Selos para Bomba de Acido Sulfurico

Sulphuric Acid:
A Challenge for Materials and Sealing

Systems for Centrifugal Pumps
AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth
Sulphuric Acid:
A Challenge for Materials and
Sealing Systems for Centrifugal
Pumps
Dr. Juergen Weinerth
Friatec AG - Division Rheinhuette Pumpen
Rheingaustrasse 96 98
65203 Wiesbaden, Germany
Sulphuric Acid:

Contents
Overview
Materials
Pump Design & Sealing Systems
Sulphuric Acid:

Overview
Sulphuric Acid
Pump Design
Materials
Sealing Systems
Vertical
Metal
Gland Packing
Horizontal
Plastic
Mechanical Seal
Ceramic
Mag Drives
Hydrodynamic Seal
Sulphuric Acid:

Contents
Overview
Materials
Sulphuric Acid:

Overview
Materials
[C]
300
200
PTFE
l
Plastic
50
PP, Pe1000, PVDF, ETFE
Concentration H2SO4 in %
Fe
sp rretic
allo ecial &
ys me
ta
100
20
nur bis 180C
l i ne
Boiling
08
44
1.
SX
Saramet 35
Lewmet
1.4136S
Siguss
Temperature
Special
metal alloys
like:
1. 44 0
50
8
100
Sulphuric Acid:

Corrosion of Plastic Materials in H2SO4

Materials
Boiling curve H2SO4

350
325
Boiling curve Sulphuric acid
Corrosion curve PP
300
Corrosion curve HD-PE 1000

Corrosion curve PVDF
275
Corrosion curve PTFE / PFA

Corrosion curve ETFE
250
Temperature [C]
225
200
175
150
125
100
75
50
25
0
10
20
30
40
50
Concentration [% ]
60
70
80
90
100
Sulphuric Acid:

Corrosion and Rotation Speed

Materials
100
Corrosion rate in mm per year

mm/a
25 C
10
4 m/s
1
2 m/s
0 m/s
0,1
0,01
0
10
20
30
40
50
60
70
80
90
Concentration in % H2SO4
Corrosion rate of SS 316 for different concentrations of H2SO4 at

different rotation speed.
100
Sulphuric Acid:

Contents
Overview
Materials
Sulphuric Acid:

Overview
[C]
300
Vertical or
Hydrodynamic
200
Temperature
Sealing
Systems
Mag-Drive
Boiling
100
l i ne
Mechanical Seal
50
20
Concentration H2SO4 in %
50
100
Sulphuric Acid:

Vertical Strong Acid Circulating Pumps

Pump
Design
Photo: Lewis PumpsTM
Photo: Ensival-Moret
Sulphuric Acid:

Horizontal Weak Acid Plastic Pumps

Pump
Design
Solid plastic
Cast iron armour
Sulphuric Acid:

Plastic Impeller Design

Pump
Design
Sulphuric Acid:

Massive Plastic Casing

Pump
Design
Sulphuric Acid:


Pump
Design
10% H2SO4
with Ni, Cu &
Co powder
Material: PE
T: 70C
Q: 2500 m/h
H: 29 m
Motor: 280 kW
Sulphuric Acid:


Pump
Design
10% H2SO4
with Ni, Cu &
Co powder
Material: PE
T: 70C
Q: 2500 m/h
H: 29 m
Motor: 280 kW
Sulphuric Acid:

Ceramic Pumps
Pump
Design
Cast iron armour

Concret filling
Silicate
ceramic
FrikorundTM
Mixed acids
at any
concentration
with solids
(e.g. TiO2)
Massive ceramic
Sulphuric Acid:

Horizontal Magnetic Driven Pumps

Pump Sealing
Systems
Spacer can
Critical
Components:
-Spacer Can
-Inner Rotor
Materials:
-SX
-Hastelloy C4
-1.4539 (904L)
Inner rotor
Sulphuric Acid:

Hydrodynamic Shaft Seal

Pump Sealing
Systems
&
Unique
Material
Silicon Cast
Iron (15% Si)
Concret
filling
Cast iron armour
Hydrodynamic shaft seal

with up to 3 expellers
Standstill seal:
grease, pneumatic, packing
Silicon cast iron
Sulphuric Acid:

Corrosion Rate per Year

340
320
Source: Rheinhuette technical

information 1
300
280
260
240
220
200
T (C)
Silicon Cast
Iron
(15% Silicon)
180
160
140
120
100
80
60
40
20
< 0,4 mm/a
< 0,1 mm/a
< 0,02 mm/a
10
20
30
40
50
%
H2SO4
60
70
80
90
Siguss is resistant against corrosion of sulphuric acid at all

concentrations and temperatures
100
Sulphuric Acid:

Pumps in a Weak Acid Evaporation Plant

Pump Sealing
Systems
&
Unique
Material
Silicon Cast
Iron (15% Si)
Sulphuric Acid:

Titanium Dioxide Production Sulfate Process

A Special Pump
for a Special
Application
Ilmenit Ore is digested in sulphuric acid

Final Product: white TiO2 pigments
German
History
Sulfate Process
industrially since 1916
Sulphuric Acid:

Titanium Dioxide Production Sulfate Process

A Special Pump
for a Special
Application
German
History
Development of Production Processes for

Titanium Dioxide at Kronos Titan
Prohibition of Ocean Dumping
Chloride Process
Sulfate Process
without spend acid regeneration
Sulfate Process
with spend acid regeneration
Sulphuric Acid:

Weak Acid Dumping at the North Sea

A Special Pump
for a Special
Application
German
History
Sulphuric Acid:

Acid Circulating Pump with an Inducer Impeller

A Special Pump
for a Special
Application
German
History
Cast iron armour
Concret filling
Hydrodynamic shaft seal

with up to 3 expellers
Pneumatic standstill
seal
Silicon cast iron
Sulphuric Acid:


A Special Pump
for a Special
Application
German
History
30 - 80% H2SO4
with metal sulfate
chrystals
T: 50 - 190C
Q: 1500 m/h
H: 3 m
DN 500
Sulphuric Acid:


A Special Pump
for a Special
Application
German
History
30 - 80% H2SO4
with metal sulfate
chrystals
T: 50 - 190C
Q: 1500 m/h
H: 3 m
DN 500
Sulphuric Acid:

Gas Lubricated Shaft Seal for Hot Sulphuric Acid

New Sealing
System
Development
Cardridge seal
Sulphuric Acid:


Selos para Bomba de Acido Sulfurico

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Sulphuric Acid:

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

PP, Pe1000, PVDF, ETFE

nur bis 180C

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Corrosion of Plastic Materials in H2SO4

Boiling curve H2SO4

Corrosion curve HD-PE 1000

Corrosion curve PTFE / PFA

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Corrosion and Rotation Speed

Corrosion rate in mm per year

Corrosion rate of SS 316 for different concentrations of H2SO4 at

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Vertical Strong Acid Circulating Pumps

Photo: Lewis PumpsTM

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Horizontal Weak Acid Plastic Pumps

Cast iron armour

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Plastic Impeller Design

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Massive Plastic Casing

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Horizontal Weak Acid Plastic Pumps

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Horizontal Weak Acid Plastic Pumps

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Cast iron armour

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Horizontal Magnetic Driven Pumps

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Hydrodynamic Shaft Seal

Cast iron armour

Hydrodynamic shaft seal

Silicon cast iron

A Challenge for Materials and Sealing

AIChE Clearwater Convention 2010; Dr. Jrgen Weinerth

Corrosion Rate per Year