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GEOCHEMICAL SOIL AND SEDIMENT SAMPLING /
ANALYSIS CONSIDERATIONS
S
oil and stream sediment sampling programs are a key component
of early stage (greenfields) exploration
GENERAL CONSIDERATIONS
Sampling Program
Parameters that need to be considered are:
Sample spacing
Soil horizon to be sampled
Soil fraction to be sampled and analysed (generally either
bulk or a particular size fraction)
Method of sample digestion and analysis
There is no substitute for a well-executed orientation program
which will answer questions relating to the above mentioned
parameters and optimise the signal to background ratio for
the target and pathfinder elements.
Sample Spacing
Sampling density and patterns are determined by the style
of target sought, the topography of the exploration area and
the prospective geology. Soil samples are typically collected
on a rectangular pattern, generally with closer spacing
of sample sites along more widely space sample lines.
Theoretically, the sampling lines are oriented normal, or at
high angle, to the expected longer dimension of the target,
but the orientation of geochemical dispersion patterns are
generally not well known, if at all, before sampling.
The optimum spacing between sampling lines and sample
sites will depend on the purpose of the survey and the
expected size of the dispersion halo to be detected.
Generally the aim is to obtain at least two (2) samples from
the anomaly on a sampling line. Common sample spacings
for reconnaissance soil sampling are 400m by 400m or
200m by 400m. For detailed anomaly detection, samples are
commonly collected at 100m intervals on 200m spaced lines
with infill sampling down to 50m on 100m spaced lines.
Stream sediment samples are usually taken from sites
within a stream and are typically active sediments
within the actual channel profile. Alternatively, overbank
sediments collected adjacent to, but just outside the main
channel, have been shown to be extremely effective in
defining mineralisation trends and centres.
Soil Fraction
Lag Fraction
Different size fractions of lag can be sampled, depending on
the purpose of the survey (i.e. regional reconnaissance, using
the generally smaller size of transported lag or, detailed target
location using the larger less transported and worked sizes).
A common size used is 3-15mm. In theory and for special
surveys it is possible to separate out a particular compositional
component (e.g. highly ferruginous, lithic, quartz) but apart
from selecting the magnetic fraction, most surveys would not
find this practical, because of the extra time involved.
Bulk lag is probably the best material to sample. Alternatively,
surveys may target magnetic lag. This material is typically
more ferruginous and contains greater than 5% maghemite.
It is easy to sample using a simple plunger type hand held
magnet. However, the magnetic fraction is generally enriched
Sampling Steps
Locate sample sites with GPS receiver and enter into
database/GIS platform
Record the regolith landform setting
Estimate the proportions of the main lag types, e.g. highly
ferruginous (including magnetic and non-magnetic);
ferruginised lithic; lithic; quartz; calcrete; other.
Estimate the range in clast size
Estimate the proportion of transported and in situ lag (based on
degree of clast rounding, size of clasts, composition of clasts).
Sweep up lag with plastic dust pan and brush over about a 5m
diameter area. A sample of approximately 2kg is sufficient.
Sieve out the coarse pebbles, sticks, etc. (greater than 1 or
2cm) on to a plastic sheet and pick out any obvious organic
material or alternatively this can be floated off by washing
the lag in water prior to sample preparation.
Extract the magnetic fraction if this is to be removed from
the final sample or targeted separately. In cases where it is
possible that only small amounts of magnetic material are
present, this should be done in the field to ensure that a
sufficient quantity of the magnetic sample has been collected.
Sample Preparation
at the laboratory
hci (4m)
ionic leach
(acid + alkaline)
0.25M hydroxylamine
0.1M hydroxylamine
acetate (pH = 5)
ion exchange
other minerals
water
water soluble
salts
acetate soluble
secondary
minerals
carbonates
surface
absorbed
Mn oxides
amorphous
Fe oxides
crystalline
Fe oxides
resistate
components
whole rock
References
McQueen, K.G., 2008. A guide for mineral exploration through the regolith in the Cobar Region, Lachlan Orogen, New South Wales. CRC LEME, Perth. 110 pp Appendix.
Recommended procedure for geochemical sampling and analysis.
Lech, M., de Caritat, P., McPherson, A., 2007. National Geochemical Survey of Australia: Field Manual. Geoscience Australia, Canberra. 53 pp Appendix 1.Soil sampling
procedures for NGSA.
The Australasian Institute of Mining and Metallurgy, 2011. Field Geologists Manual, Fifth Edition, Monograph 9. AusIMM, Carlton Victoria.480 pp Chapter 4, Section
4.7.General Notes for Geochemical Sampling.
Significant contributions gratefully accepted from Russell Birrell, Globe-Ex Solutions.
Photo contributions gratefully accepted from Map to Mine (www.maptomine.com.au)
Minerals
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