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National Metallurgical Laboratory Madras Centre, CSIR Madras Complex, Post TTTI, Taramani, Chennai 600 113, India
b
National Metallurgical Laboratory Jamshedpur 831 007, India
Received 7 November 2003; accepted 11 February 2004
Available online 2 November 2004
Abstract
Premature and frequent failures by rapid corrosion in a pressurised underground bitumen coated mild steel ERW
water pipeline were investigated. Metallurgical and chemical characterisation of the corroded region as well as the corrosion products did not show any unusual behaviour. The soil adjacent to the pipe was also found to be only mildly
aggressive in terms of the redox potential, pH, water-soluble chloride and sulphate ion concentrations and concentration of sulphate-reducing bacteria and acid-producing bacteria over the entire length of the pipe. However, soil surface
potential gradient survey and pipe-to-soil potential measurements at various locations along the pipeline as a function
of time indicated the presence of stray currents. The rapid and frequent failures observed are promoted by stray current
corrosion.
2004 Elsevier Ltd. All rights reserved.
Keywords: Failure analysis; Pipeline failures; Corrosion; Stray currents; Buried pipelines
1. Background
Repeated failures at dierent locations in a pressurised underground water pipeline were reported within
a software complex at Chennai, India. The pipe was made of mild steel ERW tube of 165 mm diameter and
5 mm thickness. The pipes had a bitumen coating of about 34 mm thicknesses all around the surface. The
pipes were buried underground at depths varying from 1 to 2.5 m and traverses a length of about 1 km
around the building. The pipes are utilised to supply pressurised water (10.5 kgf/cm2) for the re extinguishing system. The water remains static in a pressurised condition in the pipes. The pipelines are not
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1350-6307/$ - see front matter 2004 Elsevier Ltd. All rights reserved.
doi:10.1016/j.engfailanal.2004.02.006
635
cathodically protected. Failures were reported within two years of service and about six failures at dierent
locations have been reported over the past two years. The layout of the pipeline and the reported locations
of failure are shown in Fig. 1.
2. Introduction
The common types of corrosion that can occur in a buried pipeline are: (a) pitting corrosion because of
material in-homogeneities, (b) chloride or sulphate induced stress corrosion cracking, (c) corrosion by concentration cells in soil arising out of dierences in oxygen concentration in the soil adjacent to the pipe at
dierent regions, (d) microbiologically induced corrosion under anaerobic conditions by sulphate-reducing
bacteria (SRB) and acid-producing bacteria (APB), (e) tuberculation because of the build up of corrosion
products on the internal pipe surfaces and (f) stray current corrosion by earth return direct currents.
Pitting corrosion occurs in pipelines because of the formation of local galvanic cells between the top of
the pit that has access to oxygen (cathode) and the bottom of pit that is depleted of oxygen (anode). Pitting
corrosion is normally associated with small size of pits, presence of a number of pits, long period of
Fig. 1. Schematic of software complex, layout of the pressurised water pipeline and locations of failure. The locations of pipeline
excavations, redox potential and pipe-to-soil potential measurements are also shown.
636
initiation, localised and intense attack and presence of sharply dened holes. Stress corrosion cracking is
generally associated with the presence of water-soluble chloride and sulphate ions and characterised by
microscopic surface cracks. Oxygen concentration cells can form when a pipeline passes through two or
more dierent types of soil with dierent oxygen permeation characteristics or when the pipeline stretches
through a groundwater table. To assess the formation of concentration cells, possible changes along the
surface of the pipe have to be examined with regard to the extent of aeration (redox potential) and the composition and aggressiveness of the soil (pH, salt content, resistivity etc). Regions with no aeration, high salt
content, low pH and high moisture serve as anodes and regions with good aeration, low salt content, higher
pH and moderately wet areas serve as cathodes. Microbial corrosion of underground pipelines normally
occurs under anaerobic conditions and mainly by the activity of the SRB although bacterial corrosion
by APB has also been reported [1]. The environmental conditions conducive for SRBs are temperature between 10 and 30 C (optimum 2530 C), pH of 59 (optimum 67.5), soil resistivities of 50020,000
ohm cm and a redox potential of around 100 mV (with respect to standard hydrogen electrode) [2].
For coated pipes, anaerobic conditions may be found near or underneath the coating defects. The characteristic of microbiological corrosion by SRB is the presence of black iron sulphide at the regions of corrosion and consequent H2S emanation [2].
Buried pipelines sometimes provide a better conducting path than the soil for earth return currents from
electric generators. Accelerated corrosion occurs where the current leaves the pipe i.e., at points of low
resistance along the pipeline that serve as anodes. In coated steel pipe, the discharge of the current occurs
in small areas such as pinholes or other aws in pipe/coating. At these locations, pitting and perforation of
the pipe wall can occur. The most common source of stray currents is direct current (DC) systems [3]. Stray
current corrosion is characterised by rapid and localised corrosion over a small surface area at coating defects/discontinuities and presence of pits and perforations. Unlike galvanic corrosion, where current discharge is distributed over wide areas, it is restricted to a few small points of discharge in stray current
corrosion. Stray currents can operate over long distances since the anode and cathode are more likely to
be remotely separated from one another. Existence of stray currents can be detected by measuring the uctuations of the pipe-to-soil potential with respect to time and distance as well as measurement of the surface
potential gradient in the soil along the pipeline route [4]. When the stray current is interrupted, the pipeto-soil potential will shift to more negative values [5]. Similarly, the potential gradient in the soil is a measure of the current density and the higher the current density, the greater the possibility of encountering a
stray current corrosion problem on the pipeline. Recently, direct stray current mapping along the pipeline
route has also been carried out [6].
In the present study, frequent corrosion and failures in a buried pressurised water pipeline in a software
complex were investigated. A distinct feature of the software complex was the large number of battery
backed uninterrupted power supply systems of high rating and their earthing around the complex. Both
the pipeline surface at the region of corrosion as well as the properties of the soil along the pipeline were
examined. Subsequently, the variation of the pipe-to-soil potential and the surface potential gradient along
the pipeline was measured as a function of time.
3. Experimental
3.1. Visual inspection
The piping was excavated at ve dierent locations. These included one location of failure and four other
locations close to where failure was reported on earlier occasions. The photograph of one of the excavated
site is shown in Fig. 2. The failed pipe was removed and the samples from the region of failure were cut for
metallurgical examination. Samples of soil in contact with the pipe from the ve locations were taken for
637
Fig. 2. Photograph of an excavated pipeline site. The pipe-to-soil potential measurement is also demonstrated.
laboratory analysis of the soil. In addition, sixteen dierent locations along the pipeline were selected and
excavated up to depths of 0.50.75 m for measurement of soil resistivity, redox potential and soil samples
were collected from all the sixteen locations for laboratory analysis.
3.2. Redox potential measurements
Redox potentials (voltage measured between a Pt wire in the soil solution and a reference electrode) of
the soil at the excavated sites (20 locations as shown in Fig. 1) were measured using a Pt electrode and a
saturated calomel reference electrode (SCE) and a high impedance electrometer with an input impedance
exceeding 107 ohm (Eurotron, Italy, Model: Microcal 200). The redox potentials were measured at depths
of soil ranging from 0.5 to 1.7 m. The Pt electrode comprised of a 0.5 mm Pt wire tied through a hole to a Pt
sheet of size 20 12 0.5 mm (length width thickness) giving a surface area in excess of 4.8 cm2. The
standard SCE was procured from commercial sources. The electrodes were checked for their accuracy in
a Lights solution (39.2 g/l of Fe(NH4)2(SO4)2 6H2O, 48.22 g/l of FeNH4(SO4)2 12H2O and 56.2 ml/l
of H2SO4). The measured redox potential in the Lights solution using a Pt and SCE was +436 mV and
agrees with the theoretical value.
The redox potential was measured in all the excavated sites shown in Fig. 1. The Pt electrode was
buried into the soil to be in contact with the soil solution. The SCE was also buried into the soil close
(within 20 cm) to the Pt electrode. The wire from the Pt electrode was connected to the positive terminal and the SCE to the negative terminal of the electrometer. Moisture was sprinkled in the soil
around the electrodes to ensure good conductivity. The redox potential values remained constant (5
mV) for periods in excess of 30 min. The redox potentials measured were also veried by using a saturated Cu|CuSO4 reference electrode. The redox potential measured with the dierent reference electrodes were within 15 mV.
638
639
Fig. 4. Photographs of the corroded (failed) and nearby regions of the pipeline: (a) cavity covered with corrosion products and the
existence of a pinhole, (b) cavity partially corroded, (c) pipeline surface away from the cavities and (d) inner surface of pipeline.
640
the Perspex lid served as the electrode. A provision was made on the top (in the Perspex plate) for periodic
rell of saturated copper sulphate solution. The Cu|CuSO4 half-cells were tested against a SCE. The potential of the Cu|CuSO4 (sat) cell against the SCE was 60 mV (5 mV). Further, the potential between any two
Cu|CuSO4 (sat) half-cells was within 58 mV. For the surface potential gradient survey, the Cu|CuSO4 cells
were spaced several metres apart in contact with the earth and in series with a high impedance electrometer
and the potential dierence between the cells were recorded to detect the earth current. For this purpose, 20
sites were dug up with depths ranging from 0.5 to 0.75 m along the pipeline route shown in Fig. 1. The
Cu|CuSO4 cells were placed inside the pit and covered with the soil. Water was sprinkled in the soil around
the cell to improve the conductivity. A typical sketch of the Cu|CuSO4 half-cell used for the measurements
is shown in Fig. 3. The surface potential was measured as a function of time continuously for a period of
three days. On the third day, the normal power to the software complex was switched o and the diesel
generator set activated to detect any variation in the surface soil potential upon the interruption of the regular power supply. Surface soil potentials were recorded at intervals of 15 min for a 3-h period under these
conditions (power-interrupted conditions).
3.7. Pipe-to-soil potential measurements
Pipe-to-soil potential measurements were carried out at four locations. The soil was excavated up to the
level of the pipe (1.52 m). The locations are shown in Fig. 1. Water table was not encountered up to the
excavated depths. For the purpose of pipe-to-soil potential measurement, the bitumen coating was removed
over a small area (20 cm2), the metal surface thoroughly polished with emery paper and a Pt foil was
placed on the polished metal surface. A Pt wire of 0.5 mm diameter was placed between the Pt foil and
the metal surface of the pipe and a sticking tape was applied over the Pt foil to ensure good contact between
the foil and the metal surface. The Cu|CuSO4 half-cells were immersed into the soil, one close to the pipeline, and two other cells on either side along the pipeline, each at a distance of approximately 20 m. The
purpose was to measure the pipe-to-soil potential over a large distance along the pipeline. A platinum lead
connected to the Cu|CuSO4 cell served as the negative electrode and the Pt wire attached to the pipe served
as the positive electrode. The potential between the Cu|CuSO4 half-cell and the Pt wire attached to the steel
pipe was measured using a high impedance electrometer. The photograph of the pipe-to-soil potential meas-
Table 1
Redox potential (wrt SHE) of the soil at various locations along the pipeline
Location
Depth (m)
Location
Depth (m)
C1
C2
C3b
C4
C5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
0.6
0.595
0.745
0.63
0.45
0.595
0.5
0.645
0.675
0.595
0.515
0.600
0.58
0.64
0.50
0.62
481.4
440.0
545.0
495.2
450.0
430.0
445.0
441.0
546.0
495.0
471.5
466.0
391.6
458.0
466.0
495.0
P1
P2
P3
P4
1.10
1.75
1.5
1.6
377
426
415
641
urement arrangement on the site is shown in Fig. 2. The pipe-to-soil potentials were measured at intervals
of 30 min for three days continuously, both under normal power supply and power supply-interrupted
conditions.
Table 2
Minimum resistivities, pH, water-soluble chloride and sulphate concentrations of the soil excavated from various sites
Location
Minimum resistivity
(ohm cm)
pH
Water-soluble chloride
conc. (ppm)
Water-soluble sulphate
conc. (ppm)
C1
C2
C3b
C4
C5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
P1
P2
P3
P4
Soil adhering to pipe at the failed spot
Corrosion product at the cavity
7463
5495
6250
6667
5848
4926
4082
8065
9709
7194
6757
9009
6803
15,385
18,518
4785
9009
5587
6803
8696
Not measured
Not measured
8.18
8.05
8.18
7.90
8.21
8.05
7.67
8.04
7.88
8.17
8.08
7.92
7.77
7.44
7.44
7.87
7.55
8.00
8.18
8.58
8.53
7.17
Not measured
190
270
220
200
220
880
Not measured
2750
4730
3460
2780
2000
5700
Table 3
Degree of corrosivity as a function of soil resistivity, pH and water-soluble chloride and sulphate concentrations of soil
Soil resistivity (ohm cm)
Water-soluble chloride
conc. (ppm)
Water-soluble sulphate
conc. (ppm)
pH
Degree of corrosivity
0500
5001000
10002000
200010,000
Above 10,000
Over 5000
15005000
5001500
Below 500
Over 10,000
150010,000
1501500
0150
<5.5
5.56.5
6.57.5
>7.5
Very severe
Severe
Moderate
Mild
Negligible
Table 4
Population of sulphate-reducing bacteria and acid-producing bacteria in the soil adjacent to the cavity and the corrosion product
within the cavity
Concentration (count/gm)
Soil
Corrosion product
Sulphate-reducing bacteria
Acid-producing bacteria
20
Nil
230
Nil
642
Near cavity
Near cavity
Away from cavity
% Elongation
355
380
367
265
260
279
40.48
30.28
37.08
109
643
there was a pinhole (11.5 mm diameter) penetrating right through the thickness of the pipe. The other
cavity had a depth of about 23 mm and showed corrosive deposits within the cavity. It is apparent that the
corrosion was initiated on the outer surface beneath the bitumen coating and penetrated into the pipe. The
corrosion product scraped from these two cavities was taken for chemical analysis and other tests. The inner surface of the pipe (Fig. 4(d)) did not show any visible surface defect and showed only a thin magnetite
layer on the inner surface. This surface was free of excessive corrosion. The bitumen coating appeared to be
in good condition and no corrosion by-products were found at the outer surface of the pipe in the other
locations. The soil around the pipe was found to be clay-like in nature.
4.2. Redox potential measurements
The redox potentials of the soil measured with respect to SCE and corrected with reference to standard
hydrogen (SHE) electrode at the 20 excavated sites are given in Table 1. The redox potentials of the soil at
the various locations are more or less uniform and lie in the range of 400650 mV (wrt SHE). It is seen that
the conditions in the soil are largely oxidizing (>400 mV) and are not conducive to anaerobic microbiological activity.
Fig. 6. Optical micrographs at 200 of: (a) cavity region where extensive corrosion is visible and (b) pipeline surface away from the
cavity. (Microstructures at both the locations are similar, uniform and reveal a ferrite structure with ne pearlite at the grain
boundaries.)
644
Fig. 7. Microhardness prole along the pipe surface and the cross-section of the cavity. (There is no variation in microhardness both
along the pipeline surface as well as the cross-section at the cavity region.)
645
Fig. 8. Scanning electron micrographs of the corroded surface at magnications 10 and 600. (There is no evidence of inter-granular
or trans-granular corrosion.)
Table 6
Chemical analysis of the pipe sample at various locations
Location
Inside cavity
Outer surface of pipe away from cavity
Inner surface of pipe away from cavity
Composition (%)
C
Mn
Si
0.02
0.02
0.03
0.009
0.010
0.009
0.023
0.031
0.025
0.17
0.18
0.18
0.02
0.02
0.02
10 showing the two large cavities are shown in Fig. 5. The optical micrographs (200) at the cavity and the
region away from the cavity are shown in Fig. 6. It is observed that the microstructures are uniform in all
the regions and have a ferrite structure with ne pearlite at the grain boundaries. The microhardness values
646
taken at the cavities and the normal surface did not also show any variation. The microhardness prole,
both along the surface of the pipe as well as the cross-section at the cavity region is shown in Fig. 7. It
is seen that there is no variation in the values of microhardness, both along the surface as well as in the
cross-section. The scanning electron micrographs of the fracture surface at magnications of 12 and
600 are shown in Fig. 8. The fracture surface shows the presence of corrosion products (mainly iron oxide)
and does not reveal any inter-granular or trans-granular cracking.
Table 7
Results of soil surface potential survey along the pipeline route (using matched Cu|CuSO4 (sat) cells)
Location of the matched half-cells
Soil surface
potential (mV)
C1C2
C2C3a
C3aC3b
C2C3b
C3bC4
C5C6
C6C7
C7C8
C8C9
C9C10
C12C13
C5C13
C9C14
C10C14
C14C15
C15C16
92
62
49
34
18
78
57
99
2.6
43
107
109
62
29
195
73.5
39.4
17.5
23.8
40.1
18.0
22.8
25.2
39.6
31.3
30.8
31.2
22.3
30.2
37.6
34.4
2.335
3.543
2.059
0.848
1.000
3.420
2.262
2.500
0.083
1.396
3.429
4.888
0.960
5.186
2.137
Fig. 9. Variation of the soil surface potential gradient with time under normal functioning.
647
Fig. 10. Variation of the soil surface potential gradient with time under stray current-interrupted conditions.
Fig. 11. Variation of the pipe-to-soil potential with time at the excavated site P1.
648
detected by EPMA was restricted to small local regions. Conventional analysis of the corrosion product scraped from the cavity also showed slightly higher presence of chlorine in comparison to the concentrations in the soil.
4.7. Soil surface potential gradient
The results of the soil surface potential measured using two matched Cu|CuSO4 electrodes at various
locations are shown in Table 7. The potential gradient in the soil, which is linearly proportional to the current density, was then evaluated by dividing the recorded potential dierence by the distance separating the
two matched half-cells. These results derived under static conditions are tabulated in Table 7. Higher current density regions indicate anodic regions where stray current corrosion is most likely to occur. The regions of relatively high potential gradient where stray current corrosion is most probable are indicated in
Fig. 12. Variation of the pipe-to-soil potential with time at the excavated sites P2 and P3.
Fig. 13. Variation of the pipe-to-soil potential with time at the excavated site P4.
649
Fig. 1. It is seen that the predicted regions of high current density that are susceptible to pipeline failure by
stray current corrosion roughly agrees with the regions where the actual failures occurred over the past several months (shown in Fig. 1). The variation of surface potential gradient with time over a three-day period
is shown in Fig. 9. From the plot it is seen that the surface potential gradient between points C6 and C7 has
shown a spike in the positive direction, probably indicating discharge of current at that location during the
time period of the spike. The variation of surface potential gradient with time under power-interrupted conditions is shown in Fig. 10. When the regular power supply is interrupted by a switch over to the diesel
generator, there is a positive spike in the surface potential between the points C6 and C7 and a corresponding ve spike between the points C5 and C6 probably corresponding to the interruption of the stray
current.
Fig. 14. Variation of the pipe-to-soil potential with time at the excavated site P1 under stray current-interrupted conditions.
Fig. 15. Variation of the pipe-to-soil potential with time at the excavated sites P2 and P3 under stray current-interrupted conditions.
650
Fig. 16. Variation of the pipe-to-soil potential with time at the excavated site P4 under stray current-interrupted conditions.
5. Conclusions
Based on the analysis of the experimental results, the following conclusions can be reached:
(a) The redox potential measurements indicate that the soil is highly oxidizing and is not conducive to the
growth of anaerobic bacteria.
(b) The laboratory analysis of the soil indicates that the soil resistivity, pH and the water-soluble chloride
and sulphate concentrations in the soil surrounding the pipeline are not likely to result to initiate rapid
corrosion due to aggressive conditions of the soil. The XRD and scanning electron microscopy results
conrmed the absence of chlorine or sulphate induced corrosion.
(c) The material properties such as microhardness, microstructure and composition were uniform in all
the regions (in the corroded as well as the uncorroded surfaces) of the pipe.
651
(d) The surface potential gradient survey showed regions of possible high current density in the soil. The
spike in the surface potential gradient at the location between C6 and C7 indicates possible current
discharge at this location. The pipe-to-soil potential at the same location at that instant also conrmed
this.
(e) The sudden decrease in the pipe-to-soil potential upon the interruption of the regular power supply
implies the existence of a source of stray current close to location P2.
In conclusion it can be said that the corrosion in the pipeline was promoted by stray current corrosion as
evidenced by the uctuations in the pipe-to-soil potentials and the surface soil potential gradient. The current source probably lies close to the location P2 and is conrmed by the shift in the electrode potentials
related to the location P2 to more negative values. There exists an earthing from a battery backup close to
the point P2 that was identied as the source of DC stray current. Its discharge from the pipe occurs at
various locations depending on the location of the in-homogeneities in the pipe and bitumen coating.
Acknowledgements
The authors are thankful to Director, National Metallurgical Laboratory for permission to publish this
paper. The authors are also thankful to B. Ravikumar, NML, Jamshedpur for carrying out the XRD and
to Ms. Sandhya Rani, NEERI Chennai Centre for the bacterial count in the soil and corrosion product.
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