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Class: XII

(SOLUTION)-2

Target IIT-JEE 2016

Test Code: 1823

Date: 25.10.2015

PHYSICS

1. (B)

mv
Bq

2. (A)


(e) (v B)

4. (D)
C CO2H

v1

N2

Me

Me

5. (B)

F.B.D in two cases is as shown in case (b) normal will be


less and incase (b) work done by magnetic field is zero so
height in two cases will be same.]

k
B0 0 B 0

0 k
2
B0 B1
3. (B)

2
B1 B2
B0
2
4. (A)
5. (A)
6. (D) current inclosed is same so Bd will be same for both
cases.

14. (A)

10 / 2
5 2

HO

C CH + HOH

7. (B)

C = CH
H

O
CH2 CHO

tautomerism

8. (B)

3 H

3 H
(i) O3

(ii) Zn/H2O

C OH

C=O
CH
H
2
H

KOH
Aldol condensation

H2O

CHO

CHO

O
R

2 sinr

9. (A)
10. (D)

A2 = 3

It is Clemmensen reduction. OH is also converted to Cl.

H2/Ni attacks both C = C and >C = 0


H2/Pt attacks C = C only
LiAlH4 attacks >C = 0 only

11. (C)

O
||

H
|

Aldol
3H C H C CHO

16. (A)
17. (A)
L = 2m + 2m + 2m = 6 m

OH
|

reaction

H2COH
|

HOCH2

12. (A)
13. (D)
14. (B)

CHEMISTRY
H3C C = NMgBr
HOH
OMe

HO

||

OH

CH3

C = O + H2NOH

CH3
OMe

acetylation of OH group by acetic anhydride.


Iodoform Reaction followed by decarboxylation

NaOH conc.
Cannizzaro
reaction

+ HCOONa
HO

OH

Follow Cannizzaro reaction on each benzene ring.

CH3

H3C C = O

H+

HCHO
H 2 C C C

CH3

2. (B)
3. (C)

Z=

1. (D)

Y=

1 V = 1 (XL XC) = 1 5 = 5 Volt

(m1 1) A1 = (m2 1) A2
By Snell's Law
1sin 90 =
r = 45]

OCH3

The second lens is diverging.


15. (A)
18. (C)

Z (X L X C ) 2 R 2 25 25 5 2

I rms
11. (B)
12. (C)
13. (C)

ONa

X=

a 2

a 2

7. (A) M B I 8a 2
8a 2 B
Bsin 90 = I
2

8. (C)
9. (B)
10. (B)

C OH

HNO2

OH

6. (C)

(b)

(a)

Br2 +
KOH

v2
mg

mg

Ph

H C NH2

N1

C C NH2

Ph

Me

Me

CH3 CH2
CH3

C=N

H2O
+

OH

CH3

C=N

OH

CH3
(Only one compound)

C = O + H2NOH

H2O

Page #1

Class: XII
CH3 CH2

CH3 CH2

C=N

CH3

OH

OH

C=N

CH3

17. (A) O

C H CH2 COOH
H2 O
Anti M.R.
Addition

||

Ag2O

CH

/ COOH
2
\ COOH

O=C

C CH = CH

18. (C)

(MATHEMATICS)
37. (A) lim
x 0

38. (A)

(1 a 3 ) 8e1/ x
1 (1 b3 ) e1/ x
08

0 (1 b3 )
b = ( 3)1/3

lim

x 0

= 2 lim
x 0

(1 a 3 ) e1/ x 8
e1/ x (1 b3 )

Again, lim
x 0

(1 a 3 ) 8e1/ x
1 4e1/ x
f (1 h) f (1)

1 4sin 2 x 4sin x 1 = 1

=2

1 f (x) 4

(1 a 3 ) 8e1/ x
1 (1 b3 ) e1/ x
1 + a3 = 2

=2
a=1

= lim

f (x) = 30x9 56x7 + 30x5 63x2 + 6x

46. (C)

lim

[x] [x 2 ] [x 3 ] .... [x 2n 1 ] n 2

1 [x 2 ] | x | 2x
(1) 0 0 (1) 0 .... 0 (1) n 2
lim
x 0
1 0 x 2x
1
= lim
1
x 0 1 x
x 0

We have, x [2, 2] x [0, 2]

f(|x|) = |x| 1. Now, f(|x|) = x x 1 = x


1
x 1 = x for x 0 x =
And x 1 = x
2

n
4n 1 1
4n 1 1
r nr

a b =
r 0
3 x 2n
3
40. (C) When x 0 , we have [x2n + 1] = 1 and [x2n] = 0 for
n = 0, 1, 2,

sec 4 x cos ec 4 x

Clearly cos(sin x) and sin(cos x) are


decreasing
functions on [0, /2 ].

Range (f) = f , f (0) = cos1,1 sin1


2

39.(C)

f (x) =

x 3 x 4 cot x
sec 4 x cos ec 4 x
sec 4 x cos ec 4 x
( x) =
=
= f (x)
3
4
x x cot x
x 3 x 4 cot x
So, f (x) is an odd function. f (x) is not a periodic
function due to the presence of x in the
denominator.
44. (B)
Verify options
45. (B)
We have, f (x) = cos(sin x) + sin(cos x)
We observe that f (x) is not defined in ( /2 , 3 /2)
and it is a periodic function with period 2 . So let
us consider the internal [ /2, /2] as it domain.
Further, since f (x) is an even function. So, we will
consider f (x) defined on [0, /2] only.

f (1) = 30 56 + 30 63 + 6 = 53
f (1 h) f (1) 53
Hence, lim
.

h 0
3
h3 3h

x2 + 2x + 3 = (x + 1)2 + 2 2 for all x R.


n
1 cos 1
a = 2 b = lim
=
ar bn r
2
0
r

0
2

1 22 n 1
n r
n
n
n 1 n 2r


r nr
r 1
a b
2

r 0
r 0
r 0 2
1

4
2

1
1

1
4 f (x)

2x
2x

tan(2 tan 1 x)for 0 x 1 tan tan 1


2
1 x 1 x2

1

2

2sin x 12

2x
2 tan 1 x, if 1 x 1 and
42. (A) sin 1
2
1

x
1
cos1
2
2 tan x, if 0 x .
1 x
2
1
2x
1

1 1 x
tan sin 1

cos

1 x2 2
1 x2
2

43. (D)

= 2 1 b3 = 4 b3 = 3

f (1 h) f (1) 1
h 0
h 0
h
h 3h
h2 3
f (1 h) f (1) 1
1
1
= lim
= f '(1) = f '(1)
h 0
(1 h) 1 h 2 3
3
3
10
8
6
3
2
Now, f (x) = 3x 7x + 5x 21x + 3x 7.

lim

f(x) = 1 5 4sin x 4cos 2 x =

0 2sin x 1 3 1 1 2sin x 1 4
Hg2

C CH3

41. (D)

Target IIT-JEE 2016

= 1 2sin x 1 . Now 1 2sin x 1 3

(Two compound)

15. (B)
16. (B) HC C COOH

(SOLUTION)-2

47. (A)
48. (B)

x 1 = x for x 0, not possible


Clearly, f (x) is defined for all x R [ 1, 0). For

, k x k 1
any integer k 1, f (x) = k sin
k 1
So, f (x), being a constant function is continuous at
all point other than integers in its domain.
Also lim f (x) = lim f (k h)
h 0

x k

(k 1)sin , k 0.
[k h 1]
k
lim f (x) = lim f (k + h) lim f (x)

lim[k h]sin
h 0

x k

h 0

x k


lim[k h]sin
k sin
, k 1
h 0
[k h 1]
k 1
lim f (x) lim f (x), k 0 .
x k

x k

Page #2

Class: XII
Also lim f(x) = f(0)

f(x) continuous at 0

x 0

49. (C)

53. (A)
54 . (B)

dy
cot x.log cos x log sin x tan x

dx
(log cos x) 2
2

Let u = log10 x and v = x . Then,


1
du
du / dx x loge 10
1

2 log10 e
dv
dv / dx
2x
2x

PAPER - II

1. (CD)
(a)

Target IIT-JEE 2016

6. (AC) Current leads the voltage

V0 (VL VC )

f (x h) f (x)
50. (A) f '(x) = lim
h 0
h
f (x)f (h) f (x)
f (h) 1
lim f (x)
f '(x) = lim

h 0
h 0
h
h
1 hg(h) loge 2 1
= f(x) lim
= loge 2f (x)
h 0
h
51. (A) Inverse of a is a / a 1 but a / a 1 is integer
1 + a / a 1 is integer a = 0 or 2
logsin x
52. (A) We have, y = logcos x sin x =
log cos x

(SOLUTION)-2

SECTION A (Physics)
v

++++++
B ^i
0

Magnetic force is inward on right half and outward on


left body. It is constrained so no effect.
(b) Torque of electric force increases .

(c) Torque electric force decreases .


(E0dq)

VR

VR2

V0

100 25 5 5V
VC VL
7.(BCD) L = 90 103 2 1000 = 180
1
1
1000

2 1000
C 0.5 106

circuit is inductive VL > VR


voltage leads the current
L (1/ C) 80
80
tan =

R
R
R
3
1
1
at resonance,

LC
90 103 0.5 106

105

2
104
3

15 2
45 19
8. (ABD)
9. (ACD)
10. (ABC) For concave mirror real objects form real inverted
image infront of mirror and virtual erect image befined
the mirror. For convex mirror, real objects form virtual
image behind the mirror.
SECTION B (CHEMISTRY)
1. (ACD)
2. (ABD)
3. (ABD) C give cannizzaro Reaction
4. (ABD)
(A)
KCN
HOH / HF
CH C CH
CH C CH
9

/ \

CN CN

/ \

COOH COOH

CO

CH3 CH CH 3

(E0dq)

x
(E0dq)

(B)

COOH
HVZ
aq. KOH

CH3 CH COOH
CH3 C H COOH
Reaction

Br

(C) CH CH C H
3
2
2

OH

OH

(D) acid-Base Reaction


O
5. (ABC)
(E0dq)
6. (ABD)
C
(d) Rod will slow down only if force on any element is
Product is

O
CH3 CH
opposite to velocity magnetic force is always

CH CH3

to velocity vector.
O=C
2. (C)
O
K
CIS (d + ); Trans (meso)
3. (AD) (A) 0 hence K = V
2
7. (AB) It should be a methylketone

8. (AC)
(D) F = qu B hence upwards.
9. (ABD) (a) e withdrawing group favour nucleophilic addition
4. (AB)
B0x ^
(b) good leaving group favour the process
j
5. (ABCD)Wire segment (1)
L
(c) smaller acid are more reactive
L
B x iB L
(d) small alkyl group in ester favour hydrolysis
x dy
(df ) i dx 0 0
10.
(ACD)
B will form diazonium salt.
y
2
2

0
SECTION C (MATHEMATICS)
(3)

iB0 L iB0 L
k; f 3
k;
Similarly for f 2
sin(sin x) sin x
1
lim
1. (BD)

2
2 (2)
3
5
x 0
(4)
12
ax

bx

c
iB L

x
f 4 0 k
fn 0
sin x x
sin x x
2sin
2
(1)
cos

2
2

1
If coil is constrained to rotate about
lim

2
5
x 0
12
ax

bx

c
iAB0

B L
y-axis | | 1 0 L
2
2
Similarly for torque about torque has same magnitude

Page #3

Class: XII
sin x x sin x x
sin

1
2
sin x x

2
2 lim
3
cos
=
5
x 0
sin
x

x
12
2

ax bx c

sin x x
1
lim
=
x 0 (ax 3 bx 5 c)
12
x3 x5 x7

...
1

=
lim 3! 3 5! 5 7!
x 0
12
ax bx c
Clearly, LHS will be a non-zero real number, if c = 0.
When, c = 0, we have
x3 x5 x7

...
1
=
lim 3! 35! 7!
5
x 0
12
ax bx
1
1
=
for all b R
a=2
12
6a

Thus, we have a = 2, b R and c = 0.


2. (AB) Verify Choices
3. (ABD) 4 x 5 1 x 3 8 0 (x 3) 2 64
1 (x 3) 2 1 65 1 f (x) 65
4 x 5 1 x 3 8 1 x 3 0 0 x 3 8
2
1
2

2

x3
4 x3
1
4 x 5
2 f (x) f (x)
4
1 x 3 8 0 | x 3 | 8

3 f (x) 5 4 x 5 1 x 5 10
2

1 (x 5) 100 3 (x 5) 2 102
2
1
f (x)
3
51
4. (BCD) First of all f(x) should be continuous at 1.

a + b + 1 = 2b a
and then for differentiability
Lf '(1) Rf '(1)

b 2 4b a

(i)
(ii)

On solving (i) and (ii), we easily get a =

2x 5
Now f '(x) =
12 x 1
5
5

1
3
,b=
5
5

f '(x) is continuous at x = 1.
12
Also Lf "(1) = 2, Rf "(1) = .
5
f "(1) does not exist.

And Lt f( + h) = Lt
h 0

h 0

, x 0
, x 0

g(x) g(0)
g'(0) = lim
= lim
x 0
x 0
x
1
g'(0) = lim x sin = 0
x 0
x

x 2 sin
x

1
0
x

g(x) is differentiable at x = 0, which is the only


suspicious point for g(x), thus g(x) is differentiable
every where.

1
1
2x sin cos , x 0
g'(x) =
x

x

0
,x 0

1
1
lim g'(x) = lim 2h sin cos which does
h 0
h
h

x 0

not exist.

g'(h) is not continuous at x = 0.


1
x sin 0
f ( x ) f ( 0)
1
x
lim sin
f'(x) = lim
= lim
x 0
x 0
x 0
x
x
x
which does not exist.

f(x) is not differentiable at x = 0.


8. (AC) Let x is rational number between [0, 1],
then lim n! x is an integer.
n

lim cos (n!) x = 1


n

lim

lim 1 + cos2m (n! x) = 2 (a) is correct.

m n

Let x be irrational, then lim n! x integer ;


n

lim cos n! x will be a number b/w 1 and 1,

n x

i.e. 1 < lim cos n! x < 1


n

lim lim (1 + cos2m n! x) = 1 So (c) is also


m n

correct.
9. (ABC) Drawing graph verify choices
10 (BC) 13 5cos x 12sin x 13
20 5cos x 12sin x 7 6

0 5cos x 12sin x 7 20

x 1

h 0

1
2
x sin
g(x) = xf(x) =
x
0

h 0

7. (ABD)

Target IIT-JEE 2016

0 5 cos x 12 sin x 7 400

x 1

5. (ABD) lim f( h) = lim ( h )

(SOLUTION)-2

cos( h)
=1
sin( h)

Also 20 5cos x 12sin x 7 0 &


20 5cos x 12sin x 7 6
1
&

5 cos x 12 sin x 7
20
1

6 5cos x 12sin x 7

f ( h) cos( h)
=1
sin( h)

f( ) = 1, so function has jump discontinuity at x = .


m

6 (BCD) I lim

x 0

sin x n x n
nm
.
= lim xn m
. x
n

x 0
sin
x
x

Page #4

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