Académique Documents
Professionnel Documents
Culture Documents
- INTRODUCTION
Metamorphic rocks are derived from materials of igneous, sedimentary or
metamorphic rocks by changing their physical form and /or mineralogical
composition as a result of changes in pressure and /or temperature or by the effect of a
fluid phase. Metamorphism occurs in the solid state and is bounded by sedimentary
diagenesis and igneous melting. Metamorphic changes are always in a direction which
tends to restore equilibrium. The effects of metasmorphism include:
1 - Chemical recombination and growth of new minerals with or without the addition
of new elements from circulating fluids.
2 - Deformation and rotation of the constituent mineral grains
Categories of Metamorphism
Metamorphic rocks are divided on the basis of their field occurrence into the
following categories:
1- Contact (Thermal) Metamorphism:
It is the recrystallization of rocks near the contacts of igneous intrusions due to rise in
temperature. The area surrounding an intusive body is called contact aurole.
2 - Regional (Orogenic ) Metamorphism
This type outcrops over large areas and in a variety of settings. Rocks subjected to
regional metamorphism occur in a great belt, hundreds or thousands of kilometers
long and wide.
Metamorphism produced as a result of the progressive increase in temperature and
pressure, i.e. by burial of a rock within the earth, is termed prograde metamorphism
and in general terms is characterized by dehydration reactions, which release water.
With increasing depth of burial the pressure and temperature of the material increases
along the follwong gradients:
P gradient 3.5 kbar/10 km T gradient 20-30C/km
3 - Pyrometamorphism: It is recrystallization at high temperatures and takes place in
felsic, mafic and ultramfic xenoliths included in volcanic rokcs. It is an extraordinary
kinds of thermal metamorphism. It may produce partila melting. Buchite is a partially
melted rock derived from shael or sandstone.
4-Ocean-Floor Metamorphism
It is the recrystallzation of of deeper part of the basic and ultrabasic rocks of the
oceanic crust, mainly beneath the crest of the mid-ocean ridges.
5-Hydrothermal Metamoprhism
It is the recrystallization of rokcs under the influence of a hot fluid phase introduced
from the outside, mainly in geothermal fields.
A plane-foliated non micaceous rock, that may be laminated parallel to the foliation.
The term is usually reserved for rocks containing hypersthene and believed to have
crystallized at high metamorphic temperatures. Major minerals are : hypersthen,
biotite, cordierite, diopside, garnet, hornblende, kyanite, orthoclase, plagioclase,
quartz, sillimanite. Minor minerals are: apatite, corundum, graphite, ilmenite, spinel
Eclogite
A medium grained, commonly green coloured rock, consisting of pale to mediumgreen omphacite (jadeite-diopside) and lesser red garnet. Compositionally equivalent
to basalt and considered to be an extremely high pressure form resulting from regional
metamorphism. Common minerals are: alamandine-garnet, omphacite, kyanite. Minor
minerals: apatite, glaucophane, muscovite, plagioclase, zoisite.
Mylonite
A fine-grained, flinty-looking, strongly coherent, banded or streaky rock formed by
extrem granulation of parent rocks without notable chemical reconstruction. Eyes or
lenses of undestroyed parent rocks persist enclosed in the granulated ground mass.
Pseudotachyllite
Amorphous mylonite that streaked with veinlets of dark glassy-looking materials.
A phyllonite
A mylonitic rock in which mica and chlorite recrystallizing from the granulated matrix
impart a sliky sheen to the foliation surfaces.
Spotted slate and spotted phyllite
Slate and phyllite containing dark spots, the beginnings of porphyroblasts (biotite),
generally resulting from incipient contact metamorphism.
Skarn (tactite)
A contact metamorphic and commonly metasomatic (material introduced) rock,
commonly composed of red and green calcium-rich silicates (grossularite, epidote and
diopside).
Hornfles
Factors of Metamorphism
1- Temperature (T)
The rate of temperature changes with depth is known as the geothermal gradient. The
geothermal gradient is closely related to heat flow through the crust. Heat flow is
mostly due to heat flow from the mantle, radioactive decay, and rising bodies of
magma. Metamorphism, in general, refers to the reactions between minerals of a rock
in response to conditions of temperature and pressure prevailing at depth.
2-Pressure (P)
Pressure is a measure of the force per unit area to which a rock is subjected. It
depends on the weight of overlying rock (depth). The pressure due to the weight of the
overlying rocks is known as the lithostatic pressure. It is assumed that this pressure is
uniform in all directions and it is used to approximate the total confining pressure to
which a rock was subjected. However, lithostatic pressure does not itself cause
deformation. Deformation is a result of unequal stresses acting on a rock. (deviatoric
stress). Fluid pressure is the pressure exerted by fluid present in pore spaces and grain
boundaries.
Fluids
Fluid phases of volatile constituents (H2O, CO2, CO, CH4) are usually present during
metamorphism. The presence of water greatly increase the rate of crystallization due
to the catalytic action of water.
Isochemical metamorphism: transformation of a rock with gain or loss, by way of
contrast allochemical metamorphism refers to reconstitution accompanied by a change
in bulk composition of the rock (Metasomatism).
Metamorphic Zones (Barrows Zones)
In most regions of metamorphic rocks, a variation of grain size and mineralogy occurs
which suggests a variation in metamorphic grade. The grain size of the rocks tends to
become coarser with increasing temperature. Barrow ( 1912 ) was the first to
recognize that certain newly formed minerals appear in a definite sequence with
increasing temperature. These minerals were designated as index minerals. The
metamorphic zones characterized by these index minerals are well developed on a
regional scale in most continents.. The following succession of index minerals with
increasing temperature can be distinguished in many terrains:
1-Chlorite zone: chlorite-muscovite phyllite or schist
2-Biotite zone: appearance of biotite (biotite isograde)
3-Almandine (garnet) zone: appearance of garnet.
ACF Diagram
The scheme for calculating the ACF ratios (after necessary corections for magnetite,
ilmenite and sphene) is as follow:
A=(Al2O3+Fe2O3)-(Na2O+K2O)
C=CaO-3.3*P2O5
F=MgO+MnO+FeO
These values are recalcul;ated to 100%.
AFK Diagram
The general calculation scheme is :
A=(Al2O3+Fe2O3)-(Na2O+K2O+CaO)^2
K=K2O
F=FeO+MgO+MnO
A+K+F=100
AFM Diagram
A=(Al2O3-3*K2O)/((Al2O3-3*K2O+MgO+FeO)
M=MgO/(MgO+FeO)
F=FeO-Fe2O3-TiO2
TEMPERATURE LIMITS OF METAMORPHISM
The lower temperature limit, at metamorphism takes place, marks the boundary
between metamorphism and diagenesis. Lower T = 100-150C - excludes any
diagenetic changes. Some workers consider any changes not occurring under
atmospheric conditions to be the result of metamorphism. >br>
Metamorphic Reactions
If a mineral persists beyond the conditions in which it is at equilibrium iton the
styability field of another mineral, it is said to be metastable and the reaction have
been overstepped. Metamorphic reactions take place uusually close to equilibrium and
at a specific temperature and pressure. The assemblages consisting of reactants and
products has only one degree of freedum at equilibrium. This type of reaction is
univariant (discontineous). Reactions that take place progressively so that reactants
and products can coexist over an interval of pressure and temperature (divariant) are
known as contineous reactions. Reactions that involves change in the compostion of
the phases are known as cation exchange reactions. Solid-Solid reactions occurs
among solid phases e.g., transformation of andalusite to silliminaite and kyanite.
Dehydration reactions involve libration of water. Decarbonation reactions involve
libration of CO2. Oxidation-reduction reactions involve minerals containing iron.
Regional Metamorphism
Corresponds to progressive changes, increases, in Temperature & Pressure, due to
burial. Commonly this type of metamorphism is associated with orogenic events and
processes. Regionally metamorphosed rocks occur in very large belts, 10 - 100's km
wide by 100 - 1000's km long. Within each belt will be preserved at least one thermal
axis, representing the maximum temperature of metamorphism within the belt.
Temperatures will increase towards the thermal axis. Associated granitic and/or
ultramafic masses intruded into the terranes generally, but not always near the thermal
axis.
Metamorphism of Basic Rocks (Metabasites)
Metabsites are mostly the metamorphic products of basalt and andesites. IF water has
had access to the rock, the metamorphic products formed with increasing temperature
are chlorite schist (or glaucophane schist, depends on pressure), green schist and
amphibolite. IF water has not had access but load presure was very high, then eclogite
will be formed. The main constituents of basalts and andesites are plagioclase (An4070) and clinopyroxene with some hypersthene and olivine. The main changes of
basaltic and andesitic rocks during metamorphis, where amphibolites are formed are:
1-Formation of hornblende and garnet if pressure is high .