PART TEST-4 (PT-4) : Subject: Chemistry

PART TEST-4 (PT-4)
Code
(JEE ADVANCED PATTERN)

TARGET : JEE (MAIN+ADVANCED) 2016
SUBJECT : CHEMISTRY P06A-15

Date : 27-12-2015
COURSE : VIJAY (JR)
Time: 2 Hours
Maximum Marks : 168
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
1.
2.
The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
The question paper CODE is printed on the right hand top corner of this sheet.
3.
4.
Use the Optical Response Sheet (ORS) provided separately for answering the question.
Blank spaces are provided within this booklet for rough work.
5.
6.
Write your Name and Roll Number in the space provided on the below cover.
After the open booklet, verify that the booklet contains all the 44 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :

7.
This questions paper consists of Five sections.
8.
Carefully read the instructions given at the beginning of each section.
9.
Section 1 contains 10 multiple Choice question with Only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempted and 2 in all other cases.
10.
Section 2 contains 14 multiple Choice question with one or more than one correct option.
11.
Section 3 contains 3 "paragraph" type questions. Each paragraph describes an experiment, a situation or a problem. Two multiple
choice questions will be asked based on this paragraph. One or more than one correct option.
12.
13.
Section 4 contains 2 "match the following" type question and you will have to match entries in Column I with the entries in
Column-II.
Marking scheme : for each entry in Column I, +2 for correct answer, 0 if not attempted and 1 in all other cases.
Section 5 contains 12 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both inclusive).
There are 12 Questions & you have to attempt any 8 Questions. If a student attempts more than 8 questions, then
only first 8 questions which he has attempted will be checked.
OPTICAL RESPONSE SHEET :

14.
Darken the appropriate bubbles on the original by applying sufficient pressure.
15.
The original is machine-gradable and will be collected by the invigilator at the end of the examination.
16.
Do not tamper with or mutilate the ORS.
17.
Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this
purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each
digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :
18.
Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
19.
Darken the bubble COMPLETELY.
20.
Darken the bubble ONLY if you are sure of the answer.
21.
The correct way of darkening a bubble is as shown here :
22.
There is NO way to erase or "un-darkened bubble.
23.
The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are
evaluated.
NAME OF THE CANDIDATE : ..
ROLL NO. : ..
I have read all the instructions
and shall abide by them
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GENERAL %
CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION 1 : (Maximum Marks : 40)
This section contains TEN questions
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct
For each question, darken the bubble corresponding to the correct option in the ORS
Marking scheme :
+4 If only the bubble corresponding to the correct option is darkened
0
If none of the bubble is darkened
2 In all other cases

1.
In the following reaction, how is the rate of appearance of the underlined product related to rate of
disappearance of the underlined reactant :
+
BrO3 (aq) + 5 Br (aq) + 6 H (aq) 3 Br2 () + 3 H2O ()
(A)
d[Br2 ]
5 d[Br ]
=
dt
3
dt
(B)
(C)
d[Br2 ]
1 d[Br ]
=
2
dt
dt
(D)
d[Br2 ]
d[Br ]
=
dt
dt
d[Br2 ]
3 d[Br ]
=
dt
5
dt
Space for Rough Work
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JRPT4271215C0-1
CHEMISTRY
CHEMISTRY
2.
Product, the graph is plotted between

For a second order reaction A
1
and time 't'
[A]
1
[A]
time (minute)
1
tan = 1 and OC = 3L mole . The rate of reaction at beginning is

(A)
3.
1
9
(B)
1
8
(C)
1
17
(D)
1
10
Pink colour of acidified Ba(MnO4)2 is decolourised but there is no formation of any gas or
precipitate. This may happen with the compound containing the following acid radical.
(A) SO32
4.
(B) NO2
(C) S
(D) All of these
When CS2 layer containing both Br2 and I2 (2 : 1) is shaken with excess of chlorine (Cl2) water, the
violet colour due to I2 disappears and a pale yellow colour appears in the solution. The
disappearance of violet colour and appearance of pale yellow colour is due to the formation of :
(A) I3 and Br2 respectively.
(B) HIO3 and BrCl respectively.
(C) ICl and BrCl respectively.
(D) I and Br respectively.
JRPT4271215C0-2
CHEMISTRY
CHEMISTRY
CHEMISTRY
Heating KNO3 with conc. H2SO4 will liberate reddish-brown fumes. These fumes will
deepen/darken on addition of which of the following to the reactants?
(A) MnO2
(B) Cu turnings
(C) CuSO4
(D) KMnO4
T Constant
Partial
pressure
of gas
6.
O
Solubility of gas
Graph is drawn according to Henry's Law, what will be the order of Henry's Law constant (KH) for
Gas X & Y is ? Henry Law: Partial Pressure = KH Mole fraction (where mole fraction represents
solubility of gas.).
(A) X > Y
(B) X < Y
(C) X = Y
(D) Nothing can be predicted
Br
7.
x is
(A) Br2 / H2O
(B) HBr
(C) HBr / Peroxide
(D) NBS
JRPT4271215C0-3
CHEMISTRY
5.
CHEMISTRY
An organic compound (A) C9H18O3 with very dilute acid gives (B). (B) neither gives tollen's
reagent test nor lucas test but B gives yellow ppt of CHI3 with I2/NaOH. Structure of (A) is
O
(A)
(B)
O
OH
O
(C)
O
H
(D) OH
CH3
HO
9.
Which of the following is correct reaction for major product ?
Br
|
HOBr
(A) PhCCCH3
Ph CH C CH3
||
O
Hg2 /dil.H SO
2
4
(B) PhCCCH3
Ph CH2 C CH3
||
O
(i) BH THF
3
(C) PhCCCH3
(ii) H2O2 /OH
Br
2
(D) PhCCCH3
1eq.
Ph CH2 C H
||
O
Ph
Br
Br
CH3
JRPT4271215C0-4
CHEMISTRY
8.
CHEMISTRY
Chlorination of butane takes place as,
h
CH3CH2CH2CH3 + Cl2
CHEMISTRY
10.
Light
Consider the following relative reactivity of C H bonds for chlorination.

Degree of C H
1 C H
2 C H
3 C H
Relative reactivity
for chlorination (RR)
Percentage yield of 1-chlorobutane will be :

(A)
12
100
18
(B)
20
100
18
(C)
6
100
18
(D)
3
100
18
JRPT4271215C0-5
CHEMISTRY
This section contains FOURTEEN questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
11.
Which of the following graphs represents zero order if A P

At t = 0 [A]0
At t = t [A]t
(A)
(B)
(C)
(D)
JRPT4271215C0-6
CHEMISTRY
CHEMISTRY
Consider figure and mark the correct option.
CHEMISTRY
12.
(A) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.
(B) Activation energy of forward reaction is E1 + E2 and product is more stable than reactant.
(C) Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable
than product.
(D) Activation energy of backward reaction is E1 and reactant is more stable than product.
13.
For a reaction having rate law :

Rate :
k1[A]2 [B]
1
k 2 [A] 2 k 3 [B]
(A) At initial stages, when [B] tends to 0, order of reaction is
5
2
(B) At initial stages, rate is determined by A only.

(C) Overall order of reaction is
5
at any time
2
(D) At t = , when [A] 0, order of reaction is 2.

JRPT4271215C0-7
CHEMISTRY
Following is/are true when in a volatile solvent A, a volatile solute B is mixed to form ideal solution
(where symbols have their usual meaning):
(A)
15.
PB0 PB
PA0
nA
nB
(B)
PA0 PA
PA
nA
nA nB
(C) PA0
PA
1 XB
(D)
PA0 PA
n
= B
PA
nA
Which of the following statements is/are incorrect ?

(A) A filter paper moistened with cadmium acetate solution turns yellow, when brought in contact
with H2S gas.
(B) Both carbonate ions as well as bicarbonate ions in the solutions, give white ppt with aq. CaCl2
at 25C.
(C) Sulphites in presence of zinc, reacts with dilute H2SO4 to liberate SO3 gas.
(D) A filter paper moistened with KIO3 and starch turns blue in contact with SO2 vapours.
16.
17.
Which of the following imparts green/apple green colour to the Bunsen flame ?
(A) Calcium chloride
(B) PbSO4
(C) Barium chloride
(D) Triethoxyborane [B(OEt) 3]
An unknown substance (A) liberates a smelly gas (B) on addition of dil. HCl. However, on addition
of Zn dust to this system, liberation of another smelly gas (C) begins. Passing (B) and (C) through
lime water and conc. H2SO4 respectively turns them milky (in each case separately). (A) may be :
(A) BaS
(B) NH4HS
(C) NH4HSO3
(D) CuSO3
JRPT4271215C0-8
CHEMISTRY
14.
CHEMISTRY
18.
The vapour pressure of ideal solution of benzene and toluene is 550 torr at 80C then what would
CHEMISTRY
be correct statement about same solution at 100C ?
(A) Vapour pressure of solution = 725 torr.

(B) Composition of vapour is
2
9
and
.
11
11
(C) Composition of liquid remain same at equilibrium condition at any temperature, when the
starting mixture is heated.
(D) At 725 torr pressure at 90C, no vapour form.
19.
Which of the following reaction gives exclusively single product

(A)
HI
(B)
Br2
(D)
Br2
H2O
Me
(C)
Me
HBr
CCl4
JRPT4271215C0-9
CHEMISTRY
An aromatic optically active compound X gives following reactions. Its structure can be :
CHEMISTRY
20.
(A)
21.
(B)
(C)
(D)
Electrophilic aromatic substitution can be seen in significant amount in which of the following
cases?
(A)
O
H2 O
Cl
AlCl3
Cl
(B)
NH2
(C)
Fe
+ Br2
(D)
CH CH Cl/ AlCl
3
2
3
JRPT4271215C0-10
CHEMISTRY
Which of the following reaction correctly reports the major product?
CHEMISTRY
22.
Br
(A)
Fe
Br
(B)
Fe
Br
Fe
(C)
CHO
CHO
(D)
C H Cl / AlCl
2 5
3
C2H5
JRPT4271215C0-11
CHEMISTRY
In which reactions, correct stereo chemistry of reagent is mentioned.
(A)
(B)
(C)
CCl (solvent)
4
+ Br2
+ Bayer's reagent
(i) CF CO H
CHEMISTRY
23.
Anti addition
SYN addition
Anti addition
3
3
(ii) H3 O
(D)
D / Ni
SYN addition
JRPT4271215C0-12
CHEMISTRY
Which of the following reactions are not representing the correct major product :
HBr
(A)
HO
(B)
Br
(C)
(D)
CHEMISTRY
24.
OH
aq. AgNO3
CH OH
JRPT4271215C0-13
CHEMISTRY
This section contains TWELVE questions
There are 12 Questions & you have to attempt any 8 Questions. If a student attempts more
than 8 questions, then only first 8 questions which he has attempted will be checked.
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :
+4 If the bubble corresponding to the answer is darkened
Paragraph for Question Nos. 25 to 26
S, H = 10 kJ/mol. Answer the following

Given below is energy profile for a reaction P
questions.
82
64
R
H
(kJ/mol)
Q+S
P+Q
Reaction Coordinate
JRPT4271215C0-14
CHEMISTRY
CHEMISTRY
25.
Identify the correct options regarding the reaction.
CHEMISTRY
(A) The reaction is complex which consists of two elementary steps.

(B) The second elementary step of the reaction is bimolecular.
(C) The reaction has an intermediate, R.
(D) The value of
26.
Ea( R Q S )
Ea( R P Q ) = 18 kJ/mol.
What is/are true about the species, Q, in the reaction?

(A) Q gets consumed in the first step.
(B) Q acts like a catalyst for the reaction.
(C) Q may have altered the activation energy of the reaction P S carried out in absence of Q.
(D) Q has altered the overall enthalpy of the reaction P S in comparison to the same reaction
carried out in absence of Q.

Consider the phase diagram for the binary ideal liquid mixture of '1' and '2' shown in figure and
answer the following questions.
JRPT4271215C0-15
CHEMISTRY
'P' represents a point at which the mixture is present in :
CHEMISTRY
27.
(A) entirely liquid phase

(B) entirely vapour phase
(C) both vapour as well as liquid in equilbrium with each other
(D) cannot be predicted from the graph
28.
Which pair of points represent different phases in equilbrium with each other :
(A) P and T
(B) S and M
(C) A and S
(D) A and M
O
(P)
O
(i) AgNO3 + NH4OH,
(i) LiAlH4
(R)
(ii) EtOD
conc. H2SO4
(S)
(ii) NaBH4/EtOH
O
H2/Pd
(Q)
JRPT4271215C0-16
CHEMISTRY
(P) and (Q) are respectively :

OH
(A)
HO
DO
CHEMISTRY
29.
DO
OD
OH
O
O
(B)
OH
OD
OH
OH
OH
OH
HO
(C)
OH
HO
OD
(D)
OH
OD
DO
HO
OD
30.
(S) may be :
O
(A)
(B) O
(C)
(D)
O
O
JRPT4271215C0-17
CHEMISTRY
CHEMISTRY
This section contains TWO questions
Each question contains two columns, Column I and Column
Column I has four entries (A),(B), (C) and (D)
Column II has four entries (P),(Q), (R) and (S)
Match the entries in Column
One or more entries in Column
The ORS contains a 4 4 matrix whose layout will be similar to the one shown below :
II
I with the entries in Column II

I may match with one or more entries in Column II
(A)
(B)
(C)
(D)
For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry
(A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the
ORS. Similarly, for entries (B), (C) and (D).
Marking scheme :
For each entry in Column I
+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
JRPT4271215C0-18
CHEMISTRY
32.
Match the following :

Column-I
Column-II
(A) BCl3
(P) turns moist blue litmus red
(B) SnCl2
(Q) is water soluble to a significant extent
(C) Pb3O4
(R) is a reducing agent
(D) CO
(S) can dissolve in NaOH at STP
Match the column-I (Reactants) with column-II (Product) :

Column-I
Column-II
(A) Benzaldehyde + NaBH4
(P) Benzoic acid
(B) Benzoyl chloride + H2 + Pd + BaSO4 +
(Q) Benzyl amine
(C) Benzyl alcohol + H2CrO4
(R) Benzyl acohol
(D) Benzamide + LiAlH4
(S) Benzaldehyde
JRPT4271215C0-19
CHEMISTRY
31.
CHEMISTRY
This section contains TWELVE questions
There are 12 Questions & you have to attempt any 8 Questions. If a student attempts more
than 8 questions, then only first 8 questions which he has attempted will be checked.
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each question, darken the bubble corresponding to the correct integer in the ORS
Marking scheme :
+4 If the bubble corresponding to the answer is darkened
For a zero order reaction calculate ratio of time taken for 75% completion to 25% completion.
34.
Consider the following first order decomposition process :
Concentration
33.
time
nA
An
th
Here, 't' corresponds to the time at which (1/8) of reactant is decomposed. The value of "n" is
.
JRPT4271215C0-20
CHEMISTRY
CHEMISTRY
+
I2 + 2H2O, in acidic aqueous solution, order of reaction is

For a, reaction H2O2 + 2H + 2I
CHEMISTRY
35.
(if given mechanism is followed)

Step :
+
(A) H + I
K1
HI
K2
rapid equilibrium
3
H2O + HOI
(B) HI + H2O2
4
I2 + OH
(C) HOI + I
fast
+
5
H2O
(D) OH + H
36.
slow
fast
How many of the following gases will turn blue litmus finally red ?
H2, N2, O2, CO2, CO, NO2, SO2, Cl2.
37.
A Boron mineral have tetraborate anion whose molecular formula is [B4O5(OH)4] . The number of
BOB linkage present is :
38.
How many of the following can dissolve in aqueous HCl as well as in NaOH solution to liberate H2?
B, Al, B2H6, B2O3, NaAlH4, Al2O3, AlCl3, BF3
JRPT4271215C0-21
CHEMISTRY
Consider the following pairs of miscible liquids A and B :

Liquid A
Liquid B
(i)
C2H5Br
CS2
(ii)
CHCl3
CH3COCH3
(iii)
HCl
H2O
(iv)
CH3COOH
C5H5N
(v)
C6H5Cl
C6H5Br
(vi)
CH3COCH3
CCl4
CHEMISTRY
39.
If solutions showing Hmixing > 0 = x, solutions showing Smixing > 0 = y, solutions showing Vmixing
< 0 = z,
Then find |x + y z|.
40.
In the following reaction sequence how many are SN2Th reaction.

I : CH3COCl + CH3NH2
II : CH3CONH2 + NaCl
III : CH3COOC2H5 + NaOH
IV : CH3COOH + NaOC2H5
H
V : CH3COOC2H5 + H2O
H
VI : CH3COOH + C2H5OH
JRPT4271215C0-22
CHEMISTRY
How many of these compounds are inert towards nucleophilic substitution by H2O in aqueous
solution ?
Br
Br
Br
CH2Br
Br
CH3
CH2=CHCCH3
42.
Br
Cl / h
monochlorination
Products
How many total number of possible products are formed

JRPT4271215C0-23
CHEMISTRY
41.
CHEMISTRY
An aromatic hydrocarbon has molecular formula C11H16. Calculate only structural isomers for
C11H16, which can give benzene-1,3-dicarboxylic acid on oxidation with boiling alkaline KMnO4
followed by acidification.
44.
Observe the following reactions :

(1) HBr
(P)
(2) H2O
(1) HI
(Q)
(R)
(2) H2O
Br
(1) Mg/ether (2) CH2O (3) H, H2O
O
(1) CH3MgBr/ether
(S)
(2) H3O
(1) HBr
(T)
(2) H2O
(1) HBr / Peroxide
(U)
(2) H2O
How many reactions formed 1-methylcyclohexanol?
JRPT4271215C0-24
CHEMISTRY
43.

PART TEST-4 (PT-4) : Subject: Chemistry

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PART TEST-4 (PT-4)

(JEE ADVANCED PATTERN)

SUBJECT : CHEMISTRY P06A-15

COURSE : VIJAY (JR)

Maximum Marks : 168

QUESTION PAPER FORMAT AND MARKING SCHEME :

OPTICAL RESPONSE SHEET :

I have verified the identity, name and roll number

Resonance Eduventures Ltd.

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

SECTION 1 : (Maximum Marks : 40)

This section contains TEN questions

If none of the bubble is darkened

2 In all other cases

Space for Rough Work

Product, the graph is plotted between

tan = 1 and OC = 3L mole . The rate of reaction at beginning is

(D) All of these

(A) I3 and Br2 respectively.

(B) HIO3 and BrCl respectively.

(C) ICl and BrCl respectively.

(D) I and Br respectively.

Space for Rough Work

(D) Nothing can be predicted

(A) Br2 / H2O

(C) HBr / Peroxide

Space for Rough Work

Which of the following is correct reaction for major product ?

(ii) H2O2 /OH

Space for Rough Work

Chlorination of butane takes place as,

Consider the following relative reactivity of C H bonds for chlorination.

Percentage yield of 1-chlorobutane will be :

Space for Rough Work

Space for Rough Work

This section contains FOURTEEN questions

Which of the following graphs represents zero order if A P

Space for Rough Work

SECTION 2 : (Maximum Marks : 56)

Consider figure and mark the correct option.

For a reaction having rate law :

(A) At initial stages, when [B] tends to 0, order of reaction is

(B) At initial stages, rate is determined by A only.

(D) At t = , when [A] 0, order of reaction is 2.

Which of the following statements is/are incorrect ?

(C) Barium chloride

(D) Triethoxyborane [B(OEt) 3]

Space for Rough Work

be correct statement about same solution at 100C ?

(A) Vapour pressure of solution = 725 torr.

Which of the following reaction gives exclusively single product

Space for Rough Work

Space for Rough Work

Which of the following reaction correctly reports the major product?

Space for Rough Work

In which reactions, correct stereo chemistry of reagent is mentioned.

Space for Rough Work

Space for Rough Work

This section contains TWELVE questions

Paragraph for Question Nos. 25 to 26

S, H = 10 kJ/mol. Answer the following

Space for Rough Work

SECTION 3 : (Maximum Marks : 24)