Académique Documents
Professionnel Documents
Culture Documents
1 Introduction
In the manufacture of continuous cast
iron solidification begins in a watercooled, open-ended die. Because the
thermal conditions are different from
those for sand casting, solidification is
faster. Depending on the process, this
results in properties that differ from those
obtained by sand casting and a particularly close-grained, dense material
structure. Very high pressure-tightness
in respect of liquids and gases is a feature of continuous cast iron [1, 2].
There are no international (ISO), European (EN) or national standards for this
continuous cast iron. Representatives of
the following four firms therefore analysed the current production status of
continuous cast iron and came up with
an initial proposal for future standardisation:
- ACO Guss, Kaiserslautern (D)
- Contifonte Groupe Kuhn, Saverne (F)
- Gontermann-Peipers, Siegen (D)
- TASSO, Odense (DK)
Prof. Dr.-Ing. habil. Klaus Herfurth, Solingen,
coordinator of the DGVs Continuous Casting
ad hoc working party
2 Principles of
continuous casting
Continuous cast grey and SG iron is
manufactured using the horizontal continuous casting method. Figure 1 shows
the three main subassemblies in a horizontal continuous casting plant: a receiver
with a flange-mounted, water-cooled,
open-ended die that can be changed
quickly, a driving and pulling mechanism
with an electronic control system, and a
cutting and breaking mechanism. As the
most important subassembly, the openended die is largely responsible for the
surface quality of the cast strand, freedom
from defects, crystalline structure and
casting speed. It is made of graphite and
is enclosed by a water-cooled jacket.
The cubic capacity of the receiver depends on the production rate of the continuous casting plant and the supply cycle
for the molten iron. The receiver is replenished with molten iron at regular intervals
during the continuous casting process,
ensuring that the process is uninterrupted.
Having been tapped from the melting
furnace, the molten iron is treated
(magnesium addition, inoculation) before being poured into the receiver. This
process is repeated every 15 to 30 minutes, depending on the strand size and
casting speed. Depending on what size
of strand is being cast, the temperature
of the molten iron in the holding furnace
is between 1180 and 1300C. Because
of the thermal balance, the thinner the
strand being cast, the higher the overheating temperature must be.
The external, supporting, solid skin of the
strand forms during the initial cooling
phase of the cast iron in the open-ended
die primary cooling. This is followed by
secondary cooling, where the strands
are allowed to cool in still air. When the
strand leaves the open-ended die, it has
not yet solidified all the way through. The
core of the strand remains molten for a
time. The continuous casting die, which
is largely made of electrographite, performs the task of shaping and, by virtue
of its physical properties and cooling
intensity, sets the strands rate of cooling
to what is required. The water cooling of
the open-ended die can be regulated.
This allows the cooling intensity to be
varied. The lubricating effect of the graphite reduces friction between the continuous casting die and the strand. The
ferrostatic head of the molten metal in
the holding furnace acts on the strand
like a feeder. The liquid and solidification
contraction of the material is equalised
by the constant flow of molten metal. At
the same time, the expansion of the material that occurs during solidification as
a result of graphite separation counteracts cavitation. Continuous casting
therefore produces a cavity- and porefree structure that is particularly dense
and homogeneous.
a)
b)
c)
d)
Figure 4: Manufacturing sequences when making parts from continuous cast iron
Figure 5: Manufacturing sequence for continuous iron casting (picture: Gontermann-Peipers, Siegen (D))
Visual inspection
Dimensional inspection
Hardness test
Structure
Analysis
Mechanical
characteristics
Dye penetration test
Ultrasonic testing
Magnetic particle testing
Machiningstate
raw
machined
raw
machined
raw
machined
raw
machined
raw
machined
raw
machined
raw
machined
raw
machined
raw
machined
GJS
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
Standards
EN 10002-1, 10045-1
EN 10002-1, 10045-1
as per DIN-EN 571-1
DIN-EN 571-1
as per DIN-EN 583
DIN-EN 583-1
Drilled retaining holes and precise precentring of drilling positions are also
available. Round bars can be accurately
machined to a required size [2].
Cast iron materials are therefore secondary materials and continuous cast
iron is a secondary product. As materials,
cast irons are virtually unbeatable from
this point of view. They are also ecologically compatible to manufacture and
use. They can be recycled in their entirety,
with virtually nothing being left over. The
recycling rate has been very high for
many years and can scarcely be improved
on. Production and product waste have
always gone back into the material cycle.
Recycling does not mean a reduction in
quality that is to say, there is no downcycling. But an improvement in quality,
upcycling, is not a problem. It is possible,
for example, to make grey iron with
tenacity of 200 or 250 N/mm2 from scrap
grey iron with tenacity of 150 N/mm2.
Normal grades: tensile strength 350 900 N/mm2, 0.2 % permanent elongation limit 220 - 600 N/mm2, elongation at rupture 2 - 22 %, Brinell hardness 130 - 330 units.
a)
b)
c)
d)
e)
f)
Figure 14: Microstructure of continuous cast alloys (pictures: Gontermann-Peipers, Siegen (D))
a) GJL-150C
b) GJL-250C
c) GJL-300C
d) GJS-400-15C
e) GJS-500-7C
f) GJS-600-3C
The grades of cast iron can be ordered on the basis of both tensile
strength and hardness as the characteristic property.
The mechanical properties for continuous cast iron are set out in tables 4 to
7. In the case of grey iron, four grades of
cast iron covering a tensile strength
range of 80 to 220 N/mm2 are offered.
Brinell hardness is in the 110 - 290 units
range. In the case of SG iron the four
grades offered cover a tensile strength
Grey iron
GJL [%]
SG iron
GJS [%]
C
Si
Mn
P
S
Cr
Cu
Ni
Mg
2.80 3.70
2.25 3.99
0.40 1.00
0.08 0.25
> 0.03
0.05 0.50
0.05 0.60
0.05 0.80
3.00 3.85
2.00 3.00
0.10 0.80
< 0.04
< 0.01
< 0.01
0.05 1.20
0.05 1.00
0.025 0.080
Strand
diameter
[mm]
Tensile strength
Approximate value
min. [N/mm]
Controlling
wall thickness
[mm]
Strand
diameter
[mm]
30 - > 40
40 - > 160
160 - > 300
110
95
80
15 - > 20
20 - > 80
80 - > 150
15 - > 20
20 - > 80
80 - > 150
110 - 180
Brinell
hardness
[units]
Controlling
wall thickness
[mm]
15 - > 20
20 - > 80
80 - > 150
155
130
115
15 - > 20
20 - > 80
80 - > 150
195
170
155
30 - > 40
40 - > 160
160 - > 300
15 - > 20
20 - > 80
80 - > 150
140 - 210
GJL-HB205C, ferritic-pearlitic
GJL-250C, ferritic-pearlitic
30 - > 40
40 - > 160
160 - > 300
30 - > 40
40 - > 160
160 - > 300
170 - 240
15 - > 20
20 - > 80
80 - > 150
30 - > 40
40 - > 160
160 - > 300
220
200
185
15 - > 20
20 - > 80
80 - > 100
15 - > 20
20 - > 80
80 - > 150
220 - 290
Strand
diameter
[mm]
Tensile strength
Controlling
Permanent
wall thickness
min.
elongation limit
[mm]
[N/mm]
min. [N/mm2]
Elongation
at rupture
min. [%]
250
250
240
18
15
12
400
390
370
250
250
240
7
7
11
500
450
420
320
300
290
7
7
5
360
340
340
3
1
1
15 - > 30
30 - > 100
100 - > 200
15 - > 30
30 - > 100
100 - > 200
15 - > 30
30 - > 100
100 - > 200
Brinell
hardness
[units]
600
550
550
30 - > 60
60 - > 200
200 - > 370
15 - > 30
30 - > 100
100 - > 200
130 - 180
GJS-HB160C, ferritic-pearlitic
GJS-500-7C, pearlitic-ferritic
30 - > 60
60 - > 200
200 - > 400
Controlling
wall thickness
[mm]
15 - > 30
30 - > 100
100 - > 200
GJS-400-7C, ferritic-pearlitic
Strand
diameter
[mm]
30 - > 60
60 - > 200
200 - > 400
15 - > 30
30 - > 100
100 - > 200
130 - 190
GJS-HB205C, pearlitic-ferritic
30 - > 60
60 - > 200
200 - > 400
15 - > 30
30 - > 100
100 - > 200
170 - 240
15 - > 30
30 - > 100
100 - > 200
200 - 290
Depending on the process, these material grades contain small quantities of free carbides, which
can be removed by heat treatment.
C test piece taken from casting (DIN EN 1560)
Grey iron
GJL-150C
GJL-200C
GJL-250C
GJL-300C
CONTIFONTE
CONTIFONTE
CONTIFONTE
CONTIFONTE
CF 15
CF 20
CF 25
CFP
TASSO GG-F-Black
TASSO GG-FFP-Green
TASSO GG-FP-Red
TASSO GG-P-Yellow
SG iron
GJS-400-15C
GJS-400-7C
GJS-500-7C
CONTIFONTE CFS 40
TASSO GJS-400-15
CONTIFONTE CFS 50
TASSO GJS-500-7
GJS-600-3C
CONTIFONTE CFS 60
TASSO GJS-600-3
a)
b)
c)
5 Heat treatment of
cast iron
The heat treatment of metallic materials
divides into
-
thermal treatment
thermochemical treatment
thermomechanical treatment
The properties of cast iron can be positively influenced to a large extent using
thermal and thermochemical heat
treatment. Thermomechanical treatments are not relevant in the case of cast
iron because, apart from surface reforming, reforming is not part of the manufacturing sequence.
a)
b)
Figure 17: Sphere count for continuous cast GJS (picture: ACO Guss, Kaiserslautern
(D))
a) - in rim area
b) - in centre
Strand size
[mm]
SG iron
GJS
Round bars
30 100
> 100 200
> 200 440
8
12
16
10
14
18
Square bars
40 60
> 60 150
> 150 200
> 200 300
8
10
12
16
10
12
16
18
Table 10: Straightness (deviation from straight line) for continuous cast iron
Size
[mm]
30 100
> 100 200
> 200 440
SG iron
GJS
unannealed
annealed
4
3
3
6
5
4
6
5
4
Figure 22: Cast iron gear wheels and gear rims are typical endproducts of continuous casting that stand out for their high, uniform
hardness and good machinability. (Picture: Contifonte, Saverne (F))
5.2 Thermochemical
treatments
Thermochemical treatments are heat
treatments in which the chemical
composition of a material is deliberately
changed by diffusing one or more elements in or out. These thermochemical
treatments include nitriding, aluminising,
siliconising, boronising and chromising,
which produce positive changes in properties in cast iron as well as steel.
5.2.1 Nitriding
Nitriding is a thermochemical treatment
that produces the diffusion saturation of
the surface layer of a grade of steel or
cast iron with nitrogen by heating in a
suitable medium. The purpose of nitriding is to enhance the hardness, wear
resistance, fatigue strength and also the
Figure 25: Nitriding curve for GJS-400-15C (picture: Carl Gommann, Remscheid-Hasten)
6 Coating continuous
cast parts
8 Use of continuous
cast iron
Important areas of application are illustrated by figures 8, 10, 12, 22, 23 and
27, for example. These pictures demonstrate the diversity of possible uses.
9 Concluding remarks
7 Surface reforming
(deep rolling, shot
peening)
In surface reforming only the skin of a
component is compacted with a ball or
roller tool, which is moved over a surface
with a specific vertical force and a defined
speed, or by blasting with spherical shot
(shot peening). This causes compressive stresses.
Such surface reforming has been successfully used on the transition radii of
crankshaft castings made from SG iron,
for example. The internal compressive
stresses thus created increased compressive strength noticeably.
An ad hoc working party under the German Foundry Association (DGV) in Dsseldorf has assessed and described the
current manufacturing status of continuous cast grey and SG iron. This also
represents a first attempt with a view to
future standardisation.
The firms involved are thanked for their
expert and constructive cooperation.
Thanks go to the following individuals in
particular: Dipl.-Ing. Klaus Reif (leader
of ad hoc working party (DK)), Marco
Antes and Dipl.-Ing. Wolfgang Giese
(ACO guss (D)), Dipl.-Ing. Christophe
Ancel, Bernard Linder, Dipl.-Ing. Hans
Sattel and Dipl.-Ing. Franck Kootz
(Contifonte (F)), Dipl.-Ing. Klaus Beute
(Gontermann-Peipers (D)) and Dipl.-Ing.
Henrik Elmkvist (TASSO (DK)).
Literature
[1] ACO Eurobar - ein Qualittsstrangguss
aus Gusseisen. konstruieren + giessen
29 (2004) H. 2, pp. 41 - 42.
[2] Vollrath, K.: Hydraulikguss Zusatznutzen
durch Dienstleistungen nach Ma. konstruieren + giessen 29 (2004) H. 3, pp. 25 26.
[3] Werning, H., u. a.: Gusseisen mit Lamellengraphit. konstruieren + giessen 25
(2000) H. 2, pp. 1 - 82 (offprint).
[4] Steller, I.: Das neue VDG-Merkblatt W 50:
Gusseisen mit Vermiculargraphit konstruieren + giessen 28 (2003) H. 2, pp 22 - 24.
[5] Werning, H., u. a.: Gusseisen mit Kugelgraphit. konstruieren + giessen 13 (1988)
H. 1, pp. 1 - 98 (offprint).
[6] Rhrig, K.: 2. Europische ADI-Entwicklungskonferenz Eigenschaften, Bauteilentwicklung und Anwendungen. konstruieren + giessen 28 (2003) H. 1, pp. 2 - 14.
[7] Herfurth, K: Austenitisch-ferritisches
Gusseisen mit Kugelgraphit, Teil 1: Austenitisierung. Giesserei-Praxis (2003) H.
3, pp. 99 - 106.
[8] Herfurth, K.: Austenitisch-ferritisches
Gusseisen mit Kugelgraphit, Teil 2: Unvollstndige isothermische Austenitumwandlung. Giesserei-Praxis (2003) H. 4,
pp. 137 - 142.
[9] Werning, H.: Schwarzer Temperguss
Herstellung, Eigenschaften, Anwendungen. konstruieren + giessen 25 (2000) H.
1, pp. 27 - 42.
[10] Rhrig, K.: Die neue Norm fr Austenitische
Gusseisen. konstruieren + giessen 28
(2003) Nr. 3, pp. 31 - 32.
[11] Rhrig, K.: Austenitische Gusseisen.
konstruieren + giessen 29 (2004) H. 2,
pp. 2 - 33.
[12] Rhrig, K.: Verschleibestndige weie
Gusseisenwerkstoffe. konstruieren +
giessen 24 (1999) H. 1 (offprint).
[13] Herfurth, K., Ketscher, N., Khler, M.: Giessereitechnik kompakt - Werkstoffe, Verfahren, Anwendungen. Giesserei-Verlag
GmbH, Dsseldorf 2003.
[14] Lerner, Y. S.: Microstructure and properties of continuous cast ductile cast iron.
AFS Transactions, pp. 349 - 354.