A Project of the Beaconhouse Group

Concordia College Okara

Super Section 1 1st Year Series 2015-16

Chemist
ry
2nd Half
Book

Name:

_________________________________________________

Roll No: _________________ Class: __________ Date:

__________

Time:
3:00hr
T.Marks:
85

Q1: Choose the correct option.

17
1. Which of the following solutions have the highest pH?
(a 0.1 M H2SO4
(b 0.01 M NaOH
(c 0.02 M
(d 0.01 M NaHCO3
)
)
)
CH3COONa
)
2. When HC added to H2S aqueous solution, its ionization.
(a Decreases
(b Increases
(c Remains
(d First increases,
)
)
)
constant
)
then decreases
3. The concentrations of reactants and products at equilibrium are.
(a Equal
(b Maximum
(c Minimum
(d Constant
)
)
)
)
4. Molarity of pure water is
(a 1
(b 18
(c
(d 6
55.5
)
)
)
)
5. In a mixture of 7 g N2 and 8 g of O2, the mole fraction of O2 is
(a 0.5
(b 0.1
(c 0.2
(d 1
)
)
)
)
6. Depression in F.pt is directly proportional to
(a Molarity
(b Molality
(c Both A and B
(d None of these
)
)
)
)
7. The cathodic reaction in the electrolysis of dil. H2SO4 with Pt electrodes is
(a Reduction
(b Oxidation
(c Both A and B
(d None of these
)
)
)
)
8. The oxidation number of S in H2SO4 is
(a +5
(b +6
(c +4
(d -5
)
)
)
)
9. When a non-spontaneous Redox reaction is carried out by using the electrical current,
then the process is called
(a Hydrolysis
(b Electrolysis
(c Both A and B
(d None of these
)
)
)
)
10. The rate of reaction ______ as the reaction proceeds.
(a Decreases
(b Increases
(c May be A or B
(d First increases,
)
)
)
)
then decreases
11. If 75% of any given amount of radioactive element disintegrates in 60 Min, then the
half life of radioactive element is
(a 30 Min
(b 20 Min
(c 25 Min
(d 40 Min
)
)
)
)
12. A substance which makes a catalyst more effective is called
(a Inhibitor
(b Retarder
(c Activator
(d Auto catalyst
)
)
)
)
nd
13. Addition of 2 electron in the valance shell of an atom shall always be

(a Exothermic
(b Endothermic
(c May be A and B (d None of these
)
)
)
)
14. Which of the following have two Pi bonds
(a CH4
(b C2H4
(c C2H2
(d C2H6
)
)
)
)
15. The bond order for He2 molecule is
(a Zero
(b One
(c Two
(d Three
)
)
)
)
16. Molarity of a solution when 5.3 g of Na2CO3 is dissolved in 1000 cm3 solutions
(a 1 M
(b 0.1 M
(c 0.05 M
(d None
)
)
)
)
17. Solubility of NaCl varies with the temperature
(a Increases
(b Decreases
(c Remain Almost
(d None of these
)
)
)
constant
)
SECTION I
Q2: Give short answers of any 22 questions.
22*2=44
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
Q3:

How NaC can be purified by common ion effect?

Write down Ke for the following reaction, suppose that the volume of reaction
mixture is V dm3 at equilibrium stage
2 HI H2 + I2
Why are the exothermic reactions are favoured to the forward direction by cooling,
but reverse is true for endothermic reactions.
How does a Buffer act? Give an example.
Prove pKa + pKb = 14
The Radioactive decay is always a first order reaction.
A particular Catalyst is suitable for a particular chemical reaction. Give examples
How does a Catalyst affect a reversible reaction?
What are the controlling factors on activity of enzymes?
What is catalytic poisoning?
Relative lowering of vapour pressure is independent of temperature.
What are ideal and non-ideal solutions?
Define colligative properties? Why are they called so?
KNO3 is used to lower the melting point of ice.
Define Molarity and Molality.
Calculate the molality of 8% (w/w) of NaCl solution.
A Salt bridge maintains the electrical neutrality in the cell. Justify.
What is SHE?
Boiling points of Solvent increases due to the presence of Solutes. Why?
Describe the electrolysis of molten NaC
What are the electrode reactions in silver oxide battery and what is its voltage.
How does electronegativily difference decide the nature of ionic bond?
Why lone pair-lone pair repulsion is more than lone pair-bond pair repulsion.
What is the sequence of molecular orbitals in nitrogen molecule?
Why bond energy of HC molecule is found to be more than expected?
SECTION II
(a) Kc for the reaction is 0.016 at 520oC.
4
2 HI H2 + I2

The equilibrium mixture contains [HI] = 0.08 M, [H2] = 0.01 M and [I2] = 0.01 M.
To this mixture, more HI is added, so that its new concentration is 0.096 M. What
will be the concentration of H2, I2 and HI when equilibrium will be reestablished?
(b) Define half-life period and order of reaction. Explain half-life period method to
determine order of reaction.
4
Q4:

(a) Give the graphical explanation for the elevation of B.pt of a Solution.
4
(b) Balance the equations.

(i) Zn + HNO3

Zn(NO3)2 + NO + H2O

2+2
(ii) MnO4 + CN-1
Q5:

MnO2 + CNO-1(Basic medium)

(a) Give main postulates of VSEPR theory and explain the geometry of NH3
4
(b) Explain Results Law.
4