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12. The momentum of particle which has debroglie wave length of 1A (h=6.62x10-34 kgm2s1
) is ____.
a) 6.6x10-23 kgms-1 b)6.6x10-24 kgms-1 c) 6.6x10-34 kgms-1 d) 6.6x1034 kgms-1
13. The nature of hybridization in IF7 molecule is ______.
a) Sp3d
b) Sp3d2
c) Sp3d3
d) Sp3
14. The bond order of Nitrogen molecule is ______.
a) 1
b) 2
c) 3
d) 4
15. In a molecule 8 electrons are present in binding molecular orbital and 4 electrons are
present in anti bonding molecular orbital. Its bond order is _____.
a) 3
b) 4
c) 2.5
d) 2
16. Energy levels of molecular orbitals have been experimentally determined by _____.
a) Spectroscopic studies b) X-ray diffraction c) Crystallographic studies
b) d) none of these
17. Which one of the following hybridization take place in methane, ammonium ion and
carbon tetrachloride?
a) sp3
b) sp2
c) sp
d) sp3d
18. The number of nodal planes of 2S orbital is _____.
a) 5
b)3
c) 1
d) 2
19. The hybridization involved in XeF6 is ____.
a) sp3d
b) sp3d2
c) sp3d3
d) sp3
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a) Pyramidal
b) trigonal bipyramidal
c) linear
d) tetrahedral
5. The compound used as smoke screen
a)PCI3
b)PCI5
c)PH3
d)H3PO4
6. Which shows only -1 oxidation state?
a) F
b) Br
c) Cl
d) I
7. One can draw the map of building on a glass plate by ________.
a) H I
b) H F
c) HBr
d) HCl
8. Among the halogen acid, the weakest acid is _____.
a) HF
b) HCl
c) HBr
d) H I
9. The noble gases are unreactive because by
a) Have same number of electrons
c) are gases with low densities
b) Have an atomicity of one
d) have stable electronic configuration
10. The shape of XeF4 is
a) Retrahedal
b) octahedral
c) square planar
d) pyramidal
11. The lightest gas which non-inflammable
a) He
b) H2
c) N2
d)Ar
12. The compound that is used to arrest bleeding is
a) K2SO4
b) Ferricalum
c) Al2(SO4)3
d) Potash alum
13. The toxic element of Boron family is
a) Boron
b) indium
c) thallium
d) gallium
14. Which of the following does not belong to group 14?
a) Ga
b) Si
c) C
d) Pb
15. Which one of the following reacts with glass?
a) HI
b) HF
c) HBr
d) HCl
16. Inter gas used in beacon lights for safety air Navigation is
a) Helium
b) Argon
c) Neon
d) Xenon
17. An element which belongs to Group 14 is soft in nature does not react with pure water
but dissolves in water containing dissolved air. Then the element is
a) C
b) Ge
c) Pb
d) T
1.
2.
3.
4.
5.
6.
7.
8.
9.
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a) Cu(CN)2
b) K2[Cu(CN)6]
c) K[Cu(CN)2]
d) Cu2(CN)2+(CN)2
10. Which of the following has maximum number of unpaired electrons?
a) Mn2+
b) Ti3+
c) V3+
d) Fe2+
11. The chemical composition of slag formed during the smelting process in the extraction of
copper is
a) Cu2O+FeS
b) FeSiO3
c) CuFeS2
d) Cu2S+FeO
12. The transition element with the lowest atomic number is
a) Scandium
b) Titanium
c) Zinc
d) Lanthanum
13. Which transition element shows highest oxidation state?
a) Sc
b)Ti
c) Os
d) Zn
14. Ferro chrome is an alloy of
a) Cr, C, Fe, Ni
b) Cr, `co, Ni, C
c) Fe, Cr,
d) Cr, Ni, Fe
15. The most malleable and ductile of all metal is
a) Ag
b) Zn
c) Cu
d) Au
16. The colour of Purple of cassius is
a) Purple
b) blue
c) bluish green
d) apple green
17. The metals present in Nichrome alloy
a) Cr, Fe, Cu
b) Cr, Co, Ni
c) Cr, Fe
d) Cr, Ni, Fe
18. The metal used in galvanizing iron sheets is
a) Cr
b) Cu
c) Zn
d) Ag
19. K2Cr2O7 reacts with KI and dil.H2SO4 and liberates
a) l2
b) O2
c) H2
d) SO2
20. Which one of the following pairs have almost equal radii?
a) MO, W
b) Y,La
c) Zr, Hf
d) Nb, Ta
21. Bordeaux mixture contains
a) AgNO3 + HNO3 b) Zn SO4 + H2SO4 c) CuSO4 + Ca(OH)2 d) KMnO4 + HCl
22. The number of unpaired electrons in Ti3+ is one. Then value of Magnetic Moment is (B.M)
a) 1.414
b) 2
c) 1.732
d) 3
23. Which of the following ions will give colourless aqueous solution?
a) Ni2+
b) Cu+
c) Cu2+
d) Fe2+
24. A metal which precipitate gold from its Aurocyanide complex is
a) Cr
b) Ag
c) Pt
d) Zn
25. Which of the following will have maximum magnetic moment
a) 3d2
b) 3d7
c) 3d6
d) 3d9
26. The compound used in making Ruby red glass and high class pottery is
a) Colloidal Ag
b) ruby silver
c) purple of cassius d) ruby copper
27. Spitting of silver can be prevented by the layer of
a) Borax
b) charcoal
c) sand
d) silver bromide
1.
2.
3.
4.
5.
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a) MnO2
b) CeO2
c) N2O5
d) Fe2O3
6. Alloys of Lanthanides are called as
a) Mish-metals
b) Metalloids
c) Plate metals
d) Actinides
7. _____ form oxocations.
a) Lanthanides
b) Actinides c) Noble gases d) Alkali metals
8. Maximum oxidation state exhibited by Lanthanides.
a) +1
b) +2
c) +3
d) +4
9. In Lanthanides, with increasing of atomic number the reducing property of elements is
____.
a) Increases
b) decreases
c) no change
d) none of these
10. Important Ore of lanthanides is ______.
a) Pitch blande
b) monazite
c) gypsum
d) chromite
11. Which one of the lanthanide is radio active?
a) Lanthanum
b) Promethium
c) Cerium
d) Samarium
12. The long mission space probes ______ used as power source.
a) Pu
b) U
c) Th
d) Pm
13. The common oxidation state of Actinide is _____.
a) +2
b) +3
c) +4
d) +6
14. ThO2 is used in ______.
a) Toys
b) tracer bullets
c) gas lamp materials
d) dyeing
15. Which is used as fuel in Nuclear power plants?
a) Pu 238
b) U 235
c) Mo 95
d) Th - 232
16. The isotope used as a power source in long mission space probes?
a) U 235
b) Pu 238
c) U 236
d) I 131
17. The oxidation state of Uranium in UF6 is
a) +6
b) +4
c) +3
d) 0
18. According to Fajans rule decrease in size of Ln3+ ion in Ln(OH)3
a) increases the covalent character
c) increases the basic character
b) decreases the covalent character
d) increases the ionic character
1.
2.
3.
4.
5.
6.
7.
8.
9.
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d) en
d) -2
d)
d) I
d) CN
d) 6
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a) Debye unit
b) K Joules
c) BM
d) ergs
10. The type of isomerism found in the complexes [Co(NO2)(NH3)5] SO4 and
[Co(SO4)(NH3)5] NO2
a) Hydrate isomerism b) coordination isomerism c) Linkage isomerism
d) Ionisation isomerism
11. An example of a chelating ligand is
a) NO2b) chloro
c) en
d) bromo
12. Which one of the following is a cationic complex?
a) K4 [Fe(CN)6] b) [Cu(NH3)4]cl2
c) K3 [Cr(C2O4)3]
d) K3 [Fe(CN)6]
13. The Co-ordination number of Cr3+ ion in [Cr(H2O)4 Cl2]Cl.2H2O complex is
a) 3
b) 4
c) 6
d) 2
14. The type of isomerism found in the complexes [Pt(NH3)4] [CuCl4] and [PtCl4]
[Cu(NH3)4]
a) Ionization
b) Coordination
c) linkage
d) Ligand
7. NUCLEAR CHEMISTRY(1 one mark)
1. The most penetrating radiations are ______.
a) rays
b) rays
c) rays
d) all are equally penetrating
2. Which one of the following particles is used to bombard 13Al27 to give 15P30 and a neutron
a) particle
b) deuteron
c) proton
d) neutron
8
8
3. The reaction 5B 4Be takes place due to _________.
a) decay
b) decay
c) electron capture
d) positron decay
4. Radioactivity is due to
a) Stable electronic configuration
c) Unstable nucleus
b) stable nucleus
d) Unstable electronic configuration
235
5. 92U nuclear absorbs a neutron and disintegrates into 54Xe139, 38Sr94, and X. What will be
the product X?
a) 3 neutrons
b) 2 neutrons
c) particle
d) - particle
6. Loss of a particle is equivalent to
a) Increase of one proton only
b) both a & c c) Decrease of one neutron only
d) one of these
7. The t of a particular decay is 100 seconds. Its average life is
a) 100 Sec
b) 200 Sec
c) 144 Sec
d) 1000 Sec
8. Half-life period of 79Au198 nucleus is 150 days. The average life is
a) 26.1 days
b) 21.6 days
c) 261 days
d) 216 days
9. In nuclear reaction _____ is / are balanced on both sides
a) Mass b) number of atoms c) mass number d) atomic number & mass number
10. Half-life period of a radioactive element is 1500 years. The value of disintegration
constant in terms of seconds is
a) 0.1465 x 10-10 sec-1 b) 0.2465 x 10-10 sec-1 c) 0.1465 x 10-8 fsec-1 d) 0.3465 x 10-10
sec-1
11. If t is shorter
a) Explosive
b) poisonous
c) unstable
d) stable
12. After 24 hours 0.125g of the initial quantity 1 gram of a radio active isotope is left out.
The half life period is
a) 24 hours
b) 12 hours
c) 8 hours
d) 16 hours
13. When 7N15 is bombared with a proton it gives 6C12 and
a) particle
b) Neutron
c) proton
d) particle
PHYSICAL CHEMISTRY
8. SOLID STATE - II (1 one mark)
1. The Braggs equation is
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(a)= 2d sin
(b) nd = 2sin
(c) 2= nd sin
(d) n= 2d sin
2. The crystal structure of CsCl is
(a) Simple cubic
(b) face-centred cubic (c) Tetragonal (d) Body centred cubic
3. An example for Frenkel defect is
(a) NaCl
(b) AgBr
(c) CsCl
(d) FeS
4. Semiconductors which exhibit conductivity due to the flow of excess negative electrons are
called
(a) Super conductors (b) n-type semiconductors
(c) p-type semiconductors
(d) Insulators
5. In the Braggs equation for diffraction of X-rays,n represent
(a) number of moles (b) Avogadro number
(c) A quantum number (d) Order of reflection
6. The number of close neighbours in a body centred cubic lattice of identical spheres is
(a) 6
(b) 4
(c) 12
(d) 8
7. An ion leaves its regular site occupies a position in the space between the lattice sites is
called -------(a) schottky defect
(b) Impurity defect (c) frenkal defect
(d) vacancy defect
8. In a simple cubic cell, each point on a corner is shared by
(a) One unit cell
(b) Two unit cell
(c) 8 unit cell (d) 4 unit cell
9. The total number of atoms per unit cell is bcc is
(a) 1
(b) 2
(c) 3
(d) 4
10. Rutile is
(a) TiO2
(b) Cu2O
(c) MoS2
(d) Ru
11. An example of metal deficiency defect
(a) NaCl
(b) AgCl
(c) CsCl
(d) FeS
12. The co-ordination number of ZnS is ------(a) 6
(b) 2
(c) 3
(d) 4
13. In FCC, the face atom is shared between now many unit cells ? the crystal lattice with
coordination number four
(a) NaCl
(b) CsCl
(c) BN
(d) ZnO
14. The crystal having Frenkal defect the size of the anion is -----(a) bigger than cation
(b) smaller than the cation
(c) equal to the cation (d)
both are bigger in size
15. How many atoms are there in a unit cell of a metal crystallizing in fcc structure?
(a) 1
(b) 2
(c) 6
(d) 4
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a) G > 0
b) S< 0
c) G < 0
24. The network obtained from a system is given by ------------a) W+P V
b) W-P V
c) -W+P V
25. The cgs unit of entropy is -----------a) cal K-1
b) J K-1
c) cal mol-1 K-1
d) H > 0
d) -W-P V
d) eu mol-1
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b) 2SO2 + O2
2SO3, H = -47KJ mol-1
c) N2 O4
2NO2, H = +59KJ mol-1
d) b & c
14. The equilibrium constant Kc for a A(g)
B (g) is 2.5x10-2 the rate constant of
forward reaction is 0.05 sec-1 . therefore,
the rate constant of the reverse reaction is -----------a) 2sec-1
b) 2 sec
c) 2 min
d) 0.2 min
15. Forward reaction takes place when -------a) Kc=1/Q
b) Q>Kc
c) Q=Kc
d) Q<Kc
16. The equilibrium constant Kc for the reaction 2O3
3O2 is ------------a) [O2]3/[O2]2 b) [O2]2 / [O3]3
c) [O2]3 / [O3]2
d) [O3] / [O2]
17. If the equilibrium constants of the reaction 2HI
H2+ I2, and H2+ I2
2HI are
K1 and K2 respectively them.
a) K1= 2K2
b) K1= 1/K2
c) K2= (K1)2
d) K1= 1/(K2) 2
18. In which of the following gaseous reactions Kp < Kc is ----------a) H2+ I2
2HI
b) N2 + 3H2
2NH3
c) CO + H2O
CO2 + H2
d) PCl5
PCl3 + Cl2
19. In which of the following gaseous equilibrium ng= (+ve)
a) Kp = Kc
b) Kp < Kc
c) Kp > Kc
d) Kp+ Kc/2
20. In which of the following equilibrium ng= (-ve)
a) H2+ I2
2HI
b) N2 + 3H2
2NH3
c) 2H2O + 2Cl2
4HCl + O2
d) PCl5
PCl3 + Cl2
21.The unit of Kp for the equilibrium when NH3 is synthesized from N2 and H2 -----a) L-2 mol -2
b) atm -2
c) L atm -2
d) atm -1
22. The Kc for the equilibrium H2+ I2
2HI is 16 what is Kp for this equilibrium
a) 1/16
b) 4
c) 64
d) 16
23. In the equilibrium constant for the formation of a products is 25. The equilibrium constant
for the decomposition of the same product is ---------a) 25
b) 1/25
c) 5
d) 625
24. For the equilibrium 2H2O + 2Cl2
4HCl + O2 Kp and Kc are related as -------------a) Kp = Kc
b) Kp < Kc
c) Kp > Kc
d) Kp = Kc(RT) -2
25. The equilibrium constant for the reaction 2A
B is 25 mol-1 dm-3 at 900K. What is
the equilibrium constant for the
reaction B
2A in dm-3 mol at the same temperature ?
a) 25
b) 625
c) 0.04
d) 0.4
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13. Identify the compound that is used in the treatment of asthma and whooping cough ____.
a) Benzyl acetate b) phenyl acetate c)Benzyl benzoate
d) phenyl benzoate
14. Oxidation of glycerol with Bismuth nitrate gives
a) Meso oxalic acid b)glyceric acid
c) tartonic acid
d) a & c
17. ETHERS (2 one marks)
1. Which one of the following is simple ether?
a) CH3 O C2H5 b)C2H5 O CH3
c) C2H5 O C2H5 d) C3H7 O C2H5
2. Diethyl ether can be decomposed with
a) HI
b) KMnO4
c) NaOH
d) H2O
3. Oxygen atom of ether is
a) Very active
b) replaceable
c) oxidizing d) comparatively inert
4. `according to Lewis concept of acids and bases, ethers are
a) Neutral
b) acidic
c) basic
d) amphoteric
5. Intermolecular hydrogen bonds are present in
a) CH3COOH
b) C2H5O C2H5
c) CH3CH2OH
d) C2H5NH2
6. When ethyl iodide is treated with dry silver oxide it forms
a) Ethyl alcohol b) diethyl ether c) silver ethoxide
d) ethyl methyl ether
7. Williamsons synthesis is an example of
a) Nucleophilic addition
c) electrophilic substitution
b)Electrophilic addition
d) nucleophilic substitution
8. When ether is exposed to air for sometime an explosive substance produced is
a) Peroxide
b) oxide
c) TNT
d) superoxide
9. Ether is formed when alkylhalide is treated with sodium alkoxide. This method is known
as a) Hoffmann reaction b) Williamsons synthesis c) Wurtz synthesis d) Kolbes
reaction
10. Higher ethers can be prepared from lower members by the action of
a) con.H2SO4
b) AgOH
c) sodium alkoxide d) Grignard reagent
11. Ethers dissolve in con.H2SO4 due to the formation of
a) Peroxides
b) ethyl hydrogen sulphate c) oxonium salts
d) alcohols
12. Which reagent is used in the Zeisels method of detection and estimation of alkoxy
groups?
a) RMgx
b) O2
c) Con H2SO4
d) HI
13. Which one of the following is simple ether?
a) CH3 O CH3
b) C3H7 O C3H7 c) C2H5 O CH3 d) C6H5 O C6H5
14. How many alcohol isomers are possible for the formula C2H10O?
a) 2
b) 4
c) 3
d) 7
15. Identify the best solvent for Grignard reagent ______.
a) Alcohol
b) water
c) CO2
d) ether
16. Which one of the following is formed when anisole reacts with bromine?
a) m bromo anisole b) o bromo anisole c) o & p bromo anisole d) benzoid acid
17. How many ethers isomers are possible for the formula C2H10O?
a) One
b) two
c) three
d) seven
18. When diethyl ethers reacts with cl2 in presence of sunlight it gives
a) -chlorodiethyl ether b) - 1 dlichloro diethylether c) Perchloro diethyl chloro
d) both a&b
19. _____ is used as a substitute for petrol
a) Diethylether
c) diethylether mixed with alcohol
b) ether with NH3
d) diethylether with naphthalene
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20. Reaction in which oxonium salt is formed when etherial oxgyen reacts with strong mineral
acid is called
a) Electronation
b) protonation
c) deprotonation
d) dehydration
21. Ether used in perfumery is
a) Diethylether
b) dimethylether
c) methyl phenyl ethe
d) diphenylether
22. The IUPAC name of phenatole is
a) Ethyl phenyl ether b) methylphenyl ether c) diethyl ether d) ethoxy benzene
18. CARBONYL COMPOUNDS(1 one mark)
1. Schiffs reagent gives pink colour with
a) Acetone
b) acetaldehyde
c) ethyl alcohol d) methyl acetate
2. Methyl ketones are usually characterized by
a) the Felings solution b) the iodoform test
c) the Schiffs test
d) the Tollens reagent
3. Which of the following compounds is oxidized to give ethyl methyl ketone?
a) 2 praponal
b) 2 pentanone
c) 1 butanol d) 2 - butanol
4. The compound that does not undergo Canizaro reaction is
a) Formaldehyde
b) acetaldehyde
c) benzaldehyde
d) trimethyl acetaldehyde
5. The formation of cyanohydrin from a ketone is an example of
a) Electrophilic addition
c) nucleophilic substitution
b) nucleophilic addition
d) electrophilic substitution
6. Hydrogenation of benzoyl chloride in the presence of Pd on BaSO4 gives
a) Phenol
b) benzoic acid
c)benzyl alcohol
d) benzaldehyde
7. From which of the following tertiary butyl alcohol is obtained by the action of methyl
magnesium iodide?
a) HCHO
b) CH3CHO
c) CH3COCH3
d) CO2
8. Aldol is
a) 2 hydroxyl butane
b) 3 hydroxyl butanol
c) 3 hydroxyl butanal
d) 2 hydroxyl butanal
9. A cyanohydrin of a compound X on hydrolysis gives lactic acid. The X is
a) HCHO
b) CH3CHO
c) (CH3)2CO
d) C6H5CH2CHO
10. Which of the following does not give iodoform test?
a) Aceto phenone
b) benzophenone
c) CH3CH(OH)CH2
d) CH3CH(OH)-HC2CH2CH3
11. The compound which does not reduce fehling solution is
a) Formaldehyde
b) acetaldehyde
c) benzaldehyde
d) propionaldehyde
12. CH3COCH3con.H2SO4 product. The product is
a) Mesitylene
b) mesityl oxide
c) phorone
d) paraldehyde
13. The compound used in the preparation of the tranquilizer, sulphonal is
a) Acetone
b) acetophenone
c) isopropyl alcohol d) glycol
distillation
14. Calcium acetate + calcium benzoate
gives
a) Benzophenone
b) benzaldehyde c) acetophenone
d) phenyl benzoate
19. CARBOXYLIC ACIDS(1 one mark)
1. Which of the following is least acidic?
a)C2H5OH
b) CH3COOH
c) C6H5OH
d) ClCH2COOH
2. The acid which reduces Tollens reagent is
a) Acetic acid
b) benzoic acid
c) formic acid
d) oxalic acid
3. The isomerism exhibited by CH3CH2COOH and CH3COOCH2 is
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a) Metamerism
b) position
c) chain
d) functional
4. The acid that cannot be prepared by Grignard regent
a) Acetic acid
b) formic acid
c) butyric acid
d) benzoic acid
5. Which order of arrangement is correct in terms of the strength of the acid
a) CH3CH2COOH>CH3COOH<HCHOOH<CICH2COOH
b) CICH2COOH < HCOOH <CH3COOH <CH3CH2COOH
c) CH3CH2COOH <CH3COOH < HCHOOH <CICH2COOH
d) HCOOH >CH3CH2COOH <CH3COOH > CICH2COOH
6. Among the following the strongest acid is
a) CICH2COOH
b) CI3C COOH c)CH3COOH
d) CI2CHCOOH
7. The compound found in some stony deposit in kidneys is
a) Potassium oxalate b) oxalic acid c) potassium succinate d) calcium oxalate
8. Ethylene dicyanide on hydrolysis using acid gives
a) Oxalic acid b) succinic acid
c) adipic acid
d) propionic acid
9. Electrolysis of concentrated aqueous solution of sodium acetate gives
a) Ethane
b) propane
c) methane
d) butane
20. NITROGEN COMPOUNDS (3 one marks)
O
1. Isomerism exhibited by CH3 CH2 N
and CH3CH2 O N = O is
O
a) Position
b) chain
c) functional
d) tautomerism
2. In nitro alkanes NO2 group is converted to NH2 group by the reaction with
a) Sn/HCl
b) Zn dust
c) Zn/NH4Cl
d) Zn/NaOH
3. When nitromethane is reduced with Zn dust + NH4Cl in neutral medium, we get
a) CH3NH2
b) C2H5NH2
c)CH3NHOH
d) C2H5COOH
4. The compound that is most reactive towards electrophilic nitration is
a) Toluene b) benzene
c) benzoic acid
d) nitrobenzene
5. Nitromethane condenses with acetaldehyde to give
a) Nitro propane
b) 1-nitro-2propanol c) 2-nitro-1-propanol d) 3-nitro propanol
6. Which of the following compounds has the smell of bitter almonds?
a) Aniline
b) nitro methane
c) benzene sulphonic acid
d) nitro benzene
7. Nitro benzene on electrolytic reduction in con. H2SO4 the intermediate formed is
a) C6H5NH NHC6H5 b) C6H5NHOH
c) C6H5-N=N-C6H5 d) C6H5.HSO4
8. Electrophile used in the nitration of benzene is _____
a) Hydronium ion b) sulphonic ion c) nitronium ion
d) bromide ion
9. The basic character of amines is due to the
a) Tetrahedral structure c) lone pair of electrons on nitrogen atom
b) Presence of nitrogen atom
d) high electronegativity of nitrogen
10. The organic compound that undergoes carbylamines reduction is
a) (C2H5)2NH
b) C2H5NH2
c) (C2H5)3N
d) [(C2H5)4N]+111. Primary amine acts as
a) Electrophile
b) lewis base
c) lewis acid
d) free radical
12. Oxidation of aniline with acidified potassium dichromate gives
a) p-benzo quinone b) benzoic acid
c) benzaldehyde
d) benzyl alcohol
13. Which one of the following is a secondary amine?
a) Aniline
b) diphenyl amine c) sec-butylamine
d) tert-butyl amine
NaNO2/HCl
14. C6H5NH2
X. Identify X.
a) C6H5Cl
b) C6H5NHOH
c) C6H5N2Cl
d) C6H5OH
15. Which of the following will not undergo diazotisaation?
a) m-tutuidine
b) aniline
c) p-amino phenol
d) benzyl amine
16. Amiline differs from ethylamine by the reaction with
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