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Organic Chemistry

159

Section - C : Assertion - Reason Type

1.

Answer (1)
It is due to change in solvent.

2.

Answer (1)

3.

Answer (4)
Phenol is less acidic than benzoic acid, but conjugate base of phenol is resonance stabilized.

4.

Answer (1)

5.

Answer (1)

6.

Answer (1)
Information based.

7.

Answer (2)
ROK + S = C = S Xanthate product

8.

Answer (1)
Information based.

9.

Answer (3)
Boiling point depends on vapour pressure.

10. Answer (1)

Information based.
11. Answer (2)
Cyclooctatetraene is nonaromatic due to non-planar structure.
12. Answer (3)
Cl shows I and +R both effect.
13. Answer (3)
The hybridised state of positively charged carbon in phenyl carbocation is sp.
14. Answer (1)

Aromatic

(6 e )

Antiaromatic

(4 e )

15. Answer (2)

In amides lone pair of N is delocalised on carbonyl group.
16. Answer (4)
Phenol is less acidic than benzoic acid.
17. Answer (1)
For tautomerism, there should be at least one H.
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18. Answer (4)

is an aromatic compound, hence it does not absorb H2 under normal condition.

19. Answer (2)

H
C=C=C

H3C
CH3
2,3-pentadiene (non-planar)
chiral
20. Answer (1)
Propene can form more stable cation due to more hyperconjugation.
21. Answer (1)
Toluene has 3 H and ethylbenzene has only 2 H.
22. Answer (1)
Triple bonded carbon is more electronagative than double bonded carbon.
23. Answer (2)
Cyclohexane has less strain than cyclopentane.
24. Answer (3)
It has 6 electrons only.
25. Answer (3)
2 allylic (also benzylic) carbocation is more stable than 2 alkyl carbocation. Hence (I) is major product.
26. Answer (2)

D.U.

2C H 2
2
27 8 2
4
2

CH3
The compound may be

OH
(Cresol)

27. Answer (2)

1-Butyne has terminal hydrogen which makes 1-butyne stronger acid than 2-butyne.
28. Answer (3)
This is an example of electrophilic substitution reaction and Cl+ is an electrophile.
29. Answer (2)
Due to presence of peroxide more stable 2-free radical is formed.
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30. Answer (1)

Smaller the numerical value of pKb stronger in the base.
o toluidine (pKb) = 9.61
m toluidine(pKb) = 9.31
p toluidine(pKb) = 8.92
31. Answer (4)

CH3

CH3CH3

H
H

H
H
Fully Eclipsed form

H
CH3
Anti form

32. Answer (1)

33. Answer (2)
34. Answer (1)
% enol conjugation
35. Answer (4)

Cl
CH3

has only one chiral carbon atoms.

36. Answer (1)
P is cis and Q is transform.
37. Answer (2)
CH

CH + HCN

Ba(CN)2
Pressure

CH2 CH CN
vinyl cyanide

38. Answer (2)

Propyne gives silver mirror with AgNO3 in ammonia while propene does not.
39. Answer (3)
CO2 obsorb only infra red rays having higher wavelength which are emitted by earth.
40. Answer (2)
Both act as ligand for Fe metal.
41. Answer (4)
Temperature do not show regular trend along height upto some height it may increase and then decrease.
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42. Answer (4)

Fact.
43. Answer (2)
Fact.
44. Answer (4)
Flourobenzene is more reactive toward electrophilic substitution reaction.
45. Answer (3)
Reaction of alkane with F2 is highly exothermic reaction. So this method cannot be used to prepare alkyl fluoride.
46. Answer (2)
For SN1 reaction.
r = k [substrate]
47. Answer (1)
Grignard regant is highly explosive in dry state.
48. Answer (1)
KOH
CH3CH2Cl
CH2 = CH2

49. Answer (4)

RX gives different product with AgNO2 and KNO2.
50. Answer (1)
Due to symmetrical nature, p-isomer have high melting point.
51. Answer (4)
Some other by product like CH2Cl2 and CHCl3 and CCl4 are also formed.
52. Answer (4)
o-nitrophenol is less acidic
53. Answer (3)

Phenol is partially converted to

54. Answer (1)

Electron density increases on carbon attached to COOH due to + I effect and acidic strength decreases
55. Answer (2)
Anhydrides has greater van der waals force of interaction than carboxylic acid. Carboxylic exist in dimer form
even in vapour phase also. like
O..........HO

CCH3

CH3C
HO..........O
Dimer.(cyclic)
56. Answer (2)

Due to greater extent of hydrogen bonding, boiling point is high.

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57. Answer (4)

Correct order is RCONH2 > (RCO)2O > RCOOH > RCOCI.
58. Answer (1)
Nucleophilic character of NH2 is maximum and least in Cl.
59. Answer (1)
Greater the basic character of nucleophile more will be nucleophilicity.
60. Answer (1)
Alkyl group is hydrophobic group therefore on increase in alkyl group solubility decreases.
61. Answer (4)
O
||
Ac CH3 C group.

AcOAc is acid anhydride not ether.

62. Answer (1)

For the preparation of ditertbutylether by Williamsons synthesis tert-butylhalide is required which undergoes
elimination reaction and form isobutylene.
63. Answer (1)

OH-----O
N
O

Intra molecular
hydrogen bond

64. Answer (4)

O
||

OH

H
Keto form of phenol

Phenol

Phenoxide ion is more resonance stable.

65. Answer (1)
O

||
Propanal does not have CH3 C group

66. Answer (1)

Only aliphatic aldehyde give this test.
67. Answer (4)
Single reduction (for CHO) is favoured.
68. Answer (1)
Moderately acidic
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69. Answer (1)

In the mechanism (OH) ion has greatger leaving power but due to conc. NaOH (H) is released.
69a.

Answer (1)

(AIEEE 2009)

In Cannizzaro reaction, the transfer of hydride to the carbonyl group is the rate determining step.
70. Answer (2)
% of enol conjugation
71. Answer (1)
HCHO + schiffs reagent pink colour
72. Answer (1)
For coupling, diazo salt behaves as electrophile and other compound as nucleophile.
73. Answer (1)
3amine does not react with diethyl oxalate.
74. Answer (3)
Amines have greater H-bonding
75. Answer (1)
NH3 is more soluble.
76. Answer (4)

NH2

NC
CHCl3
KOH

77. Answer (2)

NHOH

NO
AgNO3
NH4OH

78. Answer (4)

These are only functional isomers.
79. Answer (2)
HNO

CH3ON
CH3NH2

CH3OCH3
80. Answer (2)

NO2

H NO2
NO2

slow

HSO4
fast

+ H2SO4

It means rate does not depend on removal of H or D.

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81. Answer (3)

CH2NH2
(No resonance stabilisation)
82. Answer (2)
83. Answer (2)
84. Answer (2)
Macromolecule may or may not contain monomer units. e.g. chlorophyll.
85. Answer (2)
Vulcanised rubber is formed by mixing molten rubber and molten sulphur under specified conditions.
86. Answer (2)
87. Answer (3)
88. Answer (4)
89. Answer (2)
Cis-configuration of double bond not allow the chains to come closer. Therefore only weak vander Waals forces
are present.
90. Answer (4)
Buna-N is a copolymer of 1, 3-butadiene and acrylonitrile.
90a.

Answer (2)

(AIEEE 2009)

Acrylonitrile + 1, 3-butadiene Buna-N

(Bu = Butadiene, na Sodium, a polymerising agent, N = Nitrile)
91. Answer (1)
Nylon 2-nylon 6 is an alternating polymer of glycine and amino caproic acid.
92. Answer (1)
Fact.
93. Answer (2)
Fact.
94. Answer (2)
Amino acid exist an zwitter ion.
95. Answer (1)
Fact.
96. Answer (2)
Fact.
97. Answer (2)
Enzymes act as catalyst.
98. Answer (4)
Glucose have aldehyde group while fructose have ketone group.
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99. Answer (2)

Factual.
100. Answer (1)
Alzarine gives rose-red colour with Al3+ ions, blue with Ba2+, brownish red with Cr3+ ions.
101. Answer (2)
Paracetamol is N-Acetyl-para-aminophenol.
102. Answer (2)
Tranquilisers are used in reducing anxiety and tension on the nerves.
103. Answer (3)
They are used for making components of bone plates and they have high thermal conductivity.
104. Answer (2)
Lassaignes test is used to detect the nitrogen in organic compound.
105. Answer (3)
Acid or base with dissociation constant Ka < 107 cannot be successfully titrated.
106. Answer (1)
Diazonium compounds loses N2 on heating.
107. Answer (2)
Both statements are correct.
108. Answer (1)
Because NaCN and Na2S interfere in detection of halogen.
109. Answer (1)
Fact.
110. Answer (2)
This is the test for 1 amine.
111. Answer (2)
I / NaOH

2

C2H5OH

CHI 3
( Yellow precipitate )

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