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Dr. N. K. Patel
Module: 3
Lecture: 19
PROPYLENE GLYCOL
INTRODUCTION
Propylene glycol, C3H8O2 or HO-CH2-CHOH-CH3, also called as 1,2propanediol or propane-1,2-diol is colourless, odourless an organic
compound. It is a clear, viscous liquid with a faintly sweet taste, hygroscopic
and miscible with water, acetone, and chloroform. The compound is
sometimes called -propylene glycol to distinguish it from the isomer
propane-1,3-diol HO-(CH2)3-OH, also called -propylene glycol. The
propylene glycol family of chemical compound consists of monopropylene
glycol (PG), dipropylene glycol (DPG) and tripropylene glycol (TPG). DPG
and TPG have several structure and stereochemical isomers. This chemicals
finds number of applications. Generally this chemicals are available in high
purity product so well defined manufacturing is possible in chemical
industries.
Propylene glycol was first prepared by Wurtz in 1859. Wurtz carried out
the hydrolysis of propylene glycol diacetate to yield propylene glycol. In
1931, by Carbide and carbon chemicals corporation the same method was
commercialized. In chlorohydrin process, first propylene oxide was produced
and further it was subsequently hydrolyzed to propylene glycol. All the
commercial process required high temperature, high pressure and noncatalytic hydrolysis of propylene oxide. Excess water is used for the
conversion of propylene oxide to propylene glycol.
Propylene glycol is maufactured from propylene oxideeither by noncatalytic high-temperature process at 200 2200C, or a catalytic process at
150 1800C in the presence of ion exchange resin or a small amount of
sulfuric acid or alkali as catalyst.Final products contain 20% 1,2-propanediol,
1.5% of dipropylene glycol and small amounts of other polypropylene glycols.
Which is further purified to 99.5% or greater. Propylene glycol can also be
bioconverted from waste glycerol produce during biodiesel production.
NPTEL
Module:3
Lecture:19 Propylene glycol
Dr. N. K. Patel
MANUFACTURE
Raw material
Basis -1000kg Propylene glycol (97% yield)
Propylene oxide
240kg
Water
230kg
Reaction
Manufacture process
Propylene
oxide
Water vapor
Water
mono propylene
glycol
Sulfuric
acid
Steam
out
Steam
in
Steam
out
Steam
in
Steam
out
Reactor
Steam
in
Drying
tower
Vacuum
distillation
column
Steam
NPTEL
Module:3
Lecture:19 Propylene glycol
Dr. N. K. Patel
PROPERTIES
NPTEL
Molecular formula
Molecular weight
Appearance
Odour
Boiling point
Melting point
Autoignition temperature
: C3H8O2
: 76.09gm/mole
: Colourless liquid
: Odourless
: 186 - 1880C
: -600C
: 4150C
Module:3
Lecture:19 Propylene glycol
Density
Vapour pressure
Solubility
Dr. N. K. Patel
: 1.036gm/cm3 at 250C
: 0.08mm Hg at 200C
: Fully miscible with water, ethanol,
chloroform, diethyl ether and acetone
USES
Mono-propylene glycol
Propylene glycol is used as chemical feedstock for the production of
unsaturated polyester resins
It reacts with propylene oxide to give oligomers and polymers that are
used in polyurethane application
As an humectant, solvent and preservative in food and for tobacco
products, as well as being the major ingredient in the liquid used in
electronic cigarettes combined with vegetable glycerine
As solvent in pharmaceutical and personal care productsincluding
oral, injectable and topical formulations, such as for diazepam
andlorazepamthat are insoluble in water, propylene glycol used as a
solvent in their clinical, injectable forms
It have tendency to lower the melting point of water, so it is used as
aircraft de-icing fluid and also used as automotive antifreeze
As minor ingredient in the oil dispersant
Di-propylene glycol
Its higher viscosity and greater solvency for some materials makes
choice compare to other glycol
Used in hydraulic brake fluid formation along with caster oil
Used in cutting oils, industrial soap and lubricants due to its affinity in
other oil also
Used as reactive monomer in producton of polyurethane, plastcizers
and polyester
Used in perfuminary industry as it having low odour and is standard
base formulating solvent
Tri-propylene glycol
Has ability to solubilize printing ink so it is used in cream formulation
which removes inks sytains from the hand
NPTEL
Module:3
Lecture:19 Propylene glycol
Dr. N. K. Patel
Used in textile soap due to its solubility power for water and organic
compounds and as well low volatility
Used in cutting oil concentrater and lubricants formulations
Used to produce acrylate resins
Used in production of adhesives, inks and radiation cured coatings
Alkoxylation of TPG results polyether which is used for the
manufacturing of urethane rigid foam insulation
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