- Pe ik Sle was precited as MaNtPO,*6H,0, then ignited ond Ee used ty Calculate % P.O, in the sample is rs @ roxio, . PrOs | MQNH.PO,*6H,0 aD Volume of titrant used vs p-values ©. Concentration of the titrant vs p-values B. high purity: D. reasonable sotubaity in tration mediumfe @ pCl iva solution that is 2.00% 10°M Nac and 5.4 x 10° in HO fPGa) 0 8, 2.699 © 2.595 D. 2.836 48 The phosphorus in a 0.2385-grem sample was precipitated as the slightly soluble TaMoOs This precipitate was filtered, washed and then redissolved. in acid, ‘of the resulting solution with an excess of Pb’? resulted in the formation of 1.6725 ‘gram of PbMOO.. Express the results of the analysis in terms of % P,O,. Molar Masses: PbMoQ, /GG7.14) and POs (141.94) Peds = OASy THA 9, % AL 258% B. 5.15% C. 11.29% D. 22.60% pte} 25 at volume: of ‘the titrant (In mi) will be used In the titration ‘of 50.0 mi of 0.100 M acetic oes 75x 10° 0 © 250 B 10.0 50.0 9 sample of canned tuna was analyzed by Kjeldahl metho; 22.46 mL OFM HO ¢ to titrate the liberated ammonia. Calculate the percent hitrogen in the sample? 4.01, H= 1.01, Cl = 35.45) © B. 4.74% CG 14.96% 0.783% 49.6 ; Eas) Oy) (487.13 g/mol) can be dissolved In 500 mi of water at 25°C LS? x B 1.78x10* © 356% 104 D, 266x107 Lets ple containing MnO; was titrated with 75.00-ml of 0.1175 M FeSO, solution, "Wes back ‘titrated with 7.850-ml 0.0879 M K;CrO,.. What ls the percentage of Mv E sample? (MW MnO; = 86.94 g/mol) Wed ers x01 +) ‘A 25.30 8 41,88 © 7795 D 83.76 0.8720 9 sample of @ mixture cansisting solely of sodium bromide and potassium bromide fylelds 1.505 g oF silver bromide. What is the percentage of potassium bromide in the sample? a= 22,99; .10; z = 107.87) © 599 pao |! °F. Js C. GH, D. CHoeie © CHa BD. GHane. CGH, D. GH alkai analkene, B. a cycloalkane. D) an aromatic compound, i Xcarbons does vot have isomers? (M) 25; Wil one of Si rac ote mene aiake dD. 8 Z oF OEM { {s an aromatic ) pre oes ci ont of gasoline refers toits| ‘ The ae eremage cin bY UM KG aeohl evel(it se rd om beloved) represents 3 different structural isomer of CH. than the one ih uy CH, CH, Pa) i yep ey i, ity DB oc t FE cn tenon tn rss four in ak ay wii Beier Cc. ey D a-c-8=n Armen tng cn a ct ARH B R-ter c ae © win Filton oes ain ean tr A vin B a--r Co RoR * RkF nich of these statements describes a condensation reaction?(M) A. addition of H,0 to a double bond 8. linking an acid and an alcohol to make an ester and water C, addition of H, to an alkene oxidation of ethanol to acetaldehyde 5. Bromination of benzene (C)H,), an aromatic compound (M) # (A) occurs by substitution rather than addition, B. occurs by addition rather than substitution, ¢ occurs more rapidly than bromination of a nonaromatic compound, ie results In formation of 1,2,3,4,5,6-hexabromacydohexane. ‘Which functional group, when present in a compound that is allowed to stand in air, poses a danger of stawly yielding explosive peroxicles?( My fA.) ether B. ketone CJalcohol L ‘of ethylene and water yields(M) 4 (4K 5 Ri ncenidemeb een eer, (Cnn organic aad (5) an atcohol duearbaxylie acid 58. Amines are(M) ‘A. organic bases that react with water to produce ammonia. B. organic acids that react with water to produce ammonia. C, organic. bases that react with acids to form ammanium salts, 1D. organic acids that react with bases to form ammonium salts. 19, Which of these reactions leads to a change in the hybridization of one or more carbon 60 ‘oxidation af an alcohol to yield @ carboxytic acid hydrolysis of an ester to yield an acid and an alcohol C. substitution of an aromatic ring using a halogen 1D. neutralization of an amine using a strong mineral acid of the following a ehirall molecule? A, CH{CBRQc © (CHaCHBrcH,CH, B. CBrch! (cHy,cHe. 1. Ragiatan from a mefcury lamp source is of energy 2.845 eV, Calculate the wavelength of the radiation, A. 579.0 nm ©. 408.7 nm 8. 355.0m D. 435.9.nm #2, Determine the de Broglie wavelenath of an electron with a kinetic eneray of 1,00 eV. A. 1.23nm © 364m i 8. 28.7 pm D. 870A 63. Calculate the energy separations in joules between the levels i= 2.and 2 = 2and n= 1 of an electron if) 2-box the size of a small plece of a conducting metallic wire of lengtht.0 em. Ay 2941s C tendo . 63a D. s serio oe the photons of a red light of wavelength 700 im, calculate the frequency per second et) (4 20c10!4 ronuv tm 1 < axre® B. dedsi0"® D, 0.238 a ele oe ~ ‘The haif life for the acid-catalysed hydrolysis of sucrose to form ‘glucose and fructose, = which { first order overall, is 3.20 h at 25°C. What is the rate constant for the reaction at this E perature? ea 4 AGB) 6.00 «10%5! 0.287 x 10s! ee B. 8.68 « 10%s" 4) 261 1055! Sage FS = r 66. Chlorine dioxide reacts in basic water to form chlorite id chlorate: foltowia chemical equation: le a 2010;{aq) + 20H'(aq) >-C10;"(99) + 1O,"(aq) + 1:00) A kinetic study of this reaction under a certain set of conditions yielded the data below, 5e) is @ cos2.30% 107 115010 7 © rote = NGO, /iony fate © k{0, [0H fs second order in A. IF this reaction is 10.% complete attor 70.5, eee action to be WOK complete? — ye Cc 05 ee (jus ~ { DB. 5406 mne follows first order kinetics. The rate constant at 700 K is 6 20 - at 760 K is 29.0 min, Fe nian energy fer tie reaction. ee 60 kl/mot > Z A) 270 Kyat Ga which of the following statements is never tue? flow in the external D. Oxidation takes place at the anode cathade. reaction Gibbs energy for the electrochemical reaction Fe + 14H" + 2CP" +2 Fe! 714.0 is -793 J mol, Calculate the standard cel! c 4274 D. +2.05¥ AGC | Ag delivers current at 25°C the E = 1.015V and = A.02 «LVR, The AG far the reaction 55 Jmol © -218.99 Yrnot D. -97,932.28 Jmol Caiculate the starciard cell potential for the reaction én(s) | 2n**{aq) || ‘MnO. faa), Ms!*(aq),H"(aq) | Pits) an? +26 > nE= -0.76¥ i+8H 45e 3 Mn 44H Ex 15ty A) +227 C4075 fF AY BD. -O75y For 01.002 tm aqusous CaCl soln. at 25°C use the Debye ~ Huckal limi Law to caleulat man tonic activity coefficient for Cacls a oa A 0.83 C. 0.695 € 8 096 D. 0.9131 74, Ps Partial moat volumes of water, H.O, and methanol, CH,OH, ae 17.8 cn! mol ‘and 38-4 car mat resonctvely at 250°C for dite matures ol methnal in ales Codes ae on methane OP et ethane sede to 250 cof water a his temperature. The dsty a € Methanol is 0.791 gem) 28° Som A 265 cm" © 261 cm! B. 269m" D. 250.cm? WA usd 75. Vihich of the following statements is true for an kewhdilte solution? ‘A. The solute and solvent both obey C. The solute obeys Menry's lew and the Raoult's taw, Salvent obeys Rawuih’s few. 5, The solute obeys Raoult’s taw and the D. ‘The solute and solvent both obey + solvent obeys Henry's law. Honey's lave, 6. At 300, the vapor pressure of pure benzene is 103.01 nunHd, and the vapor pressure of pure toluene is 32.06 mmbig. This liquids form a very néerly ideal solutions with emt other If 3 Mus of benzene and 2 moles af toluene are mised, at what pressure does the first waper form? A. 54.06 mmtig ©. 4.63 mmig B. 103.01 mmHg B. 32.06 mmbtg What lue of the freezing point constant for (he solvent 1, 4-dichlarobersene perry g/mol}, The enthalpy of fusion at 326.29K ty 18.88 bined ORs eit Ee Cc 060 A. 1.86eS ST: p hrene 11 ine salvent Wi whicli Mt fornia avi teleat oon : eine atthe nieiting prolyl ot tou Ak, alculate solvate oF Bei we eat fs C. 0 ae ae C90 hPa ot 20 ee jy WDM AP at 280 Kanal 81 Pa contest = ert A : Be ran rol! eet ©. OWT Kl nal! a pemsune Of S00 bor, Assure thot the dinsity of i a on oa Sear” abd that OF quid water Is 104 gon , 20Be u O. 280.59 6 re y po of Heoptane 1s 984°C Extirnate C0) thx enthalpy of vaporization ee eae ©. 40,12 kimol 3 ivoad ©. 3.6 Wiimot €8 of freestom for one-component system having twa phon by Bt te penan 7: 1 ins. expatltrhum constant for tee reaction \ SHANG) > COG) 4 Hi{g) 6 A= 1.01) 10 Ht 29.15 K, Caleulato the starulard waitin Energy af this tenyperature F364) maw | C240 mol! B 1244) mal! D, 9288 kimol! ftthon exes! amounts of hycrogen, H,, ancl lookin, 45, a0 Misi togodlioe at a Medal prmasuire of | thar, the partial oerssure of hyrtrogen fociie, Hi, vapour Prodkcnd fram bey the reaction Halg)* [{g) > 2 Hig) AL kia, Calculate the wepuiliy iris caeestanit fot he Fiewetion, A Oo Cc, 0.591 & OOS D. O208 Caicium carbonate underyensa thermal tecompanition CACOs(6) - CaQ(a) + COM g) at tulghs temperatuees. The equilibrium conwtant for the reaction 0.0120 at HOU, Calculate Wey prartiat Gressure of carbon dinrkde, CO;, when caldum cartonata, CaC),, |e hie at Ht ke A 1 Pa 120 bie B Laks 120 arts The equliirium constant for thie Feaction JUCKa) + O(a) > MOG) 4 Chia} ty 10700 at act ie and 429 ot SOO K. Use: the vant Hoff equattion ti determine ther stanclard ential’ of rmactiony A 457.1 imal ratio ky eet 8. -28.6 KI mal! DoT kd mat! Calculate the work dane evita syntem when 1.00 motif tyre Ketel bsehieic ae pistes coxa irreversoly From a volume of 1.00 dim! to) valine uf 10:0 in ayant ai extuerap peer OF 1.00 bar, A S710) c. ivtod AL Pot B -900) 49001 88. Which of the follwing statements ty alwoys tra fir a rection in setlehy Cope jp (yn Mace Aine Bo AN= ee NW) ane 89, Calculate the difference between the molar itoral miergy anid (oe mater eitaley foro portent © gas at 298.15 © 247901 iol! be ai i ©. M5 Final! Estimate the standard evthalpy change for the reaction Alo) +3 Ag)» 2 NCO)et “HOI A ino? pressued until the final ‘ti chine re energy of (ve Aue four iow avi fa chnrmpreetsed Ineithierrrially at 8 Lempernture of 3600 Fb AO, Tie constant iui loins to 80,621 * ral of funion of iodine ts 7.07 4 emmperatine aril rescore, which of the A ; 1D, “There iy fhe testriction on the value jG Hi engine nfrermtes between 400 nd 300K ad the Work dot Ie BOO, Wine is the erred mnearie efficiern y uf the engioal! . feo A 0 os ft Bee O75 7 Ail uf thw futloeding are conclisiare vf the Kinetic theory uf gases wicenpt A coer the Wan day Waals: Co tolation of ireerage kinetic tery of GH08 Ky Lerner a. ebro Hoa a Cai, Graham's tae of deffo A pipe 4 nitrogen gas: has a wiluine Of 32.4 Lat 20°C The gas is heated to 220eC ‘at cotealund prennurn. What isthe final volume of nitrogen? A 29AL coat fh. 19.44 5 | ‘What 16 the rond-mian-eeuare speed tf mitecian st OFC? A tah nfs G1 Its 8, 659 fe 1 ABZ ars. I. Maser cei 390 wate = Fh