Answers, Hints & Solutions of Test - 6

Comprehensive Study Package for IIT-JEE-2011

TEST-6(AnswerSheet)
Chemistry

Mathematics

Physics

1.

(B)

21.

(A)

41.

(D)

2.

(C)

22.

(B)

42.

(A)

3.

(A)

23.

(B)

43.

(C)

4.

(B)

24.

(D)

44.

(A)

5.

(C)

25.

(A)

45.

(A)

6.

(D)

26.

(C)

46.

(D)

7.

(A, B, C, D)

27.

(A, C)

47.

(A, B, C)

8.

(A, C)

28.

(A, B, C, D)

48.

(B, C, D)

9.

(A, D)

29.

(A, B, C)

49.

(B)

10.

(A, C, D)

30.

(B, C, D)

50.

(A, B, C, D)

11.

(C)

31.

(A)

51.

(B)

12.

(C)

32.

(A)

52.

(B)

13.

(A)

33.

(A)

53.

(A)

14.

(B)

34.

(B)

54.

(A)

15.

(B)

35.

(A)

55.

(A)

16.

A (p, r, s)

36.

A (s)

56.

A (p, q, r, s, t)

17.

B (p, r, s)

B (p)

B (q, r, s, t)

C (p, q, t)

C (r, t)

C (q, r, s, t)

D (p, q, r)

D (q)

D (p, q, r, s, t)

A (q, r)

37.

A (r)

57.

A (t)

B (p, r, s)

B (p, q, r, s, t)

B (p, q)

C (q, r)

C (p)

C (s)

D (q, s)

D (t)

D (r)

18.

(8)

38.

(1)

58.

(3)

19.

(3)

39.

(8)

59.

(4)

20.

(8)

40.

(2)

60.

(4)

Comprehensive Study Package for IIT-JEE-2011

Answers, Hints & Solutions of Test - 6

PART - I : CHEMISTRY
1.

Answer (B)
Reversible work done is the maximum work done & it always greater than irreversible work done because in
reversible process Pgas Pext, where as in irreversible process Pgas > Pext .

2.

Answer (C)
1

O
Cr

K3CrO8

O1

+5
1

1 O

OK

OK
OK

O 1

Cr

CrO5

O 1

O
1

+6
K2Cr2O7
+6
3.

Answer (A)
W = W (W) = 2W

4.

Answer (B)
W1 2 = 510 3 12 105 = 60 102 J = 6000 J
W2 3 = 0
W1 2 3 = 6000 + 0 = 6000 J

5.

Answer (C)
+


AgCl 



Ag + Cl
S

0.7 +S

S(S + 0.7) = 2.8 1010

S = 4 1010 moles/L
6.

Answer (D)
Fact.

7.

Answer (A, B, C, D)
A, C, D = Fact about the graph.
The tangent at critical point P is horizontal, so that

8.

dP
at critical point will be zero.
dV

Answer (A, C, D)
Fact.

9.

Answer (A, D)
Steepest curve is adiabatic curve.

10. Answer (A, B, D)

Pressure has no effect on solubility.
2

Answers, Hints & Solutions of Test - 6

Comprehensive Study Package for IIT-JEE-2011

11. Answer (C)

pH value of buffer solution will change infinitesimally an adding some acid or some base.
12. Answer (C)
Vapour pressure is not only depends on temperature but also colligative property.
It depends also on chemical compound present in it like surf in water.
13. Answer (A)
When metallic spheres are placed filled with He gas will not participate to cylinder pressure. So partial pressure
will be calculated only with that mole which are exerting the pressure on vessel.
14. Answer (B)
Volume constant
mole1 = 3
mole2 = 8

P1 P2
=
n1 n2

P0 P2
=
3
8

P2 =

8
P0
3

P = P2 P0
=

8
P0 P0
3

5
P0
3

15. Answer (B)

Total mole inside container = 1 + 2 + 10 = 13 moles.
16. Answer A(p, r, s), B(p, r, s), C(p, q, t), D(p, q, r)
17. Answer A(q, r), B (p, r, s), C(q, r), D(q, s)
18. Answer (8)
[OH] = 9 107 + 107 (From water)
[OH] = 107 (9 + 1) = 106
pOH = 6
pH = 8
19. Answer (3)
Point of infelction means critical point
PC VC 3
=
RTC
8
20. Answer (3)

and Z =

(Kw)at 10C =
=

1
(K w )at 25C
100
1
1014 = 1016
100

For pure water (or neutral solution) [H+] = [OH] = 10 8

pH = 8
3

Comprehensive Study Package for IIT-JEE-2011

Answers, Hints & Solutions of Test - 6

PART - II : MATHEMATICS
21. Answer (A)

G1

Total ways = 5!

G2 and G3

Favourable ways = 2 2

B2 and B3

Probability =

4
1
=
120 30

B1

22. Answer (B)

Clearly, (i, i ) and (i, i ) are two possible ordered pairs which satisfy the given system of equations.
23. Answer (B)
x2 3x + 2 > 0
x (, 1) (2, )

log 1 x 2 3 x + 2 > 2
2

x 2 3x + 2 <

x 2 3x +

1
4

9 9 1
< + 2
4 4 4

3
1

x <
2
2

3
1
1
<x <
2
2
2

3 2
3+ 2
<x<
2
2

3
1 3
1
, 1 2, +
Common solution is

2
2
2
2

24. Answer (D)

The given series is

1 1 3 1 5 1 7

5
5
5
= 3 5 + + + + ...
3
5
7
1

1+ 5 3
3
3
= loge
= loge
1
2
2
1 2
5

Answers, Hints & Solutions of Test - 6

Comprehensive Study Package for IIT-JEE-2011

25. Answer (A)

Put x = y 1
(y + 2)4 (y 2)4 = 1280
2{4 2y3 + 4 8y} = 1280
y3 + 4y 80 = 0
(y 4) (y2 + 4y + 20) = 0
y = 4 as y2 + 4y + 20 0 for realy
x = 3 is only one real root of the given equation.
26. Answer (C)
2n 2 n + 2
n!
n =1

L.H.S =

(i)

2 + n + 2n(n 1)
n!
n =1

1
1
1
+
+ 2
n =1 n !
n =1 ( n 1) !
n =1 ( n 2 ) !

=2

= 2(e 1) + e + 2e
Statement (1) is true

= 5e 2
(ii)

e is an irrational number

(iii)

L.H.S =

3n + 5
1
1
=3
+ 5

n
!
n
1
!
n
) n =1 !
n =1
n =1 (

= 3e + 5(e 1)
Statement (3) is true

= 8e 5
27. Answer (A, C)
nC
6

+ nC5 + 2(nC5 + nC4) + nC4 + nC3

= n + 1C6 +

n + 1C
5

n + 2C
6

n + 2C
5

=
=

n+3

C6 =

n + 1C
5

n + 1C
4

n +3

P6
6!

28. Answer (A, B, C, D)

Highest exponent of 2 in 100! is

100 100 100 100 100 100

2 + 4 + 8 + 16 + 32 + 64

= 50 + 25 + 12 + 6 + 3 +1
= 97
highest exponent of 4 in 100! is 48.
5

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Answers, Hints & Solutions of Test - 6

29. Answer (A, B, C)

y
C
(3, 4)

O
OC = 5
Maximum |z| = 5 + 2 = 7
Minimum |z| = 5 2 = 3
30. Answer (B, C, D)

1
1

100
( n 2 ) !3! ( n 1) !2!

( n + 1)!

( n + 1) n ( n 1)

( n + 1)( n 1) n

1
100
2 ( n 1)

2n 2 6
100
12 ( n 1)

2n(n + 1)(n 4) 1200

n(n +1) (n 4) 600
But n 2
n can take values 2, 3, 4
31. Answer (A)
Let ax = by = cz = k
x = loga k, y = logb k, z = logc k
y=

xz ( logb k ) = loga k .logc k

2

(log k )
2
(log b )
2

log k . log k
log a . log c

log a . log c = (log b)2

log a log b
=
log b log c

logb a = logc b
Both statements are true
6

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Comprehensive Study Package for IIT-JEE-2011

32. Answer (A)

Put 5x = y
5y +

5
= 26
y

5y2 26y + 5 = 0

y = 5 or

1
5

x = 1 or 1
Both statements are true.
33. Answer (A)
(1 + x)n = C0 + C1 x +C2 x2 + C3 x3 + ...+ Cn xn
n(1 + x)n 1 = C1 + 2xC2 + 3x2 C3 + ...+ nxn 1 Cn
Put x = 1
C1 + 2C2 + 3C3 + ...+ nCn = n.2n 1
34. Answer (B)
(C0 + C1 + C2 + ...+Cn) + 2(C1 + 2C2 + 3C3 + ...+nCn)
= 2n + 2 n . 2n 1
= 2n(n + 1)
35. Answer (A)
(1 + x)n = C0 + C1x + C2x2 + C3x3 + ...+Cnxn

(1 + x )
1

dx = C0 + C1x + C2 x 2 + C3 x 3 + ... + Cn x n
0

1
(1 + x )n + 1
C1x 2 C2 x 3 C3 x 4
Cn x n +1

= C0 x +
+
+
+ ... +

2
3
4
n + 1 0
n + 1

C C C
C
2n +1 1
= C0 + 1 + 2 + 3 + ... + n
n +1
2
3
4
n +1

36. Answer A(s), B(p), C(r, t), D(q)

(A) + 3 =

b
c
and 3 2 =
a
a
2

c
b
3
=
a
d
4

3b2 = 16 ac
(B) + + 3 =
=

b
c
and ( + 3 ) =
a
a

3a + b 3a + b
c
b 3a
3 =

and

2a
2a 2a
a

(b + 3a) (b 3a) = 4ac

b2 9a2 = 4ac
b2 = 9a2 + 4ac
7

Comprehensive Study Package for IIT-JEE-2011

2
(C) + =

b
a

( + 1) =

3 =

c
a

b
a

3
3
2
( + 3 + 3 + 1) =

Answers, Hints & Solutions of Test - 6

b 3
a3

c c
b3
b
+ 1 = 3
+ 3

a a
a
a

c {c 3b + a} =

b 3
a

2
c + ac 3bc +

b3
=0
a

(D) We have
+ 2 =

b
b
=
a
3a

b2 c
b
2 2 =
2b2 = 9ac
a
a
a
9

37. A(r), B(p, q, r, s, t), C(p), D(t)

22 =

(A)
(B)

1
6! = 360
2

( n 2 )180 = 108
n

2 3
=
n 5

2 2
=
n = 5. Which divides 280, 315, 360, 210, 105
n 5
(C) 8C2 5C2 = 28 10 = 280

(D)

15C
2

= 15 7 = 105

38. Answer (1)

We have
1!3 2!4 + 3!5 4!6 +.......2010!2012 + 2011!
= (1! + 2!) (2! + 3!) + (3! + 4!) (4! + 5!) +......(2010! + 2011!) + 2011!
=1
39. Answer (8)
OOOOO
Number of ways = 5! 6 5 4 = 14400
1800k = 14400
k = 8
40. Answer (2)
Required probability = P(leap year is selected and there are five Fridays) +P(Non leap year is selected and
there are five Fridays)

k=

1 1
+0
4 7

56k = 56

1 1
=2
4 7
8

Answers, Hints & Solutions of Test - 6

Comprehensive Study Package for IIT-JEE-2011

PART - III : PHYSICS

41. Answer (D)
The force of friction between the two surface in contact disappears when there is no relative (linear) motion
between them. Angular momentum will not be conserved as the discs will have final angular velocities in
opposite direction.
42. Answer (A)
Fext = m

dv
dm
+v
dt
dt

dv
dx
+ vk
dt
dt
dividing by k
mg = kx

dv
+ v2
dt
43. Answer (C)
xg = x

X =

mL
m+M

30 L
3L
right side
=
8
30 + 50
44. Answer (A)

mg T = ma
TR=

MR2

... (1)

( a = R)

T = ma

... (2)

g
2
45. Answer (A)
a =

mg

Total mechanical energy is conserved

GMem 1
GMem
+ mv 2 = 0
2
2R
R

v = gR
46. Answer (D)
Self explanatory.
47. Answer (A, B, C)
y = 102 sin(60t + 1.5x)
y = A sin(t + kx)
A = 102 m, = 60, k = 1.5
v =

60
= 40 m/s
1.5

2
2
4
=
=
m
k
1.5
3

f =

60
30
=
=
2
2

mg = 2m a

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Answers, Hints & Solutions of Test - 6

48. Answer (B, C, D)

X = 2 sin 2t, Y = 3 sin 2t
X 2
3
=
Y = X
3
Y
2

 dr
v=
= 2i + 3 j cos(2nt ).2
dt


a = 2i + 3 j sin ( 2nt ) .42

F = 42mx simple harmonic, periodic

49. Answer (B)
50. Answer (A, B, C, D)
Self explanatory.
51. Answer (B)
52. Answer (B)
53. Answer (A)
54. Answer (A)
55. Answer (A)
Solution for Q. Nos. 53 to 55

N
a
mg sin

mgsin fr = ma
rfr =

fr
mg cos

...(i)

mr 2

a = R

...(ii)

...(iii)
3
from equation (i), (ii) and (iii)
fr = mg sin

Condition for no slipping,

fr N
mg sin
mg cos
3
1
tan
3
min =

1
tan
3

56. Answer A(p, q, r, s, t), B(q, r, s, t), C(q, r, s, t), D(p, q, r, s, t)

57. Answer A(t), B(p, q), C(s), D(r)
10

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Comprehensive Study Package for IIT-JEE-2011

58. Answer (3)

2mu cos 60 = mvx
6

vx = u =

3
13

13

v cos 30 = u cos 60
u

v =

2 3
2

u
3

3
+ vy
13

6
13

2 3
13
3
13

3
13

2m
3
+ mv y
13

3
+ vy
13

= vy

= vy

Speed of second piece =

3
6

+
13
13

39
=
13

x=3
59. Answer (4)
v =

{2( 2)}2 + {2 2}2

8+8

16

vy
vx

2mv sin 30 = m

= 4 m/s
60. Answer (4)

V = 2 10 20 = 20m/s
Retardation inside the water =

V (2)g V ()g
Ve

Pall will go to the same depth = 20m

t = 4 sec.

q q q
11

3 =

60