Sodium Citrate Dihydrate

Safety Data Sheet 75579

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 11/14/2007

Revision date: 07/30/2013

Supersedes: 12/19/2007

Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1.

Product identifier

Product form

: Substance

Substance name

: Sodium Citrate Dihydrate

CAS No

: 6132-04-3

Product code

: LC23650

Formula

: C6H5Na3O72H2O

1.2.

Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

1.3.

: For laboratory and manufacturing use only.

Details of the supplier of the safety data sheet

LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
info@labchem.com - www.labchem.com
1.4.

Emergency telephone number

Emergency number

: CHEMTREC: 1-800-424-9300 or 011-703-527-3887

SECTION 2: Hazards identification

2.1.

Classification of the substance or mixture

GHS-US classification
Not classified

2.2.

Label elements

GHS-US labelling
No labelling applicable
2.3.

Other hazards

Other hazards not contributing to the

classification
2.4.

: None.

Unknown acute toxicity (GHS-US)

No data available

SECTION 3: Composition/information on ingredients

3.1.

Substances

Substance type

: Mono-constituent

Name

Product identifier

GHS-US classification

Sodium Citrate Dihydrate

(CAS No) 6132-04-3

100

Not classified

(Main constituent)

Full text of H-phrases: see section 16

3.2.

Mixture

Not applicable

SECTION 4: First aid measures

4.1.

Description of first aid measures

First-aid measures general

: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).

First-aid measures after inhalation

: Assure fresh air breathing. Allow the victim to rest.

First-aid measures after skin contact

: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse.

First-aid measures after eye contact

: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.

First-aid measures after ingestion

: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.

4.2.

Most important symptoms and effects, both acute and delayed

Symptoms/injuries
4.3.

: Not expected to present a significant hazard under anticipated conditions of normal use.

Indication of any immediate medical attention and special treatment needed

No additional information available

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EN (English)

SDS ID: 75579

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Sodium Citrate Dihydrate

Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 5: Firefighting measures

5.1.

Extinguishing media

Suitable extinguishing media

: Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media

: Do not use a heavy water stream.

5.2.

Special hazards arising from the substance or mixture

No additional information available

5.3.

Advice for firefighters

Firefighting instructions

: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.

Protection during firefighting

: Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.

Personal precautions, protective equipment and emergency procedures

6.1.1.

For non-emergency personnel

Protective equipment

: Safety glasses.

Emergency procedures

: Evacuate unnecessary personnel.

6.1.2.

For emergency responders

Protective equipment

: Equip cleanup crew with proper protection.

Emergency procedures

: Ventilate area.

6.2.

Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3.

Methods and material for containment and cleaning up

Methods for cleaning up

6.4.

: On land, sweep or shovel into suitable containers. Minimize generation of dust. Store aways from
other materials.

Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1.

Precautions for safe handling

Precautions for safe handling

: Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapour.

Hygiene measures

: Wash contaminated clothing before reuse.

7.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

: Protect from moisture. Keep container closed when not in use.

Incompatible products

: Strong oxidizers.

Incompatible materials

: Sources of ignition. Direct sunlight.

7.3.

Specific end use(s)

No additional information available

SECTION 8: Exposure controls/personal protection

8.1.

Control parameters

8.2.

Exposure controls

Appropriate engineering controls

: Provide adequate general and local exhaust ventilation. Emergency eye wash fountains and
safety showers should be available in the immediate vicinity of any potential exposure.

Personal protective equipment

: Avoid all unnecessary exposure.

Hand protection

: Wear protective gloves.

Eye protection

: Chemical goggles or safety glasses.

Respiratory protection

: Wear appropriate mask.

Other information

: Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1.

Information on basic physical and chemical properties

Physical state

: Solid

Appearance

: Powder.

Molecular mass

: 294.1 g/mol

Colour

: white.

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Sodium Citrate Dihydrate

Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Odour

: Mild odour.

Odour threshold

: No data available

pH

: 7 - 9 5% solution

Relative evaporation rate (butylacetate=1)

: No data available

Melting point

: 150 C

Freezing point

: No data available

Boiling point

: No data available

Flash point

: No data available

Self ignition temperature

: No data available

Decomposition temperature

: No data available

Flammability (solid, gas)

: No data available

Vapour pressure

: No data available

Relative vapour density at 20 C

: No data available

Relative density

: No data available

Density

: 1.7 g/cm

Solubility

: Soluble in water. Soluble in glycerol.

Water: 72 g/100ml

Log Pow

: No data available

Log Kow

: No data available

Viscosity, kinematic

: Not applicable

Viscosity, dynamic

: Not applicable

Explosive properties

: No data available.

Oxidising properties

: None.

Explosive limits

: No data available

9.2.

Other information

No additional information available

SECTION 10: Stability and reactivity

10.1.

Reactivity

No additional information available

10.2.

Chemical stability

Stable under normal conditions.

10.3.

Possibility of hazardous reactions

Not established.
10.4.

Conditions to avoid

Incompatible materials.
10.5.

Incompatible materials

Strong oxidizers.
10.6.

Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1.

Information on toxicological effects

Acute toxicity
Sodium Citrate Dihydrate ( \f )6132-04-3
LD50 oral rat
Skin corrosion/irritation

: Not classified
6730 mg/kg
: Not classified
(Based on available data, the classification criteria are not met)
pH: 7 - 9 5% solution

Serious eye damage/irritation

: Not classified
(Based on available data, the classification criteria are not met)
pH: 7 - 9 5% solution

Respiratory or skin sensitisation

: Not classified

Germ cell mutagenicity

: Not classified

Carcinogenicity

: Not classified

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Sodium Citrate Dihydrate

Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Reproductive toxicity

: Not classified

Specific target organ toxicity (single exposure)

: Not classified

Specific target organ toxicity (repeated

exposure)

: Not classified

Aspiration hazard

: Not classified

Potential Adverse human health effects and

symptoms

: Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1.

Toxicity

Sodium Citrate Dihydrate (6132-04-3)

EC50 Daphnia 1
12.2.

655 - 825.9 mg/l

Persistence and degradability

Sodium Citrate Dihydrate (6132-04-3)

Persistence and degradability
12.3.

Not established.

Bioaccumulative potential

Sodium Citrate Dihydrate (6132-04-3)

Bioaccumulative potential
12.4.

Not established.

Mobility in soil

No additional information available

12.5.

Other adverse effects

Other information

: Avoid release to the environment.

SECTION 13: Disposal considerations

13.1.

Waste treatment methods

Waste disposal recommendations

: Dispose in a safe manner in accordance with local/national regulations.

Ecology - waste materials

: Avoid release to the environment.

SECTION 14: Transport information

In accordance with DOT
14.1.

UN number

No dangerous good in sense of transport regulations

14.2.

UN proper shipping name

Not applicable
14.3.

Additional information

Other information

: No supplementary information available.

Overland transport
No additional information available
Transport by sea
No additional information available
Air transport
No additional information available

SECTION 15: Regulatory information

15.1. US Federal regulations
Sodium Citrate Dihydrate (6132-04-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
Sodium Citrate Dihydrate (6132-04-3)
Listed on the Canadian DSL (Domestic Sustances List) inventory.
WHMIS Classification
Uncontrolled product according to WHMIS classification criteria

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Sodium Citrate Dihydrate

Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

EU-Regulations
No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Not classified

Classification according to Directive 67/548/EEC or 1999/45/EC

Not classified
15.2.2.

National regulations

Sodium Citrate Dihydrate (6132-04-3)

Not listed on the Canadian Ingredient Disclosure List

15.3. US State regulations

No additional information available

SECTION 16: Other information

Other information

: None.

NFPA health hazard

: 0 - Exposure under fire conditions would offer no hazard

beyond that of ordinary combustible materials.

NFPA fire hazard

: 0 - Materials that will not burn.

NFPA reactivity

: 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water.

HMIS III Rating

Health

: 0 Minimal Hazard - No significant risk to health

Flammability

: 0 Minimal Hazard

Physical

: 0 Minimal Hazard

Personal Protection

: A

SDS US (GHS HazCom 2012)

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of
this SDS. The user must determine suitability of this information for his application.

07/30/2013

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SDS ID: 75579

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