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Article history:
Received 28 February 2010
Received in revised form 2 January 2011
Accepted 15 January 2011
Keywords:
Integrated gasication combined cycle
Syngas type
Gas turbine
Integration degree
Turbine metal temperature
Compressor surge
a b s t r a c t
We investigated the effects of ring syngas in a gas turbine designed for natural gas. Four different syngases were evaluated as fuels for a gas turbine in the integrated gasication combined cycle (IGCC). A full
off-design analysis of the gas turbine was performed. Without any restrictions on gas turbine operation,
as the heating value of the syngas decreases, a greater net system power output and efciency is possible
due to the increased turbine mass ow. However, the gas turbine is more vulnerable to compressor surge
and the blade metal becomes more overheated. These two problems can be mitigated by reductions in
two parameters: the ring temperature and the nitrogen ow to the combustor. With the restrictions
on surge margin and metal temperature, the net system performance decreases compared to the cases
without restrictions, especially in the surge margin control range. The net power outputs of all syngas
cases converge to a similar level as the degree of integration approaches zero. The difference in net power
output between unrestricted and restricted operation increases as the fuel heating value decreases. The
optimal integration degree, which shows the greatest net system power output and efciency, increases
with decreasing syngas heating value.
2011 Elsevier Ltd All rights reserved.
1. Introduction
Coal has the largest reserves among fossil fuels. Therefore,
worldwide efforts are focused on developing performance enhancements for current coal-based power plants and devising advanced
systems [1]. The integrated gasication combined cycle (IGCC) is
considered to be the most environmentally friendly method of
using coal. IGCC plants have been in commercial operation for more
than a decade. Four full-size plants are under operation [2], and a
number of IGCC projects are ongoing worldwide [3]. Gas turbine
original equipment manufacturers (OEMs) are actively supplying
engines that are suitable for IGCC applications [4]. All of the major
OEMs, including General Electric [5], Mitsubishi Heavy Industries
[6] and Siemens [7], are preparing for the IGCC era. In addition,
studies on the constructability of IGCC plants are also being performed [8]. In particular, OEMS are trying to improve gas turbine
performance and adapt their engines to the IGCC environment
[9,10]. IGCC technology is particularly promising in terms of coping
with global warming issues such as the reduction and ultimate
elimination of CO2 emissions, as illustrated in recent studies. Kanniche and Bouallou [11] introduced a method to capture CO2, and
Descamps et al. [12] predicted the variation in IGCC plant
Corresponding author. Tel.: +82 32 860 7307; fax: +82 32 868 1716.
E-mail address: kts@inha.ac.kr (T.S. Kim).
0196-8904/$ - see front matter 2011 Elsevier Ltd All rights reserved.
doi:10.1016/j.enconman.2011.01.009
2263
Nomenclature
A
ASU
C
cp
GT
i
IGCC
LHV
_
m
P
PR
R
T
TRIT
_
W
area (m2)
air separation unit
cooling constant
specic heat (kJ/kg K)
gas turbine
location
integrated gasication combined cycle
lower heating value (kJ/kg)
mass ow rate (kg/s)
pressure (kPa)
pressure ratio
gas constant (kJ/kg K)
temperature (K)
turbine rotor inlet (ring) temperature (K)
power (MW)
Greek symbols
/
cooling effectiveness
c
specic heat ratio
g
efciency
constant
Subscripts
aux
auxiliary
b
blade metal
C
compressor
c
coolant
CC
combined cycle
comp
auxiliary compressor
d
design point
g
gas
gen
generator
in
inlet
m
mechanical
ref
reference data
ST
steam turbine
sys
system
T
turbine
1
asymptotic
2. System modeling
2.1. System conguration
Fig. 1 shows the system analyzed in this study. Since our goal
was to investigate the operation and performance of the power
block, especially the gas turbine, the details of the gasication
block were not modeled. Instead, syngas compositions and corresponding mass balance data were taken from the literature. The
system includes the entire power block, which consists of a gas turbine and a bottoming steam turbine cycle. Also included in the
analysis are the auxiliary air compressor, and the oxygen and nitrogen compressors that interact with the gas turbine. The analysis
was performed using GateCycle [23].
Oxygen is separated from the air at the ASU and supplied to the
gasier to produce syngas. There are various ways to supply air to
the ASU. Air can be supplied solely by the gas turbine compressor,
which is called 100% integration degree design. On the other hand,
an auxiliary air compressor can supply all the air to the ASU, in
which case the integration degree is 0%. An integration degree between 0% and 100% means that both the gas turbine compressor
and the independent compressor supply air to the ASU. Integration
degree is dened as follows [16,19]:
Integration degree
_1
Air to ASU from GT m
_3
Total air to ASU
m
The turbine gas ow rate varies greatly depending on the integration degree, which affects the operating condition of the gas
turbine.
2264
Table 1
Properties syngas and natural gas.
Component (mole fraction)
Natural gas
Ar (%)
CH4 (%)
C2H6 (%)
C3H8 (%)
C4H10 (%)
CO (%)
CO2 (%)
H2 (%)
H2O (%)
N2 (%)
LHV (kJ/kg)
Syngas
91.33
5.36
2.14
0.95
0.22
49303.0
0.88
0.06
35.12
13.1
31.42
16.39
3.01
8621.6
0.86
0.03
50.8
0.05
25.79
17.52
4.94
10493.8
0.99
0.04
2.56
2.04
85.84
3.27
5.26
37018.1
0
0
0
0
100
0
0
119914.6
2.2. Syngas
Table 1 shows the compositions and heating values of four different syngas fuels used in this study and those of natural gas used
for the reference design calculation. These values were taken from
literatures [14,24], which published complete mass and energy
balances for IGCC plants including syngas properties. Syngas A
has the lowest heating value, and syngas B has a slightly higher
heating value than A. The major components are carbon monoxide
and hydrogen. Application of the CO2 capture process to syngas B
produces syngas C. Hence, the hydrogen content of syngas C is
much higher than those of syngases A and B. Syngas D is pure
hydrogen. The relative mass ow rates at different locations, as reported in [14,24], were used; thus, a detailed analysis of the gasier block was not necessary. Instead, we adopted a simplied
method used in [19]. A mass balance for the system in this study
was obtained by scaling the mass balance data given in the literaTable 2
Relative mass ow rates.
Element (location)
ASU (3)
N2 compressor (4)
O2 compressor (5)
Syngas (6)
1.684
1.297
0.387
1.0
1.766
1.324
0.442
1.0
6.923
5.333
1.589
1.0
29.058
18.708
6.971
1.0
tures [14,24]. The relative mass ow rates per unit syngas ow rate
in the four syngas types were calculated from the literature and are
_ 6 ) was detershown in Table 2. The required syngas ow rate (m
mined by the gas turbine calculation. Then, the following equation
yielded ow rates at other locations [19]:
_6
_im
m
_i
m
_6
m
2
ref
2265
This work
Inlet
288.2
101.3
0.5
435.5
288.2
101.3
NA
NA
Compressor
Pressure ratio
Number of stages
Polytropic efciency (%)
16
18
90.0
16
18
NA
Combustor
Fuel
Fuel lower heating value (kJ/kg)
Fuel ow (kg/s)
Pressure loss (%)
Natural gas
49,244
9.47
4.0
Natural gas
NA
NA
NA
Turbine
1670
1600
874.2
3
88.1
18.3
7.3
0.5
445.0
NA
1600
878.2
3
NA
NA
NA
NA
445.0
Performance
99.5
98.5
171.6
36.8
NA
NA
171.7
36.8
art frame F gas turbines, especially the GE7FA [25,26]. The design
fuel is natural gas. Comprehensive component models including turbine blade cooling were used. The turbine rotor inlet temperature
(TRIT) is the inlet temperature of the rst stage rotor, which is often
referred to as the ring temperature. All ve blade rows except the
last rotor blade were cooled. The simulation results are in good
agreement with performance data from the literature [25].
An off-design analysis of the gas turbine is required to examine
the change in operation and performance caused by the fuel
change from natural gas to syngas. A compressor map was used
to model the operating characteristics of the compressor. The
map will be illustrated in the results section with illustrations of
operating point changes. The design surge margin of the compressor was assumed to be 20%. The surge margin is dened as [16,19]
Surge margin
PRsurge PRoperation
PRoperation
v
u
p
cc1
uc
1
_ in T in
2
m
t
constant; where j
jAin Pin
R c1
Tg Tb
Tg Tc
_ c cp;c
/
m
C
_ g cp;g
/1 /
m
where /1 represents the asymptotic cooling effectiveness, the value of which is 1.0, corresponding to a very high thermal capacity
ratio. C represents the technology level of the cooling scheme, and
it value was decided to satisfy Eq. (6) at the design condition. The
equation is an asymptotic curve between the thermal capacity ratio
and the effectiveness [19], and was used to determine the blade metal temperature at off-design conditions.
The following model [29] was used to simulate the change in
coolant ow rate due to a variation in operation conditions.
_ c;d
_cm
m
Pc
Pc;d
0:5
T c;d
Tc
Once the ow rates and temperatures of the hot gas and the
coolant were known for an off-design operation, the cooling effectiveness was calculated using Eq. (6). Then, the blade metal temperature was calculated using Eq. (5).
The net power output and efciency of the gas turbine are dened as follows.
_ T g WC g
_ GT W
W
m
gen
_
W
GT
gGT _
m LHVsyngas
8
9
_ GT W
_ ST
_ CC W
W
10
2266
Table 4
Parameters of the bottoming cycle.
High pressure turbine inlet pressure (kPa)
Intermediate pressure turbine inlet pressure (kPa)
Low pressure turbine inlet pressure (kPa)
High pressure steam temperature (K)
Reheat steam temperature (K)
Condensing pressure (kPa)
Pinch temperature difference (K)
Isentropic efciency of turbine (%)
Gas side pressure loss at HRSG (%)
18,000
4000
300
833
833
7
10
82
3
Fig. 2 shows the simulated results along with reference data from
[26]. We adopted the 7FA compressor map embedded in GateCycle
[23]. The simulation results are in good agreement with the reference data. The deviation of the exhaust mass ow is almost negligible, and the maximum deviations of power output and thermal
efciency were only 1.3% and 0.5%, respectively. Therefore, both
the design and off-design simulation results conrmed that the
current simulation tool could provide a feasible simulation of gas
turbine operation.
3.2. Gas turbine operation without restrictions
Auxiliary air
compressor
N2
compressor
O2
compressor
101.3
1314.1
90
90
634.3
3171.6
90
90
634.3
5102.1
90
90
The steam turbine cycle power includes the power consumption of the pumps in the bottoming cycles.
The net performance of the entire system was less than the combined cycle performance because the entire system consumed considerable auxiliary power. The amount of auxiliary power depends
signicantly on system design options such as the integration degree. The power consumption of the auxiliary air compressor and
the oxygen and nitrogen compressors were calculated using the
previously determined mass ows at locations 2, 4, and 5. The assumed values of the parameters for the auxiliary components are
listed in Table 5. The total auxiliary power consumption was calculated as follows:
_ aux W
_ air;comp W
_ O ;comp W
_ N ;comp
W
2
2
11
Then, the net power output and efciency of the entire power
block were obtained by substracting the auxiliary power consumption from the combined cycle power output:
_ sys W
_ CC W
_ aux ; g
W
sys
_ sys
W
_ LHVsyngas
m
1.3
Calcluation results
1.2
Relative variations
Table 5
Parameters of auxiliary compressors.
Reference data
Power
Exhaust mass flow
1.1
Design point
1.0
Thermal efficiency
0.9
12
Our analysis consists of two parts. The rst part had no restrictions on gas turbine operation. The general trend of gas turbine
operation and performance with respect to the syngas type and
the integration degree was examined. The only limitation was that
the compressor surge margin was greater than zero. The second
part was an analysis with practical considerations on the restrictions of the compressor and turbine operation. Combined restrictions on the allowable surge margin and turbine metal
temperature were assumed, and their effect on system performance was comparatively evaluated for various syngas fuels.
0.8
-10
-5
20
25
30
1.3
1.2
Syngas
A
1171 K
1159 K
B
C
1156 K
PR/PR
3.1. Validation
15
1.1
10
D
Design point
1150 K
1.0
0.9
The design point analysis was validated by the excellent agreement between the simulation and the reference design data, as
shown in Table 1. The most important point in this study was
the capability of the program to precisely simulate the performance variation at off-design operating conditions. As a validation
of the off-design simulation model, the variation in the full load
(full ring; i.e., the design TRIT) performance of the gas turbine
(GE7FA) was predicted and compared with the reference data.
0.8
0.7
0.90
0.95
1.00
1.05
Relative flow
Fig. 3. Full load conditions of the gas turbine using different syngas fuels on the
compressor working line for the case of 50% integration degree.
2267
30
Syngas A
25
Syngas B
Syngas C
20
Syngas D
15
10
5
0
-5
0
20
40
60
80
100
1190
Syngas A
Syngas B
Syngas C
Syngas D
1180
Temperature (OC)
map are full load conditions. All the nitrogen from the air separation unit is supplied to the gas turbine combustor (full dilution).
The design point means the full load conditions of the gas turbine
using natural gas as fuel. It is clearly shown in Fig. 3 that the working pressure ratio of the compressor varied signicantly according
to the type of syngas fuel. As the heating value of the fuel decreased (from D to A), the gas turbine needed a larger amount of
fuel ow to maintain the same ring temperature, thus causing
the turbine inlet gas ow to increase. Then, according to the
matching between the turbine inlet and the compressor exit conditions, the compressor pressure ratio increased. Hence, syngas A,
which had the lowest heating value, exhibited the highest pressure
ratio, while syngas D showed the lowest pressure ratio. Even in this
50% integration degree, syngas A resulted in a very small surge
margin which is not usually tolerable for safe gas turbine operation. Thus, an integration degree less than this value cannot be
adopted in practice. Also indicated in Fig. 3 are the blade metal
temperatures for operation with different syngas fuels. All cases
cause the metal temperature to rise above the design temperature
(1144 K). The inuence of syngas type is explained as follows. Since
the turbine rotor inlet temperature is maintained at a constant value, the inlet gas temperature of the rst stage vane is almost constant. However, as the heating value decreases, the gas ow rate at
the rst vane inlet increases, resulting in decreased cooling effectiveness (Eq. (6)). Furthermore, the cooling air temperature also
rises due to the increased coolant pressure (i.e., the compressor
discharge pressure). As a result, as the heating value of the syngas
fuel decreases, metal overheating becomes more serious.
Figs. 4 and 5 show the combined effects of syngas type and integration degree on the compressor surge margin and the rst vane
metal temperature. It is clearly seen that the syngas type strongly
affects the operating condition. In the entire integration degree
range, surge margin decreases and metal temperature rises as
the heating value of the syngas decreases. The two problems become worse with decreasing integration degree for all syngas
types. At 100% integration degree where all the air for the ASU is
extracted from the gas turbine compressor, the surge margins of
A and B are smaller than the design margin of 20% (i.e., the compressor discharge pressure is higher) because the turbine mass
ow is greater than that of the natural gas-red case due to the
greater fuel ow. The increased turbine hot gas ow also increases
the rst vane metal temperature compared to the natural gas-red
case. However, syngases C and D exhibited larger compressor surge
margins compared to the natural gas-red case in the high integration degree regime. Note that the syngases C and D were produced
by applying the CO2 capture process to the raw syngas in the gas-
1170
1160
1150
1140
1130
0
20
40
60
80
100
ier. Thus, much of the oxygen supplied by the compressor and the
carbon supplied by coal was extracted out of the gasier and was
not fed to the combustor. This is explained by the large difference
between the ASU air ow and the syngas ow as shown in Table 2.
As the purity of the hydrogen became higher (from C to D), the
fraction of the extracted gas from the gasier increased, and thus
the turbine inlet ow rates decreased to a greater degree. Due to
this ow extraction, the compressor discharge pressure was lower
than that of the natural gas-red case in the high integration degree regime, resulting in a greater surge margin.
A lower integration degree causes a reduction in surge margin
and an increase in turbine metal temperature due to increased turbine ow, which is the same trend as in previous studies [16,19]. In
fuels C and D, a positive surge margin is still left even at 0% integration degree. In particular, the pure hydrogen case may allow more
than 5% surge margin at 0% integration degree. On the other hand,
fuels A and B do not allow a positive surge margin at near-zero
integration degrees. As the heating value of the syngas decreases,
the value of the lowest realizable integration degree, which guarantees a minimum surge margin, becomes higher. For example, if
we assume that a minimum surge margin of 5% should be ensured
for all circumstances, the lowest obtainable integration degrees are
55% and 30% for syngases A and B, respectively. At these operating
conditions, the rst vane metal temperature exceeds the design value by about 25 K. This overheating may reduce blade lifetime
considerably because the lifetime decays exponentially with
increasing temperature [30]. With fuels C and D, even though the
gas turbine is still operable at very high integration degrees, the
turbine metal overheating problem still exists and thus should be
alleviated.
Fig. 6 shows the net gas turbine power output and efciency. A
larger turbine ow is afrmative in terms of gas turbine power output [16,19]. Therefore, for all fuels, a reduced integration degree
yields a larger power output. The effect of syngas heating value
can be similarly understood. A lower syngas heating value causes
an increase in turbine ow, thus leading to a larger gas turbine
power output. Hence, fuels A and B generally produce more power
output than fuels C and D. In fuels C and D, since the hydrogen content of the fuel is very high, the combustion gas contains considerable H2O. This is advantageous in terms of turbine power because
the specic heat of H2O is higher than the specic heats of other
combustion gas components. This explains the relatively small
power gap between fuel C and B as shown in Fig. 6. The major
parameter that governs gas turbine efciency is the pressure ratio.
Therefore, a lower integration degree or a lower fuel heating value
leads to higher gas turbine efciency due to an increased pressure
ratio.
250
50
200
45
150
40
heated. As a result, the limiting (lowest obtainable) integration degree increases as the syngas heating value decreases. In other
words, operable integration degree range decreases as the syngas
heating value decreases.
(%)
GT
GT
(MW)
2268
Syngas A
100
35
Syngas B
Syngas C
Syngas D
30
50
0
20
40
60
80
100
300
55
280
1.3
54
52
200
51
180
Syngas A
Syngas B
Syngas C
Syngas D
20
40
60
80
100
50%
75%
100%
0.9
50
0
Integration
degree
0.8
160
0%
25%
1.1
PR/PRd
220
(%)
sys
240
sys
1.2
53
(MW)
260
0.7
0.90
0.95
1.00
1.05
Relative flow
Fig. 7. Variations in net system power output and efciency with integration
degree.
2269
20
1600
350
Surge margin
300
15
1580
10
1570
a
Modulation of
diluting nitrogen
modlation of
firing temp.
1560
1590
250
Power (MW)
Firing temperature
200
150
100
50
0
0
0
0
25
50
75
25
1550
100
50
75
100
Fig. 11. Variations in power outputs and auxiliary power consumption with
integration degree for the operation with restrictions (syngas A).
430
52.0
300
420
System efficiency
290
60
390
58
Turbine inlet gas flow
380
Power (MW)
400
System power
270
250
370
240
25
51.0
260
56
Syngas flow
51.5
280
Efficiency (%)
62
410
64
50
75
100
25
50
75
50.5
100
2270
320
300
280
260
240
Sygnas
Syngas
Syngas
Syngas
220
A
B
C
D
200
0
25
50
75
4. Conclusion
100
53.0
dotted lines : GT operation without restrictions
solid lines : GT operation with restrictions
52.5
52.0
51.5
51.0
Syngas
Syngas
Syngas
Syngas
50.5
A
B
C
D
50.0
0
25
50
75
100
Table 6
Peak system performance under restrictions of compressor surge and turbine metal
temperature.
Syngas
74
197.5
296.5
31.1
265.4
51.5
56
196.3
293.3
33.3
260.2
51.5
33
206.2
299.3
41.8
257.5
51.3
10
206.0
298.6
46.0
252.6
51.0
tion. However, a much greater penalty in power output was observed in regime b. It is interesting to note that the net power outputs of all cases converged to a similar level as the integration
degree approached zero. As a result, the difference in the net power
outputs of the unrestricted and restricted operations became
greater as the fuel heating value decreased. For example, at 50%
integration degree, the power penalties of fuels A, B, C, and D are
26.9, 13.4, 8.9, and 4.2 MW, respectively. If we extrapolate the performance of fuels A and B up to 0% integration degree (with the assumed design surge margin of 20%, the gas turbine cannot operate
without the restrictions using fuels A or B), the power penalties are
roughly 57 and 40 MW for A and B, respectively. The power penalties for C and D at 0% integration degree are 29.9 and 16.8 MW,
respectively. The efciency showed a trend similar to the power
output. However, the efciency differences among the four cases
are not considerable, and the efciency penalty from the unrestricted operation remains within one percentage point.
We investigated the inuence of syngas type on the performance of a gas turbine and the entire power block of an IGCC plant.
As the heating value of the syngas decreased, a greater net system
power output and efciency was possible due to increased turbine
mass ow; however, the gas turbine is more vulnerable to compressor surge and the blade metal became increasingly overheated.
As a result, the limiting (lowest obtainable) integration degree became higher as the syngas heating value decreased, i.e. the operable integration degree range decreased with decreasing heating
value.
The problems of compressor surge margin reduction and turbine metal overheating can be solved by a combination of reductions in the ring temperature and the nitrogen ow to the
combustor. With these restrictions, the net system power output
and efciency increased as the integration degree decreased until
the surge margin control began. After this peak point, the system
performance decreased with decreasing integration degree. The
net power outputs of all fuel cases converged to a similar level as
the integration degree approached zero. As a result, the difference
in the net power outputs of unrestricted and restricted operation
became larger as the fuel heating value decreased. The optimal
integration degree, which shows the greatest net system power
output and efciency, increased with decreasing syngas heating
value. The variation in net system efciency among the different
syngas types is marginal. The restrictions on the gas turbine components have a leveling effect on the obtainable performance
among different syngas fuels.
Acknowledgments
This research was supported by Basic Research Program
through the National Research Foundation of KOREA (NRF) funded
by the Ministry of Education, Science and Technology (20090073734).
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