+ reacts with the
hydrogenperoxide. [1m]
(b) type of chemicai change happens to the lrdnOr- in the reaction? Give'
' ' What
ureasooforyouranswer. [2m]
10
Section B (30 mad<s)
The tast quesrion is in the form of either/or and only one of the alternatives should be
anempted.
89 (a) iron, nicket and platinum can act as calysts. Severai indr:strial reactions
use cataiysts to iower the cost of the manufrcn:red products.
(iv) E>plam how a cataiyst is abie to lower the cost of some manufrctured
products [2m]
(b) Fineiy powdered. iron can be used as a catalyst for the laboratory
decomposition ofhydrogen peroxide.
:
ZHzAz-+ZHzO + Oz
Hydrogcn
Thermometer
l(D crn3 measuring
cylindcr
Wire
Time in seconds u i0 20 30 40 fU 50
Totai volume ofhydrogen in Stud€nt A 0 24 39 48 )5 55 ff
cmt Student B 0 9 35 62 81 95
(i) On the same axes, piot a graph of totai volume ofhydrogen obtained
against time for snrdents A and B- L"abel the graph as student A and
snrdent B.
[2m]
'12
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