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SECTION I
Straight Objective Type
This section contains 8 multiple choice questions numbered 1 to 8. Each question has
4 choices (a), (b), (c) and (d), out of which ONLY ONE is correct.
1.
C
(a)
C
O
(b)
CH2OH
CH2
O
C
(c)
2.
OH
CH2OH
OH
(d)
CH2OH
Calculate the pH of a solution made by adding 0.01 mole of HCl in 100 mL of a solution that
is 0.2 M in NH3 (pKb = 4.74) and 0.3 M in NH 4 : (Assuming no change in volume)
(a) 5.34
(b) 8.66
(c) 7.46
(d) none of these
3.
If the vapour pressures of pure A and pure B at 298 K are 60 and 15 torr respectively, what
would be the mole fraction of A in vapour phase (at this temperature) in a solution that
contains 20% of A in (A + B) binary mixture in the liquid phase?
(a) 0.2
(b) 0.3
(c) 0.5
(d) 0.7
4.
5.
6.
Which of the following pair of cations can be separated by adding NaOH solution?
(a) Pb2+, Al3+
(b) Sn2+, Pb2+
(c) Cu2+, Zn2+
(d) Zn2+, Pb2+
7.
Which one of the following is the most reactive towards electrophilic aromatic substitution
reaction?
(a) C6H5Cl
(b) C6H5NO2
(c) C6H5CH3
(d) C6H5OCH3
8.
(A)
H 2O
(B)
HCl
White fumes.
(b) Li, Al or K
(d) Li, Na or K
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SECTION II
Reasoning Type
This section contains 4 reasoning type questions numbered 9 to 12. Each question contains
Statement-1 and Statement-2. Each question has 4 choices (a), (b), (c) and (d), out of which
ONLY ONE is correct.
Directions: Read the following questions and choose
(A) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True ; Statement-2 is not a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
9.
Statement-1: Carbon reduction method is not suitable for the extraction of alkaline earth
metals from their ores.
Statement-2: Carbon reacts with group two metals to form ionic carbides.
(a) A
(b) B
(c) C
(d) D
10. Statement-1: In aqueous medium, triethylamine is less basic than diethylamine but more
basic than ethylamine.
Statement-2: In diethylamine, solvation effect is more prominent than in triethylamine but
less prominent than in ethylamine.
(a) A
(b) B
(c) C
(d) D
11.
12.
Statement-1: All gases at sufficiently high pressure will have compressibility factor Z > 1
when attractive forces are dominant.
Statement-2: Space available to the gas molecules for free movement decreases as the
pressure increases.
(a) A
(b) B
(c) C
SECTION III
Linked Comprehension Type
(d) D
This section contains 2 paragraphs C13 C18. Based upon the paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (a), (b), (c) and (d), out of which
ONLY ONE is correct.
PassageI
Redox reactions are those in which oxidation and reduction take place simultaneously.
Oxidising agent can gain electron whereas reducing agent can lose electron easily. The oxidation
state of any element can never be in fraction. If oxidation number of any element comes out to
be in fraction, it is an average oxidation state of that element which is present in different oxidation
states.
13.
14.
N
N
1
2
3
NH . In this compound HN3, oxidation state of N , N and N are
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PassageII
In the presence of a strong base, aldehydes without a primary/secondary H atoms undergo
self oxidation-reduction i.e., disproportionation reaction. This is known as Cannizzaro reaction.
Thus, C6H5CHO, HCHO, R3CCHO,
16.
17.
18.
SECTION IV
Matrix Match Type
This section contains 3 questions. Each question contains statements given in two columns
which have to be matched. Statements (A), (B), (C), (D) in Column I have to be matched
with statements (1, 2, 3, 4) in Column II. One statement in first column has one or more than
one match with the statements in second column. The answers to these questions have to be
appropriately bubbled as illustrated in the following example.
If the correct matches are A 1,3, B 3, C 2,3 and D 2,4, then the correctly bubbled
4 4 matrix should be as follows:
A
B
C
D
1 2 3 4
1
1.
Column I
(Complex ion)
Column II
(Hybridisation and number of
unpaired electrons)
(A) [NiCl4]2
1.
dsp2
(B) [Cu(NH3)4]2+
2.
paramagnetic
(C) [Zn(NH3)4]2+
3.
diamagnetic
(D) [Ni(CN)4]2
4.
sp3
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2.
(P)
conc.H2SO4
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(Q)
(i) Br2
(ii) NaNH2
(excess)
(R)
H2SO4 /
HgSO4
(Q)
KMnO4 + H2SO4
Column I
Column II
(A) (P)
1.
(B) (Q)
2.
CH3CH(OH)CH3
(C) (R)
3.
Terminal alkene
(D) (S)
4.
SECTION V
Subjective or Numerical Type
The answer to these questions would lie between
0 to 9999. For any answer all four bubbles must be
filled, for example if you plan to answer as 16 then fill
0016 and if you plan to answer 0 then fill 0000 in the
grid provided in answer sheet. In case the answer is a
fraction, round it off to the nearest whole number. For
example, 725.3 is rounded off to 0725. Any incomplete
filling will be considered as incorrect filling.
Illustration: If you want to fill 2379 as your answer
then it will be filled as
1.
2.
Calculate the resonance energy of C6H6 using kekule formula for C6H6 from the following
data.
H 0f for C6H6 = 358.5 kJ mol1
(i)
(ii) Heat of atomization of C = 716.8 kJ mol1
(iii) Bond energy of CH, CC, C=C and HH are 490, 340, 620, 436.9 kJ mol1
respectively.