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SET X (Acid)
This table shows the soil pH ranges required by different crops for growth.
crop
pH range
peanut
5.0 6.5
millet
6.0 6.5
sunflower
6.0 7.5
paprika
7.0 8.5
mango
5.5 6.0
(a) A farmer plants peanut and millet crops. Only the peanut crop grows well.
Predict the pH of the soil.
..................................................................................................................................... [1]
(b) Which other crop is most likely to grow well in the same soil?
..................................................................................................................................... [1]
(c) The farmer adds calcium hydroxide, Ca(OH)2, and ammonium sulphate, (NH4)2SO4, to
the soil.
Explain the purpose of using each compound.
..........................................................................................................................................
..........................................................................................................................................
..................................................................................................................................... [3]
(d) A reaction occurs between calcium hydroxide and ammonium sulphate.
(i) Complete the equation for this reaction.
Ca(OH)2 + (NH4)2SO4 + + 2H2O
(ii) Explain why the farmer should not have added these two compounds to the soil at
the same time.
.............................................................................................................................. [3]
[Total: 8 marks]
IGCSE QUESTIONS
5
limestone
3
(a) A student took 10 g of topsoil and shook it with 200 cm of distilled water.
(i) How can the student separate the solids in the soil from the solution?
stro
gly
acid
c
weakly acidic
neutral
weakly alkaline
[1]
(b) The soil contained large amounts of calcium ions and carbonate ions.
(i) Use the information in the diagram to suggest where these ions came from.
[1]
(ii) Complete the word equation for the reaction of calcium carbonate with hydrochloric
acid.
calcium
carbonate
hydrochloric
acid
calcium
chloride
.................
.................
.................
[2]
(c) The table shows the mass of each ion present in 200 cm of soil solution.
ion
formula of ion
calcium
Ca
carbonate
CO 23
iron(III)
Fe
magnesium
Mg
nitrate
NO
phosphate
PO3
mass present/milligrams
12
2+
20
3+
2+
others
(i) Which negative ion has the highest concentration in the soil solution?
[1]
3
(ii) Calculate the mass of iron(III) ions in one litre (1000 cm ) of solution.
[1]
(iii) Which ion in the t a bl e w i l l release ammonia when h e a t e d with aqueous sodium
hydroxide and aluminium foil?
[1]
(iv) Describe a test for iron(III) ions.
test
result
[3]
(d) The air trapped in the soil has a different composition from the air in the atmosphere.
The table shows the composition of the air in the soil.
gas
carbon dioxide
nitrogen
82
oxygen
15
other gases
State how the composition of soil air compares with the composition of air in
the atmosphere.
carbon
dioxide
nitrogen
oxygen
[3]
C
C
H
[1]
Total / 14
IGCSE QUESTIONS
SET X (Acid)
A6 A student adds aqueous sodium hydroxide from a burette into 25.0 cm3 of dilute sulphuric acid.
The student measures the pH value of the mixture during the addition of the sodium hydroxide.
(a) Describe how the pH value changes.
......................................................................................................................................[1]
(b) Give an ionic equation to represent the neutralisation reaction between sodium
hydroxide and sulphuric acid.
......................................................................................................................................[1]
(c) Sulphuric acid is a strong acid.
(i) What is meant by the term acid ?
...................................................................................................................................
...................................................................................................................................
(ii) What is the difference between a strong acid and a weak acid?
...................................................................................................................................
...................................................................................................................................
................................................................................................................................... [3]
(d) Dilute sulphuric acid reacts with magnesium to give hydrogen.
Give the ionic equation for this reaction.
......................................................................................................................................[1]
Total / 6
IGCSE QUESTIONS
3
SET X (Acid)
A student investigated the redox reaction between potassium iodate(V) and iodide ions. Two
experiments were carried out.
Experiment 1
A burette was filled up to the 0.0 cm3 mark with the solution A of sodium thiosulphate.
By using a measuring cylinder, a 10 cm3 sample of the solution B of potassium iodate(V)
was added into a conical flask. A 10 cm3 sample of dilute sulphuric acid was added to the
flask followed by 20 cm3 of aqueous potassium iodide.
Solution A was added slowly to the flask until there was a pale yellow colour in the contents
of the flask. Starch solution was then added into the flask and the colour changed to blueblack. Solution A was added to the flask until the colour just disappeared. Use the burette
diagram to record the volume in the table.
final burette reading / cm3
18
17
16
Experiment 2
Experiment 1 was repeated using solution C of potassium iodate(V) instead of solution B.
Use the burette diagrams to record the volumes in the table and complete the table.
initial burette reading /
cm3
Table of results
Burette readings/cm3
Experiment 1
Experiment 2
Final reading
Initial reading
0.0
Difference
[4]
The reaction of the mixture of potassium iodate(V), sulphuric acid and potassium iodide in the
flask produces iodine. Sodium thiosulphate then reacts with the iodine.
(a) (i) In which Experiment was the greatest volume of aqueous sodium thiosulphate used?
...............................................................................................................................[1]
(ii) Compare the volumes of sodium thiosulphate used in Experiments 1 and 2.
...................................................................................................................................
...............................................................................................................................[1]
(iii) Suggest an explanation for the difference in the volumes.
...................................................................................................................................
...............................................................................................................................[2]
(iv) Predict the volume of solution A which would be needed to react completely if
Experiment 1 was repeated with 20.0 cm3 of the solution of potassium iodate.
Explain your prediction.
volume of solution A .................................................................................................
explanation ...............................................................................................................
...............................................................................................................................[3]
(b) Suggest the reason starch solution was added.
..........................................................................................................................................
..........................................................................................................................................
......................................................................................................................................[2]
Total / 13
GCSE QUESTIONS
7
SET X (Acid)
Samples of concrete were placed in solutions of different pH. The graph shows the percentage
corrosion of the samples.
70
60
50
40
% corrosion
30
20
10
pH
(a) Draw a smooth line graph on the grid
[1]
(b) Which point on the grid appears to be inaccurate? Explain your reason for
identifying this point.
[2]
(c) What happens to the percentage corrosion as the pH changes from 1 to 7?
[1]
Total / 4
IGCSE QUESTIONS
1
The diagrams show the apparatus used to find the concentration of a nitric acid solution.
25.0 cm3 of nitric acid was added to a flask.
Sodium hydroxide was added to the acid until the solution was neutral. The volume of the
sodium hydroxide was noted.
nitric acid
sodium
hydroxide
flask
nitric acid
nitric acid
[3]
(b) How could you tell when the solution was neutral?
..........................................................................................................................................
......................................................................................................................................[2]
(c) How could the accuracy of the results be checked?
......................................................................................................................................[1]
Total / 6
IGCSE QUESTIONS
1
SET X (Acid)
A student investigated the neutralisation of dilute hydrochloric acid, using an excess of calcium
carbonate.
Step 1 Excess calcium carbonate was added to hydrochloric acid.
A
calcium carbonate
B
dilute hydrochloric acid
(a)
Four bottles were known to contain aqueous ammonia, dilute hydrochloric acid, sodium hydroxide
solution and vinegar, which is dilute ethanoic acid. The bottles had lost their labels. The pH values
of the four solutions were 1, 4, 10 and 13.
Complete the table.
solution
pH
aqueous ammonia
dilute hydrochloric acid
sodium hydroxide solution
vinegar
[2]
(b) The following apparatus was set up to investigate the electrical conductivity of dilute
acids.
+
bulb/lamp
carbon
cathode
carbon
anode
dilute sulphuric acid
bubbles of
oxygen gas
bubbles of
hydrogen gas
Dilute sulphuric acid is a strong acid. If it was replaced by a weak acid, what two
differences in the observations would you expect to make?
[2]
(c) When nitric acid is added to water the following reaction occurs.
HNO3
H2O
NO 3
H3O
Give the name and the formula of the particle which is transferred from nitric acid to
water.
name
formula
[2]
Al2O3
calcium oxide
CaO
carbon dioxide
CO2
carbon monoxide
CO
magnesium oxide
MgO
sulphur dioxide
SO2
(i) Which of the above oxides will react with hydrochloric acid but not with aqueous
sodium hydroxide?
[1]
(ii) Which of the above oxides will react with aqueous sodium hydroxide but not with
hydrochloric acid?
[1]
(iii) Which of the above oxides will react both with hydrochloric acid and with aqueous
sodium hydroxide?
[1]
(iv) Which of the above oxides will react neither with hydrochloric acid nor with
aqueous sodium hydroxide?
[1]
1.
A
pH 8.0
D
pH 6.4
B
pH 7.5
(a)
C
pH 7.0
E
pH 5.9
Choose from A, B, C, D or E.
.Answer ............................................................................................................................[1]
(b)
The table shows the names of some plants Sally wants to grow.
It also shows the soil pH the plants need to grow well.
name of plant
best pH of soil
apple
5.0 6.5
blackcurrant
6.0 8.0
mint
7.0 8.0
potato
4.5 6.0
strawberry
5.0 7.0
(i)
(ii)
(c)
Calcium oxide reacts with the nitric acid in the soil. Look at
the word equation for this reaction.
calcium oxide + nitric acid calcium nitrate + water
Write down the names of the products in this reaction.
..........................................................................and .................................................................[1]
(d)
electrolysis
neutralisation
oxidation
reduction
[1]
[Total: 5]
...........................................................................................................................................
.......................................................................................................................................[1]
(ii) A salt is made when sodium hydroxide reacts with dilute sulfuric acid.
What is the name of this salt?
.......................................................................................................................................[1]
(b) Jack also uses the internet to investigate sulfuric acid, H2SO4.
He finds out that dilute sulfuric acid contains ions.
One of these is the sulphate ion, SO42.
Write down the name or formula of another ion found in dilute sulfuric acid.
...............................................................................................................................................[1]
[Total: 3]
5
29.7
27.0
34.8
8.5
6.9
14.9
21.2
20.1
19.9
OCR 2008
9
(c) Look at the balanced symbol equation for the reaction between potassium hydroxide and nitric
acid.
KOH + HNO3
KNO3 + H2O
(i) The concentration of the potassium hydroxide solution is 0.100 mol / dm3.
Calculate the number of moles in 25.0 cm3 of the potassium hydroxide solution.
...........................................................................................................................................
...........................................................................................................................................
number of moles of potassium hydroxide = ..................................
[1]
(ii) Use your answer to (i) to work out the number of moles of nitric acid that will react with the
potassium hydroxide.
...........................................................................................................................................
...........................................................................................................................................
number of moles of nitric acid = ..................................
[1]
(iii) Calculate the concentration, in mol / dm3, of the dilute nitric acid.
Use the
average titre of titrations 2 and 3
answer to part (ii).
...........................................................................................................................................
...........................................................................................................................................
...........................................................................................................................................
concentration of nitric acid = .................................. mol / dm3
[2]
[Total: 6]
decomposition
electrolysis
neutralisation
precipitation
answer ............................................................................................................................... [1]
(b) Look at the table. It shows the name and formula of some bases.
name of base
formula of base
ammonia
NH3
calcium hydroxide
(i)
Ca(OH)2
copper oxide
CuO
sodium oxide
Na2O
(ii)
[1]
(c) (i)
formula of base
NH3
Ca(OH)2
copper oxide
CuO
sodium oxide
Na2O
(iii) CuO + 2H +
Cu 2+ + H2O
Change the ionic equation into a symbol equation.
[2]
(b) When sulphuric acid dissolves in water, the following reaction occurs.
H2SO4 + H2O
HSO4 - + H3O +
Explain why water is behaving as a base in this reaction.
[2]
[2]
[Total: 10]
5
Methylamine, CH3NH2, is a weak base. Its properties are similar to those of ammonia.
(a) When methylamine is dissolved in water, the following equilibrium is set up.
CH3NH2 + H2O
base
acid
CH3NH3+ + OH
(i) Suggest why the arrows are not the same length.
(ii)
Expla
[2]
(b) An aqueous solution of the strong base, sodium hydroxide, is pH 12. Predict the pH of
an aqueous solution of methylamine which has the same concentration. Give a reason
for your choice of pH.
[2]
Write the equation for the reaction between methylamine and hydrochloric acid.
Name the salt formed.
[2]
(ii) When aqueous methylamine is added to aqueous iron(II) sulphate, a green
precipitate is formed. What would you see if iron(III) chloride solution had been
used instead of iron(II) sulphate?
[1]
(iii) Suggest the name of a reagent that will displace methylamine from one of its salts,
for example methylammonium sulphate.
[1]
[Total: 9]
pH of solution of oxide
example
acidic
basic
neutral
[6]
(b) (i) Explain the term amphoteric.
[1]
(ii) Name two reagents that are needed to show that an oxide is amphoteric.
[2]
[Total: 9]
It makes a gas.
What is the name of this gas?
Choose from the list.
carbon dioxide
ethane hydrogen
oxygen
answer ............................................................................................................................... [1]
(d) The molar mass of hydrochloric acid, HCl, is 36.5 g / mol.
What is the molar mass of nitric acid, HNO3?
The relative atomic mass (Ar) of H is 1, of N is 14, of O is 16 and of Cl is 35.5.
...................................................................................................................................................
...................................................................................................................................................
................................................................................................................................................... molar
mass = .............................................. g / mol
[1] [Total:
4]
formula of base
ammonia
calcium hydroxide
NH3
Ca(OH)2
copper oxide
CuO
sodium oxide
Na2O
(c) Copper carbonate reacts with dilute nitric acid. It makes a gas.
What is the name of this gas?
............................................................................................................................................ [1]
(d) Calcium hydroxide contains hydroxide ions, OH.
Nitric acid contains hydrogen ions, H+.
Calcium hydroxide solution reacts with nitric acid.
This is a neutralisation reaction.
Write down the ionic equation for this neutralisation reaction.
............................................................................................................................................ [1]
[Total: 5]
2
(b) The student uses litmus paper to show that the river water is acidic.
What will be the result of this test?
(c) The student then boiled the river water to obtain the soluble solids.
The diagram shows how she heated the water.
[1]
[1]
(iii) an element,
[1]
(iv) a fuel?
[1]
name of ion
formula of ion
calcium
Ca2+
16
carbonate
CO32
35
chloride
Cl
nitrate
NO3
sodium
Na+
sulphate
SO42
(i) Which positive ion had the greatest concentration in the sample of river water?
[1]
(ii) Complete the following equation to show how a sodium ion is formed from
a sodium atom.
Na
Na+
+ ............
[1]
(g) Instead of using natural gas, the student could have used butane to heat the water.
The formula of butane is C4H10.
(i) What products are formed when butane burns in excess air?
[1]
(ii) Name the poisonous gas formed when butane undergoes incomplete