1.

Mohrs salt is a

4. Copper complex of ethylene

(a) Single salt

(a) Unidentate ligand

(b) Double salt

(b) Tridentate ligand

(c) Complex salt

(c) Polydentate ligand

(d) Chelate

(d) Chelate

2. Potassium Ferro cyanide is

5. In potassium ferroayanide, the

coordination number of iron is

(a) Sigma compound

(a) Two
(b) Pi compound
(b) Four
(c) Double salt
(c) Six
(d) Complex salt
(d) Eight
6. The coordination number of Ag in
3. Ethylene diamine is
(a) Unidentate ligand
(b) Bidentate ligand
(c) Polydentate ligand
(d) Chelating ligand

potassium argent cyanide is

(a) One
(b) Two
(c) Three
(d) Four

7. The oxication number of Cu in

10. The neutral complex is.

[Cu[NH3]4]SO4 is
(a) K[Ag (CN)2]
(a) One
(b) [Ag (NH3)2] Cl
(b) Two
(c) Ni (CO)4
(c) Three
(d) [CO (Cl6)]3
(d) Four
11. Which one of the following
compounds will exhibit linkage
isomerism?
8. Potassium hexacyanoferrate (II) is
(a) [Pt (NH3)2 Cl2]
(a) Anionic complex
(b) [Co (NH3)5 NO2] Cl2
(b) Caironic complex
(c) [Co (NH3)4 Cl2] NO2
(c) Neutral complex
(d) [Ag (NH3)2] NO2
(d) None of these

12. Which one of the following complexes

9. Diammine silver (I) chloride is
(a) Anionic complex
(b) Cationic complex
(c) Neutral complex
(d) Chelating complex

will show ionization isomerism?

(a) [Co (NH3)4 Cl2] NO2
(b) [Cr (H2 O]6 Cl3
(c) [Co (NH3)6] [Cr (CN)6]
(d) K (Ag (CN)2]

13. Diaminopropane exhibit

16. Which of the complexes has bonds

only

(a) Coordinate isomerism

(a) Ni (CO)4
(b) Lignad isomerism
(b) Pb (C2 H5)4
(c) Linkage isomerism
(c) Fe (C5 H5)2
(d) Optical isomerism
(d) Fe (CO)5

14. Dichloro diammine platinum exhibit

17. Ferrocene complex is
(a) Optical isomerism
(a) Sigma bonded
(b) Geometrical isomerism
(b) bonded
(c) Linkage isomerism
(c) Both of there
(d) Coordination isomerism
(d) None of these

15. Out of the following which complex

will exhibit optical isomerism?

18. Which one of them is not a bonded

complex

(a) Ni (CO)4
(a) Dibenzene Chromium
(b) Na2 [Ni (CN)4]
(b) CH3 Mg Br
(c) Co (H2 N. CH2. CH2 NH2) Cl2
(c) (C2 H5)2 Zn
(d) [Ni (H2 O)6]2+
(d) Al2 (CH3)6

19. Which one of the complex is not

(d) Rutherford

bonded
(e) Thompson
(a) Ferrocene
22.Radioactivity results from the decay of
(b) Dibenzene Chromium

unstable

(c) Ni (CO)4

(a) electrons.

(d) (CH3)2 Cd

(b) very light nuclei.

(c) heavy nuclei.

20. Among the following ions which one

(d) photons.

has the highest paramagnetism

(e) bonds.
(a) [Cr (H2 O)6 ]3+
23.Which type of radioactive emission has
(b) [Fe (H2 O)6 ]2+

the highest penetrating power?

(c) [Cu (H2 O)6 ]2+

(a) electrons

(d) [Zn (H2 O)6 ]2+

(b) beta particle

(c) alpha particle

21.Which of these scientists is responsible

(d) gamma rays

for coining the term radioactivity and is a

lso the only person to

(e) neutrons

receive two noble prizes in science?

(a) Becquerel
(b) Curie
(c) Einstein

24.Which of these statements about fissio

n is incorrect?

(a) Fission reactions release a large amount

(a) Why spectral lines appear when atoms

of energy.

are heated.

(b) Two lighter nuclei combine to form a hea

(b) The energies of the spectral lines for

vier nuclei.

each element.

(c)Fission of uranium238 is initiated by the

(c) Why electrons travel in circular orbits

absorption of a neutron.

around the nucleus.

(d) Fission of uranium238 nuclei was at the

(d) none of the above answers is correct.

heart of the first atomic bomb.

(e) Fermi mistakenly discovered fission tryi
ng to synthesize a new element.

27. Line spectra are caused primarily

by:
(a) The existence of many ground states in

25. What piece of laboratory equipment is

an atom

best-suited for accurately measuring the

volume ofa liquid?

(b) The existence of many excited states in

an atom

(a) graduated cylinder

(c) The existence of many atoms in a typical
(b) beaker

sample

(c) Erlenmeyer flask

(d) None of the above

(d) more than one of the above

28. A continuous spectrum is caused
primarily by:
26. Bohrs model of the atom was able to
accurately explain:

(a) The presence of so many excited states

that the lines all blur together into arainbow.

(b) The presence of so many ground states

(c) The repulsion between bonds helps

that the lines all blur together into arainbow.

determine the shapes of covalent molecules.

(c) The presence of many atoms in a typical

(d) None of these statements is correct.

sample.
(d) None of the above
31. Carbon disulfide undergoes a single
displacement reaction with oxygen to
form carbon dioxide. If 100 grams of
carbon dioxide are reacted with 50 grams
29. The magnetic quantum number of an
orbital defines:
(a) The energy level of the orbital
(b) The shape of the orbital
(c) The spatial orientation of the orbital
(d) The spin of the electrons in the orbital

30. VSEPR basically states that:

of oxygen, what will the limiting reagent

be?
(a) carbon disulfide
(b) carbon dioxide
(c) oxygen
(d) sulfur

32. The difference between dipole-dipole

forces and hydrogen bonds are that:

(a) The repulsion of atomic nuclei help

determine the shapes of covalent molecules.

(a) dipole-dipole forces only exist between

nonpolar molecules

(b) The repulsion between electrons helps

determine the shapes of covalent

(b) dipole-dipole forces occur between polar

molecules

Molecules.

(c) dipole-dipole forces are caused by the

(a)Ni(CO)4 and NiCl42- are diamagnetic; and

interaction of partial charges on both

[Ni(CN)4] 2- is paramagnetic.

molecules.

(b) [Ni(CN)4]2- and NiCl42- are diamagnetic;

(d) None of the above are able to distinguish

and Ni(CO)4 is paramagnetic.

between dipole-dipole forces and hydrogen

(c)Ni(CO)4 and [Ni(CN)4]2- are diamagnetic;

bonds.

and NiCl42- is paramagnetic.

33. For which process would the heat be

negative?
(a) Changing the temperature of ice water to
0

50 C

(d)

Ni(CO)4 is

diamagnetic;

[Ni(CN)4]2- and NiCl42- are paramagnetic.

36. Bond angle in [SO3]2- is

(a) <109.5

(b) Condensing steam.

(c) Boiling water.
(d) more than one of the above
34. Which of the following elements shows
maximum number of different oxidation
states in its compounds?
(a) Eu
(b) La

(b) 109.5
(c) <120
(d) 120
37. The IUPAC name for the complex
[Co(en)2Cl(ONO)]+ is
(a) Cobalt diethylenediaminechloranitrate
(b) Chlorodiethylenediaminenitrito
cobalt(II)

(c) Gd

(c) Chloronitritodiethylenediamine

(d) Am

cobalt(III)
(d) Chlorobis(ethylenediamine)nitrito

35.Amongst Ni(CO)4, [Ni(CN)4]2- and

NiCl42-:

cobalt(III)

38.The elevation of boiling point was 0.52

0

C when 6 g of compound X was dissolved

in 100g water. Molecular weight of X is

( Kb of water = 0.52 K mol-1)

41.What is the major product of the

following reaction?

(a) 120 g
(b) 60 g
(c) 600 g
(d) 180 g

(a) S-2-butanol
(b) R-2-butanol
(c) a racemic mixture of 2-butanol
(d) the hemiketal of 2-butanone and

39.Toluene is nitrated and the resulting

product is reduced with tin and
hydrochloric acid.
The product so obtained is diazotized and
then heated with cuprous bromide. The
reaction mixture so formed contains
(a)mixture of o and pbromotoluenes
(b)mixture of o and pdibromobenzenes
(c)mixture of o and pbromoanilines

methanol...2-hydroxy-2-methoxybutane
42. Synthetic rubber is made by
polymerization of
(a) chloroform
(b) acetylene
(c) divinyl acetylene
(d) chloroprene
43. Which ofthem is most reactive one

(d) mixture of o and mbromotoluenes

(a)Alkane

40. Sulfonamides are metabolized by

(b)Alkyne

humans principally by
(a) acetylation
(b) deamination

(c)Alkene
(d)Benzene

(c) oxidation
(d) conjugation

44. Ketones are prepared by the oxidation

(e)methylation

of

(a) primary alcohol

(d) Nucleophilic substitution

(b) secondary alcohol

(c) tertiary alcohol

47. An alcohol is converted into an

aldehyde with same number of carbon

(d) none of these

atoms in the presence ofK2CrO4/H2SO4 .

The alcohol is

45. The compound with an atom which

has an unshared pair of electron is called
(a) nucleophile
(b) electrophile

(a)CH2C(CH)2OH
(b)CH3CH2CH2OH
(c)(CH3)3COH
(d)(CH3)2CHOH

(c) protophile
(d) none of these

46.when purely alcoholic solution of

sodium/potassium hydroxide and
halogenalkane are refluxed analkene is

48. when hexanedioic acid is heated with

hexamethylenediamine the compound
formed is

formed:CH3-CH2-Br (in presence of

alcoholic KOH )--- >CH2=CH2what is the

(a) polypeptide

mechanism of the reaction

(b) ester
(a) elimination
(c) addition polymer
(b) dehydration
(d) nylon 6,6
(c) debromination

49. Glucose and fructose are common

example of
50. PVC is an example of
(a) pentoses
(a) addition polymer
(b) hexoses
(b) condensation polymer
(c) heptoses
(c) biopolymer
(d) butoses
(d) thermosetting polymer