HYDROCARBONS

PART - I : MATCH THE COLUMN

1.1

Match the reactants given in Column-I with the reagent given in Column-II of reagent in the preparation of
cyclobutane
Column-I
Column-II
COOH

(A)

(p) , NH2 NH2 /KOH

COOH

COOH

(B)

(q) Na/ ether

O

COOH

(C)

(r) NaOH/CaO/, Zn-Hg/HCl

COOH

(D) Cl CH2 (CH2)2 CH2 Cl

(s) Electrolysis, H2/ Ni

PART - II : COMPREHENSION
Read the following passage carefully and answer the questions.
Comprehension-1
An alkene having molecular formula C6H12 gives a hydrocarbon X (C6H14)on catalytic hydrogenation.
Compound A gives two monochloro product Y and Z.
2.1

2.2

Structure of alkene is(A) H3C CH2 CH2 CH2 CH = CH2

(B) H3C CH2 CH = CH CH2 CH3

(C)

(D) None of these

Hydrocarbon X is -

CH3
(A) H3C CH2 CH2 CH2 CH2 CH3

(B) H3C C CH2 CH3

CH3
(C)

CRK

(D) None of these

15

HYDROCARBONS

2.3

Monochloroproduct Y and Z are :

CH3

CH3

(A) H3C CH CH CH2 Cl ,

CH3
(B) H3C C CH CH3 , CH3 CH2 CH2 CH2 CH2 CH2 Cl

CH3 Cl

CH3 CH3
(C) H3C C C CH3 , CH3 CH2 CH2 CH2 CH2 Cl

Cl

H
CH3 CH3

Cl

(D) CH3 CH2 C CH2 CH3 , H3C C C CH3

CH3

Cl

Comprehension-2
The addition of hydrogen to an alkene is an exothermic
reaction & the enthalpy change is called the heat of
hydrogenation. More branched alkenes are more stable and
have less potential energy. The alkene having higher potential
energy releases more heat on hydrogenation. In the figure
the enthalpy changes of three isomeric alkenes has been
shown.

2.4

From the above statement & graph identify P if P, Q & R are the isomers of butene :

(A)

2.5

CRK

(B) CH3 CH2 CH = CH2 (C)

(D)

Which of the following can be R if P, Q and R are isomeric pentenes :

C H3
|
(A) CH3 CH CH CH2

C H3
|
(B) CH3 C CH CH3

C H3
|
(C) CH2 C CH2 CH3

(D) Both A and C

16

HYDROCARBONS

Comprehension - 3
When alkyne passed into dilute sulphuric acid at 330 K in the presence of HgSO4 (catalyst), alkynes add one
molecule of H2O to form carbonyl compound.
H2SO 4 ,HgSO4
H C C H + H2O

CH3 CH = O.

H2SO 4 ,HgSO4
CH3 C CH + H2O

In fact, enols are formed in the hydration of alkynes. An alcohol contain OH group on a double bonded carbon is
called an enol. Enols can not be isolated because they are unstable and are rapidly converted into corresponding
aldehydes or ketones.
Based on above passage answers the given questions.
2.6

In the sequence of reactions :

[ O]
H2SO 4 ,HgSO4
H C C H + H2O
[B]

[A]
The compounds A and B are :
(A) Acetone and acetic acid respectively.
(B) Acetaldehyde and acetic acid respectively.
(C) Acetaldehyde and ethyl alcohol respectively. (D) Ethyl alcohol and acetaldehyde respectively.

2.7

3-Methylbut-1-yne reacts with mercuric acetate in presece of water to form a product, which on reduction with
NaBH4 yield.
(A) 2-Methylbuten-2-ol
(B) 3-Methylbutanone
(C) 3-Methylbutan-2-ol
(D) 2-Methylbutan-2-ol

Comprehension - 4
The classical reagent for cleaving the carbon-carbon double bond is ozone. Ozonolysis (cleavage by ozone) is
carried out in two stage : first addition of ozone to the double bond to form an ozonide; and second, hydrolysis
of the ozonide to yield the cleavage product. Ozone gas is passed evaporation of the solvent leaves the ozonide
as a viscous oil. This unstable, explosive compound is not purified, but is treated directly with water generally in
the presence of a reducing agent.

Zn

H2O

The compounds containing the C=O group are aldehydes and ketones.
Based on above passage answers given questions.
2.8

Give the structure of alkenes that yields OHCCH2CH2CH2CHO on ozonolysis :

(A) 1, 4-pentadiene
(B) 2, 4-pentadiene
(C) 1, 3-pentadiene
(D) Cyclopentene

2.9

Which alkene on ozonolysis will give only acetone ?

(A) 2, 3-Dimethylbut-2-ene
(B) 2-Methylpenet-2-ene
(C) 3-Methylpenet-2-ene
(D) 2, 3-Dimethylbut-1-ene

2.10

Which alkene would give CH3CHO and CH3 CH CHO on ozonolysis ?

|
CH3
(A) 4-methylpent-2-ene (B) 2-methylbut-1-ene

CRK

(C) 2-methylbut-2-ene

(D) 4-methylpent-3-ene

17

HYDROCARBONS

Comprehension - 5
Consider the following reaction :

P (C9H16)
P on ozonolysis gives nona2,8dione.
2.11

2.12

What is P ?
(A) 2,3dimethylcyclohexene
(C) 2,3dimethylcyclohept1ene

(B) 1,3dimethylcycloheptene
(D) 1,2dimethylcyclohept1ene

P is formed by :
(A) Elimination only
(C) Substitution and ring expansion

(B) Elimination and ring expansion

(D) Substitution and rearrangement

PART - III : ASSERTION / REASONING

DIRECTIONS :
Each question has 5 choices (A), (B), (C), (D) and (E) out of which ONLY ONE is correct.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
(E) Statement-1 and Statement-2 both are False.
3.1

Statement-1: In the bromination of propane and 2-Methyl propane. 2-Methyl propane gives more stable
transition state.
Statement-2: 3 CH bond is weaker than 2 C H bond.

3.2

Statement-1 : In the free radical reaction, reaction slow down for the peroid of time during which inhibitor exists
and after which the reaction proceed normally.
Statement-2 :Oxygen as inhibitor slow down the reaction for some times.

3.3

Statement-1 : The melting point of neopentane is higher than n-pentane but boiling point of neopentane is lower
than n-pentane
Statement- 2 : Melting point depends upon packing of molecules whereas boiling point depends upon surface
area. Neopentane fits into crystal lattice readily but has minimum surface area.

3.4

Statements-1 : CH3 CCCH3 is more reactive for electrophilic addition reaction than CH3CH = CH CH3
Statements-2 : Carbocation intermediate formed in alkene is more stable than the alkyne

3.5

Statements-1 : Stability of alkene is governed by hyperconjugation.

Statements-2 : Hyperconjugation involves delocalisation of electron with sp2 hybridised orbitals.

3.6

Statement-1 : When double and triple bonds are in conjugation, addition takes place at triple bond.
Statement-2 : When double and triple bond are not in the conjugation, addition takes place at double bond

3.7

BrCl
alco KOH
CH3 CH = CH2 CH3CHCl CH2Br
Statement-1 : CH3 CHBrCH3

Statement-2 : In above reaction product formed, is based on the principle of E2 & electrophilic addition reaction
by markownikov's rule.
3.8
CRK

Statements-1 : Reaction of HCl with But-2-ene in the presence or absence of peroxide will give same products.
Statement-2 : Above reaction is regioselective reaction.
18

HYDROCARBONS

PART - IV : TRUE / FALSE

4.1

Cis alkenes are formed by the reduction of alkyne by use of lindlars catalyst.

4.2

The product of reaction

COONa

NaOH

Will be an alkene while

COONa CaO

COONa
Electrolysis

COONa will be an alkane.

in H2 O

4.3

Although acetylene is acidic in nature it does not react with NaOH / KOH

4.4

Although acetylene is acidic in nature it does not react with NaOH / KOH

4.5

is less basic than

4.6

C C has two bond yet it is less reactive than

4.7

The treatment of an alkene with cold dilute alkaline KMnO4 gives cis-diols.

4.8

1-Pentyne can be distinguished from 2-Pentyne with the help of ammonical AgNO3 solution.

4.9

The addition of H2 to 2-Butyne using H2 and Lindlar's catalyst gives trans-2, 2-dimethyl ethene.

4.10

A secondary alcohol on oxidation gives a carboxylic acid containg the same number of carbon atoms.

4.11

1, 2 and 3 alcohols when passed across heated cupper we get aldehyde, ketone and alkene respectively.

CRK

towards electrophilic addition reaction.

19

HYDROCARBONS

* Marked Questions are more than one correct options.

1.

2.

The product(s) via-oxymercuration (HgSO4 + H2SO4) of 1-butyne would be :

[JEE-99, 2/80]

O
||
(A) CH3 CH2 C CH3

(B) CH3 CH2 CH2 CHO

(C) CH3 CH2 CHO + HCHO

(D) CH3 CH2 COOH + HCOOH

What would be the major product in the following reaction

H
Lindlar catalyst

3.

4.

Propyne and propene can be distinguished by :

(A) Conc. H2SO4
(B) Br2 in CCl4

[JEE 2000, 1/100]

(C) Dil. KMnO4

[JEE-2000, 1/35]
(D) AgNO3 in ammonia

What would be the major product in the following reaction ?

[JEE-2000, 1/100]

H2

Lindlar catalyst

5.

The appropriate reagent for the following transformation:

(A) Zn (Hg), HCI

6.

(B) NH2NH2, OH

(C) H2/Ni

[JEE-2000, 1/100]

(D) NaBH4

Hydrogenation of the adjoining compound in the presence of poisoned palladium catalyst gives.

[JEE-2001, 1/35]
(A) an optically active compound
(C) a racemic mixture
7.

CRK

(B) an optically inactive compound

(D) a diastereomeric mixture

Assertion : Addition of bromine to trans-2-butene yields meso-2. 3-dibromobutane.

Reason : Bromine addition to an alkene is an electrophilic addition
(A) Assertion is True, Reason is True; Reason is a correct explanation for Assertion.
(B) Assertion is True, Reason is True; Reason is NOT a correct explanation for Assertion.
(C) Assertion is True, Reason is False.
(D) Assertion is False, Reason is True.

[JEE-2001, 1/35]

20

HYDROCARBONS

8.

Identify X, Y and Z in the following synthetic scheme and write their structures.
(i) NaNH

alkaline KMnO

H / Pd .BaSO

2
4
4

X 2

Y Z
CH3CH2C C H
( ii) CH CH Br
3

Is the compound Z optically active ? Justify your answer.

[JEE-2002, 5/60]

9.

Identify a reagent from the following list which can easily distinguish between 1-butyne and 2-butyne.
(A) bromine, CCl4
(B) H2, Lindlar catalyst
(C) dilute H2SO4, HgSO4
(D) ammonical Cu2Cl2 solution
[JEE-2002, 3/90]

10.

Identify the set of reagents/reaction conditions X and Y in the following set of transformations.
X

CH3 CH2 CH2Br product CH3 CH CH3

|
Br

[JEE-2002, 3/90]

(A) X = concentrated alcoholic NaOH, 80C ; Y = HBr acetic acid, 20C

(B) X = dil. aq. NaOH, 20C, Y = HBr / acetic acid, 20C
(C) X = dil. aq. NaOH, 20C, Y = Br2 / CHCl3 , 0C
(D) X = conc. alc. NaOH, 80C, Y = Br2 / CHCl3 , 0C

11.

Hg2 / H

Ph C C CH3 A, A is :

(A)

(B)

[JEE-2003, 3/84]

(C)

(D)

12.

The major product obtained on acidcatalysed hydration of 2phenylpropene is

(A) 2-Phenylpropan-2-ol
(B) 2-Phenylpropan-1-ol
(C) 3-Phenylpropan-2-ol
(D) 1-Phenylpropan-1-ol

[JEE-2004, 3/84]

13.

Amongst the following the reagent that would convert 2hexyne into trans2hexene is

[JEE-2004, 3/84]

(A) H2 .Pt / O2
14.

(B) H2 .Pd / SO42

(C) Li / NH3 / C2H5OH

(D) NaBH4

The number of chiral compounds produced upon monochlorination of 2-methylbutane is :

[JEE-2004, 3/84]
(A) 2

15.

(D) 8

(B)

(C)

(B) Ph H

(C)

[JEE-2005, 3/60]

(D)

Phenyl magnesium bromide reacting with t-Butyl alcohol gives

(A) Ph OH

CRK

(C) 6

1-Bromo-3-chlorocyclobutane will react with two moles of Na in ether producing

(A)

16.

(B) 4

[JEE-2005, 3/60]

(D)

21

HYDROCARBONS

17.

Cl / h

Fractional

(CH3)2CH CH2CH3 2 [N] [P]

distillati on

[JEE-2006, 5/184]

The number of possible isomers [N] and number of fractions [P] are
(A) (6, 6)
18.

(B) (6, 4)

(C) (4, 4)

The reagent(s) for the following conversion,

Br

?
Br H

[JEE - 2007, 3/162]

is/are
(A) alcoholic KOH
(C) aqueous KOH followed by NaNH2
19.

(B) alcoholic KOH followed by NaNH2

(D) Zn/CH3OH

The number of stereoisomers obtained by bromination of trans-2-butene is :

(A) 1

20.

(D) (3, 3)

(B) 2

(C) 3

[JEE - 2007, 3/162]

(D) 4

The major product of the following reaction is :

[JEE 2011 160/3]

(A)

(B)

(C)

(D)

Paragraph for Question Nos. 21 to 22

An acyclic hydrocarbon P, having molecular formula C6H10, gave acetone as the only organic product through
the following sequence of reactions, in which Q is an intermediate organic compound.

O
P
(C6 H10 )

CRK

(i) dil. H2SO4/HgSO4

(ii) NaBH4/ethanol
(iii) dil. acid

(i) conc. H2SO4

(catalytic amount -H2O)

C
H3C

CH3

(ii) O3
(iii) Zn/H2O

22

HYDROCARBONS

21.

The structure of compound P is

(A) CH3CH2CH2CH2 CCH

[JEE 2011 160/3]

(B) H3CH2CC C CH2CH3

H3C

H3C

(C) H C C
H3C
22.

(D) H3C C C
H3C

C CH3

CH

The structure of the compound Q is

H3C

[JEE 2011 160/3]

OH

H3C

(A) H C C CH2CH3
H3C
H

H3C

OH

(B) H3C C C CH3

H3C
H

OH

OH

(C) H C CH2CHCH3
H3C

(D) CH 3CH2CH 2CHCH2CH 3

23.

The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic

KOH is :
[JEE 2011 160/4]

24.

The major product of the following reaction is :

(A) a hemiacetal

[JEE 2011 160/3]

(B) an acetal

(C) an ether

(D) an ester

25.

The maximum number of isomers (including stereoisomers) that are possible on monochlorination of the following
compound is :
[JEE 2011 160/4]

26.

The number of optically active products obtained from the complete ozonolysis of the given compound is

CH3
H3C

CH

CH

C
H

(A) 0

CRK

(B) 1

CH

H
CH

C CH

CH CH3

[JEE 2012 136/4]

CH3
(C) 2

(D) 4

23

HYDROCARBONS

PART - II : AIEEE PROBLEMS (PREVIOUS YEARS)

1.

But-1-ene may be converted to butane by reaction with :

(1) Zn HCl

(2) Sn HCl

(3) Zn Hg

[AIEEE-2003]
(4) Pd / H2

2.

On mixing a certain alkane with chlorine and irradiating it with U. V. light, it forms only one monochloroalkane.
This alkane could be :
[AIEEE-2003]
(1) Propane
(2) Pentane
(3) Isopentane
(4) Neopentane

3.

Which one of the following is reduced with Zn/Hg and hydrochloric acid to give the corresponding hydrocarbon
[AIEEE-2004]
(1) Ethyl acetate
(2) Acetic acid
(3) Acetamide
(4) Butanone

4.

2-Methylbutane on reacting with bromine in the presence of sunlight gives mainly

(1) 1-Bromo-3-methylbutane
(2) 1-Bromo-2-methylbutane
(3) 2-Bromo-3-methylbutane
(4) 2-Bromo-2-methylbutane

[AIEEE-2005]

5.

Butene-1 may be converted to butane by reaction with :

[AIEEE-2003]

(1) Zn HCl
6.

(2) Sn HCl

(3) Zn Hg

(4) Pd / H2

Acetylene reacts with hypochlorous acid to form :

(1) Cl2CHCHO

(2) ClCH2COOH

[AIEEE-2003]
(3) CH3COCl

(4) ClCH2CHO

7.

Reaction of one molecule of HBr with one molecule of 1, 3-butadiene at 40C gives predominantly :
(1) 1-Bromo-2-butene under kinetically controlled conditions
[AIEEE-2005]
(2) 3-Bromobutene under thermodynamically controlled conditions
(3) 1-Bromo-2-butene under thermodynamically controlled conditions
(4) 3-Bromobutene under kinetically controlled conditions

8.

Acid catalyzed hydration of alkenes except ethene leads to the formation of

[AIEEE-2005]
(1) Mixture of secondary and tertiary alcohols
(2) Mixture of primary and secondary alcohols
(3) Secondary or tertiary alcohol
(4) Primary alcohol

9.

Which of the following reactions will yield 2,2-dibromopropane ?

(1) CH3 C CH + 2HBr
(3) CH CH + 2HBr

[AIEEE-2007, 3/120]

(2) CH3CH = CHBr + HBr

(4) CH3 CH = CH2 + HBr

10.

The hydrocarbon which can react with sodium in liquid ammonia is:
[AIEEE-2008, 3/105]
(1) CH3CH2 CCH
(2) CH3CH = CHCH3
(3) CH3CH2CCCH2CH3
(4) CH3CH2CH2CCCH2CH2CH3

11.

One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde having a molecular mass of
44 u. The alkene is :
[AIEEE-2010, 4/144]
(1) propane
(2) 1-butene
(3) 2-butene
(4) ethene

12.

The hybridisation of orbitals of N atom in NO3, NO2+ and NH4+ are respectively :
(1) sp, sp3, sp2

13.

(3) sp, sp2, sp3

(4) sp2, sp, sp3

How many chiral compounds are possible on monochlorination of 2 - methyl butane ?[AIEEE-2012, 4/120]
(1) 8

CRK

(2) sp2, sp3, sp

[AIEEE-2011, 4/120]

(2) 2

(3) 4

(4) 6

24

HYDROCARBONS

14.

Which branched chain isomer of the hydrocarbon with molecular mass 72 u gives only one isomer of mono
substituted alkyl halide ?
[AIEEE-2012, 4/120]
(1) Tertiary butyl chloride
(2) Neopentate
(3) Isohexane
(4) Neohexane

15.

2-Hexyne gives trans - 2 - Hexene on treatment with :

(1) Pt/H2

16.

(3) Pd/BaSO4

(4) LiAlH4

In the given transformation, which of the following is the most appropriate reagent ? [AIEEE-2012, 4/120]

(1) NH2 NH2,

CRK

(2) Li/NH3

[AIEEE-2012, 4/120]

(2) Zn Hg/HCl

(3) Na, Liq. HCl

(4) NaBH4

25

HYDROCARBONS

ANSWER KEY
EXERCISE - 1
1.1

(D)

1.2

(A)

1.3

(D)

1.4

(B)

1.5

(B)

1.6

(A)

1.7

(D)

1.8

(A)

1.9

(B)

1.10

(D)

1.11

(B)

1.12

(D)

1.13

(A)

1.14

(B)

1.15

(C)

2.1

(D)

2.2

(A)

2.3

(D)

2.4

(C)

2.5

(B)

2.6

(D)

2.7

(A)

2.8

(C)

2.9

(B)

2.10*

(A,B)

3.1

(A)

3.2

(A)

3.3

(A)

3.4*

(B,C)

3.5

(C)

4.1

(B)

4.2

(D)

4.3

(A)

4.4

(B)

4.5

(B)

4.6

(B)

4.7

(B)

4.8* (A,B,C,D) 4.9

(C)

4.10

(C)

4.11

(B)

4.12

(B)

4.13

(B)

4.14

(D)

4.15

(B)

4.16

(A)

4.17

(B)

4.18

(A)

4.19

(A,B,C) 4.20

(C)

4.21

(A)

4.22

(C)

4.23

(D)

4.24

(A)

4.25* (A,B,C,D) 4.26

(C)

4.27

(C)

4.28

(A)

4.29

(A)

4.30

(B)

4.31*

(A,B,C) 4.32

(B)

4.33

(A)

4.34

(A)

4.35

(B)

4.36

(D)

4.37

(C)

4.38

(D)

(B)

4.40

(B)

4.41

(C)

4.42

(A)

4.43

(A)

4.44

(A)

4.39

EXERCISE - 2

1.1

(ii) CH3CH2 CH CH (CH2)7CH2OH

(i)

trans

1.2

(i) H2/Pd-BaSO4-CaCO3
(ii) In this conversion CO converts into CH2 which can be achieved by any one of the following reagents :
(a) NH2NH2/KOH/

1.3

ZnHg / HCl
CH3CHO

CH3CH3

(A)

1.4

(b) Zn/Hg/Conc HCl/

(B)

CaO
CH3CH2CH2 COONa + NaOH CH3CH2CH3 + Na2CO3
630K

CaO
CH CH CH + Na CO
+ NaOH 630
3
2
3
2
3
K

CRK

26

HYDROCARBONS

1.5

Ether
(i) CH3 CH2 Cl + 2Li

CH3CH2Li + LiCl

(ii) 2CH3 CH2 Li + CuI (CH3CH2)2 Li Cu + LiI

Lithium diethyl cuprate
(iii) Li (CH3CH2)2 Cu + CH3 CH2 Cl CH3 CH2 CH2 CH3 + CH3 CH2 Cu + LiCl
Butane

1.6

X is

1.7

1.8

(i)

2.1

Chlorination of methane is a free radical reaction which occurs by the following mechanism

(ii)

X=

;Y=

(iii) PhPh + CH3CH3 + PhCH3

Homolytic Fission

Initiation

Propagation

+ HCl

CH3 Cl +

Termination

CH3 CH3
CH3 Cl
Cl Cl

2.2

(4)

(d and )

3.1

A is more stable.

4.1

CH3CH CHCH3
But 2 ene

CRK

(d and )

3.2

C2H2

27

HYDROCARBONS

4.2

3 carbocation > 2 carbocation > 1 carbocation (stability order)

4.3

(P) dil. H2SO4

(Q) (a) Hg(OAc)2 + H2O (b) NaBH4 + OH

(R) (a) BH3 + THF (b) H2O2 + OH (S) Cl2 + CCl4

(T) Cl2 then H2O

(U) Cl2 then ROH

4.4

4.5

(A) (i) H2 / Pd / BaSO4 (ii) HBr / peroxide

(B) (i) H2 / Pd / BaSO4 (ii)+HBr

(C) HgSO4 / H2SO4

(D) BH3 + THF / H2O2 + OH

(E) 2 mole HBr

(F) 1 mole HBr

Addition of the proton gives the resonance hybrid of

Since (I) is more stable so it contributes more to the resonance hybrid and reacts faster with the bromide ion.

4.6

4.7

(a) (CH3)2C=CHCH(CH3)2

4.8

(a) NH2 NH2 / KOH

4.9

(a)

(b) CH3CH2CH=CHCH2CH3

(b) Mg / ether, CH3 Br (c) Na / ether

and enantiomer

(b)

(c)

(d) Na / ether

and enantiomer

(c)

and enantiomer

EXERCISE - 3
1.1

(A) - (p, r) ; (B) - (r) ; (C) - (r,s) ; (D) - (q)

2.1

(C)

2.2

(C)

2.3

(A)

2.4

(B)

2.5

(B)

2.8

(D)

2.9

(A)

2.10

(A)

2.11

(D)

2.12

(B)

3.1

(A)

3.2

(B)

3.3

(A)

3.4

(D)

3.5

3.7

(C)

4.1

4.2

4.3

4.4

4.5

4.8

4.9

4.10

CRK

2.6

(B)

2.7

(C)

(C)

3.6

(B)

3.7

(A)

4.6

4.7

28

HYDROCARBONS

EXERCISE - 4
PART - I : IIT-JEE PROBLEMS (PREVIOUS YEARS)
1.

(A)

2.

In presence of Lindlars catalyst (Pd & CaCO3 in quinoline) partial hydrogenation takes place and gives cisisomer .

H2

Lindlar 's catalyst

3.

(D)

4.

In presence of lindlars catalyst (Pd and CaCO3) in quinoline) partial hydrogenation takes place and give cisisomer.

H2

Lindlar catalyst

5.

(B)

6.

(B)

7.

(B)

8.

CH CH C C Na
CH3 CH2 C CH
( NH3 )
3
2

( i ) NaNH

CH3 CH2 C C CH2 CH3

CH3 CH2 C

| |
H H
y

C . CH2 CH3
( Compound ' X )

cis Hex 3 ene

OH OH
| |
CH3 CH2 C C CH2 CH3
| |
H H
(Compound ' Z' )

9.

(D)

10.

(A)

11.

(A)

12.

(A)

13.

(C)

14.

(B)

15.

(A)

16.

(B)

17.

(B)

18.

(B)

19.

(A)

20.

(A)

21.

(D)

22.

(B)

23.

24.

(B)

25.

26.

(A)

PART - II : AIEEE PROBLEMS (PREVIOUS YEARS)

1.

(4)

2.

(4)

3.

(4)

4.

(4)

5.

(4)

6.

(1)

7.

(3)

8.

(3)

9.

(1)

10.

(1)

11.

(3)

12.

(4)

13.

(3)

14.

(2)

15.

(2)

16.

(1)

CRK

29