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Malik 2
THE SOLID FACTS ABOUT TRANS FATS ARTICLE SUMMARY
2007, pg. 15). Unsaturated fats on the other hand are usually produced by fish and plants. Most natural
unsaturated fats contain cis double bonds meaning on this side in Latin. The opposite of a cis double
bond is the trans double bond meaning across in Latin. In a trans double bond, the hydrogen atoms are
on opposite sides meaning the chains are on opposite sides. Cis double bonds are unique as they create
kinks in the three-dimensional structure of the fat resulting in an awkward stacking of fat molecules and a
lower attractive molecular structure. Because of lower attractive molecular surface, the oils are liquid at
room temperature (Kimbrough, 2007, pg. 15). In addition, cis double bonds are more likely to react with
oxygen in the air than both trans double bonds and saturated fats as cis fats are less stable and more
reactive. Because of this, oxidation of fats breaks the long chains into shorter chains with sticky and
unpleasant tasting products. In 1911, partial hydrogenation was first marketed by Cisco which consisted
of predominantly of hydrogenated and partially hydrogenated cottonseed oil. Partial hydrogenation was
also used to convert corn oils into margarine for a low cost alternative to butter (Kimbrough, 2007, pg.
16). Hydrogenation is the process in which a cis fat is heated at high pressures in the presence of a
catalyst where hydrogen is added across the double bond. This results in a hydrogen being bonded to each
of the double bonded carbons and the double bond becoming a single bond (Kimbrough, 2007, pg. 16).
When all double bonds become hydrogenated, the fat becomes saturated but if only some of the double
bonds are hydrogenated, the fat is referred to as partially saturated. Furthermore, the double bonds that
left unsaturated in a partial hydrogenation become trans rather than cis which is where the name trans fat
comes from (Kimbrough, 2007, pg. 16).
Not until recently have partially hydrogenated fats considered unhealthy as products such as
margarine were promoted as a healthy alternative to butter and provided to patients with heart disease or
high cholesterol. Although saturated fats and trans fats are similar, trans fats behave differently as they are
transported and metabolised (Kimbrough, 2007, pg. 16).
References:
Malik 3
THE SOLID FACTS ABOUT TRANS FATS ARTICLE SUMMARY
Doris R. Kimbrough (2007, December). The Solid facts about Trans Fats. Chem-Matters, pg. 1416