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Section - B : Linked Comprehension Type

C1. 1. Answer (1)

p p S
M
Molality
pS
1000

(M = Molecular mass of solvent)

630 600
78
Molality
600
1000

Molality

30 1000
0.641 m
600 78

2. Answer (2)
Let the weight of urea dissolved = x gm
Tb + Tf = 105
Tf 1.86

x
1000
100 60

Tb 100 0.52

(i)

x
1000
100 60

(ii)

Adding equation (i) and (ii)

Tb Tf 100

1000 x
1.86 0.52
6000

x = 12.6 g
3. Answer (3)
Elevation in boiling point i m (if solution is very dilute than m = M)
for NaCl

i=2

M = 104

for Urea

i=1

M = 103

for MgCl2

i=3

M = 103

for NaCl

i=2

M = 102

Therefore increasing order of boiling point is d > c > b > a

C2. 1. Answer (2)
2. Answer (1)
3. Answer (4)
Let the volume of the solution = 1 litre = 1000 ml

Mass of solution
density = volume of solution
1.20 =

Mass of solution
1000

Mass of solution

= 1200 gm

Mass of solute (urea) = 1200

40
100

= 480 gm
Mass of solvent

= 1200 480

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No. of moles of solute

= Volume of solution (litre)

Molarity

480 / 60
8M
1

No. of moles of solute

480 / 60
11.11 m
= Mass of solvent (kg) =
720 / 1000

Molality

moles of urea
Mole fraction of urea = moles of urea moles of water
480
8
60

= 480 720 8 40

60
18
= 0.167
C3. 1. Answer (2)
Mole of Cu2+ = 0.8

100
0.08
1000

Charge = 5 30 60 = 9000 C
Cu2+ + 2e Cu
From 2 96500 C charge deposited

= 1 mole of Cu

9000 C

1 9000
mole
2 96500

= 0.047 mole
Moles of

Cu2+

remaining in solution = 0.08 0.047

= 0.033 mole = moles of CuSO4

Mass of CuSO4 in the solution

= 0.033 159.5
= 5.26 g

2. Answer (3)
This is concentration cell Ecell = 0
Cell reaction
2Cl [Cl2]A + 2e (anode)
2e + [Cl2]C 2Cl (cathode)
net reaction [Cl2]C [Cl2]A

ECell

PCl2
0.059
log
2
PCl2

P
0.059
log 1
2
P2

for the spontaneous process ECell should be (+)ve therefore (+)ve value of ECell P2 should be greater than P1.
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3. Answer (4)
Since Al3+ has lowest value for the reduction therefore it has maximum tendency to get oxidised among
the given. Therefore strongest reducing agent.
C4. 1. Answer (2)
H2(g) + S(s)
initial moles

0.2

at equilibrium

0.2

H2S(g)
0

n = 0
KP = KC = 6.8 102
KC =

6.8 10 2
0 .2

0.2 6.8 10 2
0.01273

1 6.8 10 2

Ptotal=

nRT 0.2 0.082 363

= 5.96 atm
V
1

Partial pressure of H2S =

Ptotal
0.2
0.01272
5.96
0 .2

= 0.38 atm
2. Answer (1)
NH4HS(s)

NH3(g) + H2S(g)

K P PNH3 PH2S
KP = P2

PNH3 PH2S 250

KP = (250)2

on additional of NH3 in the mixture without change in temperature KP remain same

K P PNH3 PH2S
(250)2 = (700) PH2S

PH2S

250 2
700

89.3 torr

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3. Answer (3)
ions of NH2 are 600 ions/mm3.
therefore ions present in 1 litre 600 106 ions/litre
= 6 108 ions/litre
No. of moles of NH2 present in 1 litre =
2 NH3(l)

6 10 8
6 10 23

1 10 15 mol / L

NH2 + NH4+
= [NH2] [NH4+]

K(ionic product)

= [1015] [1015]
= 1030
C5. 1. Answer (2)
Dilute hydrochloric acid is group I cation i.e. Hg22+, Pb2+, Ag+
2. Answer (4)
K4[Fe(CN)6] can use to detect Fe3+, Zn2+, Cu2+ and Cd2+
3. Answer (2)
AgNO 3
conc H2SO 4
NO3

NO2
No reaction
AgNO 3
conc H2SO 4
Cl

HCl brown
AgCl white ppt
AgNO 3
conc H2SO 4
I

I2 violet
AgI yellow ppt
dil H2SO 4
NO2

NO2 brown

C6. 1. Answer (4)

OH
CH2

CH2

Cl

OH

CH2
Cl

CH2

CH2

CH2

2. Answer (3)
CH

tautomerise
dil H2SO4
K 2Cr2O7 H2SO 4


CH2 CH OH 
 CH 3 CHO
CH 3 COOH
CH 2
Hg
enol

Ca( OH)

2

(CH3COO)2Ca
CH3COCH3 (acetone)

3. Answer (2)
Ketones formed will further reacts with RMgX but not with R2 Cd

  

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