Académique Documents
Professionnel Documents
Culture Documents
9701 CHEMISTRY
9701/22
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2014 series for
most Cambridge IGCSE, Cambridge International A and AS Level components and some
Cambridge O Level components.
Page 2
Mark Scheme
Cambridge International AS/A Level October/November 2014
Syllabus
9701
Paper
22
Question
Mark Scheme
reduces attraction
(3rd electron for each in) inner / lower energy level / shell / closer to nucleus
(than first two) / less shielding
[2]
[1]
(ii)
[1]
(iii)
1
1
[2]
[1]
(a) (i)
(ii)
(b) (i)
(c) (i)
Marks
Total
[3]
Page 3
Question
(ii)
Mark Scheme
Cambridge International AS/A Level October/November 2014
Mark Scheme
Syllabus
9701
Paper
22
Marks
Ba
Cl
45.1
137
23.4
35.5
31.5
16
0.329
0.329
0.659
0.329
1.969
0.329
1.00
2.00
5.98 / 6
Total
[3]
X = Mg(OH)2
Y = MgO
Z = Mg(NO3)2
1
1
1
[3]
[2]
(iii)
[1]
(iv)
Mg + 2H2O Mg(OH)2 + H2
(d) (i)
(ii)
[2]
[21]
Page 4
Question
Mark Scheme
(a)
(b) (i)
(ii)
Mark Scheme
Cambridge International AS/A Level October/November 2014
Syllabus
9701
Paper
22
Marks
Total
1
1
[2]
(c) (i)
O
S
O
S
O
1+1
O
(ii)
[2]
[2]
1
1
1
1
(Forward reaction) exothermic AND (hence in accordance with LCP) equilibrium / reaction shifts left (to counteract
inc T) ora
Kp =
pSO3
[2]
[4]
pSO 2 pO 2
[1]
Page 5
Question
(iii)
Mark Scheme
Cambridge International AS/A Level October/November 2014
Mark Scheme
Syllabus
9701
Paper
22
Marks
Kp =
Total
0.5812 (2 105)2
= 1.13 103 Pa1
5 2
5
0.065 (2 10 ) 0.355 2 10
2
1+1
[5]
[19]
(a)
(b) (i)
P; CH2 = C(CH3)2
Q; CH3CH2CH = CH2
R; CH3CH = CHCH3
S; (CH3)2CO
1
1
1
1
(ii)
H
C
C
H
H
H
C
H
trans-but-2-ene
HH
C
[4]
[2]
H
C
H
H
cis-but-2-ene
[2]
Page 6
Question
(c)
Mark Scheme
Cambridge International AS/A Level October/November 2014
Mark Scheme
Syllabus
9701
Paper
22
Marks
product; propan-2-ol
Total
[2]
[10]
(a)
(b) (i)
(ii)
1+1
[2]
Oxidation
[1]
1
1
[2]
1+1
[2]
(c)
(d) (i)
CH3CO2H
warm / hot / high temperature / heat / reflux AND concentrated sulfuric acid
[2]
[1]
(ii)
[10]